Physical Sciences and Mathematics Commons^™

Synthesis, Characterization And Biologcal Evaluation Of Safranal-Loaded Metalorganic Framework Nanostructures, Alia Musabbeh Alkaabi

Thesis/ Dissertation Defenses

Liver cancer remains a primary worldwide health concern, necessitating the development of innovative and effective treatment options. In this study, we present a biocompatible iron-based metal-organic framework (Fe-MOF) consisting of iron ligands connected by terephthalate linkers loaded with safranal, a natural biomolecule extracted from stigmas of Crocus Sativus flower (also known as saffron), a therapeutic intervention with dual efficiency. This compound not only meets the demand for improved liver cancer therapies but also exhibits antibacterial properties against Escherichia coli and Lactobacillus. The synthesis stage of the study focuses on preparing MIL-88B(Fe) and loading safranal into/onto its structure. The material's composition …

Volume 10 Full Text, Bjur Staff

Butler Journal of Undergraduate Research

No abstract provided.

Stream Gauging: Investigating The Flow Rate And Residence Time In Laguna Bacalar, Mexico, Elizabeth J. Kowalczyk

Butler Journal of Undergraduate Research

Stream gauging is a standard tool used to measure the flow rate of various bodies of water. Knowing the flow rate of a body of water allows for the residence time of a body of water to be calculated. Currently, there is very little information regarding the flow rate and residence times of Laguna Bacalar. This system has been observed hydrologically consistently only in the past 6 years. In this study, 13 stream-gauging locations of interest were identified and gauged for their respective flow rates using the midsection method. Once the flow rates were acquired, maps depicting the Laguna Bacalar …

Table Of Contents And Front Matter, Bjur Staff

Butler Journal of Undergraduate Research

No abstract provided.

On The Projections And Unitary Groups Of Unital C*-Algebras, Fouzia Shaheen

Thesis/ Dissertation Defenses

H. Dye proved that the unitary group in a factor determines the algebraic type of that factor. Al-Rawashdeh, Booth and Giordano established that, for a large class of simple unital C*- algebras, an isomorphism between the unitary groups, induces an isomorphism between their K0-ordered group and K1-groups. Then using the results of Dadarlat-Elliot-Gong and KirchbergPhillips, the C*-algebras are isomorphic. Dye introduced special projections P{i,j}(a) of the matrix algebra Mn(A), and he used it as a main tool to establish his results in the case of von Neumann factors. Precisely, in case of von Neumann algebra, he proved that if  …

Induced Oxidation Effects On Physical And Mechanical Properties Of Lignite From Tempoku, Hokkaido, Japan For Sustainable Mining Via Subsurface Cultivation And Gasification Method, Akm Badrul Alam, Noritaka Aramaki, Shuji Tamamura, Akio Ueno, Takuma Murakami, Yoshiaki Fujii, Katsuhiko Kaneko

Journal of Sustainable Mining

The lignite resource has been under consideration for the subsurface cultivation and gasification (SCG) method to produce biomethane from lignite in Hokkaido, Japan. The primary phase of the method entails initiating the oxidative transformation of lignite using an H₂O₂ solution, resulting in the formation of dissolved organic carbon (DOC), a pivotal component. To examine the effects of induced oxidation on lignite's mechanical properties, artificial oxidation tests were conducted to form DOC. While there was a slight decrease in P-wave velocity and density, the uniaxial compression and indirect tensile strengths, as well as stiffness, did not decrease. These …

Factors Influencing The Perceptions Of Human-Computer Interaction Curriculum Developers In Higher Education Institutions During Curriculum Design And Delivery, Cynthia Augustine, Salah Kabanda

The African Journal of Information Systems

Computer science (CS) and information systems students seeking to work as software developers upon graduating are often required to create software that has a sound user experience (UX) and meets the needs of its users. This includes addressing unique user, context, and infrastructural requirements. This study sought to identify the factors that influence the perceptions of human-computer interaction (HCI) curriculum developers in higher education institutions (HEIs) in developing economies of Africa when it comes to curriculum design and delivery. A qualitative enquiry was conducted and consisted of fourteen interviews with HCI curriculum developers and UX practitioners in four African countries. …

