Physical Sciences and Mathematics Commons^™

Development Of A High-Resolution Mid-Infrared Spectroscopy Apparatus For The Study Of Methane And Other Astrochemical Molecules., S M Shah Riyadh

Electronic Theses and Dissertations

This research documents steps towards building a novel spectroscopic technique, namely, cavity-enhanced double-resonance (CEDR) spectroscopy, for investigating methane (CH₄) and other molecules with significance in astrochemistry. These efforts focus on tackling the complexities of their ro-vibrational energy levels and the inefficiencies in analyzing vibrational spectra, particularly for molecules with high symmetry and strong intramolecular interactions. In the CEDR spectroscopy, the first photon, generated by a continuous-wave optical parametric oscillator (CW-OPO) locked to a Doppler-free saturation absorption line, excites the molecule from its ground level to a selected excited ro-vibrational (rotational-vibrational) level, e.g., that of the asymmetric CH-stretch mode. …

Multithreaded Applications On The Heterogeneous Research Computing Environment., Sungbo Jung

Electronic Theses and Dissertations

Bioinformatics is a domain that has experienced rapid research growth in recent years, as evidenced by the increasing number of articles in biomedical databases such as PubMed, which adds over a million publications every year. However, this also poses a challenge for researchers who need to find relevant citations for their work. Therefore, developing efficient indexing and searching methods for text data is crucial for Bioinformatics. One key technique for information retrieval is document inversion, which involves creating an inverted index to enable efficient searching through vast collections of text or documents. This Ph.D. research aims to design the research …

Utilizing Metal Ligand Cooperativity To Activate Small Molecules., Christine Burgan

Electronic Theses and Dissertations

The problems created from the excessive use of fossil fuels can be approached from two directions: capture the CO₂ from the atmosphere or develop alternative energy sources. The current industrial standards for these are environmental and/or health hazards and utilize precious metals, respectively. Metal ligand cooperativity (MLC) has emerged as a promising alternative to using precious metals to activate small molecules. In this dissertation, we focus on a series of metal complexes based on the ligand diacetyl-2-(4-methyl-thiosemicarbazone)-3-(2-hydrazinopyridine) (H₂L¹) for either hydrogen evolution or CO₂ capture. The novel complexes were characterized by ¹H NMR, …

Investigations Of Physical Properties Of Novel Magnetic And Non- Magnetic Two-Dimensional (2d) Alloys., Mohammed Ameen Irziqat

Electronic Theses and Dissertations

This research work reports investigations of structural and physical properties of novel magnetic and non-magnetic 2D alloys. Three techniques were utilized in this investigation: Angle-resolved polarized Raman spectroscopy (ARPRS), Electrical &Thermoelectric power measurements, Magneto-optic Kerr effect (MOKE) spectroscopy. ARPRS and MOKE experiments were constructed during the course of this work. ARPRS was used to study the anisotropy of 2-dimensional black-arsenic phosphors (b-AsxP1-x) as a function of arsenic concentration (x). It was observed experimentally that all Raman modes of the studied samples with x=0, 0.4, 0.8 exhibit polarization dependence. More interestingly, the polarization dependence of Raman modes due to the vibrations …

Electrochemical Modulation Of Surface Plasmon Wave To Investigate Dna-Based Sensing Platforms And Detection Of Sars-Cov2., Anil Sharma

Electronic Theses and Dissertations

This study offers a thorough comparative analysis of optical and electrical signaling strategies for assessing the electrochemical properties of different redox-labeled DNA-based biosensing platforms. In addition, it illustrates the development of an optical interrogation technique with electrochemical modulation of surface plasmon waves (ECM-SPW) as a route for analyzing and implementing DNA-based hybridization sensors. For those quantitative analyses, we chose a model sensing platform composed of a methylene blue (MB)-modified single-stranded DNA (ssDNA) signaling probe and an unlabeled capture ssDNA probe that complements the signaling probe. Two types of signaling probes were employed in this work: one with MB attached to …

Pedestrian Pathing Prediction Using Complex Contextual Behavioral Data In High Foot Traffic Settings, Laurel Bingham

All Graduate Theses and Dissertations, Fall 2023 to Present

Ensuring the safe integration of autonomous vehicles into real-world environments requires a comprehensive understanding of pedestrian behavior. This study addresses the challenge of predicting the movement and crossing intentions of pedestrians, a crucial aspect in the development of fully autonomous vehicles.

