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Articles 1 - 30 of 2227
Full-Text Articles in Physical Sciences and Mathematics
Synchronicity: An Analysis Of Einstein's Halfway Rule, Preslava Nikolova
Synchronicity: An Analysis Of Einstein's Halfway Rule, Preslava Nikolova
Rushton Journal of Undergraduate Humanities Research
For the modern world to function, Global Positioning System satellites must synchronize to clocks on Earth. This paper examines a concept that underlies GPS systems, namely Albert Einstein’s halfway rule—the idea that a line of simultaneity exists between two events in different systems. This essay discusses how Einstein used conventionalist methods to establish ½ as a constant value for σ to take advantage of the property of symmetry.
Lead Bioaccessibility And Commonly Measured Soil Characteristics (Detroit, Mi, Usa) – Phase 1, Sabrina R. Good, Allison R. Harris, Patrick Crouch, Conor T. Gowan, William D. Shuster, Shawn P. Mcelmurry
Lead Bioaccessibility And Commonly Measured Soil Characteristics (Detroit, Mi, Usa) – Phase 1, Sabrina R. Good, Allison R. Harris, Patrick Crouch, Conor T. Gowan, William D. Shuster, Shawn P. Mcelmurry
Open Data at Wayne State
Contaminated urban soil is one of the major contributors to child Pb exposure. To gain a better understanding of Pb risk in urban areas, composite samples were collected from 142 residential, privately owned, parcels in Detroit, Hamtramck, and Highland Park, Michigan, with approval from the property owners. The proximity of soil sampling and former smelter locations were also reported. Sample were collected from areas covered with turf grass. Four samples were collected, one from each cardinal direction (north, south, east, and west), 20 cm from an aluminum tent stake driven into the center of the sampling site. Soils were collected …
Towards An Experimental Bibliography Of Hemispheric Reconstruction Newspapers, Joshua Ortiz Baco, Benjamin Charles Germain Lee, Jim Casey, Sarah H. Salter
Towards An Experimental Bibliography Of Hemispheric Reconstruction Newspapers, Joshua Ortiz Baco, Benjamin Charles Germain Lee, Jim Casey, Sarah H. Salter
Criticism
Digital collections of newspapers have drawn broader attention to the fragmented and scattered print histories of minoritized communities. Attempts to survey these histories through bibliography, however, quickly meet with a fundamental problem: the practice of bibliographic description calls for creating a static record of social affiliations. Given the overwhelming scholarly consensus that categories such as race, ethnicity, and language are socially constructed, this article introduces an experimental bibliographic method for mapping the vast landscape of historical newspapers. This method extends the machine learning affordances of a recent project called Newspaper Navigator to enumerate the newspapers in Chronicling America according to …
Assessing Boil Water Notices As Health-Risk Communication: Risk Perceptions, Efficacy, And Compliance During Winter Storm Uri, Ashleigh M. Day, Sydney O'Shay, Khairul Islam, Matthew W. Seeger, Shawn P. Mcelmurry
Assessing Boil Water Notices As Health-Risk Communication: Risk Perceptions, Efficacy, And Compliance During Winter Storm Uri, Ashleigh M. Day, Sydney O'Shay, Khairul Islam, Matthew W. Seeger, Shawn P. Mcelmurry
Open Data at Wayne State
Winter Storm Uri was an extreme disaster that impacted much of the United States during February of 2021. Texas and Oklahoma were generally not prepared for such an event and experienced massive power grid failures. This led to cascading risks including water system disruptions and many boil water notices (BWNs). The breakdown of some communication channels and the inability to enact protective actions due to power outages, as well as travel limitations on public roads, complicated both dissemination and implementation. Under these conditions, a non-representative, cross-sectional, survey was collected to assess individuals experience BWNs and how perceived efficacy impacts compliance. …
Two Sample Statistical Test For Location Parameters, Narinder Kumar, Arun Kumar
Two Sample Statistical Test For Location Parameters, Narinder Kumar, Arun Kumar
Journal of Modern Applied Statistical Methods
A class of distribution-free tests for the homogeneity of location parameters is proposed and compared with different competitors in terms of Pitman asymptotic relative efficiency. A numerical example is provided and a simulation study is made to check the performance of the tests.
