Physical Sciences and Mathematics Commons^™

Characterization Of Functionalized Carbon Nanotubes And Polystyrene/Cnt Composites Prepared With Microwave-Induced Polymerization, Allen Hulette

College of Graduate Studies: Theses & Dissertations

The use of carbon nanotubes in polymer composites can increase the mechanical properties of the resulting product. Carbon nanotubes are known to have chemical interactions that make them attracted to one another and fall out of solution. To reduce this agglomeration and disperse the mechanical properties throughout the composite, functional groups are covalently added to the carbon nanotubes. Another known property of carbon nanotubes is their ability to absorb microwaves and convert it into other forms of energy. This research investigates the effects of carbon nanotube absorption of microwaves and initiation of styrene monomer polymerization. Grignard reactions are used to …

Toward Novel Optical Functionalities Through Intelligent Photonic Structure Design, Robert J. Williamson

College of Graduate Studies: Theses & Dissertations

Photonic Metamaterials is a branch of electromagnetism that has been of great interest in recent years. This is further enhanced by the introduction of micro- and nanofabrication methods capable of producing metamaterial structures with which it is possible to create specific optical phenomena. The study of iso-frequency k-surfaces is of importance when discussing optical interactions with media. Previous research found evidence of materials exhibiting k-surfaces of bi-hyperbolic nature, though they failed to find any further hyperboloid dispersions. In this thesis we describe the k-surface topologies and including tri- and tetra-hyperbolic as well as analyze the polariton-interactions that cause these hyperbolic …

Non-Inferiority Testing: Kernel Estimation And Overlap Measure, Larie C. Ward

College of Graduate Studies: Theses & Dissertations

In non-inferiority testing, the decision of whether a proposed treatment is non-inferior to a reference treatment depends on model assumptions and choices of acceptable tolerance limits. Here, we consider a method that employs kernels to estimate the probability density functions of both the experimental and reference populations from two independent samples. Based on these densities, we introduce a quantity called the overlap coefficient or overlap measure. A bootstrap technique is helpful in exploring the distribution and variance empirically. We derive the distribution of this measure and define a hypothesis test that can be applied to the non-inferiority setting under some …

Synthesis And Characterization Of Multimetallic Clusters Featuring Iron, Cobalt, And 2,6-Bis(Trialkylsilylamino)Pyridines, Lynn Nguyen

College of Graduate Studies: Theses & Dissertations

Extended metal atom chain (EMAC) complexes are multimetallic complexes of three or more metals, often containing M-M bonds, with the metal ions arranged linearly. These complexes have significant potential as molecular wires. They can elicit unique physical properties and reactivities, sometimes a result of direct magnetic exchange between metal centers, especially when incorporating first row transition metals. The synthesis of the first linear, triiron (II) complex with 2,6-bis[(trimethylsilyl)amino]pyridine (H₂L^Me) featuring Fe-Fe bonding from our group, Fe₃L^Me₃, motivated the expansion of linear multimetallic EMAC complexes with Fe and Co, incorporating M-M bonds. …

Eeg Signals Classification Using Lstm-Based Models And Majority Logic, James A. Orgeron

College of Graduate Studies: Theses & Dissertations

The study of elecroencephalograms (EEGs) has gained enormous interest in the last decade with the increase of computational power and availability of EEG signals collected from various human activities or produced during medical tests. The applicability of analyzing EEG signals ranges from helping impaired people communicate or move (using appropriate medical equipment) to understanding people's feelings and detecting diseases.

We proposed new methodology and models for analyzing and classifying EEG signals collected from individuals observing visual stimuli. Our models rely on powerful Long-Short Term Memory (LSTM) Neural Network models, which are currently the state of the art models for performing …

Molybdenum Oxide/Antimony Nanobelts Embedded In Asymmetric Membranes For Use As High-Capacity Lithium/Sodium-Ion Battery Anodes, Logan Williams

College of Graduate Studies: Theses & Dissertations

Lithium-ion batteries (LIB) are a key aspect of our daily lives, from smartphones to electric vehicles. Commercially available LIB use graphite anodes due to their reliability and safety. Graphite anodes present one key disadvantage: a relatively low theoretical capacity of 372 mAh g-1. It is of great importance that new research focuses on high-capacity anode materials to further our sustainability and usage of LIB. While increasing the performance of LIB is of great interest, developing alternative energy storage devices is gaining attention in academia and industry R&D. Sodium has become a topic of interest in recent years due to sodium’s …

