Physical Sciences and Mathematics Commons^™

Two Studies: Stereoselective C-C Bond Formations Of N-Boc-Piperidines Using Selected Organolithiums And Visible-Light-Mediated Synthesis Of Fused Indolines Using Tethered Styrenes, Scott Alan Morris

Graduate Theses and Dissertations

Chemists worldwide have accepted the challenge of developing methods to access a variety of compounds as single enantiomers, including the use of enzymes, chiral auxiliaries, and resolutions. In particular, dynamic resolutions offer a unique way to access chiral compounds using a few controllable steps, including the variation of both time and temperature. Many groups have implemented this methodology to generate various polysubstituted pyrrolidines and piperidines, which are substructures ranking high on the list of nitrogen–containing pharmaceuticals.

The Gawley group revealed a catalytic dynamic resolution (CDR) of N–Boc–piperidine using a chiral ligand. Impressively, the chemistry was tolerant of a variety of …

On Compactness And Closed-Rangeness Of Composition Operators, Arnab Dutta

Graduate Theses and Dissertations

Let $\phi$ be an analytic self-map of the unit disk $\mathbb{D}:=\{z:\lvert z\rvert

Study Of Plasmonic Properties Of The Gold Nanorods In The Visible To Near Infrared Light Regime, Pijush Kanti Ghosh

Graduate Theses and Dissertations

Nanostructures of noble metals show unique plasmonic behavior in the visible to near-infrared light range. Gold nanostructures exhibit a particularly strong plasmonic response for these wavelengths of light. In this study we have investigated optical enhancement and absorption of gold nanorods with different thickness using finite element method simulations. This study reports on the resonance wavelength of the sharp-corner and round-corner rectangles of constant length 100 nm and width 60 nm. The result shows that resonance wavelength depends on the polarization of the incident light; there also exists a strong dependence of the optical enhancement and absorption on the thickness …

Electrodeionization Versus Electrodialysis: A Clean-Up Of Produced Water In Hydraulic Fracturing, Brigitte Marie Rodgers

Graduate Theses and Dissertations

Electrodeionization (EDI) is a widely studied process ranging from applications in wastewater clean-up in the food and beverage industry to purifying organic compounds. To date, there are no apparent studies on applying this technology to produced wastewater recovered from hydraulic fracking sites. Water consumption within hydraulic fracturing sites can reach in the upwards of millions of gallons per site, so a need for a water recycling process becomes necessary within areas where water requirements are scarce. Implementation of an EDI module that is capable of handling high salt solutions from produced wastewater in subsequent fracturing practices will decrease overall water …

Determination Of Optimum Fall And Spring Nitrogen Fertilizer Rate For Maximizing Grain Yield Of Soft Red Winter Wheat Sown At Variable Planting Dates, Lucas Vasconcelos Vieira

Graduate Theses and Dissertations

An optimum planting date is important for winter wheat nitrogen (N) management as it dramatically changes the growing environment including temperature and moisture, ultimately affecting fertilizer efficiency and grain yield (GY). In Arkansas, high precipitation in the fall often forces farmers to delay planting and current Arkansas recommendations include the application of fall N when soft red winter wheat (SRWW) is sown later than optimum, despite the lack of data supporting this practice. This study evaluated the effect of rate and timing of N application on GY of SRWW sown at variable planting dates in Arkansas. Granular urea was split …

Initial Structural Subsidence As Reflected In Morrowan And Atokan (Pennsylvanian) Subsurface Stratigraphy, Northern Arkoma Basin, North-Central Arkansas, Fatimah Taher Nahi Al Asadi

Graduate Theses and Dissertations

The Arkoma Basin is a carboniferous foreland basin that is known for its prolific gas production. The objective of this research is to study the initial subsidence of the basin by analyzing the strati-graphic and structural features of the study area. This was accomplished through IHS Petra, Surf-er 13, and Win-Tensor software. Field work studies comprised a large part of this study. Also, a seismic profile and Google earth elevation profiles are among the methods used to study the initial subsidence of the Arkoma Basin. The study area within the basin represents a transitional zone from the shelf into the …

Implications For The North American Lower Crustal 7.Xx Km/S Layer From An Exhumed Crustal Root, Western Canadian Shield, Calvin Everette Johnson

Graduate Theses and Dissertations

Studies of the Thorsby magnetic low, the southern extent of the 2,800 km-long Snowbird