Exploring The Association Of Brownfield Remediation Status With Socioeconomic Conditions In Wayne County, Mi, Brendan F. O'Leary, Alex B. Hill, Colleen Linn, Mei Lu, Carol J. Miller, Andrew Newman, F. Gianluca Sperone, Qiong Zhang
Exploring The Association Of Brownfield Remediation Status With Socioeconomic Conditions In Wayne County, Mi, Brendan F. O'Leary, Alex B. Hill, Colleen Linn, Mei Lu, Carol J. Miller, Andrew Newman, F. Gianluca Sperone, Qiong Zhang
Urban Studies and Planning Faculty Research Publications
Urban neighborhoods with locations of environmental contamination, known as brownfields, impact entire neighborhoods, but corrective environmental remedial action on brownfields is often tracked on an individual property basis, neglecting the larger neighborhood-level impact. This study addresses this impact by examining spatial differences between brownfields with unmitigated environmental concerns (open site) and sites that are considered fully mitigated or closed in urban neighborhoods (closed site) on the US census tract scale in Wayne County, MI. Michigan’s Department of Environment, Great Lakes, and Energy’s leaking underground storage tank (LUST) database provided brownfield information for Wayne County. Local indicators of spatial association (LISA) …
Mathematics For Biomedical Physics, Jogindra M. Wadehra
Mathematics For Biomedical Physics, Jogindra M. Wadehra
Open Textbooks
Mathematics for Biomedical Physics is an open access peer-reviewed textbook geared to introduce several mathematical topics at the rudimentary level so that students can appreciate the applications of mathematics to the interdisciplinary field of biomedical physics. Most of the topics are presented in their simplest but rigorous form so that students can easily understand the advanced form of these topics when the need arises. Several end-of-chapter problems and chapter examples relate the applications of mathematics to biomedical physics. After mastering the topics of this book, students would be ready to embark on quantitative thinking in various topics of biology and …
Control Implemented On Quantum Computers: Effects Of Noise, Nondeterminism, And Entanglement, Kip Nieman, Keshav Kasturi Rangan, Helen Durand
Control Implemented On Quantum Computers: Effects Of Noise, Nondeterminism, And Entanglement, Kip Nieman, Keshav Kasturi Rangan, Helen Durand
Chemical Engineering and Materials Science Faculty Research Publications
Quantum computing has advanced in recent years to the point that there are now some quantum computers and quantum simulators available to the public for use. In addition, quantum computing is beginning to receive attention within the process systems engineering community for directions such as machine learning and optimization. A logical next step for its evaluation within process systems engineering is for control, specifically for computing control actions to be applied to process systems. In this work, we provide some initial studies regarding the implementation of control on quantum computers, including the implementation of a single-input/single-output proportional control law on …
Actuator Cyberattack Handling Using Lyapunov-Based Economic Model Predictive Control, Keshav Kasturi Rangan, Henrique Oyama, Helen Durand
Actuator Cyberattack Handling Using Lyapunov-Based Economic Model Predictive Control, Keshav Kasturi Rangan, Henrique Oyama, Helen Durand
Chemical Engineering and Materials Science Faculty Research Publications
Cybersecurity has gained increasing interest as a consequence of the potential impacts of cyberattacks on profits and safety. While attacks can affect various components of a plant, prior work from our group has focused on the impact of cyberattacks on control components such as process sensors and actuators and the development of detection strategies for cybersecurity derived from control theory. In this work, we provide greater focus on actuator attacks; specifically, we extend a detection and control strategy previously applied for sensor attacks and based on an optimization-based control technique called Lyapunov-based economic model predictive control (LEMPC) to detect attacks …
Test Methods For Image-Based Information In Next-Generation Manufacturing, Henrique Oyama, Dominic Messina, Renee O'Neill, Samantha Cherney, Minhazur Rahman, Keshav Kasturi Rangan, Govanni Gjonaj, Helen Durand
Test Methods For Image-Based Information In Next-Generation Manufacturing, Henrique Oyama, Dominic Messina, Renee O'Neill, Samantha Cherney, Minhazur Rahman, Keshav Kasturi Rangan, Govanni Gjonaj, Helen Durand
Chemical Engineering and Materials Science Faculty Research Publications
Typical control designs in the process systems engineering literature have assumed that the primary sensing methodologies are traditional instruments such as thermocouples. Dig- italization is changing the landscape for manufacturing, and data-based sensing modalities (e.g., image-based sensing) are becoming of greater interest for plant control. These considerations require novel test/evaluation solutions. For example, process systems engineering researchers may wish to test image-based sensors in simulation. In this work, we provide preliminary thoughts on how image-based technologies might be evaluated via simulation for process systems.
