Physical Sciences and Mathematics Commons^™

Theoretical Analysis Of Oled Performances Of Some Aromatic Nitrogen-Containing Ligands, Mustafa Eli̇k

Turkish Journal of Chemistry

It is well-known that tris(8-hydroxyquinoline) aluminum (Alq3) complex and N,N'diphenyl-N,N'-bis(3-methylphenyl)-1,1'- diphenyl-4,4'-diamine compound (TPD) are widely used as electron transfer material (ETL) and hole transfer material (HTL) in organic light emitting diode (OLED) structure, respectively. Considering the reference materials, in the present work, the OLED performances of some cyclic aromatic structures such as 4,4'azopyridine [AZPY], 4,4'-bipyridine [BIPY], 1,2-bis[4'-(4-methylphenyl)2,2':6'2' '-terpyridin6-yl]ethyne (BISTERPY), 5,5'-diamino-2,2'-bipyridine (DABP), dipyrido[3,2-a:2',3'c]phenazine (DPP), 4,7-phenanthroline (PHEN) including nitrogen atom have been theoretically analyzed. It is important to note that B3LYP/6-31G(d) and B3LYP/TZP levels of the theory were taken into account for the calculations about monomeric and dimeric structures, respectively. Additionally, the …

Preparation And Application Of Caffeic Acid Imprinted Polymer, Şeyda Karaman Ersoy, Esma Tütem, Kevser Sözgen Başkan, Mustafa Reşat Apak

Turkish Journal of Chemistry

In the present study, molecularly imprinted polymers were synthesized using caffeic acid (CA) as a template molecule and then used for the extraction of CA and chlorogenic acid (CLA) from complex matrices. Syntheses were carried out in tetrahydrofuran as porogenic solvent using 4-vinyl pyridine, methacrylic acid, acrylamide, and 1-vinyl imidazole as monomers, ethylene glycol dimethacrylate as crosslinker and 2,2'-azobisisobutyronitrile as initiator. In polymerization processes, different ratios of the template:monomer:crosslinker (T:M:CrL) were used to obtain the most suitable polymer. Caffeic acid:4-vinylpiridine:ethylene glycol dimethacrylate's 1:4:16 mole ratio of MIP was determined as the most convenient polymer for CA recognition. In addition, nonimprinted …

In Vitro Antioxidant Activity Of Alginate Nanoparticles Encapsulating The Aqueous Extract Of Coccinia Grandis L., Walimuni Nayomi Deshani De Silva, Anoja Priyadarshani Attanayake, Liyanage Dona Ashanti Menuka Arawwawala, Desiree Nedra Karunaratne, Geethi Kaushalya Pamunuwa

Turkish Journal of Chemistry

Bioactive compounds in medicinal plants are more susceptible to preventing oxidative stress. Encapsulation of herbal extracts has empowered the properties and characteristics of bioactive compounds. Nanoencapsulation allows the enhancement of the stability of extracts and targeted drug delivery. The present study aims to determine the antioxidant activity of alginate nanoparticles encapsulating the aqueous extract of Coccinia grandis L. (Family: Cucurbitaceae). The aqueous extract of C. grandis (AqCG) was prepared by using ultrasonication (40 ° C, 20 min, 40 kHz) followed by refluxing (2½ h). The prepared AqCG (1-5 mg/mL) encapsulated alginate nanoparticles were synthesized by ionic gelation with the addition …

Effects Of Zsm-5 Zeolite On Pyrolysis Of Polystyrene: From Stabilizing To Catalyzing, Qing Yuan Ma, Zhen Huang, Xuan Ren, Jia Jia Zhao, Fu Chen, Li Jun Teng

