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Articles 44581 - 44610 of 294391

Full-Text Articles in Physical Sciences and Mathematics

Evaluating The On-Site Impacts Of The Ambatovy Project Through The Lens Of Environmental Justice, Nick Karlik Apr 2023

Evaluating The On-Site Impacts Of The Ambatovy Project Through The Lens Of Environmental Justice, Nick Karlik

Independent Study Project (ISP) Collection

In Madagascar, sustainable development has been established and maintained by dominant foreign actors to reconcile neoliberalism with globalized conceptions of environmental protection. The Ambatovy mining and refining project has emerged as a prominent example of this developmental mode; Ambatovy is the largest economic enterprise in the history of the country and one of the largest and most productive mining operations in the world, generating billions of dollars in revenue for a country that remains among the poorest in the world while offsetting its impact on endemic biodiversity and forest habitat through conservation initiatives. At the same time, the evaluative framework …


Women In Sustainable Leadership: A Case Study On The Perspectives, Opportunities, And Challenges Of Biologist And Conservationist Estrela Matilde, Ella Lyons Apr 2023

Women In Sustainable Leadership: A Case Study On The Perspectives, Opportunities, And Challenges Of Biologist And Conservationist Estrela Matilde, Ella Lyons

Independent Study Project (ISP) Collection

Despite the relatively small population of 8,000 occupants and the minimal international recognition of the Island of Príncipe, located off of the Gulf of Guinea on the Western Coast of Central Africa, the region has increasingly become a leading example of sustainable practices to be taken on a global scale in the near future to combat our current climate crisis. This case study explores the sustainable practices that Príncipe has learned to embrace under the leadership of Portuguese conservation biologist and project manager for the NGO Fundação Príncipe, Estrela Matilde. Estrela integrates social, cultural, and environmental conservation to align with …


Unleash The Heat: Exploring Geothermal Energy Perspectives And Energy Literacy In São Miguel, Azores, Lena Mcdonough Apr 2023

Unleash The Heat: Exploring Geothermal Energy Perspectives And Energy Literacy In São Miguel, Azores, Lena Mcdonough

Independent Study Project (ISP) Collection

The green energy transition is moving ahead in EU countries at very different paces, and there are some key challenges that all regions currently face in trying to phase fossil fuels out of their energy mixes. One of these challenges is that most regions simply cannot harness enough renewable energy sources and simultaneously have the storage technology for creating a baseload power source as reliable as oil, coal and natural gas. That is, unless you sit in the middle of the Atlantic Ocean on the boundary of three tectonic plates, with a continuous and reliable renewable energy source beneath your …


People Power & Politics: Evaluating The Impact Of The Conselho De Cidadãos De Lisboa On Climate Policy And Political Efficacy In Lisbon, Marion Linde Apr 2023

People Power & Politics: Evaluating The Impact Of The Conselho De Cidadãos De Lisboa On Climate Policy And Political Efficacy In Lisbon, Marion Linde

Independent Study Project (ISP) Collection

As the social and ecological effects of climate change intensify, governments across the globe must evaluate how best to deal with the climate crisis. Likewise, increasing citizen participation in decision-making processes has been a key strategy for dealing with such issues. Theories on the benefits of citizen participation inform real practices such as democratic mini-publics and citizens assemblies. In Lisbon, Portugal, the Câmara Municipal de Lisboa implemented the first edition of the Conselho de Cidadãos de Lisboa (CCL) in May 2022. The CCL is a citizens assembly designed to directly involve residents in city policy-making, with the first edition focusing …


A Transition Point: The Role Of The Global Power Shift In Facilitating Saudi Internal Reforms, Aidan Aguilar Apr 2023

A Transition Point: The Role Of The Global Power Shift In Facilitating Saudi Internal Reforms, Aidan Aguilar