Quantum Computing And Resilient Design Perspectives For Cybersecurity Of Feedback Systems, Keshav Kasturi Rangan, Jihan Abou Halloun, Henrique Oyama, Samantha Cherney, Ilham Azali Assoumani, Nazir Jairazbhoy, Helen Durand, Simon Ka Ng
Quantum Computing And Resilient Design Perspectives For Cybersecurity Of Feedback Systems, Keshav Kasturi Rangan, Jihan Abou Halloun, Henrique Oyama, Samantha Cherney, Ilham Azali Assoumani, Nazir Jairazbhoy, Helen Durand, Simon Ka Ng
Chemical Engineering and Materials Science Faculty Research Publications
Cybersecurity of control systems is an important issue in next-generation manufac- turing that can impact both operational objectives (safety and performance) as well as process designs (via hazard analysis). Cyberattacks differ from faults in that they can be coordinated efforts to exploit system vulnerabilities to create otherwise unlikely hazard scenarios. Because coordination and targeted process manipulation can be characteristics of attacks, some of the tactics previously analyzed in our group from a control system cybersecurity perspective have incorporated randomness to attempt to thwart attacks. The underlying assumption for the generation of this randomness has been that it can be achieved …
Challenges And Opportunities For Next-Generation Manufacturing In Space, Kip Nieman, A. F. Leonard, Katie Tyrell, Dominic Messina, Rebecca Lopez, Helen Durand
Challenges And Opportunities For Next-Generation Manufacturing In Space, Kip Nieman, A. F. Leonard, Katie Tyrell, Dominic Messina, Rebecca Lopez, Helen Durand
Chemical Engineering and Materials Science Faculty Research Publications
With commercial space travel now a reality, the idea that people might spend time on other planets in the future seems to have greater potential. To make this possible, however, there needs to be flexible means for manufacturing in space to enable tooling or resources to be created when needed to handle unexpected situations. Next-generation manufacturing paradigms offer significant potential for the kind of flexibility that might be needed; however, they can result in increases in computation time compared to traditional control methods that could make many of the computing resources already available on earth attractive for use. Furthermore, resilience …
The Short-Term Effects Of Fine Airborne Particulate Matter And Climate On Covid-19 Disease Dynamics, El Hussain Shamsa, Kezhong Zhang
The Short-Term Effects Of Fine Airborne Particulate Matter And Climate On Covid-19 Disease Dynamics, El Hussain Shamsa, Kezhong Zhang
Medical Student Research Symposium
Background: Despite more than 60% of the United States population being fully vaccinated, COVID-19 cases continue to spike in a temporal pattern. These patterns in COVID-19 incidence and mortality may be linked to short-term changes in environmental factors.
Methods: Nationwide, county-wise measurements for COVID-19 cases and deaths, fine-airborne particulate matter (PM2.5), and maximum temperature were obtained from March 20, 2020 to March 20, 2021. Multivariate Linear Regression was used to analyze the association between environmental factors and COVID-19 incidence and mortality rates in each season. Negative Binomial Regression was used to analyze daily fluctuations of COVID-19 cases …
The Local Cohomology Spectral Sequence For Topological Modular Forms, Robert Bruner, John Greenlees, John Rognes
The Local Cohomology Spectral Sequence For Topological Modular Forms, Robert Bruner, John Greenlees, John Rognes
Mathematics Faculty Research Publications
We discuss proofs of local cohomology theorems for topological modular forms, based on Mahowald–Rezk duality and on Gorenstein duality, and then make the associated local cohomology spectral sequences explicit, including their differential patterns and hidden extensions.