Turkish Journal of Chemistry

Nonisothermal pyrolysis measurements of polystyrene (PS)/ZSM-5 zeolite hybrids are conducted in N2 and thermogravimetric results have been kinetically analyzed with different isoconversional methods. Experimental results show that the addition of 5 and 10 wt.% ZSM-5 zeolite has increased the initial pyrolysis temperature of PS while the addition of 20 and 30 wt.% ZSM-5 zeolite can significantly decrease the initial pyrolysis temperature of PS. Elevated activation energy is resulted by adding low zeolite amount whereas reduced activation energy is obtained by adding high ZSM-5 amounts. The effect of zeolite ZSM-5 on PS pyrolysis can thus be observed to transfer from stabilizing …

Synthesis And Characterization Of Anderson-Evans Type Polyoxometalates, Antibacterial Properties, Hülya Avci Özbek

Turkish Journal of Chemistry

In the present work, the new aluminium-substituted polyoxometalates of the Anderson-Evans type have been prepared and structurally defined by the reaction of aluminium (III) chloride hexahydrate and sodium tungstate dihydrate/sodium molybdate dihydrate in an aqueous basic medium. Elemental analysis, FT-IR, TGA, 1H NMR, and 31P NMR analysis revealed that these polyoxometalates had the following formula: [Ph4 P]3 [Al(OH)6 Mo6 O18]·4H2 O 1, [Ph4 P]3 [Al(OH)6 W6 O18]·4H2 O 2, [C7 H10N]3 [Al(OH)6 Mo6 O18]·4H2 O 3, [C7 H10N]3 [Al(OH)6 W6 O18]·4H2 O 4. The compounds 1 and 2 show promising antibacterial activity against gram-positive Staphylcoccus aureus ATCC 25923 and gram-negative …

Electronic Structures And Dielectric Function Of (5, 5) Cnt-C2h4o System: A First-Principles Study On The Detection Capability Of Cnt For Gas Sensing Applications, Alvanh Alem Pido, Art Anthony Munio

Turkish Journal of Chemistry

Carbon nanotubes (CNTs) are known to have a wide range of applications in various fields of discipline. In this research, the ability of metallic armchair (5, 5) CNT to detect acetaldehyde (C2 H4 O) was investigated using first-principles density functional theory (DFT) as implemented in Quantum ESPRESSO with the Generalized Gradient Approximation (GGA). Accordingly, it was found that C2 H4 O preserved the metallic behavior of the CNT. However, some bands are found to have overlapped in both the valence and conduction regions of the electronic structures of the resulting system that are mainly caused by the p orbitals of …

Waste Jean Derived Self N-Containing Activated Carbon As A Potential Electrode Material For Supercapacitors, Yavuz Gökçe

Turkish Journal of Chemistry

The rapid rise of the world population increases the annual amount of waste textile products. Textile products create a significant amount of CO2 , water, and chemical footprints during production. Therefore, the reusability of textile products has an important environmental and economic impact. Waste denim was used in this study to produce activated carbon (AC) samples as the alternative substance for supercapacitor electrodes. Characterisation studies showed that AC samples contain nitrogen originating from the elastane in the denim structure. Electrochemical characterisation tests proved the pseudocapacitive behaviour of the denim-derived AC due to the nitrogen content. Specific capacitance values observed for …

Acid-Base Potentiometric Titration Using A Stainless Steel Electrode Without Oxidative Treatment, Javier E. Vilasó-Cadre, Daniel Benítez-Fernández, Ilse A. López-Álvarez, F. Yuliana Tovar-Vázquez, María A. Arada-Pérez, Iván A. Reyes-Domínguez

Turkish Journal of Chemistry

An AISI 304 stainless steel laminar electrode without oxidative treatment was investigated for the potentiometric titration of hydrochloric acid with sodium hydroxide. The proposed electrode was obtained from metalworking cuttings. Scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray fluorescence spectroscopy and X-ray diffraction were used to study the surface morphology and chemical composition of the electrode. The electrode showed a sensitivity of 59.18 ± 0.37 mV/pH, which was reproducible under intermediate conditions. Potentiometric titration showed a curve with deviations from pH 9.5 with respect to the glass electrode. However, this did not affect the quantification as the jumps of the …

