Physical Sciences and Mathematics Commons^™

Re: Comment Letter For The Butte Priority Soils Operable Unit (Bpsou) Butte Treatment Lagoons (Btl) Groundwater Treatment System Quarterly Operation And Maintenance Report – Quarter 2 2025 (Dated September 30, 2025), Emma Rott

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Revised Draft Final 2022 Unreclaimed Sites Sampling: Ur-12 Site Evaluation Summary Report, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Nonlinear Phase Space Analysis For Anomaly Detection In Ros 2 Communications: Detecting Man-In-The-Middle Attacks In Simulated Environments, William L. Locklier

Graduate Theses and Dissertations (2019 - present)

Robot Operating System 2 (ROS 2) marks a significant advancement over its predecessor through the transition from a centralized to a decentralized architecture, integrating the Data Distribution Service (DDS) to support real-time, scalable communications. Despite these improvements, inherent vulnerabilities in the ROS 2 communication stack continue to leave these systems exposed to sophisticated network-based attacks. This study leveraged nonlinear phase space analysis (NLPSA) as an intrusion detection system (IDS) to detect man-in-the-middle (MitM) attack anomalies in ROS 2 traffic. Grounded in Takens’ embedding theorem, NLPSA reconstructs the phase space of communication features and compares the resulting structure against a baseline …

Thermal And Non-Thermal Mass Transport Effects In Plasmon-Assisted Electrochemistry., Md Al Amin

Electronic Theses and Dissertations

Plasmon-assisted electrochemistry has received attention due to its effects of hot charge carriers, photothermal heating, and enhanced electromagnetic field impact on electrochemical transformation. These effects have contributed to lowering the onset potential and increasing the reaction kinetics. Numerous studies have been employed to differentiate the effect of photothermal heating from hot charge carriers on the electrochemical reaction. Most of these studies have been employed to measure and quantify the photothermal heating effects at equilibrium temperature; however, localized heating from the incident light does not result in homogeneous heating across the electrochemical cell. Many studies investigating the photothermal heating effect in …

A Persistent Homology Framework For Scrna-Seq: Assessing Clustering Robustness And Quantifying Preprocessing And Integration Effects On Topological Features., Jonah Daneshmand

Electronic Theses and Dissertations

As single-cell RNA sequencing (scRNA-seq) data expands, robust methods for integrating diverse datasets are critical. This dissertation applies Persistent Homology (PH), a technique from Topological Data Analysis (TDA), to a collection of scRNA-seq datasets spanning eight tissue types to quantify how data integration affects topological features and biological interpretability. We assessed global topological structure using Betti curves, Euler characteristics, and persistence landscapes across raw, normalized, and integrated data representations. Our analysis revealed a performance inversion: while conventional methods excelled on unintegrated data, high-granularity topological methods, particularly those sensitive to global data structure, became superior after integration. This suggests a synergy …

Controlling Selectivity In Electrocatalytic Co2 Reduction With An External Magnetic Field., Nawaraj Karki

Electronic Theses and Dissertations

My dissertation describes how to alter the speciation and concentration of molecules at the electrode-electrolyte interface, and how those alterations affect reactivity and selectivity. This dissertation presents two distinct approaches to control the mass transport of neutral molecules such as carbon dioxide (CO₂) at the electrode-electrolyte interface by using an external magnetic field. The first finding demonstrates that magnetic fields indirectly affect the mass transport of target analytes such as CO₂ molecules by selectively interacting with charged species, such as hydroxide ions (OH^-). Such interaction induces magnetohydrodynamic (MHD) effects, which generate localized hydrodynamic flow and …

Preparing Confident Elementary Mathematics Teachers: Addressing Anxiety, Building Fluency, And Strengthening Practice., Amber Diamond Pendleton

