Physical Sciences and Mathematics Commons^™

Synthesis Of 1-(2,4-Dinitrophenyl)-3,5-Diphenyl-1h-Pyrazol-4-Ol Via Trans-1,3-Diphenyl-2,3-Epoxy-1-Propanone, Oluwaseyi B Ovonramwen

Tanzania Journal of Science

The trans-1,3-diphenyl-2,3-epoxy-1-propanone was synthesized from benzaldehyde and 2-bromoacetophenone in 20 min which is more economical. The presence of ethanol and Br in 2-bromoacetophenone facilitated the reaction. The vicinal diaxial coupling constant of trans-1,3-diphenyl-2,3-epoxy-1-propanone was zero, an indication of trans configuration for a rigid 3-membered ring at ~90o dihedral angle. 1-(2,4-Dinitrophenyl)-3,5-diphenyl-1H-pyrazol-4-ol was synthesized from trans-1,3-diphenyl-2,3-epoxy-1-propanone and 2,4-dinitro phenylhydrazine in glacial CH3COOH to give 85.5% yield and characterized using FTIR, 1H, 13C NMR, DEPT 135 and MS spectra. The 1-(2,4-dinitrophenyl)-3,5-diphenyl-1H-pyrazol-4-ol can be exploited for unique biological activities and in the synthesis of synthetic fibers. Keywords:    1-(2,4-dinitrophenyl)-3,5-diphenyl-1H-pyrazol-4-ol, trans-1,3-diphenyl-2,3-epoxy-1-propanone, synthesis, 2,4-dinitro phenylhydrazine.

Potency Of Dioscorea Sansibarensis (Dioscoreaceae) Leaf Eluates On Callosobruchus Chinensis, Linnaeus 1758 (Coleoptera: Bruchidae) In The Protection Of Phaseolus Vulgaris (Fabaceae), Godfrey O. Mauti

Tanzania Journal of Science

Post-harvest losses of stored Phaseolus vulgaris to the bean weevil Callosobruchus chinensis have reached levels of significant concern. Governments and health organisations propose the discovery of reliable,  healthy and biodegradable pesticides with higher selectivity and a broad spectrum. This study presents investigations on the activities of Dioscorea sansibarensis leaf extracts on the mortality of C. chinensis and reduction of their egg-laying ability. Laboratory experiments under Completely Randomized Design (CRD) were carried out to determine the mortality and anti-oviposition activity of the vacuum liquid chromatography (VLC) eluates of n-hexane (HE), chloroform (CE), ethyl acetate (EE), n-butanol (BE) and methanol (BE) at …

Effects Of Climate Changes On Water Resources: A Case Of Mindu Dam In Morogoro Municipality, Tanzania, Simon R Melchioly

Tanzania Journal of Science

This paper presents the findings of the research conducted in Morogoro Municipality, central Tanzania. The main objective of the research was to assess the climate change impacts on water resources, taking the Mindu Dam as the case study. The study methodology involved collection, processing and analysis of both primary and secondary data. Data collection involved acquisition of Dam water level data, climate data, and Landsat 8 satellite imagery. Research findings showed that the maximum air temperature increased at a rate of 0.045% on a span of 30 years, while rainfall has been decreasing with time. Also there has been a …

Rhyolite Stratigraphy Along Succor Creek: Insights Into The Eruptive History Of The Three Fingers And Mahogany Mountain Volcanic Field, Cassandra Caryl Black

Dissertations and Theses

The Mahogany Mountain and Three Fingers calderas with their associated tuffs, the tuff of Leslie Gulch and tuff of Spring Creek, respectively, were the centerpiece of a larger rhyolite center that developed in response to Columbia River Basalt volcanism as numerous other mid Miocene rhyolite centers in a corridor from Baker City in the north to northern Nevada. Previous studies suggest a two caldera model, while others advocated for a single large caldera producing solely the tuff of Leslie Gulch. This study refines the eruptive stratigraphy along the northeastern margin of this rhyolite field with important implications for the entire …

From River To Sea: Improving Carbon System Measurement Methods For Use In Rivers, Estuaries, And Oceans, Ellie Hudson-Heck

