Physical Sciences and Mathematics Commons^™

Electrocatalytic Oxidation Of Carbohydrates Via Surface Immobilized Viologen, Dallin D.V. Scott

Theses and Dissertations

Earths most abundant biomolecules, carbohydrates, offer tremendous potential forelectricity production. Carbohydrate fuel cells are electrical fuel cells that can harvest the stored electrons in carbohydrates and offer a cheap and efficient method that could help solve growing energy demands, while providing a renewable green energy source. Viologen-mediated carbohydrate fuel cells have demonstrated the ability to accelerate carbohydrate oxidation while decreasing partial or incomplete oxidation products reducing the electricity production. Subsequent studies suggested polymeric viologen compounds could improve the efficiency by increasing the local concentration of viologen. This thesis presents the utility of surface-immobilized viologen mediators for the oxidation of simple …

Galectin-1: Development Of A Novel Protein Therapy For Lgmd2b, Mary Lorena Vallecillo Munguia

Theses and Dissertations

Muscular dystrophies are a heterogeneous group of genetic diseases that involve mutations in genes leading to progressive muscular weakness. Limb-Girdle Muscular Dystrophy 2B (LGMD2B) is a subset of muscular dystrophy caused by mutations in the DYSF gene, which encodes for dysferlin protein and has an incidence of 1/100,000-1/200,000 people, or 1/300 people of Libyan Jewish descent. Since there is no effective treatment that can cure or reverse effects of LGMD2B once diagnosed, our goal is to investigate and develop a protein therapy that mitigates effects of this disease in patients. Galectin-1 (Gal-1) is a small, soluble 14.5 kDa protein with …

Comparative Toxicity, Phytochemistry, And Use Of 53 Philippine Medicinal Plants, Lydia M. Clemen-Pascual, Rene Angelo S. Macahig, Nina Rosario L. Rojas

Chemistry Faculty Publications

The study compares the toxicity of 53 selected medicinal plants commonly used in the Philippines to treat various diseases. It uses as a benchmark Vitex negundo L., which was approved by the Philippine Food and Drug Administration as an herbal drug for cough and asthma after passing clinical trials for safety and efficacy. The methods were chosen for their simplicity and accessibility even for resource-limited laboratories. Extracts (95 % ethanol) of the medicinal parts of the plants were (1) chemically profiled using qualitative phytochemical tests that detect the presence of key classes of bioactive compounds; and (2) evaluated for toxicity …

Stratigraphic Analysis Of The Capps Limestone In The North Norton Oil Field In Runnels County, Texas, William Thompson

Electronic Theses and Dissertations

The Desmoinesian (Middle Pennsylvanian) Capps Limestone Member of the Mineral Wells Formation is a carbonate reservoir located in North Central Texas. It consists of interbedded limestone, sandstone, and shale units. Much of the Capps Limestone exists in the subsurface of Brown, Coleman, Runnels, Coke, Nolan, and Taylor counties, however, the Capps Limestone outcrops on the surface in Brown, Eastland, and Palo Pinto counties.

The cored interval from Runnels County was deposited in a marginal marine environment during the Middle Pennsylvanian Period. Although the Capps Limestone was first described in the 1890s, there is still much to be discovered about its …

Microwave-Promoted Iminyl Radical Fragmentations And The Total Synthesis Of Yaku'amide A And Its Simplified Analogues, Concordia Lo

Theses and Dissertations

The first project in this dissertation describes the use of microwave-promoted iminyl radical fragmentations to form functionalized nitriles. Nitrogen-centered radical chemistry is a useful tool to construct valuable C-N bonds commonly found in pharmaceuticals and biologically active molecules. Classically, these reactions require the use of toxic initiators and propagators. Iminyl radical chemistry has been gaining momentum as a means of avoiding these harsh conditions. This project utilizes the fragmentation of cyclic iminyl radicals via irradiation of O-phenyl oxime ethers to produce a synthetically useful nitrile tethered to an alkyl radical in the absence of metal catalysts and redox chemistry. The …

