Physical Sciences and Mathematics Commons^™

From Poetry To Policy: How H-Stem Has Guided My Research Path, Kayla D. Taylor

Student Works

Embry-Riddle PhD student Kayla Taylor was invited to share how Humanistic STEM has shaped her educational journey at the third annual Humanistic STEM symposium.

Securing Secrets: Exploring The Aes Encryption And Key Security Capabilities Of Chatgpt, Kayla Taylor

Student Works

The development and increasing accessibility of generative artificial intelligence (AI) tools and large language models (LLMs) have allowed cryptographers to explore a variety of cryptanalysis problems in dynamic and interactive ways. Prompt engineering, the process by which input text is tested and refined to elicit a desired response from LLMs, is a nascent area of research that remains largely unexplored in many contexts, including cryptography. This study will explore the potential applications and limitations of prompt engineering in the context of Advanced Encryption Standard (AES) encryption and key security with OpenAI’s ChatGPT (GPT-4o) through two main objectives: First, given a …

The City Of Sunbury Cemetery Mapping & 1936 Flood Research, Sophia M. Martinez, Fehr A. Gillett, Ben J. Faxon, Sarah M. Sanfield

Final Reports in ENST 411: Environmental Community Projects

The City of Sunbury Cemetery Mapping & 1936 Flood Research Project was a community-driven effort to restore lost historical records of the Sunbury cemetery and to understand the context of how these records were originally lost. This project was completed as a partnership between the City of Sunbury government and four undergraduate environmental studies/sciences students in Bucknell University's ENST 411 Environmental Community Projects course. In this project, we used Geographic Information System (GIS) mapping technology, historical research, and volunteer engagement to create a comprehensive digital record of the cemetery. The goal of this project was to preserve Sunbury’s rich history …

The Relationship Between Pillar[5]Arene And Pillar[6]Arene In The Synthetic Route To A Water-Soluble Pillar[6]Arene: A Case Of Kinetic And Thermodynamic Products Or Two Distinct, Competing Reactions, Helice A. Gillis

Open Access Dissertations

Pillar[n]arenes, discovered in 2008, have already made their mark as a formidable addition to the field of supramolecular chemistry, largely due to their host-guest chemistry. While the synthesis of pillar[5]arene is well established, the synthesis of pillar[6]arene, with its larger core, has not been so straightforward and mainly accomplished through the use of bulky solvents. Here we present an optimized method for a reproducible, acid-catalyzed synthesis for a brominated pillar[6]arene, starting with a brominated monomer and using chloroform as the templating solvent. Our studies have demonstrated the ratio of brominated pillar[6]arene to brominated pillar[5]arene increases with both decreasing concentration of …

Quantifying Links Between Phytoplankton Physiology And The Environment, Gabrielle M. Armin

Open Access Dissertations

Phytoplankton are microscopic, primary producers in aquatic ecosystems worldwide. They are key links in global biogeochemical cycles, converting inorganic compounds into bioavailable nutrients which fuel fisheries. Through photosynthesis, phytoplankton play an essential role in the carbon cycle and marine biological pump, drawing carbon from the atmosphere, which is eventually sequestered in the oceans, regulating our Earth’s climate. Due to their influential role in large scale processes, there have been many efforts to characterize and quantify phytoplankton impacts to ecosystem health and global nutrient cycles. Often, phytoplankton physiology has been highly simplified in global or ecosystem models, limiting their representation to …

Numerical Modeling Study Of Coastal Impacts From Extreme Storms And Sea Level Rise In Southern New England, Deborah Crowley

Open Access Dissertations

Coastal areas in southern New England are vulnerable to a range of impacts from extreme storms and sea level rise. The most frequent extreme storms are extratropical storms, commonly referred to as nor’easters, named for the direction of the strongest winds, though these storms also have strong winds from other directions.

