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Articles 69301 - 69330 of 294606

Full-Text Articles in Physical Sciences and Mathematics

2022 Final Butte Priority Soils Operable Unit Interim Site-Wide Surface Water Monitoring Quality Assurance Project Plan, Trec Inc., A Woodard And Curran Company Nov 2021

2022 Final Butte Priority Soils Operable Unit Interim Site-Wide Surface Water Monitoring Quality Assurance Project Plan, Trec Inc., A Woodard And Curran Company

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.


Silver Bow Creek/Butte Area Npl Site, Trec Inc., A Woodard And Curran Company Nov 2021

Silver Bow Creek/Butte Area Npl Site, Trec Inc., A Woodard And Curran Company

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.


Silver Bow Creek/Butte Area Npl Site 2022 Draft Butte Priority Soils Operable Unit Interim Site-Wide Groundwater Monitoring Quality Assurance Project Plan (Qapp), 11/16/21, Nikia Greene Nov 2021

Silver Bow Creek/Butte Area Npl Site 2022 Draft Butte Priority Soils Operable Unit Interim Site-Wide Groundwater Monitoring Quality Assurance Project Plan (Qapp), 11/16/21, Nikia Greene

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.


Sbc/Butte Area Npl Site Final Bpsou Interim Site-Wide Surface Water Monitoring Qapp 2020 And 2021 Monitoring Period, 10/14/20, Nikia Greene Nov 2021

Sbc/Butte Area Npl Site Final Bpsou Interim Site-Wide Surface Water Monitoring Qapp 2020 And 2021 Monitoring Period, 10/14/20, Nikia Greene

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.


Charge Transport In Dielectric: The Pulsed Electroacoustic Method, Zachary Gibson Nov 2021

Charge Transport In Dielectric: The Pulsed Electroacoustic Method, Zachary Gibson

Physics Student Research

Understanding and predicting charge accumulation and transport in dielectric materials is vital in applications where excess charge can accumulate including semiconductor devices, high-power electronic devices, high voltage DC cabling, high-energy physics facilities, plasma chambers, and spacecraft charging. Excess charge accumulation may result in electrostatic discharge events, which are the leading cause of spacecraft failure due to the space environment. The pulsed electroacoustic method allows you to “pop the hood” and non-destructively directly measure the embedded charge distributions in dielectric materials. Charge transport in disordered dielectric materials, measurements with the pulsed electroacoustic system, and comparison to models will be presented.


Automated Classification Model With Otsu And Cnn Method For Premature Ventricular Contraction Detection, Liang-Hung Wang, Lin-Juan Ding, Chao-Xin Xie, Su-Ya Jiang, I-Chun Kuo, Xin-Kang Wang, Jie Gao, Pao-Cheng Huang, Patricia Angela R. Abu Nov 2021

Automated Classification Model With Otsu And Cnn Method For Premature Ventricular Contraction Detection, Liang-Hung Wang, Lin-Juan Ding, Chao-Xin Xie, Su-Ya Jiang, I-Chun Kuo, Xin-Kang Wang, Jie Gao, Pao-Cheng Huang, Patricia Angela R. Abu

Department of Information Systems & Computer Science Faculty Publications

Premature ventricular contraction (PVC) is one of the most common arrhythmias which can cause palpitation, cardiac arrest, and other symptoms affecting the work and rest activities of a patient. However, patients hardly decipher their own feelings to determine the severity of the disease thus, requiring a professional medical diagnosis. This study proposes a novel method based on image processing and convolutional neural network (CNN) to extract electrocardiography (ECG) curves from scanned ECG images derived from clinical ECG reports, and segment and classify heartbeats in the absence of a digital ECG data. The ECG curve is extracted using a comprehensive algorithm …


Distinct Circadian Assessments From Wearable Data Reveal Social Distancing Promoted Internal Desynchrony Between Circadian Markers, Yitong Huang, Caleb Mayer, Olivia J. Walch, Clark Bowman, Srijan Sen, Cathy Goldstein, Jonathan Tyler, Daniel B. Forger Nov 2021

Distinct Circadian Assessments From Wearable Data Reveal Social Distancing Promoted Internal Desynchrony Between Circadian Markers, Yitong Huang, Caleb Mayer, Olivia J. Walch, Clark Bowman, Srijan Sen, Cathy Goldstein, Jonathan Tyler, Daniel B. Forger