Tectonic Zone (STZ) in Alberta, Canada, show pronounced lower crustal seismic reflectivity and preservation of a crustal root. These features may be correlative to the well-exposed central STZ, where two lower crustal tectonic events have been identified at 2.6-2.55 Ga and 1.92-1.89 Ga. High-resolution cross-sections of the central STZ reveal the late-stage interaction of Paleoproterozoic intracontinental thrust and strike-slip shear zones responsible for juxtaposing ca. >20,000 km2 of lower continental crust (0.9-1.5 GPa) with middle continental crust (0.5 GPa) (Mahan and Williams, 2005; Dumond et al., …

Investigation Of The Interaction Of Dimeric Ruthenium Complexes With Cytochrome B5, Christopher Dain Rupar

Graduate Theses and Dissertations

Photoreactive complexes to study the kinetics of electron transfer of proteins have been in use for a long time. It has always been speculated that complexes bind near the heme or the electron transfer reaction would not occur. But it is unkown exactly how the complex interacts with the protein. The structural, thermodynamic, and kinetic properties of rat liver microsomal cytochrome b5 were investigated when bound to ruthenium dimer complexes. Heteronuclear Single Quantum Coherence studies support a dynamic binding model of a dimer Ru complex bound near the protein’s heme involving residues H39, E44, G42, V61, G62, and H63. The …

Studies In The Asymmetric Synthesis Of The C21-C34 Fragment Of The Natural Product, Antascomicin B, Brian Lee Walker

Graduate Theses and Dissertations

This dissertation describes studies in the asymmetric synthesis of the C21 – C34 fragment of the natural product, antascomicin B. Antascomicin B is structurally related to FK506, binds strongly to FKBP12, yet does not shown immunosuppressive activity. Small ligand FKBP12 binding complexes were shown to have potent neuroprotective and neuroregenerative properties in mouse models of Parkinson’s disease. The highlighted chemical reactions include an asymmetric transfer hydrogenation (ATH), Ireland-Claisen rearrangement (ICR), directed hydrogenation and allylic diazene rearrangement.

Photoluminescence Measurement On Low-Temperature Metal Modulation Epitaxy Grown Gan, Yang Wu

Graduate Theses and Dissertations

A low-temperature photoluminescence (PL) study was conducted on low-temperature metal modulation epitaxy (MME) grown GaN. By comparing the PL signal from high temperature grown GaN buffer layers, and MME grown cap layers on top of the buffer layers, it was found that MME grown GaN cap has a significantly greater defect-related emission. The band edge PL from MME grown GaN found to be 3.51eV at low temperature. The binding energy of the exciton in GaN is determined to be 21meV through temperature dependence analysis. A PL peak at 3.29eV was found in the luminescence of the MME grown cap layer, …

Stream Microbial Communities As Potential Indicators Of River And Landscape Disturbance In North-Central Arkansas, Wilson Howard Johnson

Graduate Theses and Dissertations

In the past decade, 29 shale basins have been actively developed across 20 states for extraction of natural gas (NG) via horizontal drilling/hydraulic fracturing (=fracking). This includes ~5000 wells within the Fayetteville shale of north-central Arkansas. Development often impacts both river- and landscapes, and management requires catchment-level evaluations over time, with organismal presence/absence as indicators. For this study next-generation sequencing was used to identify/characterize microbial communities within biofilm of eight Arkansas River tributaries, so as to gauge potential catchment influences. Streams spanned a gradient of landscape features and hydrological flows, with four serving as ‘potentially impacted catchment zones’ (PICZ) and …

Lidar-Assisted Extraction Of Old Growth Baldcypress Stands Along The Black River Of North Carolina, Weston Pierce Murch

Graduate Theses and Dissertations

The remnants of ancient baldcypress forests continue to grow across the Southeastern United States. These long lived trees are invaluable for biodiversity along riverine ecosystems, provide habitat to a myriad of animal species, and augment the proxy climate record for North America. While extensive logging of the areas along the Black River in North Carolina has mostly decimated ancient forests of many species including the baldcypress, conservation efforts from The Nature Conservancy and other partners are under way. In order to more efficiently find and study these enduring stands of baldcypress, some of which are estimated to be more than …

Molecular Docking, Synthesis And Evaluation Of Pyrrolo[2,1-C][1,4]Benzodiazepines Derivatives As Non-Β-Lactam Β-Lactamases Inhibitors, Joseph Osamudiamen Osazee