Independent Study Project (ISP) Collection

The increasing political and economic influence of China represents a pivotal point within international relations. This paper aims to explore the implications of this global power shift on Saudi Arabia’s attempted economic reforms. The Kingdom’s reliance on oil has created an unsustainable economic model, and this model is intrinsically linked to Saudi Arabia’s relationship with the United States. Its growing relationship with China could create change. As such, this paper analyzes the intersection of economics and security in relation to the Saudi Vision 2030. I argue that, not only does China serve as an important source of the investment necessary …


Tropical Tree Carbon Storage At Drago Dos Forest In Boca Del Drago, Panama, Ben Dwyer Apr 2023

Tropical Tree Carbon Storage At Drago Dos Forest In Boca Del Drago, Panama, Ben Dwyer

Independent Study Project (ISP) Collection

Currently, anthropogenic carbon emissions pose a significant, global threat, contributing to Global Warming and Climate Change (CC). Today, the most effective carbon sinks are natural. Trees are highly effective carbon sinks that sequester large amounts of atmospheric carbon dioxide (CO2), most greatly in tropical areas. However, tropical tree carbon storage needs to be more accurately estimated to provide valuable information toward mitigating CC and its negative environmental effects. This study aimed to estimate CO2 sequestration at a tropical forest in Boca Del Drago, Panama, and compare it to that of a nearby mangrove forest. It was hypothesized that the tropical …


Anuran Species Diversity And Abundance Between Three Locations In El Valle De Antón, Coclé, Panamá, Xena Gehring Apr 2023

Anuran Species Diversity And Abundance Between Three Locations In El Valle De Antón, Coclé, Panamá, Xena Gehring

Independent Study Project (ISP) Collection

Panama is an incredibly biodiverse country that houses 230 species of amphibians including 188 species of frogs, 35 of which are endemic to Panama. Commonly found in terrestrial and aquatic habitats, frogs play a very important role in the regulation of insect populations and serve as a valuable food resource to other predators. The greatest threat to amphibian species at this time is Chytridiomycosis, a fungal pathogen that infects the skin and often results in death. Many species of amphibians have already gone completely extinct or are extinct in the wild due to the proliferation of this disease. The skin …


The Australian News Media And Climate Change: How Frames Impact The Response Of Individuals In An Anthropocentric Society, Laura Joelsson Apr 2023

The Australian News Media And Climate Change: How Frames Impact The Response Of Individuals In An Anthropocentric Society, Laura Joelsson

Independent Study Project (ISP) Collection

News media plays an instrumental role in shaping opinions and perceptions on climate change due to it being such a wide-reaching institution. The discourses of news media are able to use frames to determine the discursive context in which a concept or issue is discussed by promoting a central theme or message. This study aims to use critical discourse analysis to determine how climate change is framed in news media, and how these frames depict the forms and scope of possible climate action. The study also analyzes if these forms of action are predominantly anthropocentric in nature. Critical discourse analysis …


Agroforestry For The Future: Motivations Behind Tasmanian Farmers Planting Trees, Josh Lipp Apr 2023

Agroforestry For The Future: Motivations Behind Tasmanian Farmers Planting Trees, Josh Lipp

Independent Study Project (ISP) Collection

Agroforestry is the act of combining farming and tree planting, and many Tasmanian farmers are starting to plant trees on their properties for multiple reasons. Through conducting 9 interviews with farmers and researchers and visiting field sites, 3 main themes were identified to answer the question: why are Tasmanian farmers planting trees, and what are the benefits and downsides to agroforestry? Interviews help us understand farmers’ perceptions of agroforestry, and field data collection will prove the benefits of agroforestry in the future. Tasmania was chosen as the location of study as it is a state in Australia that largely focuses …


Spatial Ecology And Habitat Preference Of Yellow-Spotted Monitors (Varanus Panoptes) At Lizard Island National Park, Qld, Australia, Ryan Snyder Apr 2023