Electronic Theses and Dissertations

This dissertation, presented in three articles, examines how elementary preservice teachers (PSTs) experience and develop as mathematics learners and future educators when methods coursework deliberately integrates mathematical reasoning with affective supports. Collectively, the studies investigate how research-informed instructional design may help address mathematics anxiety (MA), mathematics teaching anxiety (MTA), procedural fluency, and instructional practice. The first article, written for practitioners and elementary mathematics teachers, illustrates how well-established instructional routines, such as number talks and student work analysis, can be facilitated to support procedural fluency in multiplication. Using classroom vignettes, this article highlights instructional moves that make structure visible, promote strategy …

Plasma-Enhanced Carbon Nanomaterial Synthesis: A Pathway To Reducing Greenhouse Gasses And Carbon-Based Waste., Zane Ronau

Electronic Theses and Dissertations

This research leveraged incorporation of capacitively coupled radio frequency plasma into chemical vapor deposition (CVD) for a reduction in the temperature requirements [a reduction of energy barrier] needed for the conversion of methane (CH₄), carbon dioxide (CO₂), and various carbon-based-waste to produce value-added carbon nanomaterials. An array of catalysts and catalyst supports were employed to optimize the synthesis of graphitic carbon under various gas environments, temperatures and pressures. The nanomaterials synthesized after fine tuning the growth parameters included graphene, carbon nanotubes (CNT), carbon microtubes and carbon nanocages with a variety of properties. Raman Spectroscopy was used …

Direct And Satellite-Based Quantification Of Greenhouse Gas Fluxes In Small Ponds., Mark Christopher Tierney

Electronic Theses and Dissertations

As evidenced by their historic losses due to anthropogenic activities, wetlands are undervalued ecosystems that provide numerous ecosystem services, from recreational opportunities to carbon (C) storage. However, these wetlands are also the largest natural source of atmospheric methane (CH₄). Additionally, small water bodies (< 10,000 m²) are disproportionately large emitters relative to larger lakes and reservoirs. As construction and restoration efforts proceed, it is crucial to identify wetlands that need restoration and to understand the factors driving both greenhouse gas (GHG) fluxes and the C balance of these systems. This dissertation investigates the drivers of greenhouse gas fluxes …

Synthesis, Characterization, And Chemical Reactivity Of Calcium-Alginate Hydrogel Beads Containing Metal Nanoparticles And Nanoclusters., Rajiv Kumar Singh

Electronic Theses and Dissertations

This dissertation explores the synthesis, stability, and reactivity of various metal nanoparticles (NPs) and nanoclusters (NCs) of varied size and stabilizers contained within millimeter-sized calcium alginate (Ca-Alg) hydrogel polymer beads. Hydrogel beads synthesized by combining sodium alginate with Au or Ag NPs stabilized with trisodium citrate (Cit) and adding dropwise into a 4.0 M Ca²⁺ solution remained stable and contained within the beads. Those synthesized Au, Pd and AuPd NCs stabilized with glutathione (SG) became partially released from the hydrogel within a day. The synthesis of beads containing aggregated Cit Au NPs occurs by inducing aggregation with tetrakis(hydroxymethyl) phosphonium …

Qualitative Stereo Vision Using Distributed Extended Waltz Filtering, Ben Mathew

Theses and Dissertations

Stereo vision is a fundamental problem in computer vision, aimed at reconstructing three-dimensional scene structure from two or more two-dimensional images. Traditional stereo algorithms rely on quantitative disparity estimation, often constrained by calibration precision, lighting variations, and surface texture. In contrast, our proposed Qualitative Stereo Vision seeks to understand depth relationships and spatial configurations from multiple planar views through symbolic reasoning and constraint satisfaction, offering a more flexible and cognitively plausible approach to scene interpretation.

This dissertation presents a novel framework called Distributed Extended Waltz Filtering, designed to provide qualitative stereo vision, particularly in the presence of occlusions—a persistent challenge …

Quantum Entanglement As A Resource For Coordinating Navigation, Aamir Ahmad

Theses and Dissertations

John Clauser, Michael Horne, Abner Shimony, and Richard Holt (CHSH) originally formulated the CHSH game as an experiment to establish entanglement as a quantum mechanical phenomenon that could not be predicted by classical theories. I will apply the quantum strategy used in the CHSH game to demonstrate that it also establishes a structure that employs entanglement as a resource to enable coordination without communication in the context of navigation.