Mathematics Sciences: Faculty Publications

Mobile measures of human circadian rhythms (CR) are needed in the age of chronotherapy. Two wearable measures of CR have recently been validated: one that uses heart rate to extract circadian rhythms that originate in the sinoatrial node of the heart, and another that uses activity to predict the laboratory gold standard and central circadian pacemaker marker, dim light melatonin onset (DLMO). We first find that the heart rate markers of normal real-world individuals align with laboratory DLMO measurements when we account for heart rate phase error. Next, we expand upon previous work that has examined sleep patterns or chronotypes …


Silver Bow Creek Butte Area Npl Site 2022 Draft Butte Priority Soils Operable Unit Interim Site-Wide Surface Water Monitoring Quality Assurance Project Plan. Consent Decree- Civil Action No. Cv 89-039-Bu-She, Josh Bryson Nov 2021

Silver Bow Creek Butte Area Npl Site 2022 Draft Butte Priority Soils Operable Unit Interim Site-Wide Surface Water Monitoring Quality Assurance Project Plan. Consent Decree- Civil Action No. Cv 89-039-Bu-She, Josh Bryson

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.


2022 Draft Butte Priority Soils Operable Unit Interim Site-Wide Surface Water Monitoring Quality Assurance Project Plan (Qapp), Trec Inc., A Woodard And Curran Company Nov 2021

2022 Draft Butte Priority Soils Operable Unit Interim Site-Wide Surface Water Monitoring Quality Assurance Project Plan (Qapp), Trec Inc., A Woodard And Curran Company

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.


Provenance: An Intermediary-Free Solution For Digital Content Verification, Bilal Yousuf, M. Atif Qureshi, Brendan Spillane, Gary Munnelly, Oisin Carroll, Matthew Runswick, Kirsty Park, Eileen Culloty, Owen Conlan, Jane Suiter Nov 2021

Provenance: An Intermediary-Free Solution For Digital Content Verification, Bilal Yousuf, M. Atif Qureshi, Brendan Spillane, Gary Munnelly, Oisin Carroll, Matthew Runswick, Kirsty Park, Eileen Culloty, Owen Conlan, Jane Suiter

Articles

The threat posed by misinformation and disinformation is one of the defining challenges of the 21st century. Provenance is designed to help combat this threat by warning users when the content they are looking at may be misinformation or disinformation. It is also designed to improve media literacy among its users and ultimately reduce susceptibility to the threat among vulnerable groups within society. The Provenance browser plugin checks the content that users see on the Internet and social media and provides warnings in their browser or social media feed. Unlike similar plugins, which require human experts to provide evaluations and …


Blue Crab In The New York Area As An Indicator For Climate Change, Adelle Molina Nov 2021

Blue Crab In The New York Area As An Indicator For Climate Change, Adelle Molina

Sustainability Seminar Series

In the northeast US, winters are getting warmer, shorter, and milder due to climate change. It is hypothesized that populations of some species near their northern range limit may experience elevated population growth rates owing to lower mortality in winter, higher growth rates in summer, and the synergistic relationship between these physiological processes. Blue crabs (Callinectes sapidus) in New York estuaries are close to their northern range edge and are potentially climate “winners” in this region. To provide advice to managers, we monitored blue crab populations in a coastal, lagoonal estuary and used a combined modeling approach to simulate the …


Advances In Rhizobial Research – Progress Priorities In Temperate Areas, Angela Sessitsch Nov 2021

Advances In Rhizobial Research – Progress Priorities In Temperate Areas, Angela Sessitsch

IGC Proceedings (1977-2023)

Rhizobia are well known for their capacity to establish a symbiosis with legumes. During this symbiosis the bacteria inhabit root nodules where they reduce atmospheric nitrogen and make it available to the plant. Biological nitrogen fixation (BNF) is an important source of nitrogen and the various legume crops and pasture species often fix as much as 200-300 kg nitrogen per hectare (Peoples et al., 1995). Globally, symbiotic nitrogen fixation has been estimated to amount to at least 70 million metric tons of nitrogen per year (Brockwell et al., 1995). Furthermore, in many cases nitrogen fertilizers are not efficiently used by …


The Legume – Rhizobia Symbiosis. Does It Vary For The Tropics Relative To The Mediterranean Basin?, J. G. Howieson, A. Mcinnes Nov 2021

The Legume – Rhizobia Symbiosis. Does It Vary For The Tropics Relative To The Mediterranean Basin?, J. G. Howieson, A. Mcinnes