Residential Metals Abatement Program Construction Completion Report Kennedy Elementary, Christopher Berg, Thomas J. Beckman, Environmental Resource Management (Erm)

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Re: Comments On The Repository And Haul Route Geotechnical Pre-Design Investigation Work Plan (Dated March 29, 2024), Repository And Proposed Haul Route – Silver Bow Creek Conservation Area Quality Assurance Project Plan (Dated March 29, 2024), And Silver Bow Creek Conservation Area Repository Data Gap Quality Assurance Project Plan (Dated March 22, 2024), Emma Rott

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Microplastics Fouling Mitigation In Forward Osmosis Membranes By The Molecular Assembly Of Sulfobetaine Zwitterion, Javad Farahbakhsh, Mitra Golgoli, Mehdi Khiadani, Amir Razmjou, Masoumeh Zargar

Research outputs 2022 to 2026

Forward osmosis (FO) membranes have potential for the efficient water and wastewater treatment applications. However, their development has faced significant challenges due to their fouling propensity. In this study, FO membranes modified with sulfobetaine zwitterions (i.e., [2-(Methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl) ammonium hydroxide) were fabricated and used for the first time to address microplastic (MP) fouling issue. Water flux, reverse salt flux (RSF), fouling, and flux recovery were evaluated for the membranes loaded with different quantities of the zwitterions ranging from 0.25 % to 2 %. The developed membranes were tested over 49 h with feed solutions containing polyethylene MPs and bovine serum albumin …

The Generation Of Terahertz Light And Its Applications In The Study Of Vibrational Motion, Aldair Alejandro

Theses and Dissertations

Terahertz (THz) spectroscopy is a powerful tool that uses ultrashort pulses of light to study the properties of materials on picosecond time scales. THz light can be generated through a variety of methods. In our lab, we generate THz through the process of optical rectification in nonlinear optical (NLO) organic crystals. THz light can be used to study several phenomena in materials, such as spin precession, electron acceleration, vibrational and rotational motion. The work presented in this dissertation is divided into two parts: (1) the generation of THz light and (2) applications of THz light. The first portion of this …

5675 Wiredcats Scouting Hub, Sebastian Smiley

Honors Theses

The WiredCats Scouting Hub was created to provide FIRST team 5675 with an application that allows them to make more informed strategic decisions regarding their competitive play. The app synthesizes data from multiple sources, parsing multiple data formats into a single source of truth. It also presents data to users through graphs and charts and provides interactive tables. The application meets the requirements set forth by the leadership of team 5675, effectively providing the capabilities they seek.

Kalamazoo Nature Center Mobile Application, Jacob Tebben

Honors Theses

This project aimed to address the challenge of enhancing visitor engagement and information dissemination at the Kalamazoo Nature Center (KNC) through the development of an integrated mobile and desktop application system. This initiative arose due to the limitations posed by traditional mobile applications which often become outdated and need to be updated by a dedicated software team. This project was designed for any user of the KNC desktop app to be able to update content on the mobile app, without the need of a dedicated software team.

The mobile application was designed for visitor use, enabling them to access up-to-date …

Application Of Density Altitude Climatology To General Aviation Impacts, Thomas A. Guinn, Daniel J. Halperin, Sarah Strazzo

Journal of Aviation/Aerospace Education & Research

Density altitude (DA) plays a key role in flight safety because it helps pilots anticipate poor aircraft performance when temperatures are warmer than standard. In this study, a 30-year climatology of DA for the conterminous United States was created using the fifth-generation European Centre for Medium-Range Weather Forecasts atmospheric reanalysis of the global climate (ERA5) dataset was applied to four separate DA-based, aircraft-performance, rules-of-thumb for general aviation (GA) flight. The goal was to demonstrate a technique to create educational visualization tools showing the variation of operational flight impacts with both month and location. Four such parameters were chosen to show …

Identifying Multilevel Predictors Of Behavioral Outcomes Like Park Use: A Comparison Of Conditional And Marginal Modeling Approaches, Marilyn E. Wende, S. Morgan Hughey, Alexander C. Mclain, Shirelle Hallum, J. Aaron Hipp, Jasper Schipperijn, Ellen W. Stowe, Andrew T. Kaczynski Ph.D.