The research focuses on leveraging Honda's TITAN dataset, comprising 700 unique clips captured by moving vehicles in high-foot-traffic areas of Tokyo, Japan. Each clip provides detailed contextual information, including human-labeled tags for individuals and vehicles, encompassing attributes such as age, motion status, and communicative actions. Long Short-Term Memory (LSTM) networks were employed and trained on various combinations of contextual …

Deterministic Global 3d Fractal Cloud Model For Synthetic Scene Generation, Aaron M. Schinder, Shannon R. Young, Bryan J. Steward, Michael L. Dexter, Andrew Kondrath, Stephen Hinton, Ricardo Davila

Faculty Publications

This paper describes the creation of a fast, deterministic, 3D fractal cloud renderer for the AFIT Sensor and Scene Emulation Tool (ASSET). The renderer generates 3D clouds by ray marching through a volume and sampling the level-set of a fractal function. The fractal function is distorted by a displacement map, which is generated using horizontal wind data from a Global Forecast System (GFS) weather file. The vertical windspeed and relative humidity are used to mask the creation of clouds to match realistic large-scale weather patterns over the Earth. Small-scale detail is provided by the fractal functions which are tuned to …

Soil Reclamation Strategies In Construction Disturbed Soil, Alexis Koelling

All Graduate Reports and Creative Projects, Fall 2023 to Present

The rapid urbanization occurring in arid environments like the Intermountain West region of the U.S. significantly alters soil conditions. Construction of roads, buildings, and other infrastructure leads to the disturbance of soil structure, nutrient depletion, and reduced fertility. This research addresses the need for sustainable soil management practices that may restore soil health post-construction. In this study, the effectiveness of various soil amendments and application methods on specific soil parameters and turfgrass establishment in construction-disturbed soils was evaluated. The study highlights the critical role of soil amendments, particularly municipal solid waste (MSW) compost, in improving soil quality and plant growth. …

Revealing The Three-Dimensional Arrangement Of Polar Topology In Nanoparticles, Chaewa Jeong, Juhyeok Lee, Hyesung Jo, Jaewhan Oh, Hionsuck Baik, Kyoung-June Go, Junwoo Son, Si-Young Choi, Sergey Prosandeev, Laurent Bellaiche, Yongsoo Yang

Physics Faculty Publications and Presentations

In the early 2000s, low dimensional ferroelectric systems were predicted to have topologically nontrivial polar structures, such as vortices or skyrmions, depending on mechanical or electrical boundary conditions. A few variants of these structures have been experimentally observed in thin film model systems, where they are engineered by balancing electrostatic charge and elastic distortion energies. However, the measurement and classification of topological textures for general ferroelectric nanostructures have remained elusive, as it requires mapping the local polarization at the atomic scale in three dimensions. Here we unveil topological polar structures in ferroelectric BaTiO₃ nanoparticles via atomic electron tomography, which …

Cloud Computing Integration Into Mixed-Reality: Physical To Abstraction, Yassine Chahid, Patrick Slattery

Publications and Research

This research evaluates the progression of cloud computing and mixed-reality technologies, and to identify how these technologies influence advancements in the latter. Both cloud computing and mixed reality have significantly impacted the IT field and the services available to the public and various institutions. Cloud computing provides a valuable way to process information or allocate computational resources on otherwise limited hardware. Augmented or virtual reality hardware would greatly benefit from this by offloading resource-intensive tasks to other machines. The research methodology involves analyzing essential components of both innovations, divided into multiple categories. These components range from physical, hardware-based elements to …

Computational Linguistics And Multilingualism: A Comparative Analysis With Spanish And English Data, Evelyn Lawrie

Student Scholar Symposium Abstracts and Posters

Computational linguistics is an increasingly ubiquitous field, serving as the basis for artificial intelligence and machine translation. It aims to analyze the syntax and semantics of individual words and phrases. While there have been in-depth advancements in computational linguistics strategies for the English language, others have not been developed as thoroughly. This lack of emphasis on multilingualism has contributed to the disappearance of Hispanic perspectives in the digital world. Especially those of indigenous heritage, as the decline of many indigenous languages has been exacerbated by the lack of digital translation services. Sentiment analysis is a branch of computational linguistics that …

