Physical Sciences and Mathematics Commons^™

Multiscale Modeling Of The Thermomechanical Behavior Of Polymeric And Molecular Organic Semiconductors, Kehinde H. Fagbohungbe

University of Kentucky Doctoral Dissertations

Organic semiconductors, derived from π-conjugated polymers and molecules, enable the development of deformable, stretchable and flexible electronics due to their tunable redox, optical, electronic and mechanical properties. However, an informed understanding of how multi-scale morphological characteristics of the polymeric and molecular semiconductors influence bulk properties that contribute to electronic and optical performance, especially under operational thermal and mechanical stresses, remains incomplete. This lack of understanding poses a challenge to scalability and commercialization of organic electronics. This dissertation develops and deploys computational modeling approaches, particularly atomistic molecular dynamics (MD) simulations, to investigate the multiscale morphological behavior of these synthetic semiconducting materials …

Math Anxiety, Math Self-Concept And Math Self-Efficacy: A Study Of The Jingle-Jangle Fallacies, Marsha Natasha Durrant-Walker

Dissertations

Problem

The overlap and lack of clear distinction among the constructs of math anxiety, math self-concept, and math self-efficacy presents issues for research and practice. The literature reveals that math anxiety is closely linked to math self-concept (Klee et al., 2022). Additionally, math self-concept and math self-efficacy often overlap and are not easily distinguishable (Kranzler & Pajares, 1997; Pajares & Miller, 1994; Pajares & Urdan, 1996). Each of these constructs has been shown to play a critical role in student math achievement (Timmerman et al., 2016). -- When constructs are not defined or measured distinctly, inconsistencies may emerge in research …

Eeg And Imu Gait Signal Processing: A Comparative Assessment Of The "Reza" Exponential Filter And Classic Filters, Reza Pousti, Daniel M. Russell, Derek C. Monroe, Christopher K. Rhea

Rehabilitation Sciences Faculty Publications

Noise degrades both EEG and gait signals, and classical IIR filters (Butterworth, Chebyshev, elliptic) involve trade-offs between passband flatness, ripple, and roll-off. This study compared a novel exponential "Reza" filter with these designs for neural and locomotor data. We analyzed an open-source mobile brain-body imaging dataset with EEG and gait data from 49 healthy adults (EEG: 256-channel, 512 Hz; IMUs: six APDM Opals, 128 Hz). EEG channels were grand-averaged and band-pass filtered at 0.5-50 Hz, while IMU axes were averaged and band-pass filtered at 0.5-5 Hz. The outcomes were signal-to-noise ratio SNR (dB) and band-integrated Welch PSD (EEG:0.5-50 Hz; IMU:0.5-5 …

Enlem: Ensemble Learning-Based Model To Detect Phishing Websites, Most Nilufa Yeasmin, Md Abu Rumman Refat, Bikash Chandra Singh, Zulfikar Alom, Zeyar Aung, Mohammad Azim

School of Cybersecurity Faculty Publications

Phishing involves manipulating individuals into revealing private data, e.g., user IDs, bank details, and passwords. The observed surge in fraud is related to increased deception, impersonation, and advanced online attacks. Thus, effective phishing detection methods are required to mitigate escalating global phishing threats. Existing methods (e.g., heuristics-based, signature-based, and visual similarity-based methods) attempt to detect phishing sites, and machine learning (ML) and deep learning (DL) methods are effective in the cybersecurity context in terms of learning from data, offering insights, and forecasting. However, independent ML algorithms are limited when handling complex data, and DL techniques surpass traditional ML methods in …

Adaptive Boundary-Aware Fact-Checker Placement For Misinformation Suppression In Social Networks, Mostafa Taghizade Firouzjaee, Ghazal Naderi, Ross Gore, Neda Moghim

School of Cybersecurity Faculty Publications

The spread of fake news on online social networks is driven by imitation-based user behavior and network topology, often leading to persistent misinformation clusters and echo chambers. In this study, we develop a spatial evolutionary game-theoretic framework in which agents update their latent opinions through payoff-biased imitation, while external fact-checkers act as non-imitative intervention nodes. Building on this formulation, we propose an adaptive, boundary-aware intervention mechanism that dynamically regulates both the density and spatial allocation of fact-checkers according to real-time system conditions. Competing information clusters are identified through local neighborhood composition, enabling boundary nodes, i.e., interfaces between fake-news and non-fake-news …