Modelling Muscle Activation Using Emg Signal, Mercy U. Okonna

College of Graduate Studies: Theses & Dissertations

(EMG) is a method for measuring muscle activity by an electrical signal, and is useful in studying motor control, postural control, and in physical therapy. A current research topic is creating an algorithm that can use the EMG signal to reliably classify a muscle as active or inactive. This thesis presents a classification algorithm for leg muscles with a single activation spike while walking. Time is rescaled into steps, which are identified using data from cameras measuring joint angles while walking. The algorithm is based on moving averages and a convex combination of mean signal strength in active and inactive …

Biomimetic Synthesis Of Palladium Nanoparticles For Catalytic Application, Emily A. Groover

College of Graduate Studies: Theses & Dissertations

The synthesis of palladium nanoparticles (Pd NPs) using materials-directed peptides is a novel, nontoxic approach which exerts a high level of control over the particle size and shape. This biomimetic technique is environmentally benign, featuring nonhazardous ligands and ambient conditions. Nanoparticles are extremely reactive catalysts, boasting a large surface-to-volume ratio when compared to their bulk counterparts. The rational design of these nanoparticles using peptides has been very successful in aqueous environments, but no research has been done to apply it in organic systems. As such, the biomimetic synthesis of Pd NPs in an organic system is here investigated, with ethanol …

Extractable Entanglement From A Euclidean Hourglass, Takanori Anegawa, Norihiro Iizuka, Daniel Kabat

Publications and Research

We previously proposed that entanglement across a planar surface can be obtained from the partition function on a Euclidean hourglass geometry. Here we extend the prescription to spherical entangling surfaces in conformal field theory. We use the prescription to evaluate log terms in the entropy of a conformal field theory in two dimensions, a conformally coupled scalar in four dimensions, and a Maxwell field in four dimensions. For Maxwell we reproduce the extractable entropy obtained by Soni and Trivedi. We take this as evidence that the hourglass prescription provides a Euclidean technique for evaluating extractable entropy in quantum field theory.

Superluminal Propagation On A Moving Braneworld, Brian Greene, Daniel Kabat, Janna Levin, Arjun S. Menon

Publications and Research

We consider a braneworld scenario in the simplest setting, M₄ × S¹, with a four-dimensional (4D) Minkowski metric induced on the brane, and establish the possibility of superluminal propagation. If the brane is at rest, the 4D Lorentz symmetry of the brane is exact, but if the brane is in motion, it is broken globally by the compactification. By measuring bulk fields, an observer on the brane sees a slice through a higher-dimensional field profile, which carries an imprint of the extra dimensions even when the brane is at rest. If the brane is in motion, we …

Defining Entanglement Without Tensor Factoring: A Euclidean Hourglass Prescription, Takanori Anegawa, Norihiro Iizuka, Daniel Kabat

Publications and Research

We consider entanglement across a planar boundary in flat space. Entanglement entropy is usually thought of as the von Neumann entropy of a reduced density matrix, but it can also be thought of as half the von Neumann entropy of a product of reduced density matrices on the left and right. The latter form allows a natural regulator in which two cones are smoothed into a Euclidean hourglass geometry. Since there is no need to tensor factor the Hilbert space, the regulated entropy is manifestly gauge invariant and has a manifest state-counting interpretation. We explore this prescription for scalar fields, …

Quark And Gluon Entanglement In The Proton On The Light Cone At Intermediate X, Adrian Dumitru, Eric Kolbusz

Publications and Research

In QCD with $N_c$ colors the antisymmetric valence quark color space singlet state $\sim \epsilon_{i_1\cdots i_{N_c}} |i_1,\cdots, i_{N_c}\rangle$ of the proton corresponds to the reduced density matrix $\rho_{ij}=(1/N_c) \delta_{ij}$ for a single color degree of freedom. Its degenerate spectrum of eigenvalues, $\lambda_i=1/N_c$, the purity $\tr \rho^2 = 1/N_c$, and the von Neumann entropy $S_\mathrm{vN}=\log(N_c)$ all indicate maximal entanglement of color. On the other hand, for $N_c\to\infty$ the spatial wave function of the proton factorizes into valence quark wave functions determined by a mean field [E. Witten, Nucl. Phys. B160, 57 (1979)] where there is no entanglement of spatial degrees of …

Bft2: A General Class Of 2d N = (0, 2) Theories, 3-Manifolds And Toric Geometry, Sebastían Franco, Xingyang Yu