IGC Proceedings (1977-2023)

Symbiotic N fixation from legumes is one of the most important biological processes on the planet. It currently provides the majority of the N requirement in agriculture, yet will have to double if cereal crop production is to meet world demand by 2020 (Kennedy and Cocking 1997). To effectively harness the value of biological N fixation from legumes we need to more fully understand G2 x E; where G refers to the genotypes of both the legume (Gl) and its microsymbiont (rhizobia; Gr), and E refers to the edaphic environment in which the symbiosis is …


Advances In Forage Legumes: Shrub Legumes, M. H. Shelton Nov 2021

Advances In Forage Legumes: Shrub Legumes, M. H. Shelton

IGC Proceedings (1977-2023)

Forage tree legumes benefit agriculture through their multi-purpose contributions to livestock feeding, to productivity of farming systems, and to protection of the environment.

Of the several hundred forage tree legume species regarded as having potential for forage only c. twenty are in common use. These are listed together with their agroecological range and tolerance of adverse environments including acid soils, cool temperatures, low rainfall, poor drainage and high salinity. The value of many species to ruminants is limited due to low nutritive value arising from low protein availability and low acceptability caused principally by high condensed tannin content. Only 10 …


Alfalfa, J. H. Bouton Nov 2021

Alfalfa, J. H. Bouton

IGC Proceedings (1977-2023)

Cultivated alfalfa or lucerne (Medicago sativa spp. sativa) is the most important forage legume in the world with approximately 32 million hectares cultivated mainly in the temperate regions of both the northern and southern hemispheres. Intensive research has been conducted on the management and physiology of the crop and a major seed industry has developed world wide. Since insect and disease pests are numerous in alfalfa, development of cultivars with the proper fall dormancy and a broad genetic base for pest resistance has been pursued in order to provide increased adaptation, persistence, and yield. There has been a …


Carbon And Nitrogen Isotopic Discrimination In Alfalfa For High Yield And Quality Forage, W. S. Oliveira, P. P. A. Oliveira, M. Corsi, S. M. Tsai Nov 2021

Carbon And Nitrogen Isotopic Discrimination In Alfalfa For High Yield And Quality Forage, W. S. Oliveira, P. P. A. Oliveira, M. Corsi, S. M. Tsai

IGC Proceedings (1977-2023)

Biological nitrogen fixation and assimilation of CO2 can be indirectly monitored in alfalfa (Medicago sativa L.) through the variation of the stable N and C isotopes in the plant (Δ values). Such measurements result in a simple, non-destructive and reliable method for identification of alfalfa cultivars of high yield and nutritional quality. A program for selection of 12 alfalfa cultivars under field and controlled conditions (lysimeters) included determination of biomass and N accumulation. Under controlled conditions yields ranged from 1.77 to 2.47 ton/ha/month (Pioneer 5312 and WL-605) and N2-fixed varied from 77.43 to 84.01% for total N (Brazilian …


A Complete Characterisation Of Vertex-Multiplications Of Trees With Diameter 5, Willie Han Wah Wong, Eng Guan Tay Nov 2021

A Complete Characterisation Of Vertex-Multiplications Of Trees With Diameter 5, Willie Han Wah Wong, Eng Guan Tay

Theory & Applications of Graphs

For a connected graph G, let D(G) be the family of strong orientations of G; and for any D ∈ D(G), we denote by d(D) the diameter of D. The orientation number of G is defined as d(G)=min{d(D) | D ∈ D(G)}. In 2000, Koh and Tay introduced a new family of graphs, G vertex-multiplications, and extended the results on the orientation number of complete n-partite graphs. Suppose G has the vertex set V(G)={v1,v2,… vn}. For any sequence of n positive integers (s …


Optimal Design Problems With State Constraints, Nha Van Tran Nov 2021

Optimal Design Problems With State Constraints, Nha Van Tran

LSU Doctoral Dissertations

This thesis focuses on constrained optimization problems with constraints on the state variables. When the constraints involve partial differential equations or variational inequalities, the optimization problem is also known as Mathematical Programs with Equilibrium Constraints. First, we applied active-set properties of optimal solutions to transform variational inequality constraints into partial differential equation constraints and devised an active-set method which allowed us to solve the optimization problems using the adjoint approach. We extended our approach to evolution problems with constraints on the trajectory of the state variable, such as the irreversibility condition in fracture mechanics. We implemented a gradient descent algorithm …


