Physical Sciences and Mathematics Commons^™

Synthesis Of Phosphonate-Based Diimide Ligands, Kenya V. Medina

Honors Program Theses and Research Projects

There has been a resurged interest in the synthesis of metal-organic frameworks because of their potential applications in energy production and drug delivery. Although diimides are insoluble in aqueous solutions, the addition of phosphonic acid allows the complex to be water soluble, which greatly increases their application. Therefore, the creation of a hybrid metal-organic complex by the addition of phosphonic groups to diimide ligands can result in a polar porous compound. In this project the ligand design included the use of dianhydrides including pyromellitic dianhydride, naphthalenetetracarboxylic dianhydride, perylenetetracarboxylic dianhydride, and biphenyl-tetracarboxylic acid dianhydride. These dianhydride precursors were refluxed under argon …

Escherichia Coli Alanyl-Trna Synthetase Maintains Proofreading Activity And Translational Accuracy Under Oxidative Stress, Arundhati Kavoor, Paul Kelly, Michael Ibba

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Aminoacyl-tRNA synthetases (aaRSs) are enzymes that synthesize aminoacyl-tRNAs to facilitate translation of the genetic code. Quality control by aaRS proofreading and other mechanisms maintains translational accuracy, which promotes cellular viability. Systematic disruption of proofreading, as recently demonstrated for alanyl-tRNA synthetase (AlaRS), leads to dysregulation of the proteome and reduced viability. Recent studies showed that environmental challenges such as exposure to reactive oxygen species can also alter aaRS synthetic and proofreading functions, prompting us to investigate if oxidation might positively or negatively affect AlaRS activity. We found that while oxidation leads to modification of several residues in Escherichia coli AlaRS, unlike …

Delaunay Walk For Fast Nearest Neighbor: Accelerating Correspondence Matching For Icp, James D. Anderson, Ryan M. Raettig, Joshua Larson, Clark N. Taylor, Thomas Wischgoll

Faculty Publications

Point set registration algorithms such as Iterative Closest Point (ICP) are commonly utilized in time-constrained environments like robotics. Finding the nearest neighbor of a point in a reference 3D point set is a common operation in ICP and frequently consumes at least 90% of the computation time. We introduce a novel approach to performing the distance-based nearest neighbor step based on Delaunay triangulation. This greedy algorithm finds the nearest neighbor of a query point by traversing the edges of the Delaunay triangulation created from a reference 3D point set. Our work integrates the Delaunay traversal into the correspondences search of …

America's Urban Sustainability Agenda: Advancing A Climate Of Hope, H. James Quigley Jr.

Sustainability Seminar Series

The 20th century in the USA was characterized, among other things, by historic national movements: feminism and women's suffrage; the labor movement; civil rights; the peace movement; and the environment. Indeed, the highly pronounced trends today in urban areas of all sizes around the country of a commitment to green our architecture while expanding public housing, conserve energy, further develop renewable energy resources, green public and private transportation, recover recyclable materials from the waste stream, expand parks and open space, advance public transportation, democratize food security, make public education and health care more comprehensive, improve urban air quality, and more …

Silage Preparation And Fermentation Characteristics Of Pearl Millet Stover Treated With Microbial Additive In West Africa, Y. Cai, Z. Du, S. Yamasaki, D. Jethro, M. Nignan

IGC Proceedings (1977-2023)

Pearl millet (Pennisetum glaucum L.) stover is one of the main crop by-products in West Africa. To effectively use the crop by-product resources as roughage for ruminant to cover the feed shortage in the dry season, the millet stover silage was prepared using laboratory-scale fermentation system without (control) or with lactic acid bacteria inoculant (LP, Lactobacillus plantarum) and cellulase enzyme (AC, Acremonium) in Burkina Faso, and their fermentation characteristics and chemical composition were analyzed. The dry matter (DM) of fresh millet before ensiling was 44.3%, and their organic matter, crude protein (CP), ether extract, neutral detergent fiber …

Seasonal Patterns Of Herbage Accumulation Dynamics In Marandu Palisadegrass Subjected To Intensities Of Continuous Stocking Management, André F. Sbrissia, Daniel Schmitt, Paulo G. Duchini, Sila C. Da Silva