Publications and Research

We introduce and initiate the study of a general class of 2d N = (0, 2) quiver gauge theories, defined in terms of certain 2-dimensional CW complexes on oriented 3- manifolds. We refer to this class of theories as BFT₂’s. They are natural generalizations of Brane Brick Models, which capture the gauge theories on D1-branes probing toric Calabi-Yau 4-folds. The dynamics and triality of the gauge theories translate into simple transformations of the underlying CW complexes. We introduce various combinatorial tools for analyzing these theories and investigate their connections to toric Calabi-Yau manifolds, which arise as their …

Magnetoexcitons In Phosphorene Monolayers, Bilayers, And Van Der Waals Heterostructures, Roman Ya. Kezerashvili, Anastasia Spiridonova, Andrew Dublin

Publications and Research

We study direct and indirect excitons in Rydberg states in phosphorene monolayers, bilayers, and van der Waals (vdW) heterostructure in an external magnetic field within the framework of the effective-mass approximation. The magnetic field is applied perpendicular to the monolayer or heterostructure and is varied between 0 and 60 T. Binding energies of magnetoexcitons are calculated by numerical integration of the Schrödinger equation using the Rytova-Keldysh potential for direct magnetoexcitons and both the Rytova-Keldysh and Coulomb potentials for indirect magnetoexcitons. The latter aids in the understanding of the role of screening in phosphorene. We report the magnetic field energy contribution …

The Octagon At Large M, Riccardo Argurio, Matteo Bertolini, Sebastían Franco, Eduardo García-Valdecasas, Shani Meynet, Antoine Pasternak, Valdo Tatitscheff

Publications and Research

Recently, the first instance of a model of D-branes at Calabi-Yau singularities where supersymmetry is broken dynamically into stable vacua has been proposed. This construction was based on a system of N regular and M = 1 fractional branes placed at the tip of the so-called (orientifolded) Octagon singularity. In this paper we show that this model admits a large M generalization, having the same low energy effective dynamics. This opens up the possibility that the effect on geometry is smooth, and amenable to describing the gauge theory all along the RG flow, including the deep IR, in terms of …

Characterizing Changes In Extreme Ozone Levels Under 2050s Climate Conditions: An Extreme-Value Analysis In California, Bradley Wilson, Mariah Pope, Jeremy R. Porter, Edward Kearns, Evelyn Shu, Mark Bauer, Neil Freeman, Mike Amodeo, David Melecio-Vazquez, Ho Hsieh, Maggie Tarasovitch

Publications and Research

Ground-level ozone has a well established climate penalty associated with changing meteorological conditions under future climate change, but most existing research focuses exclusively on ozone-temperature relationships defined at specific locations. Using an extreme-value theory approach, we model relationships between temperature, humidity, and vapor pressure deficit and maximum daily 8 h ozone concentrations (MDA8) across California using a combination of ozone station network data and Community Multiscale Air Quality Modeling System (CMAQ) model output from 2008 to 2017. We use a spatial regression with time varying bias coefficients to fuse station observations and modeled output into a spatially explicit gridded ozone …

Strain‑Induced Quantum Hall Phenomena Of Excitons In Graphene, Oleg L. Berman, Roman Ya. Kezerashvili, Yurii E. Lozovik, Klaus G. Ziegler

Publications and Research

We study direct and indirect pseudomagnetoexcitons, formed by an electron and a hole in the layers of gapped graphene under strain‑induced gauge pseudomagnetic field. Since the train‑induced pseudomagnetic field acts on electrons and holes the same way, it occurs that the properties of single pseudomagnetoexcitons, their collective effects and phase diagram are cardinally different from those of magnetoexcitons in a real magnetic field. We have derived wave functions and energy spectrum of direct in a monolayer and indirect pseudomagnetoexcitons in a double layer of gapped graphene. The quantum Hall effect for direct and indirect excitons was predicted in the monolayers …

Simulation Of Urban Heat Island During A High-Heat Event Using Wrf Urban Canopy Models: A Case Study For Metro Manila, Ronald Gil Joy P. Bilang, Ariel C. Blanco, Justine Ace S. Santos, Lyndon Mark P. Olaguera

Physics Faculty Publications

This present study aims to determine the performance of using the Weather Research and Forecasting (WRF) Model, coupled with the urban canopy models (UCMs), in simulating the 2 m air temperature and 2 m relative humidity in Metro Manila. The simulation was performed during a high heat event on 22–29 April 2018, which coincided with the dry season in the Philippines. The four urban canopy model options that were used in this study include, the bulk (no urban), SLUCM, BEP, and BEM. The results of the simulations were compared with the hourly observations from three weather stations over Metro Manila …

