Physical Sciences and Mathematics Commons^™

Improving Static Cold Storage Life Of The Human Heart Before Transplant, Juan Sebastian Rodriguez Paez

Theses and Dissertations

Organ storage and transportation are critical steps for the success of organ transplantation. Static cold storage (SCS) of hearts for heart transplantation (HTx) remains the standard approach. However, SCS may involve damage to the tissue resulting from extended hypothermic preservation, potentially affecting organ viability. More over, the temperature distribution on and within the heart is unknown during heart transplantation. Therefore, there is an interest to study different stages of the heart transplantation process towards determining the 3D temperature distribution on and within the heart. There could be a possibility of having a hypothermic injury in different parts of the heart …

Development Of Chiral Lewis Base Catalysts For Chlorosilane-Mediated Asymmetric C-C Bond Formations, Changgong Xu

Theses and Dissertations

The chiral hydrazine is a crucial structural motif that serves as pivotal structural elements in numerous natural products and biologically significant molecules. We are particularly interested in the catalytic asymmetric reduction of hydrazones, as well as the catalytic asymmetric propargylation and allenylation of hydrazones, because they provide direct pathways to these enantio-enriched chiral building blocks. In this work, we will explore the potential of two different categories of chiral Lewis base catalysts in the said transformations.

Developed by another student in our group, axial-chiral 3,3’-triazolyl biisoquinoline N,N’-dioxides derived catalysts are tested and demonstrated its capability in activating various hydrazone …

System Identification For Motion Control Of Unmanned Aerial Vehicles Platform, Raj Ramesh Agarwal

Theses and Dissertations

Comprehensive research on Unmanned Aerial Vehicles (UAV) system identification for motion control parameters is presented in this thesis, with a focus on the necessity of precise control and improved performance. Using Pseudorandom Binary Sequence (PRBS) and Normally Distributed Random Numbers, it presents a unique technique for excitation of UAV dynamic systems. It also shows how effective random signals are in time-domain identification for precise control in a range of flying circumstances. The piece of research includes a thorough analysis and implementation of various approaches and its further improvements, highlighting the benefits and drawbacks of each. These approaches include the free …

High Intraspecific Diversity Of Pocillopora Damicornis In Southeast Asia Reflects Adaptive Potential To Climate Change, Maria Lucille Carr

Theses and Dissertations

Marine heatwaves are increasing in intensity and frequency because of increased emissions of greenhouse gases. On coral reefs, warmer temperatures cause coral bleaching, mortality, and shifts in benthic composition. However, coral bleaching responses and survival vary geographically. Several hypotheses may explain such geographical differences in thermal tolerance, including the possibility that some localities may support higher intraspecific diversity than other localities, increasing the likelihood of survival of some individuals through heatwaves. Here we assessed geographic patterns of intraspecific genetic diversity in the ubiquitous coral Pocillopora damicornis. Intraspecific genetic diversity was assessed for 428 sequences across 44 sites in the Pacific …

Comparing And Assessing Four Ai Chatbots' Competence In Economics, Patrik T. Hultberg, David Santandreu Calonge, Firuz Kamalov, Linda Smail

All Works

Artificial Intelligence (AI) chatbots have emerged as powerful tools in modern academic endeavors, presenting both opportunities and challenges in the learning landscape. They can provide content information and analysis across most academic disciplines, but significant differences exist in terms of response accuracy for conclusions and explanations, as well as word counts. This study explores four distinct AI chatbots, GPT-3.5, GPT-4, Bard, and LLaMA 2, for accuracy of conclusions and quality of explanations in the context of university-level economics. Leveraging Bloom’s taxonomy of cognitive learning complexity as a guiding framework, the study confronts the four AI chatbots with a standard test …

Data Recovery Beyond The Obvious Using Digital Forensic Techniques, Smit Chandrakant Nayak

Theses, Dissertations and Culminating Projects

Advancement in drone technology, particularly for smaller drones, are creating new research fields and potential applications, particularly with regard to smaller drones. On the other hand, these enhancements bring forth additional hurdles in terms of adaptability, homogeneity, and safety. The purpose of this study is to investigate the science and technology behind drones, as well as their applications, the many ways in which citizens implement them, and the risks, precautions, and privacy problems that are associated with their utilization. This article discusses the existing literature, as well as the available solutions for drone cybersecurity, the security challenges related with drones …