On-Line Process Physics Tests Via Lyapunov-Based Economic Model Predictive Control And Simulation-Based Testing Of Image-Based Process Control, Henrique Oyama, A. F. Leonard, Minhazur Rahman, Govanni Gjonaj, Michael Williamson, Helen Durand
On-Line Process Physics Tests Via Lyapunov-Based Economic Model Predictive Control And Simulation-Based Testing Of Image-Based Process Control, Henrique Oyama, A. F. Leonard, Minhazur Rahman, Govanni Gjonaj, Michael Williamson, Helen Durand
Chemical Engineering and Materials Science Faculty Research Publications
Next-generation manufacturing involves increasing use of automation and data to enhance process efficiency. An important question for the chemical process industries, as new process systems (e.g., intensified processes) and new data modalities (e.g., images) are integrated with traditional plant automation concepts, will be how to best evaluate alternative strategies for data-driven modeling and synthesizing process data. Two methods which could be used to aid in this are those which aid in testing data-based techniques on-line, and those which enable various data-based techniques to be assessed in simulation. In this work, we discuss two techniques in this domain which can be …
The Adams Spectral Sequence For The Image-Of-J Spectrum, Robert R. Bruner, John Rognes
The Adams Spectral Sequence For The Image-Of-J Spectrum, Robert R. Bruner, John Rognes
Mathematics Faculty Research Publications
We show that if we factor the long exact sequence in cohomology of a cofiber sequence of spectra into short exact sequences, then the d_2-differential in the Adams spectral sequence of any one term is related in a precise way to Yoneda composition with the 2-extension given by the complementary terms in the long exact sequence. We use this to give a complete analysis of the Adams spectral sequence for the connective image-of-J spectrum, finishing a calculation that was begun by D. Davis [Bol. Soc. Mat. Mexicana (2) 20 (1975), pp. 6–11].
The Gelfand Problem For The Infinity Laplacian, Fernando Charro, Byungjae Son, Peiyong Wang
The Gelfand Problem For The Infinity Laplacian, Fernando Charro, Byungjae Son, Peiyong Wang
Mathematics Faculty Research Publications
We study the asymptotic behavior as p → ∞ of the Gelfand problem
−Δpu = λeu in Ω ⊂ Rn, u = 0 on ∂Ω.
Under an appropriate rescaling on u and λ, we prove uniform convergence of solutions of the Gelfand problem to solutions of
min{|∇u|−Λeu, −Δ∞u} = 0 in Ω, u = 0 on ∂Ω.
We discuss existence, non-existence, and multiplicity of solutions of the limit problem in terms of Λ.
Asymptotic Mean-Value Formulas For Solutions Of General Second-Order Elliptic Equations, Pablo Blanc, Fernando Charro, Juan J. Manfredi, Julio D. Rossi
Asymptotic Mean-Value Formulas For Solutions Of General Second-Order Elliptic Equations, Pablo Blanc, Fernando Charro, Juan J. Manfredi, Julio D. Rossi
Mathematics Faculty Research Publications
We obtain asymptotic mean-value formulas for solutions of second-order elliptic equations. Our approach is very flexible and allows us to consider several families of operators obtained as an infimum, a supremum, or a combination of both infimum and supremum, of linear operators. The families of equations that we consider include well-known operators such as Pucci, Issacs, and k-Hessian operators.
Lyapunov-Based Economic Model Predictive Control For Detecting And Handling Actuator And Simultaneous Sensor/Actuator Cyberattacks On Process Control Systems, Henrique Oyama, Dominic Messina, Keshav Kasturi Rangan, Helen Durand
Lyapunov-Based Economic Model Predictive Control For Detecting And Handling Actuator And Simultaneous Sensor/Actuator Cyberattacks On Process Control Systems, Henrique Oyama, Dominic Messina, Keshav Kasturi Rangan, Helen Durand
Chemical Engineering and Materials Science Faculty Research Publications
The controllers for a cyber-physical system may be impacted by sensor measurement cyberattacks, actuator signal cyberattacks, or both types of attacks. Prior work in our group has developed a theory for handling cyberattacks on process sensors. However, sensor and actuator cyberattacks have a different character from one another. Specifically, sensor measurement attacks prevent proper inputs from being applied to the process by manipulating the measurements that the controller receives, so that the control law plays a role in the impact of a given sensor measurement cyberattack on a process. In contrast, actuator signal attacks prevent proper inputs from being applied …
The Cohomology Of The Mod 2 Steenrod Algebra, Robert R. Bruner, John Rognes
The Cohomology Of The Mod 2 Steenrod Algebra, Robert R. Bruner, John Rognes
Open Data at Wayne State
The dataset contains a minimal resolution of the mod 2 Steenrod algebra in the range 0 <= s <= 128, 0 <= t <= 200, together with chain maps for each cocycle in that range and for the squaring operation Sq^0 in the cohomology of the Steenrod algebra. The included document CohomA2.pdf explains the contents and usage of the dataset in detail (also available as supplemental material in this record).