Toward Secure And Practical Machine Learning-Based Access Control: A Framework With Real-World Constraints And Adversarial Analysis, Olusesi Balogun, Mohammad Ghasemigol, Zhipeng Cai, Daniel Takabi

School of Cybersecurity Faculty Publications

Attribute-Based Access Control (ABAC) frameworks coordinate access requests based on subject, object, and environment attributes, as well as policy rules, and are widely used in corporate security systems. Recently, machine learning has been applied to ABAC to address policy-generation imbalances, misassigned privileges, and attribute leakages. However, existing MLBAC techniques do not consider the structural constraints and attribute interdependencies present in traditional ABAC systems. Moreover, these frameworks have not been extensively evaluated under black-box attack scenarios. To address these gaps, we propose extensions to MLBAC that integrate structural constraints, attribute dynamism, and attribute weighting into the MLBAC objective function. Additionally, we …

Exploring The Synergy Between Very Large Transformer And Lstm Models For Effective Medical Captioning From Videos To Text: The Impact Of Captioning In Healthcare, R. V. Aswiga, Moin Ahmed Zahir

Data Science Faculty Publications

In today’s rapidly evolving digital landscape, the demand for accurate and contextually relevant subtitles for image and video content, particularly in the medical domain, is increasingly critical. Despite the proliferation of visual data across various platforms, existing captioning systems often struggle due to variations in visual settings, complex temporal relationships, and nuanced semantics. Additionally, challenges such as limited datasets, privacy issues, and specialized annotation requirements make medical image captioning particularly difficult. To tackle these challenges, we investigate cutting-edge deep learning methodologies, specifically Transfer Learning and Transformer models, through a comparative analysis. Specifically, we focus on Transfer Learning through the MedVisionCapturer …

A Hybrid Cnn-Lstm Surrogate Model For Hyper-Resolution Spatiotemporal Flood Forecasting In Norfolk, Virginia, Yidi Wang, Jonathan L. Goodall, Chetan Kumar, Diana Mcspadden, Sergio A. Barbosa, Binata Roy, Ali Shahabi, Navid Tahvildari

Data Science Faculty Publications

Study region

Norfolk, Virginia, United States

Study focus

Accurate and timely flood forecasting is essential for enhancing resilience in coastal urban areas in the context of increasing frequency and intensity of rainfall, sea level rise and urbanization. This study presents a hybrid deep learning-based surrogate model that integrates Convolutional Neural Networks (CNN) and Long Short-Term Memory (LSTM) networks to enable real-time spatiotemporal flood forecasting. The model leverages CNN to capture spatial features from inputs such as elevation and Topographic Wetness Index (TWI), while LSTM processes time-series inputs of rainfall and tide data to capture temporal features.

New hydrologic insights for …

Training Set Augmentation And Biology-Aware Harmonization Improve Radiomic Models For Lung Cancer Prediction In Indeterminate Nodules, Claire Huchthausen, Menglin Shi, Gabriel De Sousa, James Larner, Einsley Janowski, Jonathan Colen, Krishni Wijesooriya

Data Science Faculty Publications

CT radiomics-based machine learning has potential to predict lung cancer in pulmonary nodules (PNs) earlier than standard-of-care methods. Low malignancy rates in early-development PNs and variable image acquisition hinder development of radiomic models for diagnosing these PNs. To address these challenges, we augmented training using later-development PNs and harmonized for acquisition effects. We examine early-development benign and malignant PNs (n = 106) below the sensitivity of standard-of-care diagnosis. Classifiers predicting malignancy performed near chance when trained on ComBat-harmonized radiomic features from only early-development PNs. We then augmented training with later-development benign and malignant PNs (n = 225). We evaluated whether …

Explainable Physics-Based Constraints On Reinforcement Learning For Accelerator Optimization, Jonathan Colen, Malachi Schram, Kishansingh Rajput, Armen Kasparian