Rising From Ashes: Generalized Federated Learning Via Dynamic Parameter Reset, Jiahao Wu, Ming Hu, Yanxin Yang, Xiaofei Xie, Zekai Chen, Chenyu Song, Mingsong Chen

Research Collection School Of Computing and Information Systems

Although Federated Learning (FL) is promising for privacy-preserving collaborative model training, it suffers from low inference performance due to heterogeneous client data. Due to heterogeneous data across clients, FL training easily learns client-specific overfitting features. Existing FL methods adopt coarsegrained averaging, which can easily cause the global model to get stuck in local optima, leading to poor generalization. Specifically, this paper presents a novel FL framework, FedPhoenix, to address this issue. It stochastically resets partial parameters in each round to destroy some features of the global model, guiding FL training to learn multiple generalized features for inference rather than specific …

Data-Driven Evaluation Of Sustainable Waste-To-Energy Pathways For Intelligent Urban Systems, Izech Brian O. Edwin, King Harold A. Recto

Electronics, Computer, and Communications Engineering Faculty Publications

The handling of municipal solid waste (MSW) in swiftly urbanizing Philippine cities poses intricate energy and governance challenges. In Baguio City, reliance on landfills has reached critical levels due to diminishing capacity, rising transport costs, and opposition to trash transfers by nearby LGUs. Although shaped by unique topographical and governance constraints, Baguio’s situation reflects issues faced by other rapidly growing Philippine cities; therefore, analyzing it offers insights for national MSW decision-making. This study applies a triple bottom line (TBL) framework to assess three management scenarios: (1) Status Quo, where all MSW is landfilled with no energy recovery; (2) Landfill with …

Engineering Risk And Indigenous Resilience Toward Intelligent Decision Support For Mining In Ancestral Lands, Izech Brian O. Edwin, King Harold A. Recto

Electronics, Computer, and Communications Engineering Faculty Publications

Mining within ancestral territories reveals an ongoing conflict between technical viability and Indigenous consent. This collaborative study, conducted by an engineering scholar and a policy researcher of Indigenous heritage in Benguet among the Ibaloi and Kankanaey peoples, investigates how risk transparency and policy alignment can bridge existing divides, while formulating principles applicable to other Indigenous mining contexts. The study provides an initial evaluation of the feasibility of a proposed large-scale mining operation within a risk-informed, data-driven governance framework. Three elements of engineering risk were assessed utilizing literature-derived and proxy parameters: (1) Land degradation is indicated by a Soil Productivity Index …

Final Quarterly Operations And Maintenance Report Butte Treatment Lagoon System – First Quarter 2024, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Long-Term Sedimentation Rates And Patterns Of Alluvial Ridge Basins (Esteros) Of The Rio Grande Delta (Tx, United States Of America), Kynan Joseph Rutan

Theses and Dissertations

Little is known about the century-scale sedimentation rates and patterns of Alluvial Ridge basins within river deltas, especially in the Rio Grande Delta (RGD). To better constrain this, 22 cores were collected in the Bahia Grande Complex (BGC) and analyzed for grain size, organic content, age dates, and elemental composition.

Results show that grain size and sedimentation rates decrease from an artificial inlet to the basin interior, with elevated sedimentation in the south. Also, human activities, such as the construction of the Brownsville shipping channel in the 1930s, altered sedimentation dynamics in the basin by blocking natural inlets and leading …

Draft Final 2022 Insufficiently Reclaimed Sites Sampling: Bres No. 50 – Zelia Site Evaluation Summary Report, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Draft Final 2022 Insufficiently Reclaimed Sites Sampling: Bres No. 96 – Washoe Dump Site Evaluation Summary Report, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Security Vulnerabilities And Defense Tactics For Generative Ai Application Development, Kyle Klein