Electronic Theses and Dissertations

Our research aim was to design, synthesize, and study the competitive enzyme inhibition kinetics of pyrrolo[2,1-c][1,4]benzodiazepine (PBD) derivatives as potential non-²-lactam ²-lactamase inhibitors. All compounds (1-13) passed the Lipinski’s rule of 5 test and were docked into the active site of TEM-1 ²-lactamase. PBD derivatives 1-7 were synthesized in high yields and tested for their potency against TEM-1 and P99 ²-lactamases. Kinetic data showed that compounds 1, 4, 5, and 7 possessed inhibitory activity against TEM-1 ranging from 4-34 %. Docking results revealed significant interactive spanning of the active site of TEM-1 by PBDs. …

Chlorine Demand Shows Thresholds And Hierarchy With Source Water Quality At Beaver Lake, Arkansas, Jaime M. Gile

Graduate Theses and Dissertations

This study investigated the effects of source water quality in Beaver Lake on the amount of chlorine (Cl) needed to develop decision support system to help guide chlorination practices in pre-treatment of source water. Chlorine demand assays were performed on water samples from Beaver Lake collected from the intake structure at Beaver Water District from March 2014 through August 2015, and using data from these assays, the two points of interest in this study were the Cl dose at which Cl residuals began to accumulate and the mean Cl demand occurring after that dose. Three methods of analysis were used …

Current Sheet Flapping Motions In The Tailwind Flow Of Magnetic Reconnection, Mingyu Wu, Quanming Lu, Martin Volwerk, Zoltán Vörös, Xuanye Ma, Shui Wang

Publications

The feature and origin of current sheet flapping motions are one of most interesting issues of magnetospheric dynamics. In this paper we report the flapping motion of the current sheet detected in the tailward flow of a magnetic reconnection event on 7 February 2009. This flapping motion with frequency about 12 mHz was accompanied by magnetic turbulence. The observations by the tail‐elongated fleet of five Time History of Events and Macroscale Interactions during Substorms probes indicate that these flapping oscillations were rather confined within the tailward flow than were due to a global process. This flapping motion could be due …

Singapore In Motion: Insights On Public Transport Service Level Through Farecard And Mobile Data Analytics, Hasan Poonawala, Vinay Kolar, Sebastien Blandin, Laura Wynter, Sambit Sahu

Research Collection School Of Computing and Information Systems

Given the changing dynamics of mobility patterns and rapid growth of cities, transport agencies seek to respond more rapidly to needs of the public with the goal of offering an effective and competitive public transport system. A more data-centric approach for transport planning is part of the evolution of this process. In particular, the vast penetration of mobile phones provides an opportunity to monitor and derive insights on transport usage. Real time and historical analyses of such data can give a detailed understanding of mobility patterns of people and also suggest improvements to current transit systems. On its own, however, …

Tafloc: Time-Adaptive And Fine-Grained Device-Free Localization With Little Cost, Liqiong Chang, Jie Xiong, Xiaojiang Chen, Ju Wang, Junhao Hu, Wei Wang

Research Collection School Of Computing and Information Systems

Many emerging applications drive the needs of device-free localization (DfL), in which the target can be localized without any device attached. Because of the ubiquitousness of WiFi infrastructures nowadays, the widely available Received Signal Strength (RSS) information at the WiFi Access points are commonly employed for localization purposes. However, current RSS based DfL systems have one main drawback hindering their real-life applications. That is, the RSS measurements (fingerprints) vary slowly in time even without any change in the environment and frequent updates of RSS at each location lead to a high human labor cost. In this paper, we propose an …

Enhancing Local Search With Adaptive Operator Ordering And Its Application To The Time Dependent Orienteering Problem, Aldy Gunawan, Hoong Chuin Lau, Kun Lu

Research Collection School Of Computing and Information Systems

No abstract provided.

