Physical Sciences and Mathematics Commons^™

Alkaline Seawater Electrolysis At Industrial Level:Recent Progress And Perspective, Tao Zhang, Yi-Pu Liu, Qi-Tong Ye, Hong-Jin Fan

Journal of Electrochemistry

Industrial hydrogen generation through water splitting, powered by renewable energy such as solar, wind and marine, paves a potential way for energy and environment sustainability. However, state-of-the-art electrolysis using high purity water as hydrogen source at an industrial level would bring about crisis of freshwater resource. Seawater splitting provides a practical path to solve potable water shortage, but still faces great challenges for large-scale industrial operation. Here we summarize recent developments in seawater splitting, covering general mechanisms, design criteria for electrodes, and industrial electrolyzer for direct seawater splitting. Multi-objective optimization methods to address the key challenges of active sites, reaction …

Recent Advances In Computational Study And Design Of Mof Catalysts For Co2 Conversion, Haoyuan Chen

School of Integrative Biological & Chemical Sciences (Formerly Dept. of Chemistry)

Catalytic conversion of the greenhouse gas CO2 into value-added chemicals and fuels is highly beneficial to the environment, the economy, and the global energy supply. Metal–organic frameworks (MOFs) are promising catalysts for this purpose due to their uniquely high structural and chemical tunability. In the catalyst discovery process, computational chemistry has emerged as an essential tool as it can not only aid in the interpretation of experimental observations but also provide atomistic-level insights into the catalytic mechanism. This Mini Review summarizes recent computational studies on MOF-catalyzed CO2 conversion through different types of reactions, discusses about the usage of various computational …

Path-Stick Solitaire On Graphs, Jan-Hendrik De Wiljes, Martin Kreh

Theory & Applications of Graphs

In 2011, Beeler and Hoilman generalised the game of peg solitaire to arbitrary connected graphs. Since then, peg solitaire and related games have been considered on many graph classes. In this paper, we introduce a variant of the game peg solitaire, called path-stick solitaire, which is played with sticks in edges instead of pegs in vertices. We prove several analogues to peg solitaire results for that game, mainly regarding different graph classes. Furthermore, we characterise, with very few exceptions, path-stick-solvable joins of graphs and provide some possible future research questions.

Uncertainty Analysis Of Operational Conditions In Selective Artificial Ground Freezing Applications, Ahmad Zueter, Saad Akhtar, Agus Sasmito

Journal of Sustainable Mining

Artificial ground freezing (AGF) systems are susceptible to uncertain parameters highly affecting their performance. Particularly, selective artificial ground freezing (S-AGF) systems involve several uncertain operational conditions. In this study, uncertainty analysis is conducted to investigate four operational parameters: 1) coolant inlet temperature, 2) coolant flow rate, 3) pipes emissivity, and 4) pipes eccentricity. A reduced-order model developed and validated in our previous work for field-scale applications is exploited to simulate a total of 5,000 cases. The uncertain operational parameters are set according to Monte Carlo analysis based on field observations of a field-scale freeze-pipe in the mining industry extending to …

Extraction, Analysis, And Occurrence Of Per- And Polyfluoroalkyl Substances (Pfas) In Wastewater And After Municipal Biosolids Land Application To Determine Agricultural Loading, Justin Caniglia, Daniel D. Snow, Tiffany Messer, Shannon Bartelt-Hunt

School of Natural Resources: Faculty Publications

Given the ubiquitous detection of per- and polyfluoroalkyl substances (PFAS) within numerous soil and water environmental compartments, there is a need for global understanding of current methodologies for extracting water, solids, polar organic chemical integrative samplers (POCIS), and plant tissue for these substances. This study provides details of several current extraction methods, demonstrates the use of POCIS in monitoring these compounds in a wastewater environment, and provides evidence of detectable levels of certain PFAS compounds within Midwestern municipalities and agroecosystems. Validated extraction procedures help characterize occurrence and release of 18 PFAS in a midwestern wastewater treatment plant (WWTP), surface water, …

Mgrre_Thinsections_05_A_63, Mgrre

Thin Sections

No abstract provided.