A Compendious Review Of Majorization-Based Resource Theories: Quantum Information And Quantum Thermodynamics, Gökhan Torun, Onur Pusuluk, Özgür Esat Müstecaplioğlu

Turkish Journal of Physics

The field of quantum resource theory (QRT) has emerged as an invaluable framework for the examination of small and strongly correlated quantum systems, surpassing the boundaries imposed by traditional statistical treatments. The fundamental objective of general QRTs is to characterize these systems by precisely quantifying the level of control attainable to an experimenter. In this review article, we refrain from providing an exhaustive summary of the extensive literature on QRT. Rather, our focus centers on a specific subliterature founded upon the theory of majorization. The primary aim is to augment our comprehension of genuine quantum phenomena manifested across diverse technological …

Modelling Long-Term Security Returns, Xinghan Zhu

Electronic Thesis and Dissertation Repository

This research focuses on the concerns of Canadian investors regarding portfolio diversification and preparedness for unexpected risks in retirement planning. It models market crashes and two main financial instruments as independent components to simulate clients’ portfolios. Initially exploring single distributions on mutual funds such as Laplace and t distributions, the research finds limited success. Instead, a normal-Weibull spliced distribution is introduced to model log returns. The Geometric Brownian Motion (GBM) model is employed to predict and evaluate returns on common stocks using the Maximum Likelihood Estimator (MLE), assuming that daily log returns follow a normal distribution. Additionally, the Merton Jump …

Terrestrial Craters As Analogues For Degraded Craters On Titan, Taylor M. Duncan

Electronic Thesis and Dissertation Repository

Besides Earth, Titan is the only planetary body in our Solar System to currently have flowing liquid on its surface. Previous works note that dendritic and rectangular stream networks are present on a global scale on Titan, but do not map networks in the vicinity of Titan’s impact craters: Selk and Sinlap. The objective of this work is to understand how stream networks form adjacent to Titan’s impact craters. This information will inform future missions to Titan (i.e., Dragonfly) about the fluvial morphology of streams near their landing site. I conduct an analogue study with the stream networks at three …

Remote Sensing And Gis Based Approach To Evaluate The Impact Of Stone Quarrying And Crushing Activities On Land Resources, R. S. Chaurasia, S. N. Mohapatra

Journal of Sustainable Mining

The land is one of the most treasures to support life, like food, fibre, medicine, and minerals, etc. Stone quarrying is one of the key elements which supports socio-economic development and industrial expansion. RS and GIS play an important role in environmental assessment to monitor the stone quarries and related activities for time to time. The present study was carried out to evaluate the impact of stone quarrying and crushing activities (SQCA) on land resources. Therefore, matrix change analysis of 2021, 2015, 2008 and 2003 were used for change detection. High-resolution Google Earth Pro images were used for the assessment …

Geometry In Spectral Triples: Immersions And Fermionic Fuzzy Geometries, Luuk S. Verhoeven

Electronic Thesis and Dissertation Repository

We investigate the metric nature of spectral triples in two ways.

Given an oriented Riemannian embedding i:X->Y of codimension 1 we construct a family of unbounded KK-cycles i!(epsilon), each of which represents the shriek class of i in KK-theory. These unbounded KK-cycles are further equipped with connections, allowing for the explicit computation of the products of i! with the spectral triple of Y at the unbounded level. In the limit epsilon to 0 the product of these unbounded KK-cycles with the canonical spectral triple for Y admits an asymptotic expansion. The divergent part of this expansion is known and …

Machine Learning-Based Classification Of Chronic Traumatic Brain Injury Using Hybrid Diffusion Imaging, Jennifer Muller, Ruixuan Wang, Devon Middleton, Mahdi Alizadeh, Kichang Kang, Ryan Hryczyk, George Zabrecky, Chloe Hriso, Emily Navarreto, Nancy Wintering, Anthony J. Bazzan, Chengyuan Wu, Daniel A. Monti, Xun Jiao, Qianhong Wu, Andrew B. Newberg, Feroze Mohamed

Marcus Institute of Integrative Health Faculty Papers

BACKGROUND AND PURPOSE: Traumatic brain injury (TBI) can cause progressive neuropathology that leads to chronic impairments, creating a need for biomarkers to detect and monitor this condition to improve outcomes. This study aimed to analyze the ability of data-driven analysis of diffusion tensor imaging (DTI) and neurite orientation dispersion imaging (NODDI) to develop biomarkers to infer symptom severity and determine whether they outperform conventional T1-weighted imaging.