Spatial Ecology And Habitat Preference Of Yellow-Spotted Monitors (Varanus Panoptes) At Lizard Island National Park, Qld, Australia, Ryan Snyder

Independent Study Project (ISP) Collection

Lizard Island National Park is an area of strong habitat diversity, especially given its small size. There are several distinct habitats represented, including open sclerophyll woodlands, mangrove swamps, dune grasslands, foothills elevations, and of course anthropogenically modified human habitats. The object of this study was to observe the abundances and behaviors of the yellow-spotted monitor lizard (V. panoptes) in each of these habitat settings to answer the question of which habitat type is preferred amongst V. panoptes in the landscape context of Lizard Island National Park.

Study transects were conducted over the course of one month measuring abundance of V. …


Impact Of Wildlife Provisioning On Species Diversity, Relative Frequency, And Richness In New South Wales, Alanah Cohen-Tigör Apr 2023

Impact Of Wildlife Provisioning On Species Diversity, Relative Frequency, And Richness In New South Wales, Alanah Cohen-Tigör

Independent Study Project (ISP) Collection

Wildlife provisioning and camera trapping are two recently evolving methods of conservation and wildlife management, aimed at protecting animals in the face of ever worsening climate change. Habitats are being destroyed by climate disruption, decreasing species diversity and abundance worldwide. It is imperative that methods of protecting species are developed to slow or reverse this era of extinction. By providing supplementary food and water to ecological communities, the hope is that species will have improved survivorship and reproduction, making them more resilient and resistant to population decline. Camera trapping is product of modern technology, allowing researchers to monitor species without …


Bridging The Education Gap: Series Of Infographic Guides To Sustainable Living For Low-Income Communities, Brianna Mateo Apr 2023

Bridging The Education Gap: Series Of Infographic Guides To Sustainable Living For Low-Income Communities, Brianna Mateo

Independent Study Project (ISP) Collection

Low-income communities in Australia face numerous negative impacts, such as health issues, social exclusion, educational disparities, and discrimination, which limit their opportunities to improve their quality of life (The Public Defenders,2022). As a result, students from these communities often have fewer resources and less funding, contributing to poor educational outcomes and underrepresentation in STEM fields, which includes environmental education (Australian Department of Education, 2022).

To address these challenges, I created an 8-page infographic series titled “Sustainable Living: On a Budget.” The series includes a cover page, an overview page, and four infographics covering : climate change, waste, preserving biodiversity, and …


Dairy & Development: An Investigation Into The Economic And Sociopolitical Dynamics Of Yak Cheesemaking In Nepal, Audrey Peiker Apr 2023

Dairy & Development: An Investigation Into The Economic And Sociopolitical Dynamics Of Yak Cheesemaking In Nepal, Audrey Peiker

Independent Study Project (ISP) Collection

Cheesemaking in Nepal is full of love, passion, and creativity. What began as a Swiss development project in the 1950s has now grown into a full-fledged industry, providing jobs, creative outlets, and cultural expression for many. Nepal’s Dairy Development Corporation owns several factories throughout the country, setting the tone for the industry by establishing the standard price for milk and process for cheesemaking. From there, privately held factories innovate and compete, bringing new products to the market and increasing wages, but also struggle with consistency and reliability. Now, Nepal’s cheesemaking market is at a turning point—much of the herding population …


Talking To The Earth: A Digital Documentation Of Biodiversity In The Sherpa Language, Dvij Sharma Apr 2023

Talking To The Earth: A Digital Documentation Of Biodiversity In The Sherpa Language, Dvij Sharma

Independent Study Project (ISP) Collection

Identified as a pressing matter by organizations as prominent as the UN, the conservation of minority and indigenous languages “is essential for ensuring the continuation and transmission of culture, customs, and history, but it is also important to address biodiversity loss and climate change.” This project focuses on one of the latter issues, biodiversity loss, as it relates to Sherpa, a minority language spoken primarily in Eastern Nepal. In an effort to help preserve the native vocabulary and descriptions of basic plants and animals found in Sherpa-speaking regions, primarily interview-based fieldwork was conducted in the lower Solu regions of Lumsa, …