Corn Oil-Based Highly Flame Retardant Rigid Polyurethane Foams For Industrial Application, Muhammad Rizwan Sulaiman

Electronic Theses & Dissertations

The synthesis of flame retardant polyurethane (PU) foam was carried out using two different flame retardants, such as triethyl phosphate (TEP) and triphenyl phosphate (TPP). The thermal and mechanical characteristics of the foam were analyzed. The obtained TGA results confirmed that the flame retardant acts in the gaseous form to stop the fire. All the prepared samples displayed excellent closed cell content, which was above 90 %. The burning time were reduced from 80 s to 7.5 s with the weight loss 3.2% of for sample E-12 (19.29 % TEP) and from 80 s to 11 s with the weight …

Quantitative Stem: A Method For Measuring Temperature And Thickness Effects On Thermal Diffuse Scattering Using Stem/Eels, And For Testing Electron Scattering Models, Paul S. Minson

Theses and Dissertations

In the last two decades, advances in the dark field detectors and microscopes of scanning transmission electron microscopy (STEM) have inspired a resurgence of interest in quantitative STEM analysis. One promising avenue is the use of STEM as a nanothermometric probe. In this application, thermal diffuse scattering, captured by a CCD camera or an annular dark field detector, acts as an indirect measurement of the specimen temperature. One challenge with taking such a measurement is achieving adequate sensitivity to quantify a change in scattered electron signal on the order of 1% or less of the full electron beam. Another difficulty …

Field Investigations And Numerical Modeling Of Earthquake And Tsunami Risk At Four Vulnerable Sites In Indonesia, Claire E. Ashcraft

Theses and Dissertations

Maps and models of seismic and tsunami risk are constructed from a variety of measurements taken in Indonesia, which have the potential to reduce loss of life and infrastructure. The first study uses the multichannel analysis of surface waves (MASW) method to calculate the time-averaged shear wave velocity to 30 m depth (Vs30). These measurements were taken at 58 sites in the city of Pacitan, Java and on the islands of Lombok, Ambon, and the Banda Islands. Vs30 calculations are compared with local geologic maps to extrapolate site class for locations not measured directly. Site class maps are then compared …

Silver Bow Creek/Butte Area Npl Site Butte Priority Soils Operable Unit, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

1,2-Diazetidine As A New Amidomethylative Reagent To Control The Selectivity For The Synthesis Of N-Heterocycles And Ru(Ii)-Catalyzed Enantioselective Hydroarylation To Form Chromane Derivatives, Chaminda Lakmal Hetti Handi

Theses and Dissertations

1,2-Diazetidine is a four-membered ring heterocyclic compound which has two adjacent nitrogen atoms. However, the syntheses of C-unsubstituted 1,2-diazetidines are rarely reported in the literature. C-unsubstituted 1,2-diazetidines were synthesized through an operationally simple intermolecular vicinal disubstitution reaction between 1,2-dibromoethane and hydrazine with N-arylsulfonyl as the protecting group. Several different types of C-unsubstituted 1,2-diazetidines derivatives were synthesized with either two of the same or two different N-arylsulfonyl groups. The electronic and steric properties were analyzed using Raman spectroscopy and computational calculations. Then, several synthetic applications were demonstrated with 1,2-ditosyl-1,2-diazetidine (DTD). As a synthetic application, a nucleophilic ring-opening reaction of the diazetidine …

Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky

Theses and Dissertations

Mississippi Valley Type (MVT) lead and zinc deposits provide a significant source of sedimentary galena and sphalerite. However, geochemical characteristics and genesis including the source and production of hydrogen sulfide required for galena and sphalerite ore formation and the reasoning for quick, episodic mineralization is not fully understood. By simulating regional MVT brines, the input and effect of biological by-products during the development of these ores as well as the cause of cyclicity within MVT deposits have been observed. Experiments using compositions from MVT fluid inclusions were conducted over two-week periods. Variables during the experiments included temperature, CO2, hydrogen sulfide …