Storm winds generate large waves and push water up along the coast in the form of storm surge. The combined impacts of increased water levels and waves include flooding and morphological change. Sea level rise (SLR) will exacerbate these processes, amplifying the associated impacts, which may pose increasing threats …

Dynamics Of Metal-Coordinated Coumarin Dyes For Photoswitching Applications, Danielle Jacoby

Open Access Dissertations

Optical transient absorption spectroscopy is a fundamental pump-probe technique that is used to analyze the photophysical and photochemical properties of molecules. Our research group specifically utilizes both a femtosecond and nanosecond set up to probe dynamics of molecules on time scales ranging from 100s of femtoseconds to approximately 50 microseconds. Chapter 2 is a standard operating procedure for the nanosecond transient absorption instrument.

Photoacids are molecules that undergo a change in the acidity of one of their protons when exposed to light. Utilizing this phenomenon, we have designed a series of dyes that, when bound to divalent first row transition …

Development And Characterization Of Polysaccharide-Based Controlled Drug Delivery Platforms, Amanda Pepler

Open Access Dissertations

Drug delivery research focuses on overcoming challenges in patient treatment. Most therapeutics are delivered systemically through oral or intravenous routes. However, these administration methods are often inefficient due to therapeutic hydrophobicity, poor bioavailability, and liver metabolic clearance, necessitating frequent dosing. When treatment plans require frequent dosing, patients experience significant fluctuations in therapeutic concentration in the bloodstream, which can increase adverse side effects. These factors contribute to low patient compliance. Therefore, the core focus of drug delivery research is to develop new administration routes for therapeutics. Drug delivery systems (DDS) that can target therapeutics to a localized region offer advantages over …

Probing Biomolecular Structure And Dynamics Via Infrared Action Spectroscopy, Madeline Schultz

Open Access Dissertations

Biomolecular structure is supported by a network of inter- and intramolecular interactions, which can be inherently complex in the condensed phase. Isolating biomolecules from the condensed phase to vacuum, via electrospray ionization (ESI), can afford precise control over experimental conditions, yielding additional structural insight. However, the loss of solvation inherent to the ESI process can drive structural rearrangement, particularly at charge sites.

Microsolvation reagents can be used to partially mimic the solvation of charged moieties in solution as they are brought into the gas phase through complexation. This serves two primary functions: 1) reducing propensity for structural rearrangement of systems …

Novel Methodology And Proof-Of-Concept For Proton Ct Using Spot Profile Rather Than Bragg Peak Location, Brett Albert Ruben

Open Access Dissertations

Proton radiation therapy offers a highly precise method for cancer treatment, theoretically providing superior dose deposition characteristics compared to conventional X-ray radiation therapy. Its steep and finite dose fall-off region allows for superior tumor coverage while reducing, though not eliminating, dose to surrounding healthy tissue. However, its full potential is limited by range uncertainties, particularly those arising from the reliance on X-ray-based imaging methods called computed tomography (CT) for proton-based treatment. CT image Hounsfield Units (HU) must be converted to stopping power ratios (SPR) as these ratios are the clinically relevant value for accurately planning particle interactions during proton therapy. …

Characterization Of Methodological Variability In Compound Specific Isotope Analysis Of Amino Acids (Csia-Aa), Audreyana Brown-Nash

Open Access Dissertations

The use of isotopes in the natural sciences stems from the principle that chemical reactions predictably alter the isotopic composition of a given sample. Recent advances in compound specific isotope analysis of amino acids (CSIA-AA) have paved the way for studies of increasingly complex ecological relationships, including the identification and characterization of organismal physiology, consumer-resource linkages, biogeochemical cycling, and movement ecology. The analytical power of CSIA-AA has caused an exponential increase in the number of application-based studies since its inception in the 1990s. With the technique constantly evolving to accommodate new research goals, it is important to understand how variation …

Confronting The Seaport Resilience Gap: Incentives, Frameworks, And Case Studies For Enhancing Resilience To Natural Hazards In Port Planning And Policy, Rosemarie Fusco

Open Access Dissertations

This dissertation investigates the critical issue of seaport resilience, focusing on the gaps in resilience planning and the role of incentives in motivating resilience investment. The research arc addresses the question: What incentivizes seaports to increase natural hazard resilience (NHR)? It is organized into three interconnected manuscripts, each examining distinct aspects of the problem.