Data Science Faculty Publications

We present a reinforcement learning (RL) framework for optimizing particle accelerator experiments that builds explainable physics-based constraints on agent behavior. The goal is to increase transparency and trust by letting users verify that the agent’s decision-making process incorporates suitable physics. Our algorithm uses a learnable surrogate function for physical observables, such as energy, and uses them to fine-tune how actions are chosen. This surrogate can be represented by a neural network or by an interpretable sparse dictionary model. We test our algorithm on a range of particle accelerator optimization environments designed to emulate the Continuous Electron Beam Accelerator Facility at …

Synthesis And Characterization Of Succinate Dehydrogenase Inhibitors H2/Z14 And C6/Z96 In Order To Combat Small Cell Lung Cancer, Lauren M. Graves

Honors Undergraduate Theses

The use of ubiquinone inhibitors to combat cancer is a recent development in medicinal science and procedures to efficiently synthesize these drugs remain limited. C6/Z96 and H2/Z14, two succinate dehydrogenase inhibitors, have been previously tested in vitro against NSCLC with positive results. Their similarity to ubiquinone is what makes them a strong candidate for a succinate dehydrogenase inhibitor at the ubiquinone binding site. The heterocyclic scaffolds and substituents are proposed to bind strongly through a combination of electronics, hydrogen-bonding, and fit, allowing them to bind well and prove to be more favorable than ubiquinone when competing for the Q-site. By …

To Print A Remake: An Analysis Of Hollywood Remakes And Their Cultural Value, Connor F. Seaton

Honors Undergraduate Theses

In recent years, audiences and movie critics have expressed concern that Hollywood’s growing reliance on remakes, sequels, franchises, and similar adaptations has led to a broader worry that originality is fading from modern cinema and that the industry is instead focused on using adaptations to maximize profits. Although adaptation is often seen as a commercially driven framework for reproducing existing intellectual property in a new media format, this thesis argues that it should be recognized as an autonomous cultural category with its own artistic, historical, and social significance and merit. By analyzing adaptation scholarship and reviewing its complex historical development, …

Body Mass Index Has No Impact On Complications And Mortality For Patients With Stage Iv Pancreatic Ductal Adenocarcinoma, Ren Bryant, Hannah Darnell, Megan Hall, Kelsey N. Karnik, Kristen J. Mcquerry, Ruben R. Plentz

Biostatistics Faculty Publications

Background: Pancreatic ductal adenocarcinoma (PDAC) is one of the leading causes of United States (USA) cancer death. Overweight and obesity developing into a growing global medical and socio-economic problem, affecting approximately 42% of adults in the USA population. The aim of our analysis was to evaluate the influence of overweight and obesity on complications and clinical outcome in patients with stage IV PDAC.

Methods: We retrospectively reviewed electronic health records of patients diagnosed with stage IV PDAC (n=162) who followed with the University of Kentucky from January 2017–October 2024. Comparisons were based on the body mass index (BMI): low BMI …

Enhancing Team Science By Training Collaborative Biostatisticians To Have A Strong Statistical Voice, Gina-Maria Pomann, Steven C. Grambow, Marissa C. Ashner, Bibhas Chakraborty, Nan Liu, Megan L. Neely, Sarah Peskoe, Lacey Rende, Emily Slade, Tracy Truong, Lexie Zidanyue Yang, Greg P. Samsa, Jesse D. Troy

Biostatistics Faculty Publications

Strong statistical voice is defined as the ability to advocate and negotiate for good and ethical statistical practices, including integrating and resolving differing scientific approaches. This skill is crucial for biostatisticians who work on biomedical research teams, as it ensures the integrity and accuracy of statistical analyses and fosters productive collaborations with non-statisticians. Despite its importance, new graduates often lack targeted training opportunities. This manuscript presents a scalable training approach through the development of online videos. Preliminary didactic materials focused on two key applications: providing written comments on manuscripts and engaging in study design discussions. To evaluate this training approach, …

Preliminary Observations From The Relativistic Electron Atmospheric Loss (Real) Satellite Mission, Evzen Selvon, Robyn Millan

Wetterhahn Science Symposium Posters

The Relativistic Electron Atmospheric Loss (REAL) spacecraft (launched in July 2025) is a 3U cubesat designed to measure the precise energies (1 keV – 2MeV) and pitch angles of electrons entering the Earth’s ionosphere. The mission involves Dartmouth, BU, JHUAPL, MSU, and NASA. REAL carries three particle sensors measuring low, medium, and high energies. This work is focused on the ElectroStatic Analyzer (ESA) instrument, designed to measure lower energy electrons (1-40 keV) in the directions parallel and perpendicular to the Earth’s magnetic field. This research aims to identify notable events observed by the REAL spacecraft for future analysis.