Uncertainty-Aware Deep Learning For Prediction Of Remaining Useful Life Of Mechanical Systems, Samuel J. Cornelius

Theses and Dissertations

Remaining useful life (RUL) prediction is a problem that researchers in the prognostics and health management (PHM) community have been studying for decades. Both physics-based and data-driven methods have been investigated, and in recent years, deep learning has gained significant attention. When sufficiently large and diverse datasets are available, deep neural networks can achieve state-of-the-art performance in RUL prediction for a variety of systems. However, for end users to trust the results of these models, especially as they are integrated into safety-critical systems, RUL prediction uncertainty must be captured. This work explores an approach for estimating both epistemic and heteroscedastic …

Synthesis And Characterization Of A Ccc-Nhc Manganese Complex And Its Catalytic Activity In Alpha-Alkylation Reactions Of Ketones Using Alcohols – Acceptorless Dehydrogenative Coupling Reaction, Thi Bao Tran Nguyen

Theses and Dissertations

N-heterocyclic carbenes are essential for the synthesis and stabilization of various metal complexes due to the tendency to act as sigma-donor of sp2 hybridized lone pair in carbene into sigma-accepting orbital of metals. Meanwhile, the electronic and steric properties of pincer complexes can be fine-tuned by modifying three sites bonded to the metals. Utilizing advantages of both NHCs and the pincer structures, NHCs-based pincer complexes have become increasingly developed in recent years. After the discovery of zirconium and rhodium complexes with CCC-NHC backbones reported in 2005, Hollis’s group has been interested in applying the CCC-NHC pincer precursor for other transition …

Characterization Of Small Molecules And Ions By Atmospheric Pressure Ionization-Mass Spectrometry, Maleesha De Silva

Theses and Dissertations

Mass spectrometry (MS) has become a widely used technique for the characterization of a wide range of substances in diverse fields. The selection of appropriate ionization techniques, source parameters, charge carriers based on the analyte’s polarity is essential in MS as only the ions are detected. When using a soft ionization technique, single stage-MS at best provides only chemical composition; thus, tandem MS is needed to determine structural information and dissociation pathways. This dissertation focuses on the characterization of various small molecules and ions using different ionization techniques, charge carriers, and collision-induced dissociation (CID).

In Chapter II, commercially available ionic …

Signatures Of A Quantum Griffiths Phase Close To An Electronic Nematic Quantum Phase Transition, Pascal Reiss, David Graf, Amir A. Haghighirad, Thomas Vojta, Amalia I. Coldea

Physics Faculty Research & Creative Works

In the vicinity of a quantum critical point, quenched disorder can lead to a quantum Griffiths phase, accompanied by an exotic power-law scaling with a continuously varying dynamical exponent that diverges in the zero-temperature limit. Here, we investigate a nematic quantum critical point in the iron-based superconductor FeSe0.89S0.11 using applied hydrostatic pressure. We report an unusual crossing of the magneto resistivity isotherms in the Non superconducting normal state that features a continuously varying dynamical exponent over a large temperature range. We interpret our results in terms of a quantum Griffiths phase caused by nematic islands that result from the local …

The Effects Of Cover Crops In An Integrated Livestock/Continuous Corn Cropping System In East-Central Mississippi, Ken Randolph Waddell

Theses and Dissertations

There is growing interest within the agricultural industry on how cover crop systems affect soil health and economic productivity in integrated crop-livestock systems. This study investigated the combined effects of cover crop species; no-till and conventional till; and grazed (G) and un-grazed (UG) in a continuous corn (Zea mays) production system in east-central Mississippi. Cover crops were established in the fall of 2019 and 2020 in two separate field studies. Corn yield was not affected by grazing or tillage but was affected by cover crop species. We then compared the difference in cover crop species treatments with their respective corn …

The Development Of Authentic Virtual Reality Scenarios To Measure Individuals’ Level Of Systems Thinking Skills And Learning Abilities, Vidanelage L. Dayarathna