The first manuscript critically examines the resilience planning approaches of Small Island Developing States (SIDS) as outlined in their National Adaptation Plans (NAPs), highlighting the limited consideration of seaports despite their critical role in economic and social connectivity. SIDS offer critical insight into seaport resilience due …

Textual Sediments: Genre And The Planetary Novel, William Bowden

Open Access Dissertations

This dissertation investigates how twenty-first-century prose fiction navigates the ecological and temporal dimensions of planetary crisis. In response to accelerating pressures - climate change, ecological collapse, and the intensification of capitalist modernity - literary studies has turned increasingly to the planetary as a conceptual frame. Yet this shift has often outpaced the development of adequate critical vocabularies and narrative methodologies. By drawing on ecocriticism, narrative theory, phenomenology, and related fields, Textual Sediments proposes a new framework for reading what it terms the planetary novel: a sedimentary genre characterized by temporal layering, formal hybridity, and a recursive engagement with scale. Through …

Quantifying Mixotrophy Potential As A Function Of Environmental And Biological Drivers In Coastal And Estuarine Plankton Communities, Erica Ewton

Open Access Dissertations

The discovery of mixotrophic plankton has bridged gaps in nutrient cycling budgets and altered the understanding of food webs and energy transfer. Mixotrophic plankton are capable of simultaneous or sequential photosynthesis and heterotrophy, providing multiple avenues of nutrition and thus reducing limitations that affect specialists. These energy dense cells provide increased biomass for higher trophic levels, which may increase organism sizes throughout the food web. Additionally, they may be physically denser, which alters biogeochemical cycling including carbon sequestration. The work presented here uses LysoTracker Green, an acidotropic stain that attaches to phagocytic vacuoles within potentially phagotrophic small (< 20 µm diameter) phytoplankton communities (‘mixoplankton’), to better understand their abundance, relative abundance, and growth rates in relation to the matrix of natural conditions they inhabit. Understanding the prevalence and drivers of mixoplankton is vital to better parameterize biogeochemical cycling and energy transfer in the ocean and for models that predict the fate of future oceans.In the first study, I compared the abundance of mixoplankton in the Northeast U.S. Shelf (NES) and Coastal California Current System (CCS) during two cruises in the NES in summer 2021 and one cruise in the CCS in summer 2022. These two contrasting coastal systems span the breadth of environmental conditions observed in temperate marine ecosystems and thus provided an opportunity to examine indicators of mixoplankton across temperate coastal regions. I discovered higher mixoplankton abundance in the NES than CCS yet similar population sizes of nanoeukaryotic photosynthesizers, resulting in higher relative abundance of mixoplankton in the NES than CCS. Across both systems, I found increased mixoplankton abundance associated with decreasing temperature and combined nitrate + nitrite concentrations (N+N), and increasing light intensity and Synechococcus abundance …

Investigating The Photophysical Dynamics Of Anthracene And Acridine Derivatives Using Time-Resolved Spectroscopy, Sophia Tiano

Open Access Dissertations

Anthracenes and acridines are among the simplest visible light absorbing heterocyclic and polycyclic aromatic hydrocarbons and as such are extensively used in a variety of applications including photosensitizers and fluorescent sensors. Although the photophysics of some derivatives have been studied in the past, there is still a lot of unknown fundamental information that is vital in order to optimize these molecules for particular applications. Transient absorption spectroscopy was used to study the photophysics of the 9-substituted methyl, hydroxymethyl and formyl derivatives of acridine and anthracene. The growth and decay of the triplet-triplet absorption peak were quantified for each dye in …