Sialidase Inhibitors With Different Mechanisms, Joseph M. Keil, Garrett R. Rafn, Isaac M. Turan, Majdi A. Aljohani, Reza Sahebjam-Atabaki, Xue-Long Sun

Chemistry Faculty Publications

Sialidases, or neuraminidases, are enzymes that catalyze the hydrolysis of sialic acid (Sia)-containing molecules, mostly removal of the terminal Sia (desialylation). By desialylation, sialidase can modulate the functionality of the target compound and is thus often involved in biological pathways. Inhibition of sialidases with inhibitors is an important approach for under-standing sialidase function and the underlying mechanisms and could serve as a therapeutic approach as well. Transition-state analogues, such as anti-influenza drugs oseltamivir and zanamivir, are major sialidase inhibitors. In addition, difluoro-sialic acids were developed as mechanism-based sialidase inhibitors. Further, fluorinated quinone methide-based suicide substrates were reported. Sialidase product analogue …

Sports And Greenhouse Gas Emissions: Building A Better Framework For Sustainable Sports Operations, Austin Anahory

USF Tampa Graduate Theses and Dissertations

This thesis analyzes the approach to sustainability of American soccer leagues and provides a Greenhouse Gas (GHG) Inventory of the Tampa Bay Rowdies. Sustainability and climate change are rising concerns for most industries, especially the sports industry as it will face many immediate and long term impacts. To address these issues, a sustainability analysis was done of each USL Championship team to assess prominence of sustainability topics from their website. To conduct the GHG inventory, the GHG Protocol was followed and resulted in assessing Scope 1, 2, and 3 of the given soccer team. Assumptions were used to estimate missing …

An Evaluation Framework For Digital Image Forensics Tools, Zainab Khalid, Sana Qadir

Journal of Digital Forensics, Security and Law

The boom of digital cameras, photography, and social media has drastically changed how humans live their day-to-day, but this normalization is accompanied by malicious agents finding new ways to forge and tamper with images for unlawful monetary (or other) gains. Disinformation in the photographic media realm is an urgent threat. The availability of a myriad of image editing tools renders it almost impossible to differentiate between photo-realistic and original images. The tools available for image forensics require a standard framework against which they can be evaluated. Such a standard framework can aid in evaluating the suitability of an image forensics …

A Study Of The Data Remaining On Second-Hand Mobile Devices In The Uk, Olga Angelopoulou, Andy Jones, Graeme Horsman, Seyedali Pourmoafi

Journal of Digital Forensics, Security and Law

This study was carried out intending to identify the level and type of information that remained on portable devices that were purchased from the second-hand market in the UK over the last few years. The sample for this study consisted of 100 second hand mobile phones and tablets. The aim of the study was to determine the proportion of devices that still contained data and the type of data that they contained. Where data was identified, the study attempted to determine the level of personal identifiable information that is associated with the previous owner. The research showed that when sensitive …

A Macrocyclic Molecule With Multiple Antioxidative Activities Protects The Lens From Oxidative Damage, Jinmin Zhang, Yu Yu, Magy A. Mekhail, Hongli Wu, Kayla N. Green

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Growing evidence links oxidative stress to the development of a cataract and other diseases of the eye. Treatments for lens-derived diseases are still elusive outside of the standard surgical interventions, which still carry risks today. Therefore, a potential drug molecule ^OHPy₂N₂ was explored for the ability to target multiple components of oxidative stress in the lens to prevent cataract formation. Several pathways were identified. Here we show that the ^OHPy₂N₂ molecule activates innate catalytic mechanisms in primary lens epithelial cells to prevent damage induced by oxidative stress. This protection was linked to …

Influence Of Surface Water Displacement On Solvation Thermodynamics, Mia Kim

Journal of the South Carolina Academy of Science

No abstract provided.

2022 October 27 - Tennessee Weekly Drought Summary, Tennessee Climate Office, East Tennessee State University

Tennessee Climate Office Weekly Drought Summaries

No abstract provided.