Unraveling The Physics Of Quasar Jets Using Hst Polarimetry, Devon Clautice

Theses and Dissertations

We present a multiwavelength study of three high-power FR II (quasar) jets -- 3C 273, PKS 0637-752, and 1150+497 -- with an emphasis on new high-quality Hubble Space Telescope (HST) optical polarimetry and Chandra X-ray Observatory imaging. Relativistic jets from active galactic nuclei transport energy and mass from the supermassive black hole’s accretion region out to Megaparsec-scale lobes, with effects that feedback into galaxy formation and cluster energetics. We build on recent work which has called into question our fundamental understanding of FR II jet physics, and suggest that highly-efficient particle acceleration must be taking place in situ …

Improving Static Cold Storage Life Of The Human Heart Before Transplant, Juan Sebastian Rodriguez Paez

Theses and Dissertations

Organ storage and transportation are critical steps for the success of organ transplantation. Static cold storage (SCS) of hearts for heart transplantation (HTx) remains the standard approach. However, SCS may involve damage to the tissue resulting from extended hypothermic preservation, potentially affecting organ viability. More over, the temperature distribution on and within the heart is unknown during heart transplantation. Therefore, there is an interest to study different stages of the heart transplantation process towards determining the 3D temperature distribution on and within the heart. There could be a possibility of having a hypothermic injury in different parts of the heart …

Development Of Chiral Lewis Base Catalysts For Chlorosilane-Mediated Asymmetric C-C Bond Formations, Changgong Xu

Theses and Dissertations

The chiral hydrazine is a crucial structural motif that serves as pivotal structural elements in numerous natural products and biologically significant molecules. We are particularly interested in the catalytic asymmetric reduction of hydrazones, as well as the catalytic asymmetric propargylation and allenylation of hydrazones, because they provide direct pathways to these enantio-enriched chiral building blocks. In this work, we will explore the potential of two different categories of chiral Lewis base catalysts in the said transformations.

Developed by another student in our group, axial-chiral 3,3’-triazolyl biisoquinoline N,N’-dioxides derived catalysts are tested and demonstrated its capability in activating various hydrazone …

System Identification For Motion Control Of Unmanned Aerial Vehicles Platform, Raj Ramesh Agarwal

Theses and Dissertations

Comprehensive research on Unmanned Aerial Vehicles (UAV) system identification for motion control parameters is presented in this thesis, with a focus on the necessity of precise control and improved performance. Using Pseudorandom Binary Sequence (PRBS) and Normally Distributed Random Numbers, it presents a unique technique for excitation of UAV dynamic systems. It also shows how effective random signals are in time-domain identification for precise control in a range of flying circumstances. The piece of research includes a thorough analysis and implementation of various approaches and its further improvements, highlighting the benefits and drawbacks of each. These approaches include the free …

High Intraspecific Diversity Of Pocillopora Damicornis In Southeast Asia Reflects Adaptive Potential To Climate Change, Maria Lucille Carr

Theses and Dissertations

Marine heatwaves are increasing in intensity and frequency because of increased emissions of greenhouse gases. On coral reefs, warmer temperatures cause coral bleaching, mortality, and shifts in benthic composition. However, coral bleaching responses and survival vary geographically. Several hypotheses may explain such geographical differences in thermal tolerance, including the possibility that some localities may support higher intraspecific diversity than other localities, increasing the likelihood of survival of some individuals through heatwaves. Here we assessed geographic patterns of intraspecific genetic diversity in the ubiquitous coral Pocillopora damicornis. Intraspecific genetic diversity was assessed for 428 sequences across 44 sites in the Pacific …

Comparing And Assessing Four Ai Chatbots' Competence In Economics, Patrik T. Hultberg, David Santandreu Calonge, Firuz Kamalov, Linda Smail

All Works

Artificial Intelligence (AI) chatbots have emerged as powerful tools in modern academic endeavors, presenting both opportunities and challenges in the learning landscape. They can provide content information and analysis across most academic disciplines, but significant differences exist in terms of response accuracy for conclusions and explanations, as well as word counts. This study explores four distinct AI chatbots, GPT-3.5, GPT-4, Bard, and LLaMA 2, for accuracy of conclusions and quality of explanations in the context of university-level economics. Leveraging Bloom’s taxonomy of cognitive learning complexity as a guiding framework, the study confronts the four AI chatbots with a standard test …

Data Recovery Beyond The Obvious Using Digital Forensic Techniques, Smit Chandrakant Nayak

Theses, Dissertations and Culminating Projects

Advancement in drone technology, particularly for smaller drones, are creating new research fields and potential applications, particularly with regard to smaller drones. On the other hand, these enhancements bring forth additional hurdles in terms of adaptability, homogeneity, and safety. The purpose of this study is to investigate the science and technology behind drones, as well as their applications, the many ways in which citizens implement them, and the risks, precautions, and privacy problems that are associated with their utilization. This article discusses the existing literature, as well as the available solutions for drone cybersecurity, the security challenges related with drones …

