Physical Sciences and Mathematics Commons^™

Synthesis And Study Of Stable Organic Radicals For Mri Contrast Agents And New Materials, Sabina Dhakal

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

The first part of this dissertation focuses on the design, synthesis, and characterization of a thermally robust S =1/2 phototetrazolinyl monoradical and the development of synthetic methodologies for a high-spin (S = 1) phototetrazolinyl diradical. Electrochemical studies of the phototetrazolium cation (precursor to the monoradical) revealed a remarkably narrow electrochemical band gap (Ecell ≈ 0.82 V), suggesting promising electrical conductivity. Thermal analysis of the monoradical demonstrated excellent stability, with the onset of decomposition at 232 °C. Building on the excellent thermal stability and promising properties for electrical conductivity of the monoradical, we developed two condensation-based synthetic routes that provide viable …

Rainfall-Runoff Modelling In An Indonesian Humid Tropical Area Using Satellite-Based Precipitation Products, Noordiah Helda

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

This dissertation explores three rainfall-runoff models in the humid tropical regions of Indonesia using satellite-based precipitation products (SBPPs) and develops integrated machine-learning modeling frameworks. Several ground-based observations from BMKG (Badan Meteorologi, Klimatologi, dan Geofisika (also known as the Indonesian Agency for Meteorology, Climatology, and Geophysics)) stations across Indonesia (133−165 stations) are compared and evaluated against satellite products, indicating that GPM performs well, with R-squared values ranging from 0.54 to 0.76 and correlation coefficients ranging from 0.45 to 0.69, respectively.

In the Martapura Watershed, South Kalimantan, due to a lack of observational discharge data, streamflow was generated using the FJ Mock …

Residential Hvac Installation Faults: Field Prevalence, Drivers, And Energy Impacts, Seyed Ali Rooholghodos

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Faults in residential comfort systems can have detrimental effects on the performance of the system, reducing the energy efficiency, affecting indoor comfort, and shortening equipment lifespan. Many of the faults occur at installation. However, there has not previously been a systematic and nationally representative study to indicate the prevalence of the faults, meaning the distribution of faults by fault type and fault intensity. Understanding true fault prevalence is essential to be able to identify derivers, and to assess the incremental electricity consumption of the new installation systems.

This study presents on-site data from 341 new central cooling systems—air conditioners and …

Assessing Crop Rotation Productivity, Soil Health, And Fertility, And Economic Performance, To Enhance Semi-Arid High Plains Cropping Systems Sustainability, Ezequiel Maria Villamil

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Sustainable crop production in the semi-arid High Plains of Nebraska faces challenges from limited precipitation, high interannual variability, and economic risk. This dissertation investigates the long-term productivity, water use, soil health, and economic sustainability of dryland crop rotations, with emphasis on the role of pulses as alternatives to fallow.

Chapter 1 analyzes nearly three decades (1995–2023) of on-farm data from the High Plains Agricultural Laboratory (Sidney, Nebraska) to compare seven crop rotations, including wheat, corn, millet, sunflower, and field peas. Results showed that wheat–corn–fallow (W–C–F) consistently outperformed traditional wheat–fallow (W–F) and more intensified four-year rotations, providing the highest grain yields, …

Detecting Prescribed Fire, Haying And Grazing Events Via Remote Sensing To Create Grassland Disturbance Landcovers For The Ring-Necked Pheasant (Phasianus Colchicus), Megan A. Baldissara

School of Natural Resources: Dissertations, Theses, and Student Research

This dissertation developed disturbance detection models to fulfill the need for remote sensing landcover products describing grassland structure. The use of landcover products derived from remote sensing is increasing over time in pheasant (Phasianus colchicus) research. Such landcover, however, does not provide relevant pheasant structural habitat information (Chapter 1). Pheasants require tall, high-density grassland for nesting, tall grassland with medium density for brood rearing, and tall grassland for wintering. Time since disturbance can serve as a proxy for structure, as it shapes vegetation by removing biomass and resetting succession. Disturbance is easier to detect than structure with current …

On Bayesian Empirical Likelihood-Based Method For Complex Survey Data With Application To Non-Probability Sampling, Md Hasibur Rahman