MATERIALS AND METHODS: A machine learning-based model was developed using a dataset of hybrid diffusion imaging of patients with chronic traumatic brain injury. We first extracted the useful features from the hybrid diffusion imaging …

One Font Doesn’T Fit All: The Influence Of Digital Text Personalization On Comprehension In Child And Adolescent Readers, Shannon M. Sheppard, Susanne L. Nobles, Anton Palma, Sophie Kajfez, Marjorie Jordan, Kathy Crowley, Sofie Beier

Communication Sciences and Disorders Faculty Articles and Research

Reading comprehension is an essential skill. It is unclear whether and to what degree typography and font personalization may impact reading comprehension in younger readers. With advancements in technology, it is now feasible to personalize digital reading formats in general technology tools, but this feature is not yet available for many educational tools. The current study aimed to investigate the effect of character width and inter-letter spacing on reading speed and comprehension. We enrolled 94 children (kindergarten–8th grade) and compared performance with six font variations on a word-level semantic decision task (Experiment 1) and a passage-level comprehension task (Experiment 2). …

Intrusion Detection: Machine Learning Techniques For Software Defined Networks, Jacob S. Rodriguez

Masters Theses

In recent years, software defined networking (SDN) has gained popularity as a novel approach towards network management and architecture. Compared to traditional network architectures, this software-based approach offers greater flexibility, programmability, and automation. However, despite the advantages of this system, there still remains the possibility that it could be compromised. As we continue to explore new approaches to network management, we must also develop new ways of protecting those systems from threats. Throughout this paper, I will describe and test a network intrusion detection system (NIDS), and how it can be implemented within a software defined network. This system will …

Digital Literacies As Policy Catalysts Of Social Innovation And Socioeconomic Transformation: Interpretive Analysis From Singapore And The Uae, Ravi S. Sharma, Intan Azura Mokhtar, Dhanjoo N. Ghista, Amril Nazir, Sana Z. Khan

All Works

Even before the COVID-19 global pandemic, the world saw the adoption and proliferation of numerous digital tools and technologies, or a global digital transformation. This paved the way for digital inclusion, particularly through e-commerce and shared services platforms which helped to reduce barriers to entry and created abundant socio-economic opportunities across income groups. As a result, digital literacy becomes a vital aspect of modern life due to the rapid global shift toward this digital transformation. Numerous scholars have investigated the benefits of digital literacies since 1995. The primary objective of this paper is to investigate good practices and lessons learned …

Hellings And Downs Correlation Of An Arbitrary Set Of Pulsars, Bruce Allen, Joseph D. Romano

Physics and Astronomy Faculty Publications and Presentations

Pulsar timing arrays (PTAs) detect gravitational waves (GWs) via the correlations they induce in the arrival times of pulses from different pulsars. We assume that the GWs are described by a Gaussian ensemble, which models the confusion noise produced by expected PTA sources. The mean correlation h2μu(γ) as a function of the angle γ between the directions to two pulsars was predicted by Hellings and Downs in 1983. The variance σ2tot(γ) in this correlation was recently calculated [B. Allen, Variance of the Hellings-Downs correlation, Phys. Rev. D 107, 043018 (2023)] for a single noise-free pulsar pair at angle γ, …

Hellings And Downs Correlation Of An Arbitrary Set Of Pulsars, Bruce Allen, Joseph D. Romano