Bridging Nlp With Environmental Management By Sentiment Analysis And Topic Modeling On Offshore Wind Energy, Isabele Mansur Costa Bittencourt

Theses, Dissertations and Culminating Projects

Offshore wind energy, which uses the power of winds on the seas to generate electricity, has emerged as a promising renewable energy source and an alternative for low-carbon future markets, especially during the climate crisis the world has been experiencing. However, it still raises controversial thoughts between people. Furthermore, amid the growth of the offshore wind energy market, the investigation of related topics, such as its impacts on wildlife, has become very common. Thus, this master’s thesis delves into the analysis of public and media opinion towards offshore wind energy. We use natural language processing techniques and pre-trained rule and …

Teaching And Learning In Human-Robot Collaborative Tasks, Omar Obidat

Theses, Dissertations and Culminating Projects

This paper describes a proposed model for human-robot collaboration (HRC), its implementation on a real-world representative application, and a final evaluation on the overall collaborative effort. Modern manufacturing places a strong emphasis on cost-reduction and increased throughput. A common means of scaling production and increasing productivity is achieved through the deployment of industrial robots, some of which work collaboratively with human workers. This contemporary pairing poses a number of challenges, including worker safety, process efficiency, reliability, among others. This paper details the approach of a human collaborating with a robot that utilizes a vision system, employs a dynamically generated finite …

Trust In Human-Robot Collaborative Tasks, Jesse Parron

Theses, Dissertations and Culminating Projects

With recent advancements in machine learning and artificial intelligence, we have entered a new era of technology. With AI on the rise, it has led to many insurgencies in a variety of domains. One area that has particularly been growing at a rapid pace is robotics. Consequently, the ubiquitous rise of robots in new workspaces leads to the influx of human-robot collaboration. Human-robot collaboration is an important factor in this domain, as it mandates the relationship between humans and robots. One key component of this relationship is trust, which many people subconsciously determine when interacting with peers, strangers, and coworkers. …

Influence Of Parsimony And Work-Related Psychological Constructs In Predicting Turnover Intention When Using Machine Learning Vs Regression, Diego Figueiras

Theses, Dissertations and Culminating Projects

This dissertation explores the ongoing debate between traditional statistical regression models and machine learning (ML) algorithms in predictive modeling, focusing on the impact of sample size and the number of variables. Study 1 investigates the relationship between sample size and predictive accuracy, proposing hypotheses regarding the advantages of ML over regression as sample size increases. Additionally, the study examines the influence of the number of variables on predictive accuracy, emphasizing the trade-off between ML and regression models. Using data from the Federal Employee Viewpoint Survey, the research aims to contribute insights into the conditions favoring each modeling approach. Study 2 …

Evaluation Of Heavy Metal Pollution, Water Quality, And The Effectiveness Of Remedial Sediment Dredging In The Lower Passaic River, New Jersey, Oluwafemi Soetan

Theses, Dissertations and Culminating Projects

Toxic metal pollution is a leading environmental concern for aquatic systems globally and remedial dredging has been widely employed to mitigate its harmful impacts. In terms of the short-term impacts of remedial dredging, mixed results are reported in several studies. Despite its immediate negative impacts including saturation of water with toxic metals, increased turbidity, and sediment resuspension, positive impacts can be recorded over a stabilization period of 6 – 24 months after dredging. Nevertheless, the sustainability of these recorded positive effects cannot be ascertained as some studies have reported long-term regression in remediated sites’ conditions. Evaluation of success determinants, site-measure …

Generalizations Of The Hardy Spaces And The Schwarz Boundary Value Problem, William L. Blair

Graduate Theses and Dissertations

We prove that many of the boundary properties associated with functions in the classic holomorphic Hardy spaces on the complex unit disk are present in Hardy classes of solutions to certain nonhomogeneous Cauchy-Riemann equations and higher-order generalizations of these equations. Also, we explicitly solve generalizations of the Schwarz boundary value problem on the complex unit disk and the upper-half plane when the boundary condition is in terms of boundary values in the sense of distributions.