Dataset is also available at the NIRD Research Data Archive, https://doi.org/10.11582/2021.00077; Data Description also available at arXiv.org, https://doi.org/10.48550/arXiv.2109.13117.
Parametric And Reliability Estimation Of The Kumaraswamy Generalized Distribution Based On Record Values, Mohd. Arshad, Qazi J. Azhad
Parametric And Reliability Estimation Of The Kumaraswamy Generalized Distribution Based On Record Values, Mohd. Arshad, Qazi J. Azhad
Journal of Modern Applied Statistical Methods
A general family of distributions, namely Kumaraswamy generalized family of (Kw-G) distribution, is considered for estimation of the unknown parameters and reliability function based on record data from Kw-G distribution. The maximum likelihood estimators (MLEs) are derived for unknown parameters and reliability function, along with its confidence intervals. A Bayesian study is carried out under symmetric and asymmetric loss functions in order to find the Bayes estimators for unknown parameters and reliability function. Future record values are predicted using Bayesian approach and non Bayesian approach, based on numerical examples and a monte carlo simulation.
Does The Type Of Records Affect The Estimates Of The Parameters?, Ayush Tripathi, Umesh Singh, Sanjay Kumar Singh
Does The Type Of Records Affect The Estimates Of The Parameters?, Ayush Tripathi, Umesh Singh, Sanjay Kumar Singh
Journal of Modern Applied Statistical Methods
The maximum likelihood estimation of the unknown parameters of inverse Rayleigh and exponential distributions are discussed based on lower and upper records. The aim is to study the effect of the type of records on the behavior of the corresponding estimators. Mean squared errors are calculated through simulation to study the behavior of the estimators. The results shall be of interest to those situations where the data can be obtained in the form of either of the two types of records and the experimenter must decide between these two for estimation of the unknown parameters of the distribution.
Design Of Sksp-R Plan For Popular Statistical Distributions, Jaffer Hussain, S. Balamurali, Muhammad Aslam
Design Of Sksp-R Plan For Popular Statistical Distributions, Jaffer Hussain, S. Balamurali, Muhammad Aslam
Journal of Modern Applied Statistical Methods
The design of a Skip-lot sampling plan of type SkSP-R is presented for time truncated life test for the Weibull, Exponentiated Weibull, and Birnbaum-Saunders lifetime distributions. The plan parameters of the SkSP-R plan under these three distributions are determined through a nonlinear optimization problem. Tables are also constructed for each distribution. The advantages of the proposed plan over the existing sampling schemes are discussed. Application of the proposed plan is explained with the help of an example. The Birnbaum-Saunders distribution is economically superior to other two distributions in terms of minimum average sample number.
Parameter Estimation Based On Double Ranked Set Samples With Applications To Weibull Distribution, Mohamed Abd Elhamed Sabry, Hiba Zeyada Muhammed, Mostafa Shaaban, Abd El Hady Nabih
Parameter Estimation Based On Double Ranked Set Samples With Applications To Weibull Distribution, Mohamed Abd Elhamed Sabry, Hiba Zeyada Muhammed, Mostafa Shaaban, Abd El Hady Nabih
Journal of Modern Applied Statistical Methods
In this paper, the likelihood function for parameter estimation based on double ranked set sampling (DRSS) schemes is introduced. The proposed likelihood function is used for the estimation of the Weibull distribution parameters. The maximum likelihood estimators (MLEs) are investigated and compared to the corresponding ones based on simple random sampling (SRS) and ranked set sampling (RSS) schemes. A Monte Carlo simulation is conducted and the absolute relative biases, mean square errors, and efficiencies are compared for the different schemes. It is found that, the MLEs based on DRSS is more efficient than MLE using SRS and RSS for estimating …
A New Goodness Of Fit Measure Based On Income Inequality Curves, Shahryar Mirzaei, S. M. A. Jahanshahi
A New Goodness Of Fit Measure Based On Income Inequality Curves, Shahryar Mirzaei, S. M. A. Jahanshahi
Journal of Modern Applied Statistical Methods
This paper uses inequality-measurement techniques to assess goodness of fit in income distribution models. It exposes the shortcomings of the use of conventional goodness of fit criteria in face of the big income data and proposes a new set of metrics, based on income inequality curves. In this note, we mentioned that the distance between theoretical and empirical inequality curves can be considered as a goodness of fit criterion. We demonstrate certain advantages of this measure over the other general goodness of fit criteria. Unlike other goodness of fit measures, this criterion is bounded. It is 0 in minimum difference …
Synthesis Of Molybdenum Containing Thin Films Using Organic Reducing Agents And Synthesis Of Magnesium Silyl Intermediate Complexes For Use In Atomic Layer Deposition, Michael David Overbeek
Synthesis Of Molybdenum Containing Thin Films Using Organic Reducing Agents And Synthesis Of Magnesium Silyl Intermediate Complexes For Use In Atomic Layer Deposition, Michael David Overbeek
Wayne State University Dissertations
Thin films of a variety of materials have shown great potential in the fields of microelectronics, catalysis, and energy applications. Vapor deposition methods, including PVD and CVD, have been traditionally used as the primary method to deposit these thin films. However, these methods do not provide the necessary thickness uniformity and conformality needed for future uses of these thin films as they shrink to smaller dimensions. ALD provides a high degree of uniformity and conformality due to the intrinsic nature of the self-limited reaction mechanism of an ALD process.
