Physical Sciences and Mathematics Commons^™

The Molecular Structure And Curious Motions In 1,1-Difluorosilacyclopent-3-Ene And Silacyclopent-3-Ene As Determined By Microwave Spectroscopy And Quantum Chemical Calculations, Thomas M.C. Mcfadden, Nicole Moon, Frank E. Marshall, Amanda J. Duerden, Esther J. Ocola, Jaan Laane, Gamil A. Guirgis, Garry S. Grubbs

Chemistry Faculty Research & Creative Works

The molecules 1,1-difluorosilacyclopent-3-ene (3SiCPF2) and silacyclopent-3-ene (3SiCP) have been synthesized and studied using chirped pulse, Fourier transform microwave (CP-FTMW) spectroscopy. For 3SiCP this is the first ever microwave study of the molecule and, for 3SiCPF2, the spectra reported in this work have been combined with that of previous work in a global fit. The spectra of each contain splitting which has been fit using a Hamiltonian consisting of semirigid and Coriolis coupling parameters. A refit of the original 3SiCPF2 work was also carried out. All fits and approaches are reported. Analyses of the spectra provide evidence that the molecule is …

Many-Objective Evolutionary Algorithms: Objective Reduction, Decomposition And Multi-Modality., Monalisa Pal Dr.

Doctoral Theses

Evolutionary Algorithms (EAs) for Many-Objective Optimization (MaOO) problems are challenging in nature due to the requirement of large population size, difficulty in maintaining the selection pressure towards global optima and inability of accurate visualization of high-dimensional Pareto-optimal Set (in decision space) and Pareto-Front (in objective space). The quality of the estimated set of Pareto-optimal solutions, resulting from the EAs for MaOO problems, is assessed in terms of proximity to the true surface (convergence) and uniformity and coverage of the estimated set over the true surface (diversity). With more number of objectives, the challenges become more profound. Thus, better strategies have …

Revised Silver Bow Creek Butte Area Npl Site 2022 Final Butte Priority Soils Operable Unit Interim Site-Wide Surface Water Monitoring Quality Assurance Project Plan. Consent Decree- Civil Action No. Cv 89-039-Bu-She, Josh Bryson

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Silver Bow Creek/Butte Area Npl Site Butte Priority Soils Operable Unit 2022 Final Interim Site-Wide Surface Water Monitoring Qapp, Trec Inc., A Woodard And Curran Company

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Advances Of Phosphide Promoter Assisted Pt Based Catalyst For Electrooxidation Of Methanol, Meng Li, Li-Gang Feng

Journal of Electrochemistry

Transition metal phosphide (TMP), as an ideal catalytic promoter in methanol fuel oxidation, has received increased attention because of its multifunctional active sites, tunable structure and composition, as well as unique physical and chemical properties and efficient multi-composition synergistic effect. Some advances have been made for this catalyst system recently. In the current review, the research progresses of transition metal phosphides (TMPs) in the assisted electrooxidation of methanol including the catalysts fabrication and their performance evaluation for methanol oxidation are reviewed. The promotion effect of TMPs has been firstly presented and the catalyst systems based on the different metal centers …

A High-Performance Continuous-Flow Mea Reactor For Electroreduction Co2 To Formate, Pei-Xuan Liu, Lu-Wei Peng, Rui-Nan He, Lu-Lu Li, Jin-Li Qiao

Journal of Electrochemistry

The electrochemical carbon dioxide reduction reaction (CO₂RR) is a promising approach to produce liquid fuels and industrial chemicals by utilizing intermittent renewable electricity for mitigating environmental problems. However, the traditional H-type reactor seriously limits the electrochemical performance of CO₂RR due to the low CO₂ solubility in electrolyte, and high ohmic resistance caused by the large distance between two electrodes, which is unbeneficial for industrial application. Herein, we demonstrated a high-performance continuous flow membranes electrode assembly (MEA) reactor based on a self-growing Cu/Sn bimetallic electrocatalyst in 0.5 mol·L^-1 KHCO₃ for converting CO₂ to …

Acetate Solutions With 3.9 V Electrochemical Stability Window As An Electrolyte For Low-Cost And High-Performance Aqueous Sodium-Ion Batteries, Dao-Yun Lan, Xiao-Feng Qu, Yu-Ting Tang, Li-Ying Liu, Jun Liu