Characterizing The Role Of Chemo-Mechanical Couplings In The Activation Process Of Proteins That Undergo Conformational Changes, Ugochi Isu

Graduate Theses and Dissertations

Proteins are not static entities; rather, they are dynamic macromolecules that undergo conformational changes to perform their biological functions. These structural transitions are often coupled to chemical events such as lipid interactions, or changes in the cellular environment. Understanding the intricate interplay between chemical perturbations and the resulting mechanical response is crucial for elucidating the activation mechanisms of proteins. This dissertation aims to characterize the role of chemo-mechanical couplings in the activation process of two G protein-coupled receptors (GPCRs): Cannabinoid Receptor 1 (CB1) and Metabotropic Glutamate Receptor 1 (mGluR1). We employ molecular dynamics simulations to investigate the conformational landscapes of …

Geochemical Analysis Of Basement Rock As A Potential Metal Source In Mississippi Valley-Type Ores, Southern Midcontinent U.S.A., Mackenzie Moorhead

Graduate Theses and Dissertations

Mississippi Valley-Type (MVT) ores are epigenetic, sedimentary hydrothermal base metal deposits that exist worldwide with type localities in the midcontinent United States. These Permian-aged sulfide ores represent an extraordinary concentration of economic metals, Pb and Zn. Ore deposits occur in vast districts that have a rich mining history. The Pb and Zn from these deposits account for 24% of worldwide reserves. The geologic processes responsible for MVT ore genesis are not fully understood, especially the sourcing of ore constituents. In the midcontinent, the Ouachita Orogeny expelled saline hydrothermal brines in response to high rates of subsidence. These fluids migrated through …

Fabrication And Characterization Of Black Phosphorus Terahertz Photoconductive Antennae, Katie Michelle Welch

Graduate Theses and Dissertations

Advancements in terahertz (THz) imaging systems, particularly for applications like post-surgical analysis of breast cancer, have led to the exploration of novel materials such as black phosphorus as the active material for a THz photoconductive antenna (PCA). This thesis, motivated by innovative techniques developed at the University of Arkansas, investigates the potential of black phosphorus as a material to enhance the performance of THz PCAs, focusing on generation efficiency and bandwidth. Previous implementations of BP as THz emitters have shown limitations, highlighting the need for thorough material characterization and optimized fabrication processes. Therefore, we adopted a dual-phase approach to this …

Determining The Climatic Effects Of The Central Atlantic Magmatic Province Across The End Triassic Mass Extinction In The Elliot Formation, Southern Africa, Danielle Elizabeth Oberg

Graduate Theses and Dissertations

Understanding the intricate relation between carbon-cycle perturbations, climate change, and biodiversity stability is crucial in the face of ongoing anthropogenic greenhouse-gas emissions. This thesis explores the impacts of rapid climate change induced by carbon-cycle perturbations and their potential repercussions on global climate. Large igneous provinces, particularly the Central Atlantic Magmatic Province, offer a lens through which to examine the nexus of volcanic activity, mass extinctions, and climate change. The emplacement of Central Atlantic Magmatic Province, covering vast regions across continents, emitted substantial amounts of carbon dioxide, profoundly impacting global climate and ecosystems. The end-Triassic Mass Extinction, attributed to Central Atlantic …

Two Studies: Aromatization-Driven Ring Opening Functionalization Of Unstrained Cycloalkanones Through Visible Light Catalysis, And Synthesis Of Amino Endoperoxides Using Self-Doped Titanium Dioxide (Ti3+@Tio2) As A Photocatalyst, Enoch Kudoahor

Graduate Theses and Dissertations

The pharmaceutical industry has been focused on discovering new innovative drugs over the last decade, but the syntheses are either inefficient or the approach to environmental sustainability raises significant concerns. Photochemistry and photocatalysis have found widespread applications in organic synthesis as a result of this pressing issue. Our role as organic chemists is to improve environmental quality by creating a "greener" world through the development of efficient synthetic methods and strategies. Solar energy is now one of the most abundant and renewable natural resources. The emergence of environmental sustainability concerns has led to the development of new techniques for harnessing …

Establishing “The Fossil Record”: A Database Of Vertebrate Paleontological Sites Across The State Of Tennessee, Sarah Mclaurine

Electronic Theses and Dissertations

Fossil localities across the state of Tennessee and the data related to those sites were compiled from Tennessee Division of Geology Bulletin 84, titled “Tennessee’s Prehistoric Vertebrates,” and stored in a Microsoft Access geodatabase housed by the Department of Collections at the East Tennessee State University Museum of Natural History located at the Gray Fossil Site. Included in the database are forms to enter new site localities, view information about those already entered, view and add data to a master faunal list for the state, view sites repository information and store and add documents that are key-word searchable from the …