A Modulated Structure Derived From The Xa-Type Mn2Rusn Heusler Compound, Xingzhong Li, Wen-Yong Zhang, Ralph Skomski, David J. Sellmyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

A modulated structure derived from the inverse Heusler phase (the XA-type and the disordered variant L2₁B-type) has been observed in rapidly quenched Mn2RuSn ribbons. The powder X-ray diffraction pattern of the quenched ribbons can be indexed as an L2₁B-type structure. Electron diffraction patterns of the new structure mostly resemble those of the XA-type (and the disordered variant L2₁B-type) structure and additional reflections with denser spacing indicate a long periodicity. Orthogonal domains of the modulated structure were revealed by a selected-area electron diffraction pattern and the corresponding dark-field transmission electron microscopy images. The structure was …

Localization Effects And Anomalous Hall Conductivity In A Disordered 3d Ferromagnet, Paul M. Shand, Y. Moua, G. Baker, Shah R. Valloppilly, Pavel V. Lukashev, Parashu Kharel

Nebraska Center for Materials and Nanoscience: Faculty Publications

We have prepared the Heusler alloy CoFeV_0.5Mn_0.5Si in bulk form via arc melting. CoFeV_0.5Mn_0.5Si is ferromagnetic with a Curie temperature of 657 K. The longitudinal resistivity exhibits a minimum at 150 K, which is attributable to competition between quantum interference corrections at low temperatures and inelastic scattering at higher temperatures. The magnetoresistance (MR) is positive and nearly linear at low temperatures and becomes negative at temperatures close to room temperature. The positive MR in the quantum correction regime is evidence of the presence of the enhanced electron interaction as a contributor to …

A Gis Analysis Of Potential Wetland Mitigation Opportunities In The Brandywine Creek Watershed, Chester County, Pennsylvania, Shannon Ryan

West Chester University Master’s Theses

Wetlands provide innumerous functions and values that are beneficial to both the natural environment and economic systems. Historically these habitats have suffered significant losses and it is crucial to preserve existing wetlands and plan for future restoration opportunities. This research examines six sub-watersheds within the Brandywine Creek watershed within Chester County, Pennsylvania to determine where potential wetland mitigation opportunities occur. Using a Geographic Information Systems (GIS) analysis, three wetland characteristics including watercourse locations, existing National Wetlands Inventory (NWI) wetlands, and hydric soils were mapped throughout each of the watersheds. Areas of agricultural easements and steep slopes were used to exclude …

Unique Lifting To A Functor, Mark Myers

West Chester University Master’s Theses

We develop a functorial approach to quotient constructions, defining morphisms quotient relative to a functor and the dual concept of unique liftings relative to a functor. Various classes of epimorphism are given detailed analysis and their relationship to quotient morphisms characterized. The behavior of unique lifting morphisms with respect to products, equalizers, and general limits in a category are studied. Applications to generalized covering space theory, coreflective subcategories of topological spaces, topological groups and rings, and Galois theory are explored. Finally, we give conditions for the product of two quotient morphisms to be quotient in a braided monoidal closed category.

Optimal Impulse Controls With Changing Running Cost And Applications In Mortgage Refinance, Yuchen Cao

Electronic Theses and Dissertations, 2020-2023

Almost all home buyers have mortgages and it is quite common to have mortgage refinanced. There are two main reasons that make people decide to refinance the mortgage: (i) need some cash for urgent purposes, and (ii) lower the monthly payment. In this dissertation, we are not going to discuss (i), and we are investigating problems related to (ii). To begin with, let us intuitively make the following observations: If the interest rate remains the same as the current mortgage interest rate, then the monthly payment will automatically lower if you start a new mortgage with the same term, say, …

Development Of An Hipsc-Cortical Neuron Long-Term Potentiation Model And Its Application To Alzheimer's Disease Modeling And Drug Evaluation, Kaveena Autar

Electronic Theses and Dissertations, 2020-2023

Alzheimer's disease (AD) is commonly characterized by a loss of cognitive function due to the deterioration of neuronal synapses from the presence of senile amyloid beta-42 (Aß42) plaques. Evaluating cognitive deficits caused by Aß42 using human cortical neurons poses a challenge due to sourcing difficulties, and the use of animal models to assess drug efficacy creates biological hurdles from lack of species translatability. Recent advances in induced-pluripotent stem cell technology have enabled the development of mature, human-based cortical neuron models. The development of an hiPSC-cortical neuron differentiation protocol facilitates the exploration of disease onset and functional analysis from a patient-derived …