Intermediaries Vs Peer-To-Peer: A Study Of Lenders’ Incentive On A Donation-Based Crowdfunding Platform, Ling Ge, Zhiling Guo, Xuechen Luo

Research Collection School Of Computing and Information Systems

Donation-based crowdfunding platform Kiva seems to hold the promise of peer-to-peer lending with zero interest rate to help the poor. However, it is actually intermediated by microfinance institutions, which raise funds from Kiva lenders, disburse the funds to borrowers and collect high interest. Later Kiva launched another platform Kiva Zip that implements interest-free loans directly from lenders to borrowers. This unique setup enables us to examine how lenders choose between Kiva and Kiva Zip, i.e. a platform with intermediaries and a real P2P platform. We develop a theoretical model and explicate that the lenders trade-off is between the sustainability of …

Social Sentiment And Stock Trading Via Mobile Phones, Kwansoo Kim, Sang Yong Lee, Robert John Kauffman

Research Collection School Of Computing and Information Systems

What happens when uninformed investors trade stocks via mobile phones? Do they react to social sentiment differently than more informed traders in traditional trading? Based on 16,817 data observations and econometric analysis for the trading of 251 equities in Korea over 39 days, we present evidence of herding behavior among uninformed traders in the mobile channel. The results indicate that mobile traders seem more easily swayed by changing social sentiment. In addition, stock trading in the traditional channel probably influences sentiment formation in the market overall. Mobile traders follow signals in social media suggesting that they engage in less beneficial …

Detecting Communities Using Coordination Games: A Short Paper, Radhika Arava, Pradeep Varakantham

Research Collection School Of Computing and Information Systems

Communities typically capture homophily as people of the same community share many common features. This paper is motivated by the problem of community detection in social networks, as it can help improve our understanding of the network topology. Given the selfish nature of humans to align with like-minded people, we employ game theoretic models and algorithms to detect communities in this paper. Specifically, we employ coordination games to represent interactions between individuals in a social network. We provide a novel and scalable two phased algorithm NashOverlap to compute an accurate overlapping community structure in the given network. We evaluate our …

Api Recommendation System For Software Development, Ferdian Thung

Research Collection School Of Computing and Information Systems

Nowadays, software developers often utilize existing third party libraries and make use of Application Programming Interface (API) to develop a software. However, it is not always obvious which library to use or whether the chosen library will play well with other libraries in the system. Furthermore, developers need to spend some time to understand the API to the point that they can freely use the API methods and putting the right parameters inside them. In this work, I plan to automatically recommend relevant APIs to developers. This API recommendation can be divided into multiple stages. First, we can recommend relevant …

Forward Light Scattering In An Extended Sample Of Cold Atoms, Stetson Roof

Physics Theses & Dissertations

We present results on the forward emitted light from a cold atomic sample of 87Rb. Specifically,we study single-photon superradiance which is characterized by a rapid decay faster than the single atom lifetime with the light preferentially emitted in the forward direction. Additionally, we report measurements on its counterpart, the cooperative Lamb shift. The results are interpreted using microscopic light scattering theory as well as techniques from classical optics. The comparison of the two analytical techniques provides a new perspectiveon what is meant by cooperative and collective scattering effects in cold atomic physics.

Galaxy And Mass Assembly (Gama) : Understanding The Wavelength Dependence Of Galaxy Structure With Bulge-Disc Decompositions., Rebecca Kennedy, Steven P. Bamford, Boris Haußler, Ivan K. Baldry, Malcolm Bremer, Sarah Brough, Michael J. I. Brown, Simon P. Driver, Kenneth Duncan, Alister W. Graham, Benne W. Holwerda, Andrew M. Hopkins, Lee S. Kelvin, Rebecca Lange, Steven Phillipps, Marina Vika, Benedetta Vulcani

Faculty and Staff Scholarship

With a large sample of bright, low-redshift galaxies with optical–near-IR imaging from the GAMA survey we use bulge-disc decompositions to understand the wavelength-dependent behaviour of single-Sérsic structural measurements. We denote the variation in single-Sérsic index with wavelength as N N , likewise for effective radius we use R R . We find that most galaxies with a substantial disc, even those with no discernable bulge, display a high value of N N . The increase in Sérsic index to longer wavelengths is therefore intrinsic to discs, apparently resulting from radial variations in stellar population and/or dust reddening. Similarly, low values …

Molecular Probes For Pancreatic Cancer Imaging, Lei Wang

Dissertations and Theses

Pancreatic ductal adenocarcinoma (PDAC) has the poorest five-year survival rate of any cancer. Currently, there are no effective diagnostics or chemotherapeutics. Surgical resection is the only curative therapy. However, most patients experience recurrence due largely to challenges in assessing tumor margin status in the operating room. Molecular probes that selectively highlight pancreatic cancer tissue, having the potential to improve PDAC margin assessment intraoperatively, are urgently needed. In this work, a series of red and near-infrared fluorescent probes is reported. Two were found to distribute to normal pancreas following systemic administration. One selectively accumulates in genetically modified mouse models of PDAC, …