USF Tampa Graduate Theses and Dissertations

Over the last 30 years, spectrophotometric methodologies have been developed, with increasing rigor, to accurately measure all four carbon system parameters: total alkalinity (A_T), total carbon (C_T), partial pressure of CO₂ (pCO₂), and pH. Spectrophotometric measurements of carbon system parameters rely on quantitative characterizations of the response of sulfonephthalein indicator dyes (e.g., meta-cresol purple (mCP), thymol blue (TB), and bromocresol purple (BCP)) to changing solution pH, as well the response of indicator physical-chemical characteristics to key environmental variables (salinity (S_P), temperature (T), and pressure). Until recently, the physical-chemical properties …

Effect Of Fungicide Application On Seed Yield Of Perennial Ryegrass, Piotr Goliński

IGC Proceedings (1977-2023)

In four plot experiments established according to random blocks, application effectiveness of propiconazol + carbendazim (Tilt), propiconazol + fenpropimorph (Archer), flusilazol + carbendazim (Alert) and epoxiconazol + crezoxim-metil (Juwel) pesticides regarding the infection by fungal diseases of plant inflorescence structure, biological floret site utilisation, thousand seed weight and harvested seed yield of perennial ryegrass cv. Anna (2n) and cv. Maja (4n) was analysed. The Archer preparation was found to be the most effective, both in the case of Anna and Maja cultivars. Its application was found to increase seed yield in Anna and Maja cultivars by, respectively, 21,5% and 14,5%. …

Genetic Control Of Parthenogenesis In Kentucky Bluegrass: Results From A Sexual X Apomictic Cross, E. Albertini, G. Barcaccia, A. Porceddu, D. Rosellini, Mario Falcinelli

IGC Proceedings (1977-2023)

Apomixis, as it exists in Poa pratensis L., permits to combine genotype fixation with propagation by seed. The process of apomictic seed production involves the formation of embryo sacs without meiotic reduction (apospory) and embryos without egg cell fertilization (parthenogenesis). Further information on the genetic control of apomixis was obtained by analyzing aposporous parthenogenesis and the segregation of molecular markers in a progeny resulting from a “sexual” (S) x “apomictic”(A) cross. Data from the 35 F₁ plants examined so far have shown that parthenogenesis segregated 1:1, confirming control by a dominant gene, simplex in the parthenogenetic parent. Analysis of …

Effects Of Water Stress On Seed Production In Ruzi Grass (Brachiaria Ruziziensis Germain And Everard), N. Wongsuwan, A. C. P. Chu, B. R. Watkin

IGC Proceedings (1977-2023)

Water stress at different stages of reproductive development influenced seed yield in Ruzi grass differently. Under mild water stress, the earlier in the reproductive developmental stage the stress was applied (before ear emergence) the faster the plants recovered and the less the ultimate damage to inflorescence structure and seed set compared with the situation where water stress occurred during the later stages after inflorescences had emerged. Conversely, severe water stress before ear emergence had a severe effect in damaging both inflorescence numbers and seed quality. Permanent damage to the reproductive structures resulted in deformed inflorescences. Moreover, basal vegetative tillers were …

Effect Of Temperature On Phenology In Triple-Awned Grass (Stipagrostis Plumosa), Hossein Azarnivand, H. Dastmalchi

IGC Proceedings (1977-2023)

Phenology of triple-awned grass in different stages of vegetative growth, flowering and seed falling was investigated. Each phenological stage was related to minimum and maximum air and soil surface temperatures. Soil surface temperature was measured two times per day during different seasons. Climate data were obtained from the nearest weather station. The study was carried out in sand dunes of band-e-rig of Kashan in the central region of Iran. This species is important in terms of wind erosion control and livestock feeding in arid areas. The results showed that air temperatures ranged from –22 ^oC to 41.5 ^oC …

Morphogenesis And Growth Analysis Of Mombaçagrass (Panicum Maximum) During Establishment And Regrowth, Carlos A. M. Gomide, J. A. Gomide, C. A. M. Huaman

IGC Proceedings (1977-2023)

Mombaçagrass grown in pots was evaluated regarding leaf appearance, elongation and senescence rates; leaf area indices, photosynthetcly active radiation (PAR) interception and the growth indices: leaf area ratio (LAR), net assimilation rate (NAR) and relative growth rate (RGR). Three growths were considered: seminal growth and regrowth after harvest take on the 16^th and 37^th day of the seminal growth.