Department of Statistics: Dissertations, Theses, and Student Research

This thesis develops a Bayesian empirical likelihood (BEL) framework for inference under complex survey designs and extends it to non-probability sampling. Parametric likelihood based methods are difficult to apply to complex survey data because the likelihood is rarely available in closed form. EL provides a flexible alternative by replacing the parametric likelihood with an empirical likelihood constructed from moment conditions. The proposed method first integrates empirical likelihood constraints with survey design features then extends BEL to non-probability sampling through selection models and design consistent restrictions. Posterior inference is carried out using a Metropolis–Hastings MCMC algorithm. A real-data analysis further illustrates …

The Urban Heat Island And Its Role In Shaping Convective Environments: An Observational Study, Benjamin W. Moll

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The continued spread of urbanization and its well-documented effects on regional weather and climate necessitate further research. Urban environments are often warmer and drier than their rural surroundings. This trade-off between a warmer but drier environment could have a complex impact on deep convection and its initiation. Previous studies have noted significant changes in precipitation patterns around cities as well as changes to ongoing deep convection. Given the well-documented theory and past research, it is hypothesized here that urban areas have a significant impact on the PBL thermodynamics of convective environments. The urban heat island (UHI) component of the Micro …

Dancing With Logic: The Impact Of Integrating Dance In Teaching Introductory Computer Science Concepts On Student Understanding And Engagement, April Monk

Master's Theses

The purpose of this study was to investigate the effectiveness of dance-integrated pedagogical methods in enhancing the learning experiences of students in an introductory computer science course. In particular, the research aimed to measure the impact of creative movement on student comprehension, engagement, and perceptions of computer science. To guide this investigation, the study explored three research questions: Does integrating dance into lessons impact students’ comprehension of fundamental computer science concepts? How does dance integration affect student perceptions of both dance and computer science? And what elements of dance contribute to differences in comprehension between dance-integrated and traditional lessons? A …

N-Aryl Phenoxazines As Polymer Supported Photocatalysts, Mary Kathryn Hall

Master's Theses

In photosynthesis, the energy of sunlight is perfectly harnessed to facilitate the production of small molecules that are essential for plant life on earth. Inspired by this model of energy efficiency and simplicity, this work seeks to mimic that ability to use the energy in visible light to perform new and more efficient chemistries. Just like in photosynthesis, photocatalysts can act as chromophores absorbing light to excite electrons opening new pathways for previously untapped reactivity. Recent research has provided a wide range of small molecule reactions that are made possible or easier by the use of a photocatalyst. However, these …

Implications Of The Attenuated Allee Effect On Population Dynamics, Dana Strong

All Graduate Theses and Dissertations, Fall 2023 to Present

The Allee effect is an ecological phenomenon characterized by a per capita growth rate that increases as the population size increases in the context of low population density. The Allee effect can lead to rapid extinction events. Consequently, ecologists can attempt to control the strength of the Allee effect to help increase the population (in the case of endangered species) or decrease the population (in the case of parasites or pests).

This research aimed to study not the strength of the Allee effect, but the intensity of the Allee effect, or how rapidly cooperation between individuals causes the per capita …

Marsanywhere: Dataset And Cross-View Diffusion Model For Satellite-To-Ground View Synthesis With Mars Data, Benjamin T. Hinchliff

Master's Theses

Satellite-to-ground view synthesis aims to create a realistic ground view image from a corresponding satellite view image. This is a well-studied problem for street level imagery, with good results being achieved by using modern image synthesis techniques such as diffusion models. However, despite the public availability of satellite and ground level imagery on Mars, these techniques have yet to be applied to the domain due to difficulties in collating and processing the data into a usable form. We address this deficiency by creating a dataset consisting of ground view panorama imagery from the Perseverance rover, along with associated satellite view …

The Moderating Effect Of Income Inequality On The Income–Emissions Relationship In G20 Countries, Zahra Rizky Fadilah, Budiasih Budiasih

Economics and Finance in Indonesia

This study analyzes the moderating effect of income inequality on the income–emissions relationship in the environmental Kuznets curve (EKC) framework. Findings indicate that the relationship is inverted U-shaped in middle-income G20 countries, but monotonically increasing in high-income G20 countries. Interestingly, income inequality moderates this relationship only in the latter group. These findings suggest that middle-income G20 countries should focus on raising income per capita to mitigate environmental degradation, while their high-income counterparts need to prioritize reducing income inequality to effectively decouple income from emissions.