Does A Taste Of Computing Increase Computer Science Enrollment?, Steven Mcgee, Randi Mcgee-Tekula, Jennifer Duck, Taylor White, Ronald I. Greenberg, Lucia Dettori, Dale F. Reed, Brenda Wilkerson, Don Yanek, Andrew Rasmussen, Gail Chapman

Computer Science: Faculty Publications and Other Works

This study investigated the impact of the Exploring Computer Science (ECS) program on the likelihood that students of all races and gender would pursue further computer science coursework in high school. ECS is designed to foster deep engagement through equitable inquiry around computer science concepts. If the course provides a meaningful and relevant experience, it will increase students' expectancies of success as well as increase their perceived value for the field of computer science. Using survey research, we sought to measure whether the relevance of students' course experiences influenced their expectancies and value and whether those attitudes predicted whether students …

Manganese-Reducing Bacterial Communities From A Hypersaline Estuary In South Texas Under Conditions Of Changing Salinity, Omar R. Elizondo, Rebecca Vasquez Villarreal, Sonia Y. Del Rio, Kristine L. Lowe

School of Integrative Biological & Chemical Sciences (Formerly Dept. of Biology)

Manganese reducing bacteria were quantified and enriched from sediments at two sites (ABC and LMT050) in the Laguna Madre of South Texas. Bacteria were tested for Mn(IV) reduction under different salinities. Denaturing gradient gel electrophoresis (DGGE) was used to profile bacterial communities from Mn(IV) saline enrichments. Results showed that the density of manganese reducing bacteria at ABC was 30X greater than LMT050. The ABC bacteria were able to reduce Mn(IV) at similar rates at different salinities; however, at LMT050, Mn(IV) reduction rates decreased at higher salinities. Three population genotypes were observed by DGGE. All were present and similarly abundant in …

Preterm Birth And Air Pollution: Critical Windows Of Exposure For Women With Asthma, Pauline Mendola, Maeve Wallace, Beom Seuk Hwang, Danping Liu, Candace Robledo, Tuija Männistö

School of Medicine Publications

Background: Ambient air pollutants may increase preterm birth (PTB) risk, but critical exposure windows are uncertain. The interaction of asthma and pollutant exposure is rarely studied.

Objective: We sought to assess the interaction of maternal asthma and air pollutant exposures in relation to PTB risk.

Methods: Electronic medical records for 223,502 US deliveries were linked with modified Community Multiscale Air Quality model outputs. Logistic regression with generalized estimating equations estimated the odds ratio and 95% CIs for PTB on the basis of the interaction of maternal asthma and particulate matter with aerodynamic diameter of less than 2.5 microns and particulate …

Determining The Viability Of Recent Storms As Modern Analogues For North-Central Gulf Of Mexico Paleotempestology Through Sedimentary Analysis And Storm Surge Reconstruction, Joshua Caleb Bregy

Master's Theses

The northern Gulf of Mexico has been devastated by recent intense storms. Camille (1969) and Katrina (2005) are two notable hurricanes that made landfall in virtually the same location in Mississippi. However, fully understanding the risks and processes associated with hurricane impacts is impeded by a short and fragmented instrumental record. Paleotempestology could potentially use modern analogues from intense storms in this region to extend the hurricane record back to pre-observational time. Existing empirically based models can back-calculate surge heights over coastal systems as a function of transport distance, particle settling velocity, and gravitational acceleration. We collected cores in a …

Krylov Subspace Spectral Method With Multigrid For A Time-Dependent, Variable-Coefficient Partial Differential Equation, Haley Renee Dozier

Master's Theses

Krylov Subspace Spectral (KSS) methods are traditionally used to solve time-dependent, variable-coefficient PDEs. They are high-order accurate, component-wise methods that are efficient with variable input sizes.

This thesis will demonstrate how one can make KSS methods even more efficient by using a Multigrid-like approach for low-frequency components. The essential ingredients of Multigrid, such as restriction, residual correction, and prolongation, are adapted to the timedependent case. Then a comparison of KSS, KSS with Multigrid, KSS-EPI and standard Krylov projection methods will be demonstrated.