The seminal growth exhibited the highest values for leaf appearance, elongation and senescence rates as compared to aftermath growths. LAI rose linearly from the 20^th to the 77^th day of the seminal growth, as well as during …

Tillering Dynamics In Mombaça Grass (Panicum Maximum, Jacq.) Under Grazing, E. M. Coelho, V. R. Herling, M. A. Gomes, R. J. Schmidt, C. G. Lima

IGC Proceedings (1977-2023)

An experiment was conducted in Pirassununga, Southeastern Brazil, to observe tillering pattern of Mombaça grass (Panicum maximum Jacq.) after grazing. A complete randomized block design was used with treatments arranged in factorial (3 herbage allowances X 2 grazing periods). There was high and positive correlations between the total tiller population and the number of tillers until the third week after grazing, giving evidence of a higher tillering until the second week and a slight reduction on the third one. The Mombaça grass tillering dynamics alters along the weeks according the allowance level adopted.

Response Of Mombaça Grass (Panicum Maximum Jacq.) To Nitrogen Doses And Clipping Frequency, Gustavo J. Braga, P. H. C. Luz, V. R. Herling, R. J. Schmidt, C. G. Lima

IGC Proceedings (1977-2023)

The present experiment had the objectives of determining the response of Mombaça grass (Panicum maximun Jacq.) to three levels of nitrogen fertilizer (0, 250, 500 kg/ha) and two clipping frequencies (28 and 42 days). Dry matter yield (DMY), density and the average weight of tillers and the mean stage count (MSC), value that represents the quantity of the plant phenological development were evaluated. Nitrogen levels affected DMY, with the 500 kg/ha of N resulting in highest yield, and highest MSC as well. The number of tillers responded positively until the 250 kg/ha level. The 42-day frequency gave higher numbers …

Climate On The Blanca Massif, Sangre De Cristo Mountains, Colorado, Usa, During The Last Glacial Maximum, Keith A. Brugger, Eric M. Leonard, Kurt A. Refsnider, Peter Dolan

Geology Publications

Temperature-index modeling is used to determine the magnitude of temperature depression on the Blanca Massif, Colorado, required to maintain steady-state mass balances of nine reconstructed glaciers at their extent during the Last Glacial Maximum (LGM). The mean temperature depression thus determined is ~8.6 +0.7/−0.9 degrees C where the uncertainties account for those inherent in the glacier reconstructions, in model parameters (e.g., melt factors), and possible modest changes in LGM precipitation. Associated equilibrium-line altitudes (ELAs) exhibit a statistically significant directional dependency being lower toward the north and east. Under the assumption that regional temperature change was uniform, required changes in precipitation …

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Sediqa: Sound Emitting Document Image Quality Assessment In A Reading Aid For The Visually Impaired, Jane Courtney

Articles

For visually impaired people (VIPs), the ability to convert text to sound can mean a new level of independence or the simple joy of a good book. With significant advances in optical character recognition (OCR) in recent years, a number of reading aids are appearing on the market. These reading aids convert images captured by a camera to text which can then be read aloud. However, all of these reading aids suffer from a key issue—the user must be able to visually target the text and capture an image of sufficient quality for the OCR algorithm to function—no small task …

Spin-Orbit Dependence Of Anisotropic Current-Induced Spin Polarization, L. L. Tao, Evgeny Y. Tsymbal

Department of Physics and Astronomy: Faculty Publications

Studies of the current-induced spin polarization (CISP) have been recently reinvigorated due to the discoveries of CISP in some burgeoning materials such as oxide interfaces, van der Waals, and topological quantum materials. Here, we investigate the CISP in two-dimensional systems for different types of spin-orbit coupling (SOC) using the Boltzmann transport theory. We find an anisotropic response of CISP to the current direction which strongly depends on the type of SOC. We demonstrate that the CISP is nonlinear with respect to the SOC magnitude, depends on the Fermi energy, and exhibits two different transport regimes for low or high carrier …

Silver Bow Creek/Butte Area Npl Site Butte Priority Soils Operable Unit, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Herbage Allowance And Nitrogen Fertilization Effects On Morphological Characteristics Of Paspalum Notatum Flügge, P. Boggiano, G. E. Maraschin, Carlos Nabinger, J. Riboldi, Mónica Cadenazzi

IGC Proceedings (1977-2023)