Faculty Publications

This study compared marginal and conditional modeling approaches for identifying individual, park and neighborhood park use predictors. Data were derived from the ParkIndex study, which occurred in 128 block groups in Brooklyn (New York), Seattle (Washington), Raleigh (North Carolina), and Greenville (South Carolina). Survey respondents (n = 320) indicated parks within one half-mile of their block group used within the past month. Parks (n = 263) were audited using the Community Park Audit Tool. Measures were collected at the individual (park visitation, physical activity, sociodemographic characteristics), park (distance, quality, size), and block group (park count, population density, age structure, racial …

Multifunctional And Moisture Tolerant Zinc-Based Mono- And Bi-Metallic Metal-Organic Framework (Mof) Thin Films, Emmanuel Agbata

Theses and Dissertations

Many applications of metal-organic frameworks (MOFs) are highly dependent on their structures. The type and consistency of structure inform their properties. Zinc-based MOFs are applicable in different fields because of the low toxicity of zinc materials and are therefore also useful for catalysis. While MOF-5, a zinc-based MOF with carboxylate linkers is moisture intolerant, a variant of this is moisture tolerant. The introduction of a nitrogen-based linker in the zinc MOF which renders the structure moisture-tolerant. This material has not been explored as much, despite its multifunctional properties. Furthermore, the growth of Zn-based bimetallics of this MOF has not yet …

Residential Metals Abatement Program Construction Completion Report (Non- Residential Parcels – Indoor Dust) Small World Day Care, Environmental Resource Management (Erm)

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Development Of Novel Analytical Methods For The Investigation Of Mammalian Tissues And Cells, Grace A. Binder

USF Tampa Graduate Theses and Dissertations

This dissertation endeavors to advance the frontiers of analytical chemistry by addressing critical challenges across three distinct chapters. In the first chapter, the focus is on the evaluation of digestion methods for the analysis of trace metals in mammalian tissues and the Standard Reference Material NIST 1577c. The primary goal is to optimize methodologies, laying the groundwork for reliable trace metal analysis and furthering our understanding of their roles in biological systems.

Transitioning into the realm of immunomodulation, the second chapter elucidates immune response, disease and treatment through the optimization and discovery of STING modulators, utilizing the luciferase assay for …

Forest Biomass With The Nasa, Jpl Misr: Validation With Nasa Lidar-Derived Estimates, Mark Chopping

Sustainability Seminar Series

As our planet heats up, tracking changes in forest aboveground biomass density (AGB, Mg ha-1) at large scales is an increasingly pressing concern and one addressed primarily using space-based remote sensing. The European Space Agency hosted its 4th Carbon from Space Workshop in October 2022; NASA launched the Global Ecosystem Dynamics Investigation (GEDI) lidar to the International Space Station in 2018; and the NASA-ISRO SAR (NISAR) and ESA BIOMASS radar missions will launch in 2024. However, the record from SAR and lidar is limited and sporadic. Here, AGB estimates obtained using 672 nm (red) band reflectance data from the Multiangle …

Theoretical And Computational Astrochemistry: A Variational Quantum Monte Carlo (Vqmc) Study Of The Trihydrogen Molecule Cation (H3 + ), Ahmed Saeed Alsaed

Thesis/ Dissertation Defenses

H3 + is the simplest three-center two-electron molecule and it is of much interest in astrochemistry due to its high occurrence in the outer space, high reactivity, and strong acidic properties. In addition, H3 + is involved in many chemical reactions in the interstellar medium (ISM) and its significant ability to absorb energy contributed to the cooling of the universe during its early stages. The main objective of this thesis is to approximate the ground state electronic energy of H3 + by using a simple trial wavefunction consisting of a doubly occupied molecular orbital multiplied by a Jastrow factor. The …