3-Dimensional Structural Determination Of Epidermal Growth Factor-Like Repeat 27 From Mouse Notch1 Using Nuclear Magnetic Resonance Spectroscopy, Justin Grennell Nov 2021

3-Dimensional Structural Determination Of Epidermal Growth Factor-Like Repeat 27 From Mouse Notch1 Using Nuclear Magnetic Resonance Spectroscopy, Justin Grennell

LSU Doctoral Dissertations

NOTCH1 has been associated with a variety of human ailments, such as cancer and heart disease. NOTCH1 is a transmembrane protein that contains 36 epidermal growth factor-like (EGF) repeats, which facilitate cell signaling by binding proteins on neighboring cells. Each repeat contains about 40 amino acids and has to be folded in a specific manner to function properly. The amino acid sequence, carbohydrate pattern, and calcium-binding sites of EGF-like repeats vary, but the pattern along the 36-repeat chain is conserved. The Abruptex region (EGF24-29) of NOTCH1 is a highly glycosylated (having undergone sugar addition) and flexible region, which gained its …


Mgrre_Pureoilscouttickets_Kyncl, Jos & Marie_1_21127118890000, Mgrre Nov 2021

Mgrre_Pureoilscouttickets_Kyncl, Jos & Marie_1_21127118890000, Mgrre

Legacy Scout Tickets from Pure Oil Company

No abstract provided.


A 6-Cpg Validated Methylation Risk Score Model For Metabolic Syndrome: The Hypergen And Goldn Studies, Bertha A. Hidalgo, Bre Minniefield, Amit Patki, Rikki Tanner, Minoo Bagheri, Hemant K. Tiwari, Donna K. Arnett, Marguerite Ryan Irvin Nov 2021

A 6-Cpg Validated Methylation Risk Score Model For Metabolic Syndrome: The Hypergen And Goldn Studies, Bertha A. Hidalgo, Bre Minniefield, Amit Patki, Rikki Tanner, Minoo Bagheri, Hemant K. Tiwari, Donna K. Arnett, Marguerite Ryan Irvin

Epidemiology and Environmental Health Faculty Publications

There has been great interest in genetic risk prediction using risk scores in recent years, however, the utility of scores developed in European populations and later applied to non-European populations has not been successful. The goal of this study was to create a methylation risk score (MRS) for metabolic syndrome (MetS), demonstrating the utility of MRS across race groups using cross-sectional data from the Hypertension Genetic Epidemiology Network (HyperGEN, N = 614 African Americans (AA)) and the Genetics of Lipid Lowering Drugs and Diet Network (GOLDN, N = 995 European Americans (EA)). To demonstrate this, we first selected cytosine-guanine dinucleotides …


An Efficient High-Order Meshless Method For Advection-Diffusion Equations On Time-Varying Irregular Domains, Varun Shankar, Grady B. Wright, Aaron L. Fogelson Nov 2021

An Efficient High-Order Meshless Method For Advection-Diffusion Equations On Time-Varying Irregular Domains, Varun Shankar, Grady B. Wright, Aaron L. Fogelson

Mathematics Faculty Publications and Presentations

We present a high-order radial basis function finite difference (RBF-FD) framework for the solution of advection-diffusion equations on time-varying domains. Our framework is based on a generalization of the recently developed Overlapped RBF-FD method that utilizes a novel automatic procedure for computing RBF-FD weights on stencils in variable-sized regions around stencil centers. This procedure eliminates the overlap parameter δ, thereby enabling tuning-free assembly of RBF-FD differentiation matrices on moving domains. In addition, our framework utilizes a simple and efficient procedure for updating differentiation matrices on moving domains tiled by node sets of time-varying cardinality. Finally, advection-diffusion in time-varying domains …


Discovery Of Imidazole-Based Inhibitors Of Plasmodium Falciparum Cgmp-Dependent Protein Kinase, Rammohan R. Yadav Bheemanaboina, Mariana Laureano De Souza, Mariana Lozano Gonzalez, Shams Ul Mahmood, Tyler Eck, Tamara Kreiss, Samantha O. Aylor, Alison Roth, Patricia Lee, Brandon S. Pybus, Dennis J. Colussi, Wayne E. Childers, John Gordon, John J. Siekierka, Purnima Bhanot, David P. Rotella Nov 2021