Essays On Human Decisions Related To Water Quality Problems In The United States, Sonia M. Refulio Coronado

Open Access Dissertations

Water pollution remains a pervasive and inequitable environmental threat in the United States, with mounting evidence that its burdens - whether in recreational or drinking water contexts - are unevenly distributed across communities. Urbanization, aging infrastructure, and industrial contamination have degraded both coastal waters and drinking water systems, posing serious public health and welfare concerns. At the same time, the extent to which water quality influences behavioral decisions, such as beach recreation or household adoption of water filters, remains poorly understood. Although drinking water pollution is widely ranked as a top environmental concern in national surveys, public knowledge of specific …

A Socio-Ecological Investigation Of Ulithian Spearfishing, Joshua Pi

Open Access Dissertations

Coral reef socio-ecological systems (SESs) characterize the interconnected relationships between coral reef ecosystems and reef-dependent communities. One such SES exists in Ulithi Atoll, Federated States of Micronesia, where Ulithians fish, steward, and govern their reefs through customary marine tenure, traditional ecological knowledge, and cultural taboos. In recent decades, rapid modernization in Ulithi has introduced new fishing technologies, transformed fishing practices, and ultimately reshaped the functioning of Ulithi’s traditional SES. One significant change was the introduction of spearfishing during the mid-20^th century, which is more selective and individualistic compared to other community-centric fishing methods that have existed for generations. This …

Incorporating Time-Varying Parameters And Climate Drivers Into Fisheries Models, Rachel Catherine Marshall

Open Access Dissertations

Commercial fishing is a highly valuable industry in the United States and globally, and as such, managing based on the best available science is necessary to maintain important fish stocks. Some parameters in stock assessment models that are assumed to be constant over age and time may actually vary to an extent that stock assessment modeling results could be improved by allowing the parameters to vary in the models. In the present dissertation, two stock assessment parameters that are typically held constant are explored for potential time or age variance. Potential environmental drivers of nonstationary parameters are also explored. Productivity, …

Coupled Numerical Modeling Of Wave-Current Interactions In Tropical Cyclones, Angelos Papandreou

Open Access Dissertations

This Ph.D. dissertation presents a numerical modeling study of wave-current interactions in tropical cyclones. Chapter 1 focuses on wave-current interaction in shallow water during hurricane landfall, when strong winds often generate severe storm surges that dramatically raise water levels and cause significant damage to human lives and property. Large waves generated by these winds further amplify storm surges, making it necessary to couple storm surge models with wave prediction models. Currently, two-dimensional coupled storm surge-wave models incorporate the effect of waves on the storm surge through the forcing of radiation stress gradients. However, recent studies on wave-current interactions indicate that …

A Multispectral Analysis Of High Redshift Quasars And Their Energy Production Mechanisms, Erik Carlson

Open Access Dissertations

We present a complete sample of radio-loud (P_3.0 GHz = 10^27.26 W/Hz) high-redshift (z ≥ 2.5) quasars in the Northern Hemisphere (δ ≥ 0). Each source was imaged with a user-defined imaging protocol developed for the Very Large Array Sky Survey. Higher-resolution images were generated from archival observations and new Enhanced Very Large Array observations (Project Code: 24B-010).  We produced 407 images of galaxies, where we are likely the first humans to see them. Twenty of these sources were high-redshift jets which increased the number of known high-redshift jets by 69%. This sample represents one of the largest …

The Goddard Rocket Researches: A Photographic Record, Esther C. Goddard

The Goddard Rocket Researches: A Photographic Record [Photo Album]

This page contains a pdf scan of 'The Goddard Rocket Researches: A Photographic Record' in its entirety. The individual photographs and their descriptions can be seen here.

'The Goddard Rocket Researches: A Photographic Record' is an annotated photo album covering Robert H. Goddard's work and experimentation with rocketry. It was assembled and curated by Esther Goddard sometime after her husband's passing in 1945.