Predicting Next-Day Eur/Usd Direction Using News Sentiment And Technical Indicators With Finbert And Xgboost, Darshan Sanjaybhai Khunt

Selected Full-Text Master Theses 2021-

Forecasting exchange-rate movements is a challenging task because currency prices are influenced not only by macroeconomic and financial variables but also by market sentiment reflected in financial news. This thesis examines whether financial news headlines can be used to predict the next-day directional movement of the EUR/USD exchange rate by applying finance-specific natural language processing and machine learning techniques.

The study uses a dataset of approximately 466,000 finance-related English-language news headlines collected between 2021 and 2025, aligned with daily EUR/USD closing prices. After preprocessing and temporal alignment, the data are used to construct a binary classification task in which the …

Ai-Powered Lawyering: Ai Reasoning Models, Retrieval Augmented Generation, And The Future Of Legal Practice, Daniel Schwarcz, Sam Manning, J. J. Prescott, Patrick Barry, David R. Cleveland, Beverly Rich

Articles

Generative AI is set to transform the legal profession, though its most promising uses and ultimate effects are still unclear. While AI models like GPT-4 improve efficiency, they can also “hallucinate” and may undermine legal judgment, particularly in complex tasks typically handled by skilled lawyers. This article examines two emerging AI innovations that may mitigate these concerns: Retrieval Augmented Generation (RAG), which grounds AI-powered analysis in legal sources, and AI reasoning models, which structure complex reasoning before generating output. We conduct the first randomized controlled trial assessing these technologies, assigning upper-level law students to complete legal tasks using a RAG-powered …

Forecasting Precipitation In Cuba Using Graph Based Deep Learning, Taufiqul Islam

Earth & Environmental Sciences Theses

Daily precipitation forecasting remained a challenging problem in regions characterized by strong spatial heterogeneity, nonlinear atmospheric dynamics, and intermittent rainfall behavior. Cuba represented a particularly complex case due to the combined influence of tropical cyclones, easterly waves, mesoscale convective systems, and orographic effects, which produced highly variable rainfall patterns in both space and time. Conventional statistical and machine-learning models typically treated stations independently and therefore overlooked spatial dependencies that strongly influenced rainfall variability across the island.

This study developed a spatiotemporal deep-learning framework for daily precipitation forecasting across 40 spatial nodes in Cuba using data from 1979 to 2023. The …

Investigation Of Reey Concentrations In Argillaceous Rocks Associated With Coal Beds In Southwestern West Virginia, Alyssa Cameron Long

Theses, Dissertations and Capstones

Rare earth elements (REEs) and Yttrium are classified as “critical minerals” that are used in many industries and are typically extracted from carbonatites and related alkaline plutonic rocks. The limited availability of REE+Y requires finding alternate sources such as coal fly ash, tonstein, fireclays, and shales. This study investigates the potential enrichment of shales, fireclays, and siltstones interbedded with coal from southwestern WV in REEY, and the mechanisms of such enrichment. Using ICP-AES analysis of various rock types shows that shales, silty shales, and siderite nodules interbedded with Fire Clay and Chilton Coal beds in the Kanawha Formation record the …

Game-Based Learning For Asynchronous Ai Literacy Course: Approach To Improve Students' Cognitive, Behavioural, Affective, And Ethical Learning Of Ai, Jinhee Kim, Guang Yang, Wing Sha Chan, Xi Lin, Yukyeong Song

STEMPS Faculty Publications

Educators in higher education face persistent challenges in scaling AI literacy across disciplines and helping novice learners understand abstract AI concepts. Although research on game-based learning (GBL) reports mixed outcomes, few studies have examined its large-scale use in mandatory, asynchronous AI literacy courses for diverse undergraduate populations. Addressing this gap, this study investigates a scalable GBL-based AI literacy course delivered to 4898 first-year undergraduates across disciplines. Using a mixed-methods design with 311 valid pre- and post-survey responses and 20 interviews, the study evaluates students' cognitive, behavioural, affective, and ethical learning of AI. Quantitative results show significant improvements in overall AI …