Journal of Electrochemistry

Low-cost and high-safety aqueous sodium-ion batteries have received widespread attention in the field of large-scale energy storage, but the narrow electrochemical stability window (1.23 V) of water limits the energy density of aqueous sodium-ion batteries. The “water-in-salt” strategy which uses the interaction between cations and water molecules in the solution can inhibit water decomposition and broaden the electrochemical stability window of water. In this work, two types of low-cost salts, namely, ammonium acetate (NH₄CH₃COOH) and sodium acetate (NaCH₃COOH), were used to configure a mixed aqueous electrolyte for aqueous sodium-ion batteries. The solution consisted of …

Progress Of Pt-Based Catalysts In Proton-Exchange Membrane Fuel Cells: A Review, Long Huang, Hai-Chao Xu, Bi Jing, Qiu-Xia Li, Wei Yi, Shi-Gang Sun

Journal of Electrochemistry

Fuel cells are energy conversion devices that convert chemical energy directly into electricity. It has the advantages of high energy density, high utilization efficiency of fuel, clean and noiseless during working. Among all kinds of fuel cells, proton exchange membrane fuel cells (PEMFCs) are most popular since PEMFCs function at near ambient temperature, while their power densities are higher than those of other fuel cells. Currently, Pt-based nanomaterials are still the unreplaceable catalysts in commercialized PEMFCs. The lack of low-cost and high-performance cathode catalysts is still one of key factors that hampers the commercialization of PEMFCs. In this review, the …

Oxidative Efficiency Of Ozonation Coupled With Electrolysis For Treatment Of Acid Wastewater, Ze-You Hu, Feng-Yun Xiang, Ji-Qiang Mao, Ya-Lei Ding, Shao-Ping Tong

Journal of Electrochemistry

Establishment of an ozone-based advanced oxidation process (AOPs-O₃) for effective treatment of acid wastewater is an important and difficult task. The process of ozonation coupled with electrolysis (electrolysis-ozonation, E-O₃) has been reported to effectively degrade pollutants in neutral solution. We studied the efficiency of E-O₃ for degradation of acetic acid (HAc, an ozone inert chemical) in acid solution and found that E-O₃ had high oxidative efficiency at pH less than 3. For example, 52.2% of 100 mg·L^-1 HAc could be removed by E-O₃ in 120 min at pH 1.0, but only 2.2% …

Synthesis Of Lithium-Rich Manganese-Based Layered Cathode Materials And Study On Its Structural Evolution Of First Cycle Overcharge, Chen-Xu Luo, Chen-Guang Shi, Zhi-Yuan Yu, Ling Huang, Shi-Gang Sun

Journal of Electrochemistry

Lithium-rich manganese-based cathode materials have become one of promising cathode materials due to their low cost and large discharge specific capacity exceeding 250 mAh·g^-1. However, their problems such as low coulombic efficiency of first cycle and apparent voltage decay influence commercialization process. The high charging voltage will cause instability of structure and increase the hidden danger of the battery. Therefore, structural evolution of first cycle at higher voltage needs to be further studied. In this work, the precursor was synthesized by the co-precipitation method, and the lithium-rich manganese-based layered cathode materials were prepared by lithium-mixed and high-temperature sintering, …

Copy Of Revision Summary - Sbc/Butte Area Npl Site Final Bpsou Interim Site-Wide Surface Water Monitoring Qapp 2020 And 2021 Monitoring Period, 10/14/20, Atlantic Richfield Company, Trec Inc., A Woodard And Curran Company

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Silver Bow Creek/Butte Area Npl Site, Trec Inc., A Woodard And Curran Company

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Forage Systems To Optimize Agronomic And Economic Performance In Organic Dairy Systems, S. Ray Smith, G. Pighetti, D. M. Butler, Kenneth H. Burdine, Krista Lea, K. Mercier, K. Payne, J. Allison, Gary E. Bates, N. Colton, A. Rius, P. Krawczel, E. Eckelkamp

IGC Proceedings (1977-2023)