Bridging Nlp With Environmental Management By Sentiment Analysis And Topic Modeling On Offshore Wind Energy, Isabele Mansur Costa Bittencourt

Theses, Dissertations and Culminating Projects

Offshore wind energy, which uses the power of winds on the seas to generate electricity, has emerged as a promising renewable energy source and an alternative for low-carbon future markets, especially during the climate crisis the world has been experiencing. However, it still raises controversial thoughts between people. Furthermore, amid the growth of the offshore wind energy market, the investigation of related topics, such as its impacts on wildlife, has become very common. Thus, this master’s thesis delves into the analysis of public and media opinion towards offshore wind energy. We use natural language processing techniques and pre-trained rule and …

Teaching And Learning In Human-Robot Collaborative Tasks, Omar Obidat

Theses, Dissertations and Culminating Projects

This paper describes a proposed model for human-robot collaboration (HRC), its implementation on a real-world representative application, and a final evaluation on the overall collaborative effort. Modern manufacturing places a strong emphasis on cost-reduction and increased throughput. A common means of scaling production and increasing productivity is achieved through the deployment of industrial robots, some of which work collaboratively with human workers. This contemporary pairing poses a number of challenges, including worker safety, process efficiency, reliability, among others. This paper details the approach of a human collaborating with a robot that utilizes a vision system, employs a dynamically generated finite …

Trust In Human-Robot Collaborative Tasks, Jesse Parron

Theses, Dissertations and Culminating Projects

With recent advancements in machine learning and artificial intelligence, we have entered a new era of technology. With AI on the rise, it has led to many insurgencies in a variety of domains. One area that has particularly been growing at a rapid pace is robotics. Consequently, the ubiquitous rise of robots in new workspaces leads to the influx of human-robot collaboration. Human-robot collaboration is an important factor in this domain, as it mandates the relationship between humans and robots. One key component of this relationship is trust, which many people subconsciously determine when interacting with peers, strangers, and coworkers. …

Influence Of Parsimony And Work-Related Psychological Constructs In Predicting Turnover Intention When Using Machine Learning Vs Regression, Diego Figueiras

Theses, Dissertations and Culminating Projects

This dissertation explores the ongoing debate between traditional statistical regression models and machine learning (ML) algorithms in predictive modeling, focusing on the impact of sample size and the number of variables. Study 1 investigates the relationship between sample size and predictive accuracy, proposing hypotheses regarding the advantages of ML over regression as sample size increases. Additionally, the study examines the influence of the number of variables on predictive accuracy, emphasizing the trade-off between ML and regression models. Using data from the Federal Employee Viewpoint Survey, the research aims to contribute insights into the conditions favoring each modeling approach. Study 2 …

Evaluation Of Heavy Metal Pollution, Water Quality, And The Effectiveness Of Remedial Sediment Dredging In The Lower Passaic River, New Jersey, Oluwafemi Soetan

Theses, Dissertations and Culminating Projects

Toxic metal pollution is a leading environmental concern for aquatic systems globally and remedial dredging has been widely employed to mitigate its harmful impacts. In terms of the short-term impacts of remedial dredging, mixed results are reported in several studies. Despite its immediate negative impacts including saturation of water with toxic metals, increased turbidity, and sediment resuspension, positive impacts can be recorded over a stabilization period of 6 – 24 months after dredging. Nevertheless, the sustainability of these recorded positive effects cannot be ascertained as some studies have reported long-term regression in remediated sites’ conditions. Evaluation of success determinants, site-measure …

Generalizations Of The Hardy Spaces And The Schwarz Boundary Value Problem, William L. Blair

Graduate Theses and Dissertations

We prove that many of the boundary properties associated with functions in the classic holomorphic Hardy spaces on the complex unit disk are present in Hardy classes of solutions to certain nonhomogeneous Cauchy-Riemann equations and higher-order generalizations of these equations. Also, we explicitly solve generalizations of the Schwarz boundary value problem on the complex unit disk and the upper-half plane when the boundary condition is in terms of boundary values in the sense of distributions.