Elevated Sulfate Concentrations In Groundwaters Of Glaciated Terrains—Natural Or Anthropogenic?, Christabel Obi, Eric W. Peterson

Faculty Publications - Geography, Geology, and the Environment

Increasing sulfate (SO₄²⁻) concentrations in groundwater systems are a growing environmental concern due to their implications for drinking-water quality and biogeochemical cycling. While sulfate is commonly of geogenic origin, its behavior in agriculturally influenced glacial aquifers remains poorly constrained. This study investigates the distribution, depth dependence, and seasonal variability of sulfate concentrations in groundwater within a riparian system comprised of sediments deposited by glaciers in central Illinois, USA. The study specifically evaluates whether sulfate concentrations 1) vary with groundwater depth, 2) exhibit seasonal trends, and 3) reflect contributions from agricultural tile drainage waters. Groundwater samples collected from …

A Digital Calibration Source For 21 Cm Cosmology Telescopes, Kalyani Balkrishna Bhopi

Graduate Theses, Dissertations, and Problem Reports (ETD)

Precise calibration of radio telescope beams and gains is a central requirement for 21 cm intensity mapping experiments, which aim to measure large scale cosmological structure through the redshifted emission line of neutral hydrogen. Bright astrophysical foregrounds dominate the sky at these frequencies, and separating them from the cosmological signal demands precise control over instrumental systematics, particularly the telescope beam and its frequency-dependent response. Existing aerial calibration sources are incoherent broadband emitters, detectable only as total power. They provide no direct phase information and suffer from poor sensitivity in low signal-to-noise regimes.

We present the Precision Emitter for 21cm Array …

Floodwater Salinity And Flood Duration Regulate Greenhouse Gas Production In High- Latitude Coastal Wetland And Tundra Soils, Mia J. Dicianna

Electronic Theses and Dissertations

Coastal high-latitude ecosystems are increasingly flooded from storm surges associated with climate change, exposing soils that were historically infrequently inundated to higher-salinity waters for longer durations. Sub-Arctic wetlands and tundra store large amounts of carbon, yet how flooding characteristics, particularly flood duration, influence microbial mineralization and, consequently, greenhouse gas (GHG) production in these soils remains poorly understood. We conducted a full-factorial microcosm incubation experiment in which coastal wetland and tundra soils were subjected to simulated flooding with three durations (1, 3, and 10 days) and four salinity treatments (unflooded, freshwater, 3 ppt, and 12 ppt) and measured carbon dioxide (CO2) …

Absolute Quantification And Identification Of Rna From Rna-Lipid Nanoparticles Using High Resolution Mass Spectrometry, Jason C. Funderburk, Yasir A. Alshehry, Matthew S. Halquist Phd, Sandro R.P. Da Rocha Phd

Graduate Research Posters

Background

RNA therapeutics are a rising drug category with potential use for a range of conditions encompassing infectious diseases to therapies for cancer, diseases, and genetic disorders. RNA-lipid nanoparticles (RNA-LNPs) are the prominent delivery method for these therapeutics approved products include mRNA vaccines and polyneuropathy treatments. The emergency use authorizations and orphan drug status of current RNA-LNP drugs has allowed approval without finalization of the regulatory analytical procedures for quality monitoring. The objective of the study was to develop an LC-MS assay to simultaneously measure identity and concentration of two therapeutically relevant intact RNA constructs extracted from RNA-LNPs to enhance …

Geospatial Analysis Of Sinkhole Density And Characteristics In West Virginia, Marissa Shannon Loftus

Graduate Theses, Dissertations, and Problem Reports (ETD)

Creation of a sinkhole map of West Virginia provides useful data to help identify areas susceptible to sinkhole related hazards, as well as allowing for detailed analysis of factors controlling karst development. Newly available, statewide LiDAR-derived digital elevation data have made mapping sinkholes over larger spatial extents feasible. For this study, sinkholes were mapped for all areas of West Virginia that are underlain by carbonate rocks; then the distribution and characteristics were evaluated overall and in four focus areas (Berkeley and Jefferson counties, Pendleton County, Greenbrier County, and Monroe County). These areas correspond to broader physiographic regions, with Berkeley, Jefferson, …