Numerical Calculations Of The Electromagnetic And Gravitational Wave Signatures Of Unequal Mass Black Hole Binary Inspirals, Madeline Clyburn

All Dissertations

In 2015, the Laser Interferometer Gravitational-Wave Observatory (LIGO) measured the first gravitational waves (GWs) from the coalescence of two stellar-mass black holes. This detection marked a historic milestone in astrophysics, confirming general relativity and establishing the existence of gravitationally bound black holes. Since then, researchers have extended the search to even more massive black hole mergers. Recently, the International Pulsar Timing Array (IPTA), including the North American Nanohertz Observatory for Gravitational Waves (NANOGrav), detected a nanohertz GW background from supermassive black hole binaries (SMBHBs), black holes with masses M ≃10^7−10^9 M⊙ orbiting throughout the universe. However, a single SMBHB has …

Dual-Model Approach For Accurate Chest Disease Detection Using Gvit And Swin Transformer V2, Kamal Ahmad, Hafeez Ur Rehman, Babar Shah, Farman Ali, Irfan Hussain

All Works

The precise detection and localization of abnormalities in radiological images are very crucial for clinical diagnosis and treatment planning. To build reliable models, large and annotated datasets are required that contain disease labels and abnormality locations. Most of the time, radiologists face challenges in identifying and segmenting thoracic diseases such as COVID-19, Pneumonia, Tuberculosis, and lung cancer due to overlapping visual patterns in X-ray images. This study proposes a dual-model approach: Gated Vision Transformers (GViT) for classification and Swin Transformer V2 for segmentation and localization. GViT successfully identifies thoracic diseases that exhibit similar radiographic features, while Swin Transformer V2 maps …

Curvilinear Image Segmentation Using Multiscale Variational U-Net, Rebekah Fortes

LSU New Orleans Theses and Dissertations

Segmentation of curvilinear structures such as water contours, cracks in cement, and vascular networks in biomedical imaging, poses unique challenges due to extreme class imbalance, irregular morphology, low contrast against complex backgrounds, and the need to preserve global connectivity while detecting fine-scale details. We propose a Multiscale Variational U-Net (MSVU-Net) architecture designed specifically to address these challenges. The model integrates multiscale convolutional filters to capture both global context and local detail, while embedding a variational model in the bottleneck layer to enhance structural representation. To mitigate class imbalance and improve fidelity, the network optimizes a hybrid loss function that combines …

Coupled Machine Learning Models: Combining Observations And Numerical Analysis In A Physics-Regularized Approach, Austin B. Schmidt

LSU New Orleans Theses and Dissertations

This dissertation investigates surrogate modeling for fixed-location environmental forecasting using novel data-combination techniques. The work surveys the landscape of observational measurements and numerically generated data, identifying similar research and gaps in current methodologies. The ratio-coupled training framework is introduced to combine two data sources per predicted feature through a tunable parameter that weights training signal strength. An optimization scheme is developed to simultaneously tune surrogate weights and the coupled signal ratio, allowing relative influence between signals to act as an explicit regularizer. Three case studies demonstrate the methodology and approach in a variety of contexts. The first study is based …

Peptoid-Based Molecular Analysis Utilizing High-Speed Molecular Dynamics Methods, In Chul Hwang

LSU New Orleans Theses and Dissertations

Polypeptoids are N-substituted glycine polymers, which differ from peptides in the placement of the side chain being present on the amide nitrogen rather than the backbone C_α. While both peptoids and peptides are composed of linked amino acids, the structural changes resulting from the differing origin of the side chain leads to distinct backbone structure, as well as remove the chirality found in the peptide structure. These differences lead peptoids to have different physiochemical and biological properties, such as being resistant to proteolysis and diverse three-dimensional structures that are not observed in peptides. With the shifting of the …

Relativistic Three Particle Scattering, Md Habib E Islam

Physics Theses & Dissertations

In this dissertation, we develop and apply a relativistic framework for studying three-body scattering amplitudes, their analytic structure, and the emergence of universal phenomena such as the Efimov effect. The work integrates three complementary components.