Characterizing The Role Of Chemo-Mechanical Couplings In The Activation Process Of Proteins That Undergo Conformational Changes, Ugochi Isu

Graduate Theses and Dissertations

Proteins are not static entities; rather, they are dynamic macromolecules that undergo conformational changes to perform their biological functions. These structural transitions are often coupled to chemical events such as lipid interactions, or changes in the cellular environment. Understanding the intricate interplay between chemical perturbations and the resulting mechanical response is crucial for elucidating the activation mechanisms of proteins. This dissertation aims to characterize the role of chemo-mechanical couplings in the activation process of two G protein-coupled receptors (GPCRs): Cannabinoid Receptor 1 (CB1) and Metabotropic Glutamate Receptor 1 (mGluR1). We employ molecular dynamics simulations to investigate the conformational landscapes of …

Geochemical Analysis Of Basement Rock As A Potential Metal Source In Mississippi Valley-Type Ores, Southern Midcontinent U.S.A., Mackenzie Moorhead

Graduate Theses and Dissertations

Mississippi Valley-Type (MVT) ores are epigenetic, sedimentary hydrothermal base metal deposits that exist worldwide with type localities in the midcontinent United States. These Permian-aged sulfide ores represent an extraordinary concentration of economic metals, Pb and Zn. Ore deposits occur in vast districts that have a rich mining history. The Pb and Zn from these deposits account for 24% of worldwide reserves. The geologic processes responsible for MVT ore genesis are not fully understood, especially the sourcing of ore constituents. In the midcontinent, the Ouachita Orogeny expelled saline hydrothermal brines in response to high rates of subsidence. These fluids migrated through …

Fabrication And Characterization Of Black Phosphorus Terahertz Photoconductive Antennae, Katie Michelle Welch

Graduate Theses and Dissertations

Advancements in terahertz (THz) imaging systems, particularly for applications like post-surgical analysis of breast cancer, have led to the exploration of novel materials such as black phosphorus as the active material for a THz photoconductive antenna (PCA). This thesis, motivated by innovative techniques developed at the University of Arkansas, investigates the potential of black phosphorus as a material to enhance the performance of THz PCAs, focusing on generation efficiency and bandwidth. Previous implementations of BP as THz emitters have shown limitations, highlighting the need for thorough material characterization and optimized fabrication processes. Therefore, we adopted a dual-phase approach to this …

Determining The Climatic Effects Of The Central Atlantic Magmatic Province Across The End Triassic Mass Extinction In The Elliot Formation, Southern Africa, Danielle Elizabeth Oberg

Graduate Theses and Dissertations

Understanding the intricate relation between carbon-cycle perturbations, climate change, and biodiversity stability is crucial in the face of ongoing anthropogenic greenhouse-gas emissions. This thesis explores the impacts of rapid climate change induced by carbon-cycle perturbations and their potential repercussions on global climate. Large igneous provinces, particularly the Central Atlantic Magmatic Province, offer a lens through which to examine the nexus of volcanic activity, mass extinctions, and climate change. The emplacement of Central Atlantic Magmatic Province, covering vast regions across continents, emitted substantial amounts of carbon dioxide, profoundly impacting global climate and ecosystems. The end-Triassic Mass Extinction, attributed to Central Atlantic …

Two Studies: Aromatization-Driven Ring Opening Functionalization Of Unstrained Cycloalkanones Through Visible Light Catalysis, And Synthesis Of Amino Endoperoxides Using Self-Doped Titanium Dioxide (Ti3+@Tio2) As A Photocatalyst, Enoch Kudoahor

Graduate Theses and Dissertations

The pharmaceutical industry has been focused on discovering new innovative drugs over the last decade, but the syntheses are either inefficient or the approach to environmental sustainability raises significant concerns. Photochemistry and photocatalysis have found widespread applications in organic synthesis as a result of this pressing issue. Our role as organic chemists is to improve environmental quality by creating a "greener" world through the development of efficient synthetic methods and strategies. Solar energy is now one of the most abundant and renewable natural resources. The emergence of environmental sustainability concerns has led to the development of new techniques for harnessing …

Life On The Edge: The Cambrian Marine Realm And Oxygenation, Sara Pruss, Benjamin C. Gill

Geosciences: Faculty Publications

The beginning of the Phanerozoic saw two biological events that set the stage for all life that was to come: (a) the Cambrian Explosion (the appearance of most marine invertebrate phyla) and (b) the Great Ordovician Biodiversification Event (GOBE), the subsequent substantial accumulation of marine biodiversity. Here, we examine the current state of understanding of marine environments and ecosystems from the late Ediacaran through the Early Ordovician, which spans this biologically important interval. Through a compilation and review of the existing geochemical, mineralogical, sedimentological, and fossil records, we argue that this interval was one of sustained low and variable marine …