Status Of Pangolins: A Case Study On "The Most Trafficked Mammal In The World" In Central-South Of Nepal, Tsogyal Wangmo Lama Apr 2023

Status Of Pangolins: A Case Study On "The Most Trafficked Mammal In The World" In Central-South Of Nepal, Tsogyal Wangmo Lama

Independent Study Project (ISP) Collection

Pangolins are subject to constant trafficking in Asia and increasingly in Africa for their meat and scales. Very little research is done on this species due to its nocturnal, burrowing, and elusive nature. The larger the size of an animal is, the better it is known to the people and vice versa. Hence all these eight species of pangolins despite being under the International Union for Conservation of Nature (IUCN) red list with the four Asian species declared endangered or critically endangered, are still illegally abused and used for ulterior motives due to a lack of awareness among the general …


Biodiversidad De Plantas En La Reserva Natural Urbana Punta Popper En Río Grande: Una Propuesta Para Senderos Para La Gestión De La Conservación Y Métodos De Campo Replicables En Un Etorno Educativo, Lili Weir Apr 2023

Biodiversidad De Plantas En La Reserva Natural Urbana Punta Popper En Río Grande: Una Propuesta Para Senderos Para La Gestión De La Conservación Y Métodos De Campo Replicables En Un Etorno Educativo, Lili Weir

Independent Study Project (ISP) Collection

The Patagonian Steppe is an ecoregion that is rich in plant biodiversity (both native and introduced), and the Urban Nature Reserves like Punta Popper in Río Grande provide an opportunity to preserve these sensitive species and educate the public, especially students, about the value of this trophic level. However, many beautiful species are being affected by human activities in the Reserve: such as the mismanagement of the trail systems which has led to erosion of the sand dunes, and the pressures of rapid urban expansion contributing to trash pollution. It is essential that stakeholder communities have access to information and …


Inside The Wave: How “The 100 Foot Wave” Changed The Lives Of The Local Community In Nazaré, Emilie Cohen Apr 2023

Inside The Wave: How “The 100 Foot Wave” Changed The Lives Of The Local Community In Nazaré, Emilie Cohen

Independent Study Project (ISP) Collection

Surfing and surfing tourism are a critical part of Portugal’s economy and culture. Nazaré is a town that embodies a transition from a traditional fishing village to one that lives and breathes surf. Such a quick change in the leading industry of a town raises concerns about the impacts it has on the community. Therefore, the project focuses on the economic, social and cultural, and environmental impacts of tourism intensification on the local community in Nazaré through the perspective of the local people who are directly impacted and witness these changes. Other stakeholders are included, such as the Garrett McNamara …


Considerations For Solar Development: Comprehensive Assessment Of Solar Production Benefits And Consequences In Portugal, Jonathan Ramos Marcuse Apr 2023

Considerations For Solar Development: Comprehensive Assessment Of Solar Production Benefits And Consequences In Portugal, Jonathan Ramos Marcuse

Independent Study Project (ISP) Collection

In this paper, the potential for solar energy development in Portugal is explored, with a focus on the Alentejo region of Portugal. The Fernando Pessoa Photovoltaic plant that is approved for construction in the Santiago do Cacém municipality is analyzed. The size of the plant and the location are considered when studying the environmental, social, and economic impacts of the project. The possibility of a centralized solar array in Sines is also explored as an alternative, taking into account the environmental and social impacts on local communities. Additionally, the feasibility and benefits of implementing a decentralized energy grid, utilizing scattered …


A Multi-Factorial Analysis Of The Sustainability Of Non-Governmental Organizations’ Psychosocial Support Programs In Jordan, Dina Abdalla Apr 2023