University Honors Theses

Generative AI (GenAI) applications such as OpenAI's ChatGPT leverage large language models (LLMs) trained on enormous amounts of data to accomplish tasks such as document editing, summarization, and query response. Chatbots and LLM programs that are equipped with retrieval-augmented generation (RAG) have the ability to draw upon data provided by developers and users to improve the quality of the program's responses. LLM technology has even expanded to generate images, audio, and video from user instructions. Designed around unpredictable user input and typically composed of many opaque components, LLM software products face a paradigm shift of new, constantly evolving security challenges. …

Quantization For The Mixtures Of Overlap Probability Distributions, Asha Barua, Angelina Chavera, Ivan Djordjevic, Valerie Manzano, Sergio Soto Quintero, Mrinal Kanti Roychowdhury, Hilda Tejeda

School of Mathematical & Statistical Sciences Faculty Publications

Optimal quantization for mixed distributions has emerged as a compelling area of study. In this work, we have focused on a mixed distribution formed from two uniform distributions with partially overlapping supports. For this class of distributions, we have examined the structure of optimal sets of n-means and the corresponding nth quantization errors for all positive integers n. Initially, we explicitly determined the optimal sets and quantization errors for 1 < = n < = 6. Subsequently, we established several key lemmas and propositions and proposed an algorithm that facilitates the computation of optimal n-means and quantization errors for all n >= 5. Numerical results are also presented to illustrate the application of the algorithm in deriving these quantities. The findings of this study offer valuable insight and serve as a …

On Sobolev Spaces And The Existence Of Weak Solutions To Boundary Value Problems, Skye X. Paul

Master's Theses

Many boundary value problems that arise in mathematical models have close connections to second order elliptic partial differential equations. This thesis introduces the idea of weak derivatives and Sobolev Spaces to generalize possible solutions. Using functional analysis centered around the Lax-Milgram theorem, we show the existence of these generalized solutions to boundary value problems including Laplace's Equation, 2nd order linear ODEs, and ultimately a general second order elliptic PDE. The work cumulates with recovering a number of central theorems of functional analysis in the context of Sobolev Spaces, creating a new perspective on the solvability of these boundary value problems.

Semi-Hyponormality Of Commuting Pairs Of Hilbert Space Operators, Raul E. Curto, Jasang Yoon

School of Mathematical & Statistical Sciences Faculty Publications

We first find an explicit formula for the square root of positive 2 ×2 operator matrices with commuting entries, and then use it to define and study semi-hyponormality for commuting pairs of Hilbert space operators. For the well-known 3–parameter family 𝑊(𝛼,𝛽)⁡(𝑎,𝑥,𝑦) of 2–variable weighted shifts, we completely identify the parametric regions in the open unit cube where 𝑊(𝛼,𝛽)⁡(𝑎,𝑥,𝑦) is subnormal, hyponormal, semi-hyponormal, and weakly hyponormal. As a result, we describe in detail concrete sub-regions where each property holds. For instance, we identify the specific sub-region where weak hyponormality holds but semi-hyponormality does not hold, and vice versa. To accomplish this, …

On Variations Of Isolation In Graphs, Geoffrey Boyer

All Dissertations

In 2015, Caro and Hansberg introduced a wonderful and natural generalization of the well-studied parameter of domination in graphs. For a graph $G$ and a family of graphs $\FF$, they define $S$ to be an $\FF$-isolating set if $G-N[S]$ contains no member of $\FF$ as a subgraph. The case where $\FF=\{K_1\}$ coincides with domination. The case where $\FF=\{K_2\}$ is now simply referred to as an isolating set. We strengthen known results about the isolation number of a graph, and explore variations of the parameter including the independent and total versions.

In particular for connected graphs of order $n$, a bound …

Exploring Halogen Bonding Interactions In Cocrystals And Deep Eutectic Solvents, Madhushi Bandara

All Dissertations

Halogen bonding is a noncovalent intermolecular interaction analogous to hydrogen bonding that occurs between an electrophile and a nucleophile. This is often observed in compounds containing heavy halogens such as iodine and bromine. When these halogens are covalently bonded to another atom or molecule, preferably to an electron-withdrawing moiety, an electrophilic region called a sigma hole is created on the halogen atom on the extension of the covalent bond.