The vast majority of these photographs were taken by Esther herself. Esther was an avid camerawoman and photographer, and during Robert's lifetime she meticulously documented his life's work in rocketry--from experiments and instruments to processes and …

Elucidating The Role Of Hydrogen At C-In2o3/A-In2o3−X Interface, Julia E. Medvedeva, Mariana I. Bertoni

Physics Faculty Research & Creative Works

Ab initio molecular dynamics simulations and hybrid functional electronic structure calculations are employed to determine the formation, the structural and electronic properties, and the dynamics of covalent (In-OH) and ionic (In-H-In) hydrogen defects at crystalline-In2O3/amorphous-In2O3−x interface. This comprehensive computational study considers (i) various interstitial and substitutional hydrogen site locations within the crystalline, amorphous, and interfacial regions; (ii) several oxygen-to-hydrogen ratios; and (iii) possible defect charged states. The results reveal hydrogen's inability to fully passivate the undercoordinated under-shared in atoms in amorphous highly substoichiometric oxide, giving rise to the formation of deep electron traps even in net-charge neutral structures. These trap …

Comparing Surface Currents Near The Mouth Of Three Bays Along The U.S. East Coast: Chesapeake Bay, Delaware Bay, And New York Bay, Tal Ezer, Teresa Updyke

CCPO Publications

Monthly surface currents at 2 km resolution near the mouths of three U.S. east coast bays were obtained from high-frequency radars (Coastal Ocean Dynamics Application Radar, CODAR) during 2012–2024. The currents near these bays, the Chesapeake Bay (CB), the Delaware Bay (DB) and the New York Bay (NB) were analyzed to infer similarity and differences, as well as potential common forcing from regional and basin-scale factors. The contribution to flow variability from local and remote forcing is evaluated by comparing surface currents with (a) river discharges into each bay, (b) with local and regional winds, and (c) with the North …

Surface Currents In The Mid-Atlantic Bight: The Role Of The Gulf Stream Versus Wind, Tal Ezer

CCPO Publications

Surface currents of the Mid-Atlantic Bight (MAB) were studied using high frequency radar (HFR) observations at 6 km resolution during a five-year period (2020-2024). The study's focus on the role of the Gulf Stream (GS) contrasts with most past studies that focused on the seasonal wind-driven currents. Empirical Orthogonal Function (EOF) analyses of the daily HFR currents were conducted with and without the GS, revealing modes of current variability linked to the seasonal wind pattern and storms versus modes linked to GS variability. The remote impact of the GS on coastal currents is complex, with different impacts seen on different …

Wasting Disease Of A Marine Foundation Species Links Community Interactions To Disease Dynamics, Lillian R. Aoki, Olivia J. Graham, Reyn M. Yoshioka, Rebecca Maher, Lindsay Alma, Eileen E. Hofmann, Colleen A. Burge, Drew Harvell, Maya L. Groner

CCPO Publications

Infectious disease plays a key role in shaping marine communities, including in seagrass meadows, which form biodiverse coastal habitats. Eelgrass (Zostera marina) is the most widespread seagrass species and is susceptible to seagrass wasting disease, caused by the protist Labyrinthula zosterae. As a foundation species, eelgrass strongly influences ecosystem structure, function and services; recent work has begun to explore the links between critical community interactions and seagrass wasting disease. Here, we highlight recent advances about how the eelgrass community regulates and responds to seagrass wasting disease, from the microbiome to herbivores and filter feeders. We further show …

Multi-Model Estimate Of Antarctic Ice-Shelf Basal Mass Budget And Ocean Drivers, Benjamin K. Galton-Fenzi, Richard Porter-Smith, Sue Cook, Eva Cougnon, David E. Gwyther, Wilma G. C. Huneke, Madelaine G. Rosevear, Xylar Asay-Davis, Fabio Boeira Dias, Michael S. Dinniman, David Holland, Kazuya Kusahara, Kaitlin A. Naughten, Keith W. Nicholls, Charles Pelletier, Ole Richter, Hélène Seroussi, Ralph Timmerman