The grazing study was conducted at the Estação Experimental Agronomica – UFRGS, 30^o S, on a native pasture, to evaluate the leaf area index and structural morphological traits of bahiagrass (Paspalum notatum Fl.), within the requirements of a Central Composite Rotatable experimental design, providing for equal precision, with two blocks, encompassing two factors at five levels each, namely: Herbage Allowance (HA) = 4.0; 5.5; 9.0; 12.5 and 14.0 kg green dry matter per 100 kg liveweight per day (% LW), in association with Nitrogen (N) fertilization levels of 0; 30; 100; 170 and 200 kg ha^-1 as …

Influence Of Fertilization On Botanical Composition And Productivity Of Rangeland In A Semi-Arid Climate Of South Africa, Hennie A. Snyman, I. B. Oosthuizen

IGC Proceedings (1977-2023)

The objective of this study was to determine the short-term response of rangeland to fertilization rangeland (all combinations of 0; 10; 30 and 50 kg ha^-1 nitrogen, with 0 and 10 kg ha^-1 of phosphorus) in terms of dry matter production and botanical composition. After three years of fertilization, the botanical composition of the high-N fertilized plots changed completely from a climax to sub-climax vegetation. Wire grass (Elionurus muticus) showed the greatest decrease in frequency (62%) due to N fertilization. Phosphorus fertilization had an insignificant influence on species composition over the three years. The increase (P< 0.01) in production with increased N fertilizer, peaked in the second season, declining afterwards. With N and P fertilizer applied together, the production increased constantly and peaked in the last season. After three years the production increased (P≤ 0.01) with the application of N together with P, compared to the applying of only N. The higher the amount of fertilizer, the more sensitive to drought the climax grasses became. The results confirm the vulnerability of native grasses in dry areas, due to change in soil fertility.

Defoliation And Water Deficit: Their Influence On Pasture Growth And Water Use Of White Clover, F. H. Santiñaque

IGC Proceedings (1977-2023)

With the objective of understanding the physiological basis of defoliation and water use relationships of white clover (Trifolium repens L.) pastures during water deficits, an experiment in controlled conditions was carried out. Outdoors nine liters pots were filled with a loam-clay soil with a water content at field capacity (FC), of 35%(w/w), at a bulk density of 1.1 g/cm³. Pre-germinated and inoculated clover seeds were transplanted, and the number of plants was adjusted to permit the development of full plant cover. The level of P in the soil did not limit plant establishment or growth. The …

Seasonal Botanical Composition And Available Forage Of Natural Grasslands In The Southeastern Range Region Of Rio Grande Do Sul, Brazil, J. C. L. Reis, H. Alfaya, O. J. W. Siqueira, C. B. Farias Jr.

IGC Proceedings (1977-2023)

The objective of the study was to verify the influence of climatic seasons on botanical composition and on available dry matter of grasslands in the physiographic region known as Serra do Sudeste (Southeastern Range), RS, Brazil. The climate is Cfb according to Koëppen`s classification. The experiment was conducted in two natural grasslands submitted to two pre-experimental stocking rates [area 1: 0.65 AU ha^-1 (normal grazing); area 2: over 2.0 AU ha^-1 (overgrazing); AU: Animal Unit = 500kg live weight]. Stocking rates throughout the experimental period (June 1996–July 1997) were 0.4 and 0.65 AU ha^-1, over winter …

Effect Of Sowing Time On Phytomass Production During Early Growth Of Two Varieties Of Stylosanthes Guianensis (Aubl.) Sw., M. L.S. Paterniani, T. J. D. Rodrigues, G. T. Pereira, L. R. A. Rodrigues

IGC Proceedings (1977-2023)

The objective of this research was to determine the effect of two sowing times on phytomass production of two varieties of Stylosanthes guianensis (var. pauciflora and var. vulgaris). Two experimental periods were studied (1: January - May/1998 and 2: November/1998 - March/1999) using a completely randomized factorial design 2 x 2 x 14 (two periods, two varieties and fourteen ages of evaluation), with four replications. The results showed a difference between the periods concerning the growth and development of Stylosanthes, and that period 2 was the most favourable to this forage plant. There was, also, different adaptability between …

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No abstract provided.