Physics and Astronomy Faculty Publications and Presentations

Pulsar timing arrays (PTAs) detect gravitational waves (GWs) via the correlations they induce in the arrival times of pulses from different pulsars. We assume that the GWs are described by a Gaussian ensemble, which models the confusion noise produced by expected PTA sources. The mean correlation h2μu(γ) as a function of the angle γ between the directions to two pulsars was predicted by Hellings and Downs in 1983. The variance σ2tot(γ) in this correlation was recently calculated [B. Allen, Variance of the Hellings-Downs correlation, Phys. Rev. D 107, 043018 (2023)] for a single noise-free pulsar pair at angle γ, …

The Patchwork Governance Of Ecologically Available Water: A Case Study In The Upper Missouri Headwaters, Montana, United States, Amanda E. Cravens, Julia B. Goolsby, Theresa Jedd, Deborah J. Bathke, Shelley Crausbay, Ashley E. Cooper, Jason Dunham, Tonya Haigh, Kimberly R. Hall, Michael J. Hayes, Jamie Mcevoy, Rebecca L. Nelson, Markéta Poděbradská, Aaron Ramirez, Elliot Wickham, Dionne Zoanni

Drought Mitigation Center: Faculty Publications

Institutional authority and responsibility for allocating water to ecosystems (“ecologically available water” [EAW]) is spread across local, state, and federal agencies, which operate under a range of statutes, mandates, and planning processes. We use a case study of the Upper Missouri Headwaters Basin in southwestern Montana, United States, to illustrate this fragmented institutional landscape. Our goals are to (a) describe the patchwork of agencies and institutional actors whose intersecting authorities and actions influence the EAW in the study basin; (b) describe the range of governance mechanisms these agencies use, including laws, policies, administrative programs, and planning processes; and (c) assess …

Smartphone Loss Prevention System Using Ble And Gps Technology, Noshin Tasnim

Electronic Thesis and Dissertation Repository

Being an all-in-one gadget, smartphones play a vital role in our everyday lives. However, millions of people suffer every year by losing their phones. A lost phone creates a huge security threat and data loss possibility to the users. Some preventive measures are available to protect from unauthorized access. Moreover, there are some post-loss solutions to track down, retrieve data from a lost locked phone, and protect the privacy and security of lost phone data, but those have some drawbacks as well. Considering the situation, our proposed system offers a preventive solution which will protect the smartphones from getting lost. …

Global Cyber Attack Forecast Using Ai Techniques, Nusrat Kabir Samia

Electronic Thesis and Dissertation Repository

The advancement of internet technology and growing involvement in the cyber world have made us prone to cyber-attacks inducing severe damage to individuals and organizations, including financial loss, identity theft, and reputational damage. The rapid emergence and evolution of new networks and new opportunities for businesses and technologies are increasing threats to security vulnerabilities. Hence cyber-crime analysis is one of the wide range applications of Data Mining that can be eventually used to predict and detect crime. However, there are several constraints while analyzing cyber-attacks, which are yet to be resolved for more accurate cyber security inspection.

Although there are …

Double Barrier Backward Doubly Stochastic Differential Equations, Tadashi Hayashi

Journal of Stochastic Analysis

No abstract provided.

Finite Charges From The Bulk Action, Robert Mcnees, Céline Zwikel

Physics: Faculty Publications and Other Works

Constructing charges in the covariant phase space formalism often leads to formally divergent expressions, even when the fields satisfy physically acceptable fall-off conditions. These expressions can be rendered finite by corner ambiguities in the definition of the presymplectic potential, which in some cases may be motivated by arguments involving boundary Lagrangians. We show that the necessary corner terms are already present in the variation of the bulk action and can be extracted in a straightforward way. Once these corner terms are included in the presymplectic potential, charges derived from an associated codimension-2 form are automatically finite. We illustrate the procedure …