Antibody Prevalence And Risk Factors Associated With Rickettsia Spp. In A Pediatric Cohort: Sfgr Remains Underdiagnosed And Underreported In El Salvador, Kyndall C. Dye-Braumuller, Marvin Stanley Rodríguez Aquino, Kia Zellars, Hanna Waltz, Madeleine Meyer, Lídua Gual-Gonzalez, Stella C.W. Self, Mufaro Kanyangarara, Melissa Nolan Ph.D., Mph

Faculty Publications

Spotted fever group rickettsioses (SFGR) are caused by a group of tick-borne pathogens that are increasing in incidence globally. These diseases are typically underreported and undiagnosed in low- and middle-income countries, and thus, have been classified as neglected bacterial pathogens. Countries with high poverty, low human development index score, and limited health infrastructure—like El Salvador in Central America—lack necessary surveillance for SFGR and other tick-borne pathogens. This paucity of baseline SFGR infection prevalence leaves vulnerable populations at risk of misdiagnosis. Further, tick-borne disease burdens in El Salvador are severely limited. To lay the foundation for tick-borne disease epidemiology in El …

Comparative Analysis Of All-Terrain Vehicles, Motorcycle And Automobile-Related Trauma In A Rural Border Community Of The Usa, Haissam S. Elzaim, Kristina Vatcheva, Annelyn Torres-Reveron, Gregery Pequeno, Monica Michelle Betancourt-Garcia

School of Mathematical & Statistical Sciences Faculty Publications

Introduction: There is widespread use of all-terrain vehicles (ATVs) in the USA for both work-related and recreational activities. In this study, we aimed to determine the difference in injury severity, Glasgow Coma scales and length of stay between ATV-related injuries and injuries sustained from motorcycles (MOTOs) and automobiles (AUTOs).

Methods: We retrospectively analysed ATV, MOTO and AUTO injuries from a Level 2 Trauma Center between 01 January 2015 and 31 August 2020. Proportional odds regression analyses, as well as multivariable regression models, were used to analyse the data.

Results: There were significantly more male and paediatric patients that suffered ATV-related …

The Role Of Extended Grazing In Profitable Ruminant Livestock Operations, Jim Gerrish

Kentucky Grazing Conference

No abstract provided.

Data Sharing Through Open Access Data Repositories, Karin Bennedsen

All Things Open

The National Institutes of Health has expanded their data sharing requirements for obtaining funding to now include all awards for research producing scientific data to accelerate “biomedical research discovery, in part, by enabling validation of research results, providing accessibility to high-value datasets, and promoting data reuse for future research studies.” The new policy requiring a Data Management & Sharing Plan (DMSP) for all applications goes into effect January 25th, 2023. A DMSP includes where the data will be stored. This lightning talk will review Open Access Data Repositories. Don’t let the task of trying to find data storage hold you …

Hay Feeding Strategies To Build Fertility In Grazing Systems, Nick Roy, Fred Thomas

Kentucky Grazing Conference

No abstract provided.

Grazing Myths That Reduce Profitability, Greg Halich

Kentucky Grazing Conference

No abstract provided.

Carbonised Fluidised Fly Ash (Cffa); A New Product For Mining Engineering Purposes (Discussion Of Possible Applications), Marian Jacek Łączny, Przemysław Rompalski

Journal of Sustainable Mining

The article presents and summarises the current state of research and laboratory results on the carbonation of fly ash with carbon dioxide in the context of its use in mining engineering. Based on previous publications and patent applications, the possibilities of using carbonated fly ash from fluidised bed boilers for the following applications were discussed: securing excavations particularly susceptible to fire hazards, shotcreting and securing longwalls and supports, constructing cases, securing decommissioned shafts, and others, which means wherever the use of cement is required. It was pointed out that the removal of excess free calcium oxide makes it possible to …

The Degree Gini Index Of Several Classes Of Random Trees And Their Poissonized Counterparts—Evidence For Duality, Carly Domicolo, Panpan Zhang, Hosam Mahmoud

Journal of Stochastic Analysis

No abstract provided.

Right Sizing Your Cows For Profit, Les Anderson

Kentucky Grazing Conference

No abstract provided.

My Soil Is Alive! Introduction To Soil Life And Its Role In Profitable Grazing Systems, Ray Archuleta

Kentucky Grazing Conference

No abstract provided.