First, we introduce a systematically improvable numerical method for solving relativistic three-body integral equations in momentum space. By discretizing the continuum problem into finite matrix equations and extrapolating to the continuum limit, we obtain stable partial-wave amplitudes in the presence of a two-body bound state. Two complementary treatments of the pole contribution are implemented and shown to reproduce previous finite volume results, with controlled estimates …

(R2115) Analysis Of Single Server Queueing System With Differentiated Vacations And Differentiated Breakdowns, V. Karthick, V. Suvitha

Applications and Applied Mathematics: An International Journal (AAM)

This research work considers a single server queueing model with differentiated vacations. In addition there is a possibility of two types of failures when the server is in a busy period; namely hard failure and soft failure. In the time of soft failure server may work with a slow service rate. We analyzed as a Quasi-Birth-and-Death (QBD) process, using the matrix geometric method, the steady state probability vector of the number of customers in the queue and the stability conditions are produced. Busy period analysis of the proposed model in given. The effects of various parameters on the system performance …

(R2132) A Multi Server Markovian Working Vacation Queue With Randomly Varying Environment, A. Sundaramoorthy, R. Kalyanaraman

Applications and Applied Mathematics: An International Journal (AAM)

In this article, we consider a multi server Markovian queueing system with working vacation. During busy period, the arrival and service completion are generated by K distinct randomly varying environments. At a service completion epoch, if no customer in the system, the servers take vacation, the vacation policy is multiple vacation policy and the vacation period follows negative exponential distribution. In addition, during vacation period the servers serve customers if they arrive. Based on the vacation termination point we define two Models. For the two models, the steady state probability vector of number of customers in the queue, the stability …

(R2135) System Dynamical Analysis For Ann-Based Numerical Solutions Of A Compartmental Model: A Bio-Mathematical Model Of Drug Diffusion Through The Compartments Of Blood And Tissue, Rakesh Kumar, Sudarshan Dhua

Applications and Applied Mathematics: An International Journal (AAM)

This paper provides a considerably efficient numerical approach to acquire the solutions of a biomathematical model administrating oral and intravenous distribution of pharmaceuticals in the human body. The proposed numerical approach based on an artificial neural network is employed to extract numerical solutions for a detailed set of ordinary differential equations and analyze the change in concentration of drug diffusion via the compartments of blood and tissue medium. We primarily focus on analyzing three different models established on the diffusion process, exercising laws of mass action and Fick’s principle. In this work, the existing model is reformulated as an optimization …

(R2107) Analysis Of A Bivalent Vaccine Model With Peer Influence Effect On Testing, Manoj Kumar Singh, Anjali .

Applications and Applied Mathematics: An International Journal (AAM)

The coronavirus caused havoc around the world. There was a terrible situation in villages and cities, and no one knew how to deal with it. Although the governments of each country tried their best to save the common people, vaccination programs and testing centers were built everywhere. However, people were not utilizing it due to fear. Because of this, the infection spread rapidly. The qualitative study of the mathematical model here is in context with the situation when bivalent vaccination and testing are available for an epidemic. The mathematical model combines the exposed period and influenza model with vaccination included …

Topic Modeling And Culturomic Analysis Of 30,000 Books Over 100 Years Using Gensim, Michael A. Freeman

Electronic Theses and Dissertations

This thesis explores the cultural influence of historical events on English-language fiction published between 1820 and 1929. Using a corpus of 30,256 digitized books from Project Gutenberg, Latent Dirichlet Allocation (LDA) topic modeling was applied to identify recurring themes across eleven decades. The study sought to determine whether historically significant events could be detected within fictional narratives. One clear instance emerged: Napoleon Bonaparte and the Napoleonic Wars appeared explicitly in the 1820s corpus. Beyond this, several thematic patterns were observed—such as maritime language in the 1840s, national identity in the 1880s, and youth-oriented dialogue in the early 20th century—that plausibly …

Isolation Of The 2019 Bonnet Carré Spillway Effects On The Habitat Suitability Of Brown Shrimp (Farfantepenaeus Aztecus) And Blue Crab (Callinectes Sapidus) Using A Modeling Approach, Mallory Dyson

Master's Theses

In 2019, an unprecedented flood year, the Bonnet Carré Spillway (BCS) was opened on two separate occasions (February 27^th to April 11^th, and May 10^th through July 27^th) diverting a volume 6 times the volume of Lake Pontchartrain into the surrounding coastal waters of Louisiana, Mississippi, and Alabama. The goal of this research was to determine the spatio-temporal influence of these freshwater releases on two economically and ecologically important species (Farfantepenaeus aztecus and Callinectes sapidus) with variable responses to salinity and temperature depending on the age class. The Habitat Suitability Index (HSI) …

Early Career Setback And Future Achievement In Professional Sports, Suman Kalyan Maity, Yang Wang, Nima Dehmamy, Victoria Medvec, Brian Uzzi, Dashun Wang