The first study of this dissertation presents a comprehensive characterization of eight newly synthesized triiodide salts using single-crystal X-ray diffraction, powder X-ray diffraction, thermal analysis (DSC and TGA), and Raman spectroscopy. …

First Principles Calculation Of Electron-Phonon Coupling In Nonequilibrium Quantum Materials, Chendi Xie

All Dissertations

This dissertation combines first-principles computation and light-induced nonequilibrium analysis to understand and control electron–phonon coupling (EPC) and emergent many-body phenomena in quantum materials, in both equilibrium and nonequilibrium states.

Chapters 1 and 2 build the theoretical and computational foundation, beginning with electron and phonon self-energies, linewidths, and perturbation theory for EPC, followed by density functional theory (DFT) and density functional perturbation theory (DFPT), which serve as the first-principles workhorses used throughout. Chapter 3 reviews Bardeen-Cooper-Schrieffer (BCS) and Migdal-Eliashberg theory, including the BCS gap - transition temperature (T_c) relation and the strong-coupling generalization, and delineates the practical validity bound …

Examining The Roles Of Embodiment And Theory Of Mind In Shaping User Perceptions Of Llm-Driven Conversational Agents, Elizabeth A. Schlesener

All Dissertations

Large Language Models (LLMs) have advanced conversational agents, enabling natural, human-like interactions in domains such as education, programming, and workplace collaboration. Yet, user distrust persists over privacy, accuracy, and bias. As developers work to mitigate these issues and human-AI collaboration expands, reinforcing trust in LLM-driven systems is essential. To address this problem, this dissertation explores the role of anthropomorphic form in LLM-driven conversational agents and its impact on user perception.

According to the familiarity thesis, humans attribute human-like characteristics to nonhuman entities — a process known as anthropomorphism — to better comprehend unfamiliar phenomena, based on the assumption that they …

Ai In Consideration Of Her: Accounting For Gendered Workplace Dynamics In The Design And Evaluation Of Human-Centered Ai Integration In Everyday Workplaces, Kelsea S. Schulenberg

All Dissertations

Rapid advancements in the technical capabilities and availability of generative Artificial Intelligence (AI) systems, such as OpenAI's ChatGPT, have drawn widespread attention to the opportunities and challenges associated with AI integration into everyday workplaces (i.e., office-type work). Following calls for organizations to consider the ethical and workplace-specific impacts of generative AI's use before integrating it into the workplace, this dissertation addresses three critical gaps in Human-Centered Computing (HCC) and AI workplace integration research. First, this dissertation unpacks the underdeveloped links between women's representation - or lack thereof - in AI-related fields and how their experiences with gendered workplace dynamics in …

Contributions To Statistical Modeling And Estimation Of Rainfall Intensity–Duration–Frequency Curves, Jiyun Huang

All Dissertations

Extreme rainfall can cause flooding, damage infrastructure, and create serious risks for communities. Engineers use Intensity-Duration-Frequency (IDF) curves to estimate precipitation extremes over different lengths of time, such as one hour or one day, and the average time one would expect wait for one of these events to occur. Several approaches exist for estimating IDF curves, but no single approach is known to be best in all cases. In this dissertation, I study statistical methods that aim to improve IDF curve estimation. I use the Canadian Regional Climate Model (CanRCM4) Large Ensemble, which contains 35 independent climate simulations. These simulations …

Reverse (Bio)Engineering: A Machine Learning Approach To Optimize Baseball Pitcher Health And Performance, Robert C. Moore

All Dissertations

Ball tracking systems are becoming ubiquitous in sport, creating an unprecedented opportunity for big data applications to optimize human health and performance. These applications are especially common in baseball, a sport known for analyzing ball flight data to quantify performance. Analysts routinely use ball flight data to identify the attributes of top performing pitchers, finding that the best pitchers throw with optimal combinations of release speed and spin to precise locations. However, for certain pitchers, the throwing motion required to produce optimal ball flight places exceedingly high biomechanical load on the elbow, and consequently injury rates continue to rise. This …