Organic dairy production in the USA is growing, but most forage systems research focuses on conventional production practices. As a result, organic dairy producers have limited science-based information to assist with farm and livestock management. The objective of this project was to use a multi-faceted approach to determine the ideal species mixtures for organic dairy production as well as document forage quality, forage yield, soil characteristics, milk production and milk quality during the grazing season. The forages studied ranged from a single species monoculture to a four species mixture of warm and cool season grasses and legumes. Nine distinct forage …

Fodder Crop Adoption Through Push-Pull Technology (Ppt) For Fall Armyworm (Faw) Control In Cereals Cropping Systems, Michael N. Njunie, E. N. Muthiani, A. Mzingirwa, N. F. Pole, B. M. Muli, A. O. Esilaba

IGC Proceedings (1977-2023)

There is an urgent need to increase grain yields and animal products due to increasing human population in Africa. Push-pull technology (PPT) is a conservation agriculture intercrop technology which protects and enhances natural resources productivity and ecosystem services in mixed farming systems. The technology involves growing of a cereal crop with a repellent intercrop, Desmodium genus (silverleaf, D. uncinatum and greenleaf, D. intortum) with grass such as Pennisetum purpureum or Brachiaria spp. planted as a border around the cereal-legume intercrop. The plants accompanying the cereal crop are typically valuable high quality fodder thus integrating crop-livestock production. The PPT was …

Evaluation Of The Chemical And Biological Characteristics Of Sake Lees, S. Katsumata, S. Yamanaka, M. Yamauchi, H. Hirooka, H. Kumagai

IGC Proceedings (1977-2023)

Sake lees (SLs), produced from brewing Japanese Sake and known to be rich in yeast, is expected to be an alternative of feed protein sources for ruminants. Previous studies showed that yeast improved the digestibility of fibers in ruminants. However, the nutrient composition and the numbers of live and dead yeast in the SLs, have large diversity because of the different brewing materials and processes. The objective of this study was to evaluate the chemical and biological characteristics of SLs with diverse brewing processes and storing periods (0-23 weeks). Seven types of SLs (SLs 1-7) were collected from two breweries. …

Effect Of High-Intensity, Short-Duration Grazing On Species Density And Botanical Composition Of Arid Rangelands, Mounir Louhaichi, Mouldi Gamoun, Fethi Gouhis, Ezzeddine Belfekih, Mohamed Abdelkader

IGC Proceedings (1977-2023)

Rangelands are the mainstay of pastoral and agropastoral livelihoods worldwide. They have provided forage for livestock and wildlife for centuries, but steady degradation of rangelands is causing increasing concern. Many rangeland managers believe exclusion of livestock grazing for extended periods would allow degraded rangelands to recover. The purpose of this current ongoing research is to evaluate the effect of high-intensity short-duration grazing on plant density, species richness and botanical composition on arid rangelands during favorable years. The site, which is protected for two years in southern Tunisia and covers an area of 6 ha, was grazed by a flock of …

Economics Of Greenhouse Gas Mitigation Strategies In A North-Eastern Brazilian Beef Production System, K. Agethen, Rogerio M. Mauricio, C. Deblitz

IGC Proceedings (1977-2023)

The state of Maranhão, Brazil, has been among the country’s fastest-growing cattle regions in recent years and it now faces important conflicts for beef production. Pasture degradation, low cattle productivity, and land-use changes due to agriculture and forestry expansion are key challenges. Additionally, beef production systems are a focus for emissions reduction, particularly in the context of increasing deforestation and its impact on global warming. A sustainable intensification of currently used pastures, enhancing economic viability and reducing environmental effects of beef production can help to mitigate the climate impact. Since economics is an important incentive in the decision-making processes of …

Environmental Isotope Geochemistry Ocg 550, Joanna Burkhardt

Library Impact Statements

No abstract provided.

A History Of Wright State University's Department Of Geological Science, Paul J. Wolfe

Earth and Environmental Sciences Faculty Publications

A history of Wright State University's disbanded and reintegrated Department of Geological Sciences written by department faculty member Paul J. Wolfe. Wolfe describes the development of the program, the faculty throughout the years, and the programs offered through the department.

Optimal Eavesdropping In Quantum Cryptography, Atanu Acharyya Dr.