Discovery Of Imidazole-Based Inhibitors Of Plasmodium Falciparum Cgmp-Dependent Protein Kinase, Rammohan R. Yadav Bheemanaboina, Mariana Laureano De Souza, Mariana Lozano Gonzalez, Shams Ul Mahmood, Tyler Eck, Tamara Kreiss, Samantha O. Aylor, Alison Roth, Patricia Lee, Brandon S. Pybus, Dennis J. Colussi, Wayne E. Childers, John Gordon, John J. Siekierka, Purnima Bhanot, David P. Rotella

Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works

The discovery of new targets for the treatment of malaria, in particular those aimed at the pre-erythrocytic stage in the life cycle, advanced with the demonstration that orally administered inhibitors of Plasmodium falciparum cGMP-dependent protein kinase (PfPKG) could clear infection in a murine model. This enthusiasm was tempered by unsatisfactory safety and/or pharmacokinetic issues found with these chemotypes. To address the urgent need for new scaffolds, this paper presents initial structure–activity relationships in an imidazole scaffold at four positions, representative in vitro ADME, hERG characterization, and cell-based antiparasitic activity. This series of PfPKG inhibitors has good in vitro PfPKG potency, …


Molecular Design Of Polymer Coatings Capable Of Photo-Triggered Stress Relaxation Via Dynamic Covalent Bond Exchange, Autumn M. Mineo, Maren E. Buck, Reika Katsumata Nov 2021

Molecular Design Of Polymer Coatings Capable Of Photo-Triggered Stress Relaxation Via Dynamic Covalent Bond Exchange, Autumn M. Mineo, Maren E. Buck, Reika Katsumata

Chemistry: Faculty Publications

Polymer coatings are frequently used to modify surface properties of inorganic substrates. However, the disparity in physical properties between polymer film and substrate often leads to residual stress development, which can be deleterious to the overall performance of coated materials. This work reports the molecular design of polymer films that dissipate stress upon irradiation with ultraviolet (UV) light. These polymers are synthesized by post-polymerization modification of the reactive polymer, poly(2-vinyl-4,4-dimethyl azlactone), to introduce dynamic crosslinks capable of light-initiated addition transfer fragmentation chemistry. Using a custom-built optical cantilever, contrasting film stress responses are observed between films containing dynamic bonds and analogous …


Peruvian Fur Seals As Archivists Of El Niño Southern Oscillation Effects, Mickie Rae Edwards, Susana Cardenas-Alayza, Michael Adkesson, Mya Daniels-Abdulahad, Amy Hirons Nov 2021

Peruvian Fur Seals As Archivists Of El Niño Southern Oscillation Effects, Mickie Rae Edwards, Susana Cardenas-Alayza, Michael Adkesson, Mya Daniels-Abdulahad, Amy Hirons

Marine & Environmental Sciences Faculty Articles

Peru’s coastal waters are characterized by significant environmental fluctuation due to periodic El Niño- La Niña- Southern Oscillation (ENSO) events. This variability results in ecosystem-wide food web changes which are reflected in the tissues of the Peruvian fur seal (Arctocephalus australis). Stable isotope ratios (δ13C and δ15N) in Peruvian fur seal vibrissae (whiskers) are used to infer temporal primary production and dietary variations in individuals. Sea surface temperature anomaly (SSTA) recordings from the Niño 1+2 Index region captured corresponding ENSO conditions. Fluctuations in δ15N values were correlated to SSTA records, indicating that …


All-Sky Search For Long-Duration Gravitational-Wave Bursts In The Third Advanced Ligo And Advanced Virgo Run, Ligo Scientific Collaboration, Virgo Collaboration, Kagra Collaboration, Tiffany Z. Summerscales Nov 2021

All-Sky Search For Long-Duration Gravitational-Wave Bursts In The Third Advanced Ligo And Advanced Virgo Run, Ligo Scientific Collaboration, Virgo Collaboration, Kagra Collaboration, Tiffany Z. Summerscales

Faculty Publications

After the detection of gravitational waves from compact binary coalescences, the search for transient gravitational-wave signals with less well-defined waveforms for which matched filtering is not well suited is one of the frontiers for gravitational-wave astronomy. Broadly classified into “short” ≲1  s and “long” ≳1  s duration signals, these signals are expected from a variety of astrophysical processes, including non-axisymmetric deformations in magnetars or eccentric binary black hole coalescences. In this work, we present a search for long-duration gravitational-wave transients from Advanced LIGO and Advanced Virgo’s third observing run from April 2019 to March 2020. For this search, we use …