CCPO Publications

Societal adaptation to rising sea levels requires robust projections of the Antarctic Ice Sheet's retreat, particularly due to ocean-driven basal melting of its fringing ice shelves. Recent advances in ocean models that simulate ice-shelf melting offer an opportunity to reduce uncertainties in ice–ocean interactions. Here, we compare several community-contributed, circum-Antarctic ocean simulations to highlight inter-model differences, evaluate agreement with satellite-derived melt rates, and examine underlying physical processes. All but one simulation use a melting formulation depending on both thermal driving (T^⋆) and friction velocity (u^⋆), which together represent the thermal and ocean current forcings at the …

Characterization And Leaching Feasibility Studies Of Copper Flue Dust For The Recovery Of Main And Trace Metals, Fardis Nakhaei, Marek Locmelis, Lana Alagha, Michael S. Moats, Carlos Eyzaguirre, Cory Smith

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Although copper smelter dust (CSD) is classified as hazardous waste, it also serves as a valuable secondary resource, offering potential for the recovery of critical elements. In this study, CSD samples were collected from the waste heat boiler (WHB) and electrostatic precipitator (ESP) units connected to the flash smelting furnace at a copper smelter. The representative samples were extensively characterized by particle size, and chemical and mineralogical analyses. Following sample characterization, leaching experiments were performed to evaluate the potential extraction of Cu, Fe, As, Zn, Pb, In, Ga, and Ge from the flue dusts. Distilled water, H2SO4, and HCl were …

Integrating Sentiment Analysis In Predictive Models: A Comparative Study On Game Popularity On Steam, Khaleefa Alhemeiri

CMC Senior Theses

Over the past decades, the gaming industry has managed to evolve into a multi-billion-dollar enterprise. Gaming platforms such as Steam foster unprecedented amounts of engagement among players worldwide daily. In this thesis, we investigate the effect of incorporating sentiment-driven metrics, specifically YouTube view counts and positive reviews, into predictive models for game popularity. In addition, by comparing our linear regression sentiment-based approach to the Bayesian hierarchical folded normal model used by De Luisa et al. (2021), we can understand the many differences, strengths, and limitations of each methodology. In our thesis, we focus on three games. Each is of varying …

Measuring The Similarity Between Trees Of Different Order, Camilo Morales

HMC Senior Theses

Graphs encode relationships between data. However, due to their versatility, it is often difficult to generalize the notion of similarity between two graphs using a distance function. Since graphs can represent various data sets, specific distance metrics need to be tailored for questions we are interested in answering or the data set we are working with. This project is motivated by ongoing investigations into the evolution of female gender representation in mathematics. By building off previous work that has taken data from the Mathematics Genealogy Project and modeled this evolution of representation via a tree, we would like to develop …

Predicting Biomechanical Risk Factors For Division - I Women’S Basketball Athletes, Aayushi Shah, Vanaja Agarwal, Dhairya Shah, Harman Jani, Sristi Sharma, Kaya Tolga, Christopher Taber, Mehul Raval

School of Computer Science & Engineering Faculty Publications

Collegiate basketball is characterized by high-impact movements such as jump landings, making athletes more susceptible to injuries. Critical biomechanical factors like knee flexion, lateral trunk flexion, and foot landing asymmetry are strongly associated with injury risk. This study aims to predict six biomechanical risk factors in the landing error scoring system (LESS). The dataset comprises 8600 video frames of counter-movement jumps (CMJs) from 17 NCAA Division I female basketball athletes, recorded from frontal and lateral perspectives and annotated using a customized error annotation algorithm. The study uses the You Only Look Once (YOLOv5nu) model to analyze the basketball athletes’ CMJ …