IGC Proceedings (1977-2023)

It is relatively well reported in the literature that pastures can have similar forage net accumulation when managed with contrasting structures. However, we hypothesized that the patterns of forage accumulation dynamics of pastures managed at different canopy heights is dependent on environmental conditions. The experimental treatments were four canopy heights (10, 20, 30, and 40 cm), allocated to experimental units according to a randomized complete block design with four replicates and evaluated throughout four contrasting environmental seasons (Summer, Autumn, Winter-Early Spring, and Late Spring). Under favourable growing conditions greater forage accumulation was observed in pastures maintained taller; on the contrary, …

Screening Of Napier Grass (Pennisetum Purpureum Schumac.) Clones For Stunt Disease In Western Kenya, Caroline A. O. Kute

IGC Proceedings (1977-2023)

Napier stunt disease (NSD) is a threat to Napier grass farming in the smallholder dairy industry in east and central Africa. NSD in Kenya is caused by Candidatus Phytoplasma oryzae (Ns-phytoplasma) belonging to the 16SrXI group; vectored by a leaf hopper Maiestas banda. The objective of the study was to determine the incidence (proportion of diseased leaves) and severity (proportion of leaf area diseased [PLAD]) of stunt disease in Napier clones by screening in Bungoma, Kakamega and Busia Counties in Western Kenya. The Napier clones were germplasm collections maintained at KALRO Kitale and Muguga nurseries and in farmers’ fields. …

Revisiting Nitrogen Fertilisation Rates Of Kikuyu And Kikuyu-Ryegrass Pastures, C. Viljoen, Janke Van Der Colf, Pieter A. Swanepoel

IGC Proceedings (1977-2023)

Irrigated pastures are used for dairy production in South Africa. Minimum-tillage and nitrogen (N) fertilisation are important management practices for kikuyu (Pennisetum clandestinum) and ryegrass (Lolium spp.) pastures. Nitrogen fertiliser application rates as high as 500 kg N ha^-1 year^-1 have been reported. Conventional tillage as well as cutting and removal of herbage material (opposed to removal through grazing) are the basis on which these fertiliser guidelines were developed. The current management practices have substantially changed the soil organic carbon and N stoichiometry. The aim of this study was to determine an optimum rate of …

Review Of Urochloa Breeder’S Toolbox With The Theory Of Change And Stage Gate System Approach, E. Sweitzer, L. Hernandez, D. Florian, A. Notenbaert, S. Burkart, J. Arango, J. Cardoso, M. Peters, V. Castiblanco

IGC Proceedings (1977-2023)

Livestock production in the global south is at crossroads as there is a demand to increase Animal Source Foods to address hunger and pressure to lighten the environmental footprint often associated with livestock production. To satisfy both needs, the use of technologies that improve animal performance, while reducing land use and net Greenhouse Gas emissions produced by animals is essential. One of such technologies are Urochloa forage grasses.

Urochloa forage grasses are well known for their rusticity and their ability to grow in soils of low fertility and high aluminum content. These characteristics allow Urochloa to grow in areas temporally …

Residual Feed Intake (Rfi) And Efficiency Of Feed Utilization (Efu) Of Total Mixed Ration (Tmr) Fed Frisian Cross Bred Cows – A Case Study, S. C. Somasiri, A. M. C. S. Karunarathna

IGC Proceedings (1977-2023)

Residual Feed Intake (RFI) is the difference between an animal’s actual feed and expected feed intakes for a given period of time. Literature shows that highly efficient animals have a negative or lower RFI. Thus understanding about RFI is important to maintain an efficient herd. A feeding trial was undertaken at a commercial farm in Sri Lanka having Frisian cross bred cows. The cows were fed with a grass-based Total Mixed Ration (TMR) having maize (Zea mays), CO3 (Pennisetum perpureum X Pennisetum americarnum), beer pulp (wet brewer’s grain), dhal meal (Lens culinaris), mineral mixture …

Mgrre_Thinsections_Mgrre-83_2, Mgrre

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