Doctoral Theses

Quantum key distribution (QKD) has raised some promise for more secured communication than its classical counterpart. It allows the legitimate parties to detect eavesdropping which introduces error in the channel. If disturbed, there are ways to distill a secure key within some threshold error-rate. The amount of information gained by an attacker is generally quantified by (Shannon) mutual information. Knowing the maximum amount of information that an intruder can gain is important for post-processing purposes, and we mainly focus on that side in the thesis. Renyi information is also useful especially when post-processing is considered. The scope of this thesis …

Applications Of Unsupervised Machine Learning In Autism Spectrum Disorder Research: A Review, Chelsea Parlett-Pelleriti, Elizabeth Stevens, Dennis R. Dixon, Erik J. Linstead

Engineering Faculty Articles and Research

Large amounts of autism spectrum disorder (ASD) data is created through hospitals, therapy centers, and mobile applications; however, much of this rich data does not have pre-existing classes or labels. Large amounts of data—both genetic and behavioral—that are collected as part of scientific studies or a part of treatment can provide a deeper, more nuanced insight into both diagnosis and treatment of ASD. This paper reviews 43 papers using unsupervised machine learning in ASD, including k-means clustering, hierarchical clustering, model-based clustering, and self-organizing maps. The aim of this review is to provide a survey of the current uses of …

Reply To Comment: Controls On Turnover Of Marine Dissolved Organic Matter-Testing The Null Hypothesis Of Purely Concentration-Driven Uptake, Yuan Shen, Ronald Benner

Faculty Publications

Our recent bioassay experiments indicate that molecular properties are a primary control on the microbial utilization of dissolved organic matter in the ocean. This finding is questioned by Lennartz and Dittmar who modeled our experiments and concluded that our observations could be largely explained by concentration-driven uptake independent from molecular properties. We suggest the authors' models are deficient for establishing the relative roles of molecular properties and concentration-driven uptake. Our conclusion is consistent with earlier and recent experimental results and biogeochemical observations, supporting a unified theory with molecular properties as a more prominent control than concentration-driven uptake on marine organic …

P3k14c, A Synthetic Global Database Of Archaeological Radiocarbon Dates, Erick Robinson

Anthropology Faculty Publications and Presentations

Archaeologists increasingly use large radiocarbon databases to model prehistoric human demography (also termed paleo-demography). Numerous independent projects, funded over the past decade, have assembled such databases from multiple regions of the world. These data provide unprecedented potential for comparative research on human population ecology and the evolution of social-ecological systems across the Earth. However, these databases have been developed using different sample selection criteria, which has resulted in interoperability issues for global-scale, comparative paleo-demographic research and integration with paleoclimate and paleoenvironmental data. We present a synthetic, global-scale archaeological radiocarbon database composed of 180,070 radiocarbon dates that have been cleaned according …

On The Security Of Bluetooth Low Energy In Two Consumer Wearable Heart Rate Monitors/Sensing Devices, Yesem Kurt Peker, Gabriel Bello, Alfredo J. Perez

Computer Science Faculty Publications

Since its inception in 2013, Bluetooth Low Energy (BLE) has become the standard for short-distance wireless communication in many consumer devices, as well as special-purpose devices. In this study, we analyze the security features available in Bluetooth LE standards and evaluate the features implemented in two BLE wearable devices (a Fitbit heart rate wristband and a Polar heart rate chest wearable) and a BLE keyboard to explore which security features in the BLE standards are implemented in the devices. In this study, we used the ComProbe Bluetooth Protocol Analyzer, along with the ComProbe software to capture the BLE traffic of …

Drought Severity In Somalia, Food And Agricultural Organization Of The United Nations, Somalia Water And Land Information Management

East Africa

The poor rains during the last three consecutive seasons (October 2020 to December 2021) have caused widespread and worsening drought condi-tions across most parts of Somalia. This has result-ed in failed crop harvests, widespread water short-age, triggering abnormal livestock migration, de-cline in livestock production and increased live-stock deaths. Water and food prices have contin-ued to rise sharply.