The Kruger Collection Reimagined: A Case Study In 3d Scanning And Interactive Exhibit Design, Annissa Davis

Department of Anthropology: Theses and Student Research

This thesis examines the use of 3D modeling in museum exhibition to create exploratory exhibits that facilitate unique relationships between the visitors and the collection beyond what is provided by the collection’s in person counterparts. Typical use of 3D modeling in museums is currently often representative rather than exploratory. By employing a Digital Humanities lens to approach the development of a digital exhibition utilizing 3D technology and interactive elements created in a video game engine (Unity), this thesis project evaluates these potential new relationships. Using the Eloise Kruger Collection of Miniatures as a case study, the following text details the …

Student Self-Efficacy And Attitude In Organic Chemistry: A Comparison Of Two Pedagogical Approaches, Matthew Autry

Arts & Sciences Graduate Student Theses and Dissertations

No abstract provided.

Bidding Strategy For A Wind Power Producer In Us Energy And Reserve Markets, Anne Stratman

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

Wind power is one of the world's fastest-growing renewable energy resources and has expanded quickly within the US electric grid. Currently, wind power producers (WPPs) may sell energy products in US markets but are not allowed to sell reserve products, due to the uncertain and intermittent nature of wind power. However, as wind’s share of the power supply grows, it may eventually be necessary for WPPs to contribute to system-wide reserves. This paper proposes a stochastic optimization model to determine the optimal offer strategy for a WPP that participates in the day-ahead and real-time energy and spinning reserve markets. The …

Vr Circuit Simulation With Advanced Visualization For Enhancing Comprehension In Electrical Engineering, Elliott Wolbach

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

As technology advances, the field of electrical and computer engineering continuously demands innovative tools and methodologies to facilitate effective learning and comprehension of fundamental concepts. Through a comprehensive literature review, it was discovered that there was a gap in the current research on using VR technology to effectively visualize and comprehend non-observable electrical characteristics of electronic circuits. This thesis explores the integration of Virtual Reality (VR) technology and real-time electronic circuit simulation with enhanced visualization of non-observable concepts such as voltage distribution and current flow within these circuits. The primary objective is to develop an immersive educational platform that makes …

Towards Explainable Harmful Meme Detection Through Multimodal Debate Between Large Language Models, Hongzhan Lin, Ziyang Luo, Wei Gao, Jing Ma, Bo Wang, Ruichao Yang

Research Collection School Of Computing and Information Systems

The age of social media is flooded with Internet memes, necessitating a clear grasp and effective identification of harmful ones. This task presents a significant challenge due to the implicit meaning embedded in memes, which is not explicitly conveyed through the surface text and image. However, existing harmful meme detection methods do not present readable explanations that unveil such implicit meaning to support their detection decisions. In this paper, we propose an explainable approach to detect harmful memes, achieved through reasoning over conflicting rationales from both harmless and harmful positions. Specifically, inspired by the powerful capacity of Large Language Models …

Escaping Saddle Points In Heterogeneous Federated Learning Via Distributed Sgd With Communication Compression, Sijin Chen, Zhize Li, Yuejie Chi

Research Collection School Of Computing and Information Systems

We consider the problem of finding second-order stationary points in the optimization of heterogeneous federated learning (FL). Previous works in FL mostly focus on first-order convergence guarantees, which do not rule out the scenario of unstable saddle points. Meanwhile, it is a key bottleneck of FL to achieve communication efficiency without compensating the learning accuracy, especially when local data are highly heterogeneous across different clients. Given this, we propose a novel algorithm PowerEF-SGD that only communicates compressed information via a novel error-feedback scheme. To our knowledge, PowerEF-SGD is the first distributed and compressed SGD algorithm that provably escapes saddle points …

Q-Learning Based Framework For Solving The Stochastic E-Waste Collection Problem, Dang Viet Anh Nguyen, Aldy Gunawan, Mustafa Misir, Pieter Vansteenwegen