A Sensitivity Study Of Triboson Production Processes To Dimension-6 Eft Operators At The Lhc, R. Bellan, S. Bhattacharya, G. Boldrini, F. Cetorelli, P. Govoni, A. Massironi, A. Mecca, C. Tarricone, A. Vagnerini

Department of Physics and Astronomy: Faculty Publications

We present the first parton-level study of anomalous effects in triboson production in both fully and semi-leptonic channels in proton-proton collisions at 13TeV at the Large Hadron Collider (LHC). The sensitivity to anomalies induced by a minimal set of bosonic dimension-6 operators from the Warsaw basis is evaluated with specific analyses for each final state. A likelihood-based strategy is employed to assess the most sensitive kinematic observables per channel, where the contribution of Effective Field Theory operators is parameterized at either the linear or quadratic level. The impact of the mutual interference terms of pairs of operators on the sensitivity …

A Search For Decays Of The Higgs Boson To Invisible Particles In Events With A Top-Antitop Quark Pair Or A Vector Boson In Proton-Proton Collisions At √S = 13 Tev, Armen R. Tumasyan

Department of Physics and Astronomy: Faculty Publications

The first search for nonresonant production of Higgs boson pairs (HH) with one H decaying into four leptons and the other into a pair of b quarks is presented, using proton-proton collisions recorded at a center-of-mass energy of √s = 13 TeV by the CMS experiment. The analyzed data correspond to an integrated luminosity of 138 fb⁻¹. A 95% confidence level upper limit of 32.4 is set on the signal strength modifier μ, defined as the ratio of the observed HH production rate in the HH → ZZ*bb → 4ℓbb decay channel to the standard model …

Characteristics And Source-Specific Health Risks Of Ambient Pm2.5-Bound Pahs In An Urban City Of Northern Taiwan, Yu-Chieh Ting, Chun-Hung Ku, Yu-Xuan Zou, Kai-Hsien Chi, Jhy-Charm Soo, Chin-Yu Hsu, Yu-Cheng Chen

Department of Biostatistics, Epidemiology, and Environmental Health Sciences Faculty Publications

Polycyclic aromatic hydrocarbons (PAHs) with highly toxic compounds mainly exist in small-sized particles and can induce considerable human health risks. Studies on PM2.5-bound PAHs and their source-specific human health risks still remain scarce. Daily PM2.5 samples (n = 119) were collected every three days from 2016 to 2017 in Taipei city, Taiwan. Fifteen PAHs in PM2.5 were analyzed via gas chromatography tandem mass spectrometry (GC/MS-MS). We utilized a positive matrix factorization (PMF) model, diagnostic ratios, and potential source contribution function (PSCF) to identify the origins of PM2.5-bound PAHs. The annual concentration of total PAHs (TPAH) was 0.79 ± 0.67 ng …

Euler Archive Spotlight: Translations Of Euler's Works To Languages Other Than English, Michael P. Saclolo

Euleriana

The Euler Archive is home to almost all of Euler’s original publications and roughly a quarter of them have accompanying translations to English. A small number of Euler’s works also have translations to a handful of other languages, namely, Dutch, French, German, Italian, Portuguese, and Turkish that are available in the archive. We put a spotlight on these non-English translations in this issue.

Perfect Numbers, Uwe Hassler

Euleriana

We provide a selected review of results known or conjectured before Euler entered and changed the quest for perfect numbers. Then we discuss his contributions to the determination of Mersenne primes that fueled research on primality tests.

Euler’S Variational Approach To The Elastica, Sylvio R. Bistafa

Euleriana

The history of the elastica is examined through the works of various contributors, including those of Jacob and Daniel Bernoulli, since its first appearance in a 1690 contest on finding the profile of a hanging flexible cord. Emphasis will be given to Leonhard Euler’s variational approach to the elastica, laid out in his landmark 1744 book on variational techniques. Euler’s variational approach based on the concept of differential value is highlighted, including the derivation of the general equation for the elastica from the differential value of the first kind, from which nine shapes adopted by a flexed lamina under different …