A Multi-Factorial Analysis Of The Sustainability Of Non-Governmental Organizations’ Psychosocial Support Programs In Jordan, Dina Abdalla

Independent Study Project (ISP) Collection

This research paper aims to explore the factors that affect the sustainability of psychosocial support (PSS) programs provided by non-governmental organizations (NGOs) in Jordan. NGOs in Jordan are facing a significant issue when it comes to the sustainability of their programs, and they provide crucial programs for refugees and underserviced populations. So, it is crucial to investigate the factors affecting and solutions to sustainability. It is hypothesized that sustainability is a multi- factorial concept, affected by financial, organizational, and environmental factors. It is predicted that NGO characteristics, program effectiveness, and program type can affect sustainability. To combat sustainability issues, it …


Consumo Verde ¿Para Quién?: Las Tierras, Cosmovisiones, Y Personas Escondidas Detrás De La Fiebre Del Oro Blanco / Green Consumption, For Who?: The Lands, World Views, And People Hidden Behind The White Gold Rush., Gabriel Gómez Apr 2023

Consumo Verde ¿Para Quién?: Las Tierras, Cosmovisiones, Y Personas Escondidas Detrás De La Fiebre Del Oro Blanco / Green Consumption, For Who?: The Lands, World Views, And People Hidden Behind The White Gold Rush., Gabriel Gómez

Independent Study Project (ISP) Collection

La “Transición energética” a consumo verde ha sido reconocida globalmente como el camino necesario para evitar lo peor de la crisis climática, pero es una solución que depende en un aumento del litio. La manera más usada para extraer el litio genera impactos destructivos en los ambientes que contienen el recurso, y en Sudamérica, donde los habitantes son mayormente indígena. Usando las comunidades de Salinas Grandes y Laguna de Guayatayoc en Jujuy, Argentina como un caso práctico, este proyecto propone analizar cómo el discurso hegemónico del consumo verde invisibiliza a gente indígena, y cómo estas comunidades resisten entendimientos occidentales y …


Hydropower To The People: Implications Of A Comparative Macroinvertebrate Study On Either Side Of The Central Hidroeléctrica Topo In Tungurahua, Ecuador, Grace Mazur Apr 2023

Hydropower To The People: Implications Of A Comparative Macroinvertebrate Study On Either Side Of The Central Hidroeléctrica Topo In Tungurahua, Ecuador, Grace Mazur

Independent Study Project (ISP) Collection

This study uses macroinvertebrates as bioindicators to assess the water quality upstream and downstream of a hydroelectric project in Ecuador’s eastern cloud forest. Ecuador has increasingly turned to hydropower to supply its energy needs as pressure mounts to turn away from fossil fuels. This transition has been realized on the Río Topo, located in the province of Tungurahua. This study aims to determine how the Central Hidroeléctrica Topo (CHT), a diversion hydroelectric project (HEP) constructed on the Río Topo in the 2010s, has affected the water quality of the river. Samples were taken of benthic (bottom-dwelling) macroinvertebrates in the Río …


Sebd: A Stream Evolving Bot Detection Framework With Application Of Pac Learning Approach To Maintain Accuracy And Confidence Levels, Eiman Alothali, Kadhim Hayawi, Hany Alashwal Apr 2023

Sebd: A Stream Evolving Bot Detection Framework With Application Of Pac Learning Approach To Maintain Accuracy And Confidence Levels, Eiman Alothali, Kadhim Hayawi, Hany Alashwal

All Works

A simple supervised learning model can predict a class from trained data based on the previous learning process. Trust in such a model can be gained through evaluation measures that ensure fewer misclassification errors in prediction results for different classes. This can be applied to supervised learning using a well-trained dataset that covers different data points and has no imbalance issues. This task is challenging when it integrates a semi-supervised learning approach with a dynamic data stream, such as social network data. In this paper, we propose a stream-based evolving bot detection (SEBD) framework for Twitter that uses a deep …