Cognizant Composites: Seamless Integration Of Circuitry And Sensors Into Structural Composites, Reuben Fresquez Nov 2021

Cognizant Composites: Seamless Integration Of Circuitry And Sensors Into Structural Composites, Reuben Fresquez

Computer Science ETDs

This thesis describes a set of novel techniques for embedding sensors, circuitry, and electronics into structural composites. I leverage recent developments in human computer interaction to create sensors and circuitry that are seamlessly incorporated into structural composites. I fabricate bend and compression sensors, along with circuitry, from textiles, which enables me to add electronic capabilities without impacting the composite’s structural integrity. I describe the construction of these “cognizant composites” and demonstrate their functionality. I also explore techniques for embedding standard electronic components, including microcontrollers, into structural composites. Potential applications of this technology include buildings that can warn occupants if load-bearing …


Lignin, Sugar, And Furan Production Of Industrial Hemp Biomass Via An Integrated Process, Jikai Zhao, Jason Griffin, Kraig Roozeboom, Juhee Lee, Donghai Wang Nov 2021

Lignin, Sugar, And Furan Production Of Industrial Hemp Biomass Via An Integrated Process, Jikai Zhao, Jason Griffin, Kraig Roozeboom, Juhee Lee, Donghai Wang

School of Earth, Environmental, & Marine Sciences Faculty Publications

Traditional pretreatment of lignocellulosic biomass is often accompanied by washing and disposal of wastewater, which leads to overuse of water and loss of by-products. The objectives of this study were to validate the potential of an acid-base integrated process for simultaneous sugars, furans, and lignin production without washing and wastewater discarding. The difference in conversion performance among different biomass resources was also demonstrated. Parallel acetic acid (HOAc, pH = 2.25) and sodium hydroxide (NaOH, pH = 13.46) pretreatments followed by solid and liquid integration were applied to four genotypes of industrial hemp (Cannabis sativa L.) biomass that were harvested …


Reducing Kidney Discard With Artificial Intelligence Decision Support: The Need For A Transdisciplinary Systems Approach, Richard Threlkeld, Lirim Ashiku, Casey I. Canfield, Daniel Burton Shank, Mark A. Schnitzler, Krista L. Lentine, David A. Axelrod, Anil Choudary Reddy Battineni, Henry Randall, Cihan H. Dagli Nov 2021

Reducing Kidney Discard With Artificial Intelligence Decision Support: The Need For A Transdisciplinary Systems Approach, Richard Threlkeld, Lirim Ashiku, Casey I. Canfield, Daniel Burton Shank, Mark A. Schnitzler, Krista L. Lentine, David A. Axelrod, Anil Choudary Reddy Battineni, Henry Randall, Cihan H. Dagli

Engineering Management and Systems Engineering Faculty Research & Creative Works

Purpose of Review: A transdisciplinary systems approach to the design of an artificial intelligence (AI) decision support system can more effectively address the limitations of AI systems. By incorporating stakeholder input early in the process, the final product is more likely to improve decision-making and effectively reduce kidney discard.

Recent Findings: Kidney discard is a complex problem that will require increased coordination between transplant stakeholders. An AI decision support system has significant potential, but there are challenges associated with overfitting, poor explainability, and inadequate trust. A transdisciplinary approach provides a holistic perspective that incorporates expertise from engineering, social science, and …


The Profound Photophysical Effects Of Organic Chromophore Connectivity And Coupling, David J. Walwark Jr Nov 2021

The Profound Photophysical Effects Of Organic Chromophore Connectivity And Coupling, David J. Walwark Jr

Nanoscience and Microsystems ETDs

Through-bond and through-space interactions between chromophores are shown to have wide-ranging effects on photophysical outcomes upon light absorption in organic molecules. In collapsed poly(3-hexylthiophene), through-space coupling creates hybrid chromophores that act as energy sinks for nearby excitons and favorable sites for molecular oxygen to dock. Upon excitation with visible light the highly-coupled chromophores react with the docked oxygen and subsequently do not quench nearby excitons as efficiently. In tetramer arrays of perylene diimide chromophores the central moiety through-bond connectivity is synthesized in two variants which exhibit vastly different single-molecule blinking behavior and theoretically-predicted electronic transition character. In the more-connected tetramer …