2022 Celebration Of Scholarship, Creativity, And Engagement, Todd Bruns, Beth Heldebrandt

Programs

At this annual celebration, the entire Division of Academic Affairs is pleased that the important work of faculty continues and evolves as EIU’s professors have individually and collectively redefined the boundaries of scholarship, creativity, and innovation for the emerging post-COVID era. Indeed, we are excited to come together to celebrate the achievements and outstanding contributions of our colleagues and students to their disciplines and professions. And, as the following pages illustrate, faculty have engaged in continuing scholarly and creative activities that have provided outstanding mentoring experiences for our undergraduate and graduate students.

In addition to sharing faculty productivity, research excellence …

Decency Won't Save Us: Critical Considerations For Occupational Sustainability, Nia Johnson

Sustainability Research & Practice Seminar Presentations

Professor Nia Johnson, Graduate Social Work - Decency Won't Save Us: Critical Considerations for Occupational Sustainability

Mgrre_Thinsections_05_A_62, Mgrre

Thin Sections

No abstract provided.

Measurement In Chemistry, Mathematics, And Physics Education: Student Explanations Of Organic Chemistry Reaction Mechanisms And Instructional Practices In Introductory Courses, Brandon J. Yik

USF Tampa Graduate Theses and Dissertations

The work in this dissertation is presented in two parts. The first part (Chapters 3 and 4) details work relating to students’ explanations of reaction mechanisms in organic chemistry. The second part (Chapters 5 and 6) details work relating to the evaluating the uptake of research-based instructional practices in introductory chemistry, mathematics, and physics courses.

To evaluate learning of organic chemistry reactions, instructors must ask students to construct written explanations of reaction mechanisms. Written assessments should focus on what is happening and why it is happening to promote deeper student understanding. However, for instructors to gain insight into students’ understanding, …

Process Evaluation Methods And Results From The Health In Pregnancy And Postpartum (Hipp) Randomized Controlled Trial, Sarah Wilcox Phd, Alicia A. Dahl, Alycia K. Boutté, Jihong Liu Sc.D., Kelsey Day, Gabrielle Turner-Mcgrievy Ph.D., Rd, Ellen Wingard

Faculty Publications

Background

Excessive gestational weight gain has increased over time and is resistant to intervention, especially in women living with overweight or obesity. This study described the process evaluation methods and findings from a behavioral lifestyle intervention for African American and white women living with overweight and obesity that spanned pregnancy (≤ 16 weeks gestation) through 6 months postpartum.

Methods

The Health in Pregnancy and Postpartum (HIPP) study tested a theory-based behavioral intervention (vs. standard care) to help women (N = 219; 44% African American, 29.1 ± 4.8 years) living with overweight or obesity meet weight gain guidelines in pregnancy and …

Addressing Specific Safety And Occupational Health Challenges For The Canadian Mines Located In Remote Areas Where Extreme Weather Conditions Dominate, Rachid Halabi, Mustafa Kumral

Journal of Sustainable Mining

The number of mining operations is increasing in the Canadian North, where extreme weather conditions govern. Currently, many mine development projects are also in progress in this region. These mines’ working atmosphere and employment circumstances are highly different from regular mines. One of the main differences is the special safety issues of the Canadian North. The primary sources of these special issues are: the difficulty of finding skilled employees; high employee turnover rate; insufficient training and certification requirements; delicate employment circumstances affecting the psychological well-being of employees; permafrost; mine inspection challenges; inventory and logistic hardship; and the legislative and regulative …

Flow Regime Evolution Of A Major Cave System In The Eastern Alps (Hirlatzhöhle, Dachstein), Lukas Plan, Gottfried Buchegger, Eva Kaminsky, Gabriella Koltai, Tanguy Racine, Jacek Szczygieł

International Journal of Speleology

The 116 km-long and 1560 m-deep Hirlatzhöhle is one of the major cave systems in the Northern Calcareous Alps (NCA; Austria). It is located in the NW part of the Dachstein, an extensive karst massif encompassing 576 km² with its highest point at 2995 m a.s.l. In contrast to most other caves in the NCA, Hirlatzhöhle comprises old (epi)phreatic passages located up to 1 km above the base level as well as two modern major drainage systems. The aim of this study is to define the palaeo- and the active flow conditions in combination with speleogenesis, and the age of …