Effects Of Long-Term Fluoride Exposure Are Associated With Oxidative Biochemistry Impairment And Global Proteomic Modulation, But Not Genotoxicity, In Parotid Glands Of Mice, Giza Hellen Nonato Mirandai, Leidiane Alencar De Oliveira Lima, Leonardo Oliveira Bittencourt, Sa´Vio Monteiro Dos Santos, Michel Platini Caldas De Souza, Lygia Sega Nogueira, Edivaldo Herculano Corrêa De Oliveira, Marta Chagas Monteir, Aline Dionizio, Aline Lima Leite, Juliano Pelim Pessan, Juliano Pelim Pessan, Marı´Lia Afonso Rabelo Buzalaf, Rafael Rodrigues Limai

Department of Chemistry: Faculty Publications

Fluoride has become widely used in dentistry because of its effectiveness in caries control. However, evidence indicates that excessive intake interferes with the metabolic processes of different tissues. Thus, this study aimed to investigate the effects of long-term exposure to F on the parotid salivary gland of mice, from the analysis of oxidative, proteomic and genotoxic parameters.

The animals received deionized water containing 0, 10 or 50 mg/L of F, as sodium fluoride, for 60 days. After, parotid glands were collected for analysis of oxidative biochemistry, global proteomic profile, genotoxicity assessment and histopathological analyses.

The results revealed that exposure to …

A Hybrid Multi Objective Cellular Spotted Hyena Optimizer For Wellbore Trajectory Optimization, Kallol Biswas, Amril Nazir, Tauhidur Rahman, Mayeen Uddin Khandaker, Abubakr M. Idris, Jahedul Islam, Ashikur Rahman, Abdul-Halim M. Jallad

All Works

Cost and safety are critical factors in the oil and gas industry for optimizing wellbore trajectory, which is a constrained and nonlinear optimization problem. In this work, the wellbore trajectory is optimized using the true measured depth, well profile energy, and torque. Numerous metaheuristic algorithms were employed to optimize these objectives by tuning 17 constrained variables, with notable drawbacks including decreased exploitation/exploration capability, local optima trapping, non-uniform distribution of non-dominated solutions, and inability to track isolated minima. The purpose of this work is to propose a modified multi-objective cellular spotted hyena algorithm (MOCSHOPSO) for optimizing true measured depth, well profile …

Rangeland Degradation In Mongolia – Using State And Transition Models To Help Understand Rangeland Dynamics, S. Sainnemekh, B. Densambuu, B. Bestelmeyer, I. C. Barrio, A. L. Aradóttir

IGC Proceedings (1977-2023)

Rangeland degradation and soil erosion pose constant challenges to the management of natural resources in Mongolia. Large increases in livestock numbers since the early 1990s, together with increasing temperatures and higher frequency of extreme weather events have led to widespread degradation of rangeland resources, to the extent that today, nearly 57% of rangelands in Mongolia are considered degraded to some degree. New ways of understanding the dynamics of rangeland ecosystems and guidelines to conserve healthy and productive rangelands are urgently needed. The application of State and Transition Models (STMs) in ecosystem management has shown promise to understand the mechanistic processes …

An Approach To Evaluate Soils Influence On Floristic Composition Of Natural Grasslands, F. L. F. De Quadros, R. M. R. De Carvalho, R. Farenzena, L. Marin, P. L. Nascimento

IGC Proceedings (1977-2023)

This trial aims to evaluate floristic composition of most abundant species in three soil typical of Pampa biome on Brazil. The survey was held at Maronna Fundation located on southern Alegrete municipality, on Rio Grande do Sul, Brazil’s state. Regional climate belongs to Koeppen’s Cfa class. Soil types were shallow basalt (Psamments e Orthents), deep basalt (Vertisols) and sandy soil (Acrisols or Ultisols). Floristic composition were evaluated by visual ranking of aerial biomass of the major species (transformed to kg of dry matter per hectare), calibrated by cuts at ground level, according to field procedures of BOTANAL method. Grasses were …

Interindividual Differences And Their Consistency In Grazing Cattle Behavior Across Seasons, H. Anzai, M. Shitajikkoku, K. Hani, N. Yamada, M. Hirata

IGC Proceedings (1977-2023)

Interindividual differences and their consistency in behavior were investigated for cattle (Bos taurus) grazing a bahiagrass (Paspalum notatum) and centipedegrass (Eremochloa ophiuroides) dominated pasture as a herd of about 30 breeding cows with their calves. Behavior of the cows was monitored directly by observers and also using GPS and accelerometer data loggers attached to focal cows for a period of 1–5 days every month during the grazing seasons (from May to October) in 2018 and 2019. The data were converted into behavioral variables (e.g. time spent grazing, ruminating and resting, time spent in particular …