Computer Science Faculty Research & Creative Works

A central tenet of human performance posits that past success is a key predictor of future outcomes. This principle underpins selection processes in various human endeavors, shaping opportunity, wage, and winner-take-all inequalities. Here we systematically examine the future performance of previous winners and non-winners across two sports contexts using two different empirical strategies. First, we track young athletes participating in world-class track and field competitions and compare the future performance of bronze medalists to those finishing just shy of the podium. Next, we study a novel natural experiment in tennis, where we compare future performances of 'lucky losers'—players who advanced …

Understanding Bias And Fairness In Large Language Models: An Empirical Study, Joshua Johnson

Electrical Engineering and Computer Science Undergraduate Honors Theses

This thesis investigates demographic bias in large language models (LLMs) through the use of evaluating outcome disparities when utilized in decision making tasks as well as underlying associations that could contribute to furthering these disparities. Using profiles from the Adult dataset, we analyze how Gemini 2.0 Flash performs in an income prediction task using zero-shot and few-shot prompting methods. Our findings show that models exhibit measurable differences in demographic parity and false positive rates, with the use of few-shot prompting reducing these disparities. Alongside this line of testing, we tested associational bias in Qwen 2.5 using probability based association tests …

Geochemical Analysis Of The Eagle Ford Shale In Webb And Dimmit Counties, Tx, Natalie G. Girlinghouse

Electronic Theses and Dissertations

The Late Cretaceous Eagle Ford Shale of South Texas is a mixed carbonate–siliciclastic succession that serves as both a prolific hydrocarbon source and reservoir. This study integrates chemostratigraphy, mineralogical analysis, and elemental ratio proxies to reconstruct depositional environments and assess controls on detrital influx, paleoproductivity, and redox conditions across multiple cores in Webb and Dimmit counties. Major, trace, and redox-sensitive elements were evaluated alongside Total Organic Content (TOC) and carbonate content to identify stratigraphic trends and environmental shifts.

Results reveal distinct geochemical signatures between the Upper and Lower Eagle Ford Shale, with the Lower Eagle Ford characterized by elevated Al-rich …

Structural Geology Of The Brady Mountain Area, Ouachita Mountains, Arkansas: Integrating Field Mapping, Geospatial Techniques, Photogrammetry And 3d Modeling For Structural Analysis, Emmanuel Darko, Zachariah Fleming

Electronic Theses and Dissertations

Much of the Ouachita orogenic belt, representing the deformed Paleozoic rocks flanking the southern margin of the North American craton, is buried beneath post-orogenic Mesozoic and Tertiary sediments composing the Gulf Coastal Plain. The Ouachita Mountains of Arkansas and Oklahoma are the largest areas of outcrop for the Pennsylvanian-age Ouachita orogenic belt, making it an ideal place to study the orogeny. This study focuses on the Brady Mountain area within the Benton Uplift, the orogenic core of the Ouachita Mountains in western Arkansas. The region is comprised of numerous ridges trending nearly east-west and are for the most part densely …

Navigating Seismic Anisotropy, With Applications To Alaska, Aakash Gupta

Geosciences

Seismic anisotropy characterizes how elastic waves travel through solid materials with different speeds, depending on the direction of the waves and the direction of particle motion of the waves. Evidence of seismic anisotropy in the Earth is widespread, from seismic waves sampling the crust, mantle and even the core, to active-source, industry-scale seismic experiments, to laboratory mea­ surements of rock samples from boreholes or at the surface. Global models of the Earth provide a highly averaged image of anisotropy. Studies based on shear wave splitting measurements from local and global earthquakes indicate that the anisotropy in the Earth is much …

Ice Surface Change And Flow Dynamics Analysis Of Sít’ Tlein (Malaspina Glacier) Through Remote Sensing, Victor Devaux-Chupin

Geosciences

Sít’ Tlein, located in southeast Alaska, is the largest piedmont glacier in the world. Periglacial lake expansion, low-lying bed, and proximity to the Pacific Ocean put its glacier lobe at risk of rapid retreat. Its disappearance would equate to removing an area of land about half the size of Rhode Island. Sít’ Tlein exhibits complex ice flow responsible for its iconic folded moraines, and for its heterogeneous ice resupply in its lobe, which occasionally surges. This lobe is gradually mantled by debris and vegetation as the ice flow fades towards its margins, protecting it from melting. This the­ sis is …