Simulating Social Attitudes With Llms: Accuracy, Demographic Effects, And Refusal Behavior In The Sensitive Domain Of Suicide Prevention, Cristina J. Perez, Michael P. Vasquez Jr., Philippe J. Giabbanelli, Patrick Y. Wu

VMASC Publications

Large language models (LLMs) are increasingly used to simulate public opinion, yet their validity in sensitive policy domains remains underexplored. We evaluate whether LLMs can reproduce attitudes toward suicide prevention policies using 32 questions drawn from seven nationally representative U.S. surveys (2023-2025). We systematically vary demographic conditioning (race/ethnicity, gender, age, education, income, party), prompt framing (direct elicitation, respondent embodiment, specialist embodiment), and model architecture (GPT-5 Nano, DeepSeek V3.2, Meta Llama 3.1 8B, Mistral Small 24B). Across 811,560 prompts, the mean absolute error—the average gap between predicted and human response distributions—is 23 percentage points. We also find that LLM responses to …

An Exploration Of Geomagnetically Induced Currents And The Accessibility Of Geomagnetic Data Collection, Richard Le

Physics Theses

Geomagnetically Induced Currents (GICs) are electrical currents induced in long grounded conductors during geomagnetic disturbances. They represent one of the primary space weather hazards to critical infrastructure, particularly high-voltage power transmission systems and other grounded conductor networks such as pipelines. As modern society becomes more dependent on these systems, understanding and mitigating the impacts of space weather has become increasingly important. This thesis examines the physical mechanisms that generate GICs, from the interaction of the solar wind with Earth’s Magnetosphere to Magnetosphere-Ionosphere-Thermosphere (MIT) coupling and the current systems that drive geomagnetic disturbances (GMDs). Case studies from Zimbabwe and Finland illustrate …

Computational Study Of Rotating Detonation Combustors, Aditya Balasubramaniam

Mechanical and Aerospace Engineering Theses

Rotating detonation combustors (RDCs) are pressure-gain combustion devices that sustain one or more continuously rotating detonation waves, offering potential thermodynamic and performance advantages over conventional deflagration-based systems. Their behavior depends strongly on combustor geometry and operating conditions. Understanding these effects is therefore essential for the design and optimization of practical RDCs. Accordingly, this thesis numerically investigates annular RDCs with two primary objectives: (1) to evaluate the effects of propellant mass flux and (2) to assess the influence of annular width on detonation-wave dynamics and combustor performance.

A finite-volume framework is used to solve the compressible reactive Euler equations with hydrogen–air …

Reliable And Label-Efficient Learning For Open-World Visual Perception And Robot Learning Under Uncertainty, Zongyao Lyu

Computer Science and Engineering Dissertations

Modern learning systems deployed in open-world environments must make reliable decisions despite predictive uncertainty, previously unseen classes, limited annotations, and distribution shifts. This dissertation develops methods for reliable and label-efficient learning in visual perception and robot control.

First, this work studies uncertainty in object detection by representing semantic and spatial predictions probabilistically. A deep-ensemble framework aggregates detections into class-probability distributions and probabilistic bounding boxes, while a subsequent extension combines deep ensembles with Monte Carlo dropout to further investigate predictive uncertainty. Second, this dissertation addresses open-set recognition, where classes absent during training may appear at inference time. An empirical study shows …

Advancing Hate Speech Detection: Binary And Multiclass Approaches From Traditional Methods To Parameter-Efficient And Ontology-Guided Language Models, Mahmoud Abusaqer

Graduate Theses/Dissertations

The widespread proliferation of hate speech on social media platforms poses significant challenges for content moderation and user safety, requiring automated systems that are simultaneously accurate, efficient, and capable of fine-grained distinctions. This thesis investigates hate speech detection through five published manuscripts organized into two complementary threads: binary detection (hateful vs. non-hateful) and multiclass detection across demographic targeting categories. The binary thread progresses from a broad 38-model baseline spanning traditional machine learning, deep learning, and transformer architectures (where RoBERTa reaches 91.48% accuracy and CatBoost remains competitive at 88.60%) to parameter-efficient adaptation, in which Low-Rank Adaptation (LoRA) of large language models …