Silk-Cellulose Acetate Biocomposite Materials Regenerated From Ionic Liquid, Ashley Rivera-Galetti, Chrtstopher R. Gough, Farhan Kaleem, Michael Burch, Chris Ratcliffe, Ping Lu, David Salas-De La Cruz, Xiao Hu

College of Science & Mathematics Departmental Research

The novel use of ionic liquid as a solvent for biodegradable and natural organic biomaterials has increasingly sparked interest in the biomedical field. As compared to more volatile traditional solvents that rapidly degrade the protein molecular weight, the capability of polysaccharides and proteins to dissolve seamlessly in ionic liquid and form fine and tunable biomaterials after regeneration is the key interest of this study. Here, a blended system consisting of Bombyx Mori silk fibroin protein and a cellulose derivative, cellulose acetate (CA), in the ionic liquid 1-ethyl-3-methylimidazolium acetate (EMIMAc) was regenerated and underwent characterization to understand the structure and physical …

Influence Of Water Stress On Protein Concentration In Themeda Triandra Forsk. In A Semi-Arid Climate Of South Africa, I. B. Oosthuizen, Hennie A. Snyman

IGC Proceedings (1977-2023)

The objective of this study was to determine the influence of four water treatments (T1 = 75-100%, T2 = 50-75%, T3 = 25-50% and T4 = 0-25% of Field Water Capacity) on the concentration of water-soluble protein as growth reserve during three growth stages (vegetative, pipe and reproductive) in three plant parts (roots, stubble and leafs). The water-soluble protein concentration (WSPC) in the plants under the four water treatments differed (P≤0.01) among the plant parts as well as among growth stages (P≤0.05). WSPC in leafs increased (P≤0.01) with increased water stress from T1 to T4 for the pipe growth stage. …

Effects Of Photoperiod, Low Temperature And N Nutrition On Vsp Accumulation In Taproot Of Alfalfa, J. C. Avice, C. Noquet, A. Ourry, J. J. Volenec

IGC Proceedings (1977-2023)

In Medicago sativa L., vegetative storage protein (VSP), specifically accumulated in taproot, are strongly involved in nitrogen storage. How the accumulation of such VSPs is regulated remains largely unknown. Experiments were designed with non-nodulated alfalfa to determine if length of the photoperiod, a decrease of temperature, or high availability of mineral nitrogen may induce the accumulation of VSPs. ¹⁵N labelling was used to quantify nitrogen uptake and its further relative translocation within the plant while VSPs accumulation was analysed by ELISA quantification. Results showed that environmental factors such as shortening daylength or low temperature changed biomass allocation within the …

Fructans From Elongating Leaf Bases Are A Source Of Carbon For Regrowth After Defoliation In Lolium Perenne, A. Morvan-Bertrand, J. C. Avice, M. P. Prud'homme

IGC Proceedings (1977-2023)

A detailed study of carbohydrate metabolism in perennial ryegrass (Lolium perenne L.) during the first 48 h of regrowth showed that the decline in fructan concentration occurred not only in the differentiation zone (30-60 mm from leaf base), but also in the elongation zone of the elongating leaf bases. Unlike other soluble carbohydrates, the net deposition rate of fructose remained positive and even rose during the first day following defoliation. FEH (fructan exohydrolase) activity, which was maximum in the differentiation zone before defoliation, increased in all segments but peaked in the elongation zone after defoliation. Taken all together, these …

Effect Of Climatic Factors On The Plant Population Dynamics In Temperate Pasture Implantation, B. Martin, R. Refi, S. Montico, M. Costanzo

IGC Proceedings (1977-2023)

The objective of this experiment was to determine the environmental influence on seedling emergence of alfalfa and fescue in mixture. We hypothesized that the temperature and precipitation data could be used to estimate field emergence of alfalfa and fescue. A field trial was carried out at Zavalla, Argentina and consisted of sowing a tall fescue – alfalfa mixture at different seeding date (March, April and June). Relationships between the range of temperature, rainfalls and alfalfa and fescue seedling emergence were described by linear regression models. Patterns of emergence and death of alfalfa and fescue seedling were found in the different …

Commuting Isometries And Invariant Subspaces In Several Variables., Sankar T. R. Dr.

Doctoral Theses

A very general and fundamental problem in the theory of bounded linear operators on Hilbert spaces is to find invariants and representations of commuting families of isometries.In the case of single isometries this question has a complete and explicit answer: If V is an isometry on a Hilbert space â„‹, then there exists a Hilbert space Hu and a unitary operator U on â„‹u such that V on â„‹u and[ S ⊗ IW 0 0 U] ∈ B((l 2 (ℤ+) ⊗ W) ⊕ â„‹u),are unitarily equivalent, whereW = ker V∗ ,is the wandering subspace for V and S is the …

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No abstract provided.