Pricing Asian Options During Crises With The Impact Of Exogenous Events, Moath Ali Bakour

Thesis/ Dissertation Defenses

Asian options are path-dependent options since their payoff is built on the prices of the underlying asset over a time period. The Asian option pricing problem is primarily subject to the prediction model for asset prices. The pioneer Black Scholes paper suggests a GBM- Geometric Brownian motion. The Black-Scholes formula suffers from several shortcomings. For instance, the GBM does not take into consideration crises. Another problem with the Black-Scholes model is that it does not deal with the impact of external events. This work aims at a suggested model that encompasses the impacts of crises and external events together. It …

Enhancing Health Analytics: Secure And Private Federated Learning Solutions, Nisha Thorakkattu Madathil

Thesis/ Dissertation Defenses

Federated Learning (FL) is a collaborative approach permitting individuals to jointly train a model without sharing their local datasets with others. FL utilizes decentralized data sources to train machine learning models while protecting privacy, has emerged as a promising method. This holds especially true in medical contexts, where the confidentiality of data is critical. FL permits the utilization of heterogeneous datasets from a variety of healthcare organizations while maintaining patient confidentiality. It also plays a crucial role in advancing medical research and healthcare services while adhering to data distribution and compliance requirements. The primary challenges within federated healthcare encompass privacy …

Influence Of Low-Level Condensed Tannins Concentrations In Temperate Forages On Sheep Performace, F Montossi, F Liu, J Hodgson, S T. Morris, T N. Barry, D F. Risso

IGC Proceedings (1977-2023)

Results from a series of six comparative lamb grazing trials with temperate forages are summarised, and compared with results from the literature. Condensed tannin (CT) concentrations in the diet ranged from 0.12% to 0.47% on a dry matter (DM) basis. Values were generally similar for Yorkshire fog (Holcus lanatus), perennial ryegrass (Lolium perenne) and annual ryegrass (L. multiflorum), each grown with white clover (Trifolium repens), in similar circumstances. Concentrations for tall fescue (Festuca arundinacea)/white clover pastures were relatively low, but may have been artefacts. Drenching with polyethylene glycol (PEG) to bind …

Tannin Contents Of Some Indigenous Browse Plants Of Botswana, A A. Aganga, C M. Tsopito, K M. Morake

IGC Proceedings (1977-2023)

A study was carried out to evaluate the tannin content and crude protein degradation of leaves and twigs from indigenous browsable trees which provide feed for grazing livestock on natural rangelands of Botswana. These browses include the families Leguminosae (Acacias), Capparidaceae (Boscias), Combretaceae (Combretum) and Tiliaceae (Grewias). These were found to be of good nutritive value, with the leaves having a high content of crude protein (9 - 16%) and a wide range of dry matter digestibility (37 - 69.82%). The correlation between crude protein disappearance and tannin content was found to be negative (-0.582) and significant (P<0.05).

Effect Of Tannin In Animal Diet On Nitrification Rate Of Pasture Soil Under Dung Patches, J R. Crush

IGC Proceedings (1977-2023)

The rate of formation of nitrate and ammonium in the soil under dung patches was compared for dung from animals fed either ryegrass (Lolium perenne)/white clover (Trifolium repens) or ryegrass/Lotus pedunculatus forage. Tannin derived from the Lotus did not inhibit ammonification in the soil under dung but nitrate formation was strongly inhibited. The results support the theory that polyphenolics may bind to nitrite in acid soils and cause immobilisation of mineral nitrogen. Apart from their effect of reducing the proportion of dietary nitrogen excreted in urine, tannins in animal diets may make a further contribution to …

Condensed Tannins In Tropical Legumes: Concentration, Astringency And Effects On The Nutrition Of Ruminants, R Barahona, C E. Lascano, R C. Cochran, J L. Morrill, E C. Titgemeyer

IGC Proceedings (1977-2023)