Drinking Water Contaminants: Bacteria, Bruce I. Dvorak, Becky O. Schuerman Apr 2023

Drinking Water Contaminants: Bacteria, Bruce I. Dvorak, Becky O. Schuerman

Department of Civil and Environmental Engineering: Faculty Publications

Testing drinking water for fecal bacteria or Escherichia coli (E. coli) is commonly used as an indicator of the presence of pathogenic microorganisms. The presence of pathogenic (disease-causing) microorganisms is a concern when considering the safety of drinking water. Pathogenic microorganisms can cause flu-like systems, intestinal infections, dysentery, hepatitis, typhoid fever, cholera, and other illnesses.


A Diffusion Network Event History Estimator, Jeffrey J. Harden, Bruce A. Desmarais, Mark Brockway, Frederick J. Boehmke, Scott J. Lacombe, Fridolin Linder, Hanna Wallach Apr 2023

A Diffusion Network Event History Estimator, Jeffrey J. Harden, Bruce A. Desmarais, Mark Brockway, Frederick J. Boehmke, Scott J. Lacombe, Fridolin Linder, Hanna Wallach

Government: Faculty Publications

Research on the diffusion of political decisions across jurisdictions typically accounts for units’ influence over each other with (1) observable measures or (2) by inferring latent network ties from past decisions. The former approach assumes that interdependence is static and perfectly captured by the data. The latter mitigates these issues but requires analytical tools that are separate from the main empirical methods for studying diffusion. As a solution, we introduce network event history analysis (NEHA), which incorporates latent network inference into conventional discrete-time event history models. We demonstrate NEHA’s unique methodological and substantive benefits in applications to policy adoption in …


Molecular Cluster Complex Of High-Valence Chromium Selenide Carbonyl As Effective Electrocatalyst For Water Oxidation, Ibrahim Munkaila Abdullahi, Manashi Nath Apr 2023

Molecular Cluster Complex Of High-Valence Chromium Selenide Carbonyl As Effective Electrocatalyst For Water Oxidation, Ibrahim Munkaila Abdullahi, Manashi Nath

Chemistry Faculty Research & Creative Works

Developing Simple, Affordable, and Environmentally Friendly Water Oxidation Electrocatalysts with High Intrinsic Activity and Low overpotential Continues to Be an Area of Intense Research. in This Article, a Trichromium Diselenide Carbonyl Cluster Complex (Et4N)2[Se2Cr3(CO)10], with a Unique Bonding Structure Comprising Bridging Se Groups, Has Been Identified as a Promising Electrocatalyst for Oxygen Evolution Reaction (OER). This Carbonyl Cluster Exhibits a Promising overpotential of 310 MV and a Low Tafel Slope of 82.0 MV Dec−1 at 10 MAcm−2, with Superior Durability in an Alkaline Medium, for a Prolonged …


Nitric Oxide As A Signaling Molecule For Biofilm Formation And Dispersal In Mediated Electron Transfer Microbial Electrochemical Systems, Kevin Beaver, Ashwini Dantanarayana, Ana Bonizol Zani, Danielle L. Lehto, Shelley D. Minteer Apr 2023

Nitric Oxide As A Signaling Molecule For Biofilm Formation And Dispersal In Mediated Electron Transfer Microbial Electrochemical Systems, Kevin Beaver, Ashwini Dantanarayana, Ana Bonizol Zani, Danielle L. Lehto, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

With applications in bioremediation, biosensing, and bioenergy, microbial electrochemical systems are a rapidly growing, multidisciplinary field within biological, chemical, and materials science. Since these systems use living microorganisms as biocatalysts, it is important to understand how microbial physiology, namely biofilm formation, affects these electrochemical systems. Specifically, the literature lacks research that assesses the effects of biofilm on metabolic current output in mediated electron transfer systems. in this study, Rhodobacter capsulates and Pseudomonas putida GPo1 were used as model, nonpathogenic strains that facilitate electron transfer via diffusible redox mediators. Nitric oxide has gained attention in biomedicine as a gaseous signaling molecule, …