Research Collection School Of Computing and Information Systems

Electrical and Electronic Equipment (EEE) has evolved into a gateway for accessing technological innovations. However, EEE imposes substantial pressure on the environment due to the shortened life cycles. E-waste encompasses discarded EEE and its components which are no longer in use. This study focuses on the e-waste collection problem and models it as a Vehicle Routing Problem with a heterogeneous fleet and a multi-period planning problem with time windows as well as stochastic travel times. Two different Q-learning-based methods are designed to enhance the search procedure for finding solutions. The first method involves utilizing the state-action value to determine the …

Ublade: Efficient Batch Processing For Uncertainty Graph Queries, Siyuan Yao, Yuchen Li, Shixuan Sun, Jiaxin Jiang, Bingsheng He

Research Collection School Of Computing and Information Systems

The study of uncertain graphs is crucial in diverse fields, including but not limited to protein interaction analysis, viral marketing, and network reliability. Processing queries on uncertain graphs presents formidable challenges due to the vast probabilistic space they encapsulate. While existing systems employ batch processing to address these challenges, their performance is often compromised by the suboptimal selection of parallel graph traversal methods, the excessive costs in random number generation, and additional sampling-loads intrinsic to batch processing. In this paper, we introduce uBlade, an efficient batch-processing framework for uncertain graph queries on multi-core CPUs. uBlade utilizes the work-efficient graph traversal, …

Enabling Roll-Up And Drill-Down Operations In News Exploration With Knowledge Graphs For Due Diligence And Risk Management, Sha Wang, Yuchen Li, Hanhua Xiao, Zhifeng Bao, Yanfei Dong

Research Collection School Of Computing and Information Systems

Efficient news exploration is crucial in real-world applications, particularly within the financial sector, where numerous control and risk assessment tasks rely on the analysis of public news reports. The current processes in this domain predominantly rely on manual efforts, often involving keyword-based searches and the compilation of extensive keyword lists. In this paper, we introduce NCEXPLORER, a framework designed with OLAP-like operations to enhance the news exploration experience. NCEXPLORER empowers users to use roll-up operations for a broader content overview and drill-down operations for detailed insights. These operations are achieved through integration with external knowledge graphs (KGs), encompassing both fact-based …

Text-Attributed Graph Representation Learning : Methods, Applications, And Challenges, Ce Zhang, Menglin Yang, Rex Ying, Hady Wirawan Lauw

Research Collection School Of Computing and Information Systems

Text documents are usually connected in a graph structure, resulting in an important class of data named text-attributed graph, e.g., paper citation graph and Web page hyperlink graph. On the one hand, Graph Neural Networks (GNNs) consider text in each document as general vertex attribute and do not specifically deal with text data. On the other hand, Pre-trained Language Models (PLMs) and Topic Models (TMs) learn effective document embeddings. However, most models focus on text content in each single document only, ignoring link adjacency across documents. The above two challenges motivate the development of text-attributed graph representation learning, combining GNNs …

Factored Mdp Based Moving Target Defense With Dynamic Threat Modeling, Megha Bose, Praveen Paruchuri, Akshat Kumar

Research Collection School Of Computing and Information Systems

Moving Target Defense (MTD) has emerged as a proactive defense framework to counteract ever-changing cyber threats. Existing approaches often make assumptions about attacker-side knowledge and behavior, potentially resulting in suboptimal defense. This paper introduces a novel MTD approach, leveraging a Markov Decision Process (MDP) model that eliminates the need for prior knowledge about attacker intentions or payoffs. Our framework seamlessly integrates real-time attacker responses into the defender's MDP using a dynamic Bayesian network. We use a factored MDP model to enable a more comprehensive and realistic representation of the system having multiple switchable aspects and also accommodate incremental updates of …

Fashionregen: Llm‑Empowered Fashion Report Generation, Yujuan Ding, Yunshan Ma, Wenqi Fan, Yige Yao, Tat‑Seng Chua, Qing Li

Research Collection School Of Computing and Information Systems

Fashion analysis refers to the process of examining and evaluating trends, styles, and elements within the fashion industry to understand and interpret its current state, generating fashion reports. It is traditionally performed by fashion professionals based on their expertise and experience, which requires high labour cost and may also produce biased results for relying heavily on a small group of people. In this paper, to tackle the Fashion Report Generation (FashionReGen) task, we propose an intelligent Fashion Analyzing and Reporting system based the advanced Large Language Models (LLMs), debbed as GPT-FAR. Specifically, it tries to deliver FashionReGen based on effective …