Theses and Dissertations

This dissertation develops virtual reality modules to capture individuals’ learning abilities and systems thinking skills in dynamic environments. In the first chapter, an immersive queuing theory teaching module is developed using virtual reality technology. The objective of the study is to present systems engineering concepts in a more sophisticated environment and measure students learning abilities. Furthermore, the study explores the performance gaps between male and female students in manufacturing systems concepts. To investigate the gender biases toward the performance of developed VR module, three efficacy measures (simulation sickness questionnaire, systems usability scale, and presence questionnaire) and two effectiveness measures (NASA …

Basis For Changes In The Disease Burden Estimates Related To Vitamin A And Zinc Deficiencies In The 2017 And 2019 Global Burden Of Disease Studies, Sonja Y. Hess, Alexander C. Mclain, Haley Lescinsky, Kenneth H. Brown, Ashkan Afshin, Reed Atkin, Saskia Jm Osendarp

Faculty Publications

Background:

The Global Burden of Disease (GBD) Study provides estimates of death and disability from eighty-seven risk factors, including some micronutrient deficiencies. Objectives:

To review methodological changes that led to large differences in the disease burden estimates for vitamin A and Zn deficiencies between the GBD 2017 and 2019 Studies. Methods:

GBD publications were reviewed; additional information was provided by GBD researchers. Results:

Vitamin A deficiency prevalence is based on plasma retinol concentration, whereas the estimate for Zn deficiency prevalence uses dietary adequacy as a proxy. The estimated global prevalence of vitamin A deficiency for children aged 1–4 years in …

Butte Priority Soils Operable Unit (Bpsou) Draft Final Quarterly Operations And Maintenance Report Butte Treatment Lagoon System – Third Quarter 2021, Dave Griffis

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

A Longitudinal Analysis Of Pathways To Computing Careers: Defining Broadening Participation In Computing (Bpc) Success With A Rearview Lens, Mercy Jaiyeola

Theses and Dissertations

Efforts to increase the participation of groups historically underrepresented in computing studies, and in the computing workforce, are well documented. It is a national effort with funding from a variety of sources being allocated to research in broadening participation in computing (BPC). Many of the BPC efforts are funded by the National Science Foundation (NSF) but as existing literature shows, the growth in representation of traditionally underrepresented minorities and women is not commensurate to the efforts and resources that have been directed toward this aim.

Instead of attempting to tackle the barriers to increasing representation, this dissertation research tackles the …

Nuclear Transparency From Quasi-Elastic $^{12}C(E,E'P)$ Scattering Reaction Up To $Q^2=14.2 ~(Gev/C)^{2}$ In Hall C At Jefferson Lab, Deepak Kumar Bhetuwal

Theses and Dissertations

Color Transparency $(CT)$ is a unique prediction of Quantum Chromodynamics $(QCD)$ where the final (and/or initial) state interactions of hadrons with the nuclear medium are suppressed for exclusive processes at high momentum transfers. While this phenomenon has been observed for mesons, there has never been a conclusive observation for baryons. A clear signal of $CT$ for baryons would be the first evidence of baryons fluctuating to a small size in the nucleus, and the onset would show the transition from nucleon-meson picture to quark-gluon degrees of freedom. The experiment $E1206107$, searching for the onset of $CT$ in protons was completed …

Disease Biomarker Discovery And Fungal Metabolites Extraction Protocol Optimization Using Gcms Based Metabolomics, Chathuri Udeshika Gamlath Mohottige

Theses and Dissertations

Metabolomics is a powerful science that can be applied for the discovery of disease biomarkers, and investigation of altered metabolomes due to abiotic and biotic perturbations. This dissertation is focused on untargeted metabolomic applications to investigate fungal metabolite alterations associated with pathogenicity, fungal disease propagations, and symbiosis. This dissertation employs qualitative analysis of metabolite mixtures using HS-SPME coupled GC-MS and TMS derivatization followed by GC-MS analytical platforms. In the first study, we discovered a biomarker combination to diagnose fungal soft tissue disease in sweet potato at an early stage of disease propagation. We used an HS-SPME GC-MS untargeted metabolomics workflow …