Exploring New Techniques For Precision Deuteration Of Alkenes And Alkynes, Zoua Pa Vang Apr 2023

Exploring New Techniques For Precision Deuteration Of Alkenes And Alkynes, Zoua Pa Vang

Dissertations (1934 -)

Deuterium labeled compounds are often utilized in chemical research as internal standards in mass spectrometry, to study reaction mechanisms and in the pharmaceutical industry to slow the rate of metabolism. With the increase interest for deuterium labeled molecules, there is a renewed interest in selective methods for the installation of deuterium atoms into small organic molecules. However, current methods to incorporate deuterium atoms into organic molecules can lead to isotopic mixtures such as isotopologues and isotopomers. These isotopic species are indistinguishable due to their similar physical properties, leading to inseparable products by common purification techniques. Furthermore, common spectroscopic techniques to …


A Package Of Smartphone And Sensor-Based Objective Measurement Tools For Physical And Social Exertional Activities For Patients With Illness-Limiting Capacities, Arafat Mahmood Apr 2023

A Package Of Smartphone And Sensor-Based Objective Measurement Tools For Physical And Social Exertional Activities For Patients With Illness-Limiting Capacities, Arafat Mahmood

Dissertations (1934 -)

Patients with several incompletely diagnosed and understood chronic diseases suffer from symptoms that limit their functional capacity. In particular, patients with chronic fatigue syndrome/myalgic encephalomyelitis (CFS/ME) and long covid syndromes have variable fatigue, malaise, poor and unrefreshing sleep, and delayed post-exertional exacerbations of these symptoms. There are no specific tests for these patients to diagnose their diseases properly. These patients must be aware of their daily activities and energy expenditure. Even a little physical effort or socially extroverted behavior can make them tired and incapable of continuing their daily routine. A comprehensive summary of the measured activities at any particular …


Using Caulobacter Crescentus As A Model To Probe The Environmental Reactivity Of Silver Nanoparticles, Madeline M. Farber , '23 Apr 2023

Using Caulobacter Crescentus As A Model To Probe The Environmental Reactivity Of Silver Nanoparticles, Madeline M. Farber , '23

Senior Theses, Projects, and Awards

Silver nanoparticles (AgNPs) are an increasingly common environmental pollutant with antimicrobial and antibacterial properties. The elucidation of their interaction with cellular membranes and subsequent mechanisms of toxicity are critical areas of research that need to be better understood in order to manage potential adverse environmental effects. This work investigates the interaction of AgNPs with large unilamellar vesicles (LUVs) as a model membrane system. Similar studies conducted by others in this field have largely been conducted with uncoated AgNPs, ignoring the effect of environmental conditions on the formation of an eco-corona on AgNPs. Thus, in this study, the spent medium (SM) …


Master Equation Modeling Of Prompt Dissociation Kinetics For Isoprene Derived Criegee Intermediates, Rory R. Schmidt , '23 Apr 2023

Master Equation Modeling Of Prompt Dissociation Kinetics For Isoprene Derived Criegee Intermediates, Rory R. Schmidt , '23

Senior Theses, Projects, and Awards

Isoprene ozonolysis is a major atmospheric producer of atmospheric oxidizers and aerosols. This complex reaction pathway forms an exothermic cascade, where constant competition between bimolecular sinks, unimolecular isomerizations, and collisional relaxation dictate reactivity. This work focuses on two isoprene derived Criegee intermediates, methacrolein oxide (MACR oxide) and formaldehyde oxide (FO). While the potential energy surface of FO is well understood, the reactivity of energetically excited FO has not been explored in detail. MACR oxide isomerization and primary products have been adequately characterized and explored computationally and experimentally, but the potential energy surface beyond isopropenyl dioxirane has not received the same …