The research herein focuses on two metals that have untapped potential …
The Development Of Fundamental Insights Into The Electronic Behaviors Of Next-Generation Materials, Sydney Lavan
The Development Of Fundamental Insights Into The Electronic Behaviors Of Next-Generation Materials, Sydney Lavan
Wayne State University Dissertations
We develop the fundamental mechanistic understanding of the microscopic behavior of three next generation materials: antiferroelectrics, hybrid perovskites and metal organic frameworks. These materials have the potential to be used in energy and light related applications which could provide a solution for the energy efficiency challenges we face in todays society. Ideally we need to begin to bridge the gap of developing candidate materials that possess high power density and high energy density. The first step in bridging this gap is understanding how the material influ- ences its structure and thus the properties and performance. We leverage vibrational spectroscopy and …
Lepton Flavor Violation And Effective Field Theories, Renae Conlin
Lepton Flavor Violation And Effective Field Theories, Renae Conlin
Wayne State University Dissertations
The Standard Model is believed to be a low energy effective theory of some completetheory at higher energies. This is already evidenced in the observation of neutrino oscillations. Standard Model processes conserve the lepton flavor quantum numbers. Adding massive neutrinos to the Standard Model, the branching ratios of lepton flavor violating processes are found to be incredibly small. For example, a process μ → eγ has a branching ratio order ∼ 10^−54. These tiny branching ratios of lepton flavor violating processes indicate that they are especially clean areas to look for beyond the Standard Model physics. Any observed flavor violation …
Segmentation Of Intracranial Structures From Noncontrast Ct Images With Deep Learning, Evan Porter
Segmentation Of Intracranial Structures From Noncontrast Ct Images With Deep Learning, Evan Porter
Wayne State University Dissertations
Presented in this work is an investigation of the application of artificially intelligent algorithms, namely deep learning, to generate segmentations for the application in functional avoidance radiotherapy treatment planning. Specific applications of deep learning for functional avoidance include generating hippocampus segmentations from computed tomography (CT) images and generating synthetic pulmonary perfusion images from four-dimensional CT (4DCT).A single institution dataset of 390 patients treated with Gamma Knife stereotactic radiosurgery was created. From these patients, the hippocampus was manually segmented on the high-resolution MR image and used for the development of the data processing methodology and model testing. It was determined that …
Development Of New Photochemical Tools For Applications In Cancer Research And Enzymatic Signaling, Nicholas Paul Toupin
Development Of New Photochemical Tools For Applications In Cancer Research And Enzymatic Signaling, Nicholas Paul Toupin
Wayne State University Dissertations
Photochemical tools empower researchers to act with precision and control over the cellular environment through production of reactive oxygen species (ROS), targeted drug delivery, and modulation of enzymatic activity. These molecular tools use light as a readily available, biorthogonal reagent for initiating advantageous light-activated reactions. Using light in this way allows researchers to affect the cellular environment in specific ways with high spatio-temporal control. This dissertation focuses on expanding the applications of, mostly Ru(II)-based, photoactivated chemicals. Complexes of this type are able to act as photosensitizers in photodynamic therapy (PDT), as photocages (PCT), or as dual-action compounds capable of both …