Patterned Liquid Crystal Devices For Near-Eye Displays, Kun Yin

Electronic Theses and Dissertations, 2020-2023

As a promising next-generation display, augmented reality (AR) and virtual reality (VR) have shown attractive features and attracted broad interests from both academia and industry. Currently, these near-eye displays (NEDs) have enabled numerous applications, ranging from education, medical, entertainment, to engineering, with the help of compact and functional patterned liquid crystal (LC) devices. The interplay between LC patterns and NEDs stimulates the development of novel LC devices with unique surface alignments and volume structures, which in turn feedback to achieve more compact and versatile NEDs. This dissertation will focus on the patterned LC with applications in NEDs. Firstly, we propose …

Reverse Engineering Of Adversarial Samples By Leveraging Patterns Left By The Attacker, Rahul Ambati

Electronic Theses and Dissertations, 2020-2023

Intrinsic susceptibility of deep learning to adversarial examples has led to a plethora of attack techniques with a common broad objective of fooling deep models. However, we find slight compositional differences between the algorithms achieving this objective. These differences leave traces that provide important clues for attacker profiling in real-life scenarios. Inspired by this, we introduce a novel problem of 'Reverse Engineering of aDversarial attacks' (RED). Given an adversarial example, the objective of RED is to identify the attack used to generate it. Under this perspective, we can systematically group existing attacks into different families, leading to the sub-problem of …

A Novel Antibody-Dependent Mc-Lr Detecting Biosensor For Early Warning Of Harmful Algal Blooms (Habs), Stephanie Stoll

Electronic Theses and Dissertations, 2020-2023

Microcystins (MCs) are toxins produced by cyanobacteria commonly found in harmful algal blooms (HAB) occurring in many surface waters. Due to their toxicity to humans and other organisms, the World Health Organization (WHO) set a guideline of 1 µg/L for microcystin-leucine-arginine (MC-LR) in drinking water. However, current analytical techniques for the detection of MC-LR such as liquid chromatography-mass spectrometry (LC-MS) and enzyme-linked immunosorbent assay (ELISA) are costly, bulky, time-consuming, and mostly conducted in a laboratory, requiring highly trained personnel. Therefore, an analytical method that can be used in the field for rapid determination is essential. In this study, an Anti-MC-LR/MC-LR/Cysteamine …

Extensions Of The General Solution To The Inverse Problem Of The Calculus Of Variations, And Variational, Perturbative And Reversible Systems Approaches To Regular And Embedded Solitary Waves, Ranses Alfonso Rodriguez

Electronic Theses and Dissertations, 2020-2023

In the first part of this Dissertation, hierarchies of Lagrangians of degree two, three or four, each only partly determined by the choice of leading terms and with some coefficients remaining free, are derived. These have significantly greater freedom than the most general differential geometric criterion currently known for the existence of a Lagrangian and variational formulation since our existence conditions are for individual coefficients in the Lagrangian. For different choices of leading coefficients, the resulting variational equations could also represent traveling waves of various nonlinear evolution equations. Families of regular and embedded solitary waves are derived for some of …

Physics And Applications Of Space-Time Wave Packets, Murat Yessenov

Electronic Theses and Dissertations, 2020-2023

Space-time wave packets (STWP) constitute a broad class of pulsed optical fields that are rigidly transported in linear media without diffraction or dispersion, and are therefore propagation-invariant in absence of optical nonlinearities or waveguiding structures. Such wave packets exhibit unique characteristics, such as controllable group velocities in free space and exotic refractive phenomena. At the root of these behaviors is a fundamental feature underpinning STWP: their spectra are not separable with respect to the spatial and temporal degrees of freedom. Indeed, the spatio-temporal structure is endowed with angular dispersion, in which each spatial frequency is associated with a single prescribed …

Diffractive Liquid Crystal Optical Elements For Near-Eye Displays, Jianghao Xiong

Electronic Theses and Dissertations, 2020-2023

Liquid crystal planar optics (LCPO) with versatile functionalities is emerging as a promising candidate for overcoming various challenges in near-eye displays, like augmented reality (AR) and virtual reality (VR), while maintaining a small form factor. This type of novel optical element exhibits unique properties, such as high efficiency, large angular/spectral bandwidths, polarization selectivity, and dynamic modulation. The basic molecular configuration of these novel reflective LCPO is analyzed, based on the simulation of molecular dynamics. In contrast to previously assumed planar-twist structure, our analysis predicts a slanted helix structure, which agrees with the measured results. The optical simulation model is established …