Assessing The Potential For Lightning-Induced Damage In Commercial Broiler Houses In Mississippi And Alabama, Matthew R. Rowland

Theses and Dissertations

Modern broiler houses are expensive to build, maintain, and insure. Protecting them from extreme weather events is a major concern to producers, integrators, and insurance companies. Lightning strikes can cause catastrophic fires and electrical damage and can lead to costly bird losses. A greater understanding of the impact of lightning on the commercial broiler industries of MS and AL is needed. The objectives of this research were collection of baseline resistance data for broiler houses and equipment in both states, and mapping lightning strike densities across MS and AL, evaluating annual, monthly, seasonal, and diurnal patterns. 63.5% of surveyed broiler …

A Framework For Phrase Based Smt In The Technical Translation Domain, Hisham Farouk Khodeir

Archived Theses and Dissertations

No abstract provided.

Using Parallel Primary Caches To Improve Capacity And Bandwidth, John Rubena Wani

Archived Theses and Dissertations

No abstract provided.

Error Correction In Quantum Cryptography, Mohamed Salah El Ashmawy

Archived Theses and Dissertations

No abstract provided.

Burning And Management Alternatives On Forage Accumulation And Floristic Composition Of A Native Pasture, I. Heringer, A. V. A. Jacques

IGC Proceedings (1977-2023)

The forage accumulation and floristic composition of native pasture, submitted to burning and alternative management practices, was evaluated during one year. The experimental design was a completely randomized, with five treatments and three replications. The forage accumulation was evaluated in a grazing exclusion cage, and the floristic composition was estimated with Botanal method. The systems without burning were more productive and, among these, the forage accumulation was similar between the one without burning and without mowing and the improve treatments, and the annual accumulation was greater than 9,000 Kg/ha of green forage dry matter. The species Paspalum notatum, P. …

Nitrogen Flow To Duodenum Of Steers Grazing On Orchardgrass And Meadowfescue Pastures, Masaaki Hanada, Y. Aibibula, Meiji Okamoto

IGC Proceedings (1977-2023)

This experiment was conducted to evaluate nitrogen flow to the duodenum of steers grazing on orchardgrass (Dactylis glomerata L., OG) or meadowfescue (Festuca elatior L., MF) pasture. Holstein steers fitted with cannulas in the rumen and duodenum were used. Nitrogen content and in vitro dry matter digestibility of herbage did not differ between OG and MF pastures. Herbage nitrogen intake of steers grazing on OG and MF pastures averaged 229 and 271 g/day, respectively. Nitrogen flows to the duodenum of steers grazing on orchardgrass and meadowfescue pastures averaged 187 and 195g/d, respectively. Microbial nitrogen flow to the duodenum …

The Effects Of Post-Grazing Sward Conditions On Herbage Accumulation In Winter And Spring, F. P. Hughes, P. N. P. Matthews, C. Matthew

IGC Proceedings (1977-2023)

Two on-farm experiments were conducted in the winter and spring of 1998 on a New Zealand seasonal production dairy farm to determine the effect of herbage mass present after grazing on subsequent pasture growth rates. Experiments involved a range of post-grazing levels of herbage mass (870, 1140, 1390, 1640, 1920 kg DM/ha in winter, and 1100, 1420, 1700 and 1910 kg DM/ha in spring) representing a range in cow intakes of 6.1-20.0 and 7.6-18.5 kg DM/cow/day in winter and spring, respectively. In both experiments there was a range of postgrazing herbage mass (1200-1600 kg DM/ha in winter and 1400-1800 kg …

Some Optical And Electrical Properties Of Cadmium Sulfide And Lead Sulfide Thin Films Prepared By Electron Beam Deposition, Achiri Celestine Tange

Archived Theses and Dissertations

No abstract provided.