A feeding trial was carried out to determine the effect of extractable condensed tannins (ECT) concentration and tannin astringency in tropical legumes on nitrogen (N) digestion by sheep. Test legumes were Desmodium ovalifolium (Do) and Flemingia macrophylla (Fm) which had similar concentrations of Extractable CT (9% DM) but tannins with different degree of astringency (Do, 0.6 and Fm, 0.3 g protein bound/g of ECT). Chopped sun-dried forage of each legume was sprayed with either water (control) or polyethylene glycol (PEG, 3.5% DM) to reduce ECT and fed to 8 sheep with ruminal and duodenal canulas arranged in a replicated 4 …

Effect Of Condensed Tannin In Lotus Corniculatus And Lotus Pedunculatus On Digestion Of Rubisco In The Rumen, W C. Mcnabb, R J. Aerts, A Brand, J S. Peters, Y L. Foo, G C. Waghorn

IGC Proceedings (1977-2023)

The in vitro precipitation of ribulose-1,5-bisphosphate carboxylase (Rubisco) by condensed tannin (CT) extracted from Lotus corniculatus and Lotus pedunculatus and the effect of these CT on the in vitro rumen degradation of Rubisco was used to compare the reactivity of these CT. The chemical structure of CT from Lotus corniculatus was homogenous with epicatechin stereochemistry and mostly procyanidin units. The CT from Lotus pedunculatus was heterogenous with mostly prodelphinidin units. The amount of CT required to precipitate all the Rubisco when total soluble leaf protein was incubated with CT from Lotus corniculatus and Lotus pedunculatus was similar. Although CT from …

Nitrogen And Fiber Digestion In Sheep Fed Fresh-Frozen And Field-Dried High And Low Tannin Sericea Lespedeza, T H. Terrill, W R. Windham, C S. Hoveland, H E. Amos, B Kouakou, S Gelaye

IGC Proceedings (1977-2023)

Field-drying reduces extractable condensed tannin (CT) of sericea lespedeza [Lespedeza cuneata (Dum-Cours) G. Don], but effects on specific bound and unbound forms of CT and the relationship to protein and fiber digestion in ruminants are unclear. Intake and digestibility of fresh-frozen and field-dried high- and low-tannin sericea were investigated in a feeding trial with sheep (Ovis spp.). Field-drying had no effect on crude protein (CP) and fiber content of sericea, but shifted CT from extractable to bound forms. Digestion coefficients for CP, neutral detergent fiber (NDF), and acid detergent fiber (ADF) were lower for high-tannin sericea than the low-tannin …

Alteration Of Condensed Tannin Sythesis In Transgenic Forage Legumes, F Paolocci, G Tanner, S Arcioni, F Damiani

IGC Proceedings (1977-2023)

The transformation of Lotus corniculatus plants with the maize gene Sn, reorganizes the tissue specificity of condensed tannins accumulation. In particular the transformed plants show an increase of tannin content in roots and a decrease in leaves. Molecular and enzymatic analyses suggest that the transgene can functionally substitute an endogenous unknown gene not expressed in roots and induces its silencing when it is expressed. These findings could have applications for reducing tannin content in unpalatable plants and for cloning genes involved in tannin synthesis.

Comparison Of The In Vitro Fermentation Characteristic Of Fractionated Alfalfa And Sainfoin, L R. Mcmahon, M Goto, T A. Mcallister, G A. Jones, K J. Cheng

IGC Proceedings (1977-2023)

Alfalfa and sainfoin leaves were lyophilized and ground (A, S, respectively) or were fractionated into soluble (A_SOL, S_SOL) and insoluble (A_INS, S_INS)components and lyophilized and incubated in vitro with diluted ruminal fluid for 24h. Whole leaf and soluble fractions were also incubated with polyethylene glycol 8000 (PEG). Gas production (GP), ammonia concentration [NH3] and volatile fatty acid (VFA) production were lower (P< 0.05) from S and SSOL than from A and ASOL Insoluble fractions differed only in [NH3] (SINS < AINS, P < 0.05). Inclusion of PEG increased (P < 0.05) GP, [NH3] and VFA production from whole leaf and soluble fractions of sainfoin, but not alfalfa. Inactivating the condensed tannins in sainfoin with PEG overcame differences in degradability between these two forages.