Physical Sciences and Mathematics Commons^™

Various Operators In Relation To Fractional Order Calculus And Some Of Their Applications To Normalized Analytic Functions In The Open Unit Disk, Hüseyi̇n Irmak

Turkish Journal of Mathematics

The main object of this scientific work is firstly to introduce various operators of fractional calculus (that is that fractional integral and fractional derivative(s)) in certain domains of the complex plane, then to determine certain results correlating with normalized analytic functions, which are analytic in certain domains in the complex plane, as a few applications of those operators, and also to present a number of extensive implications of them as special results.

Fluorescent Labelling Of Ribosomal Rna In Live Mammalian Cells, Amir Agharezaee

Legacy Theses & Dissertations (2009 - 2024)

This thesis describes a bio-orthogonal chemistry-based approach for new methods of fluorescence labelling of RNA in live HeLa cells via an IEDDA reaction of TCO with tetrazine. The key step of the approach is synthesis of two nucleobase analogues which were modified with TCO and a masked 5′-phosphate group using aryl phosphonamidite chemistry. Synthesis of tubercidin and uridine analogues were considered in this investigation for incorporation into RNA in live HeLa cells. Synthetic approach was successful at installing the handle containing TCO to tubercidin and uridine to make compounds 12 and 21 respectively (the synthesis of both of which are …

Dynamic Impacts Of Hadley Circulation On Saharan Desert Warming Amplification, Alejandro Manuel Ayala

Legacy Theses & Dissertations (2009 - 2024)

Changes in temperature due to climate change are not spatially uniform, and deserts and other drylands, which are greatly underrepresented in climate studies, are warming at a much faster rate than much of the globe with increasing concentrations of greenhouse gases. This strong warming amplification over deserts, termed Desert Amplification (DA), is most pronounced over the world’s largest and driest Sahara Desert and the Arabian Peninsula. The Sahara and Arabian deserts are formed in the subtropical subsiding branch of the Hadley Circulation (HC) and so the changes in large-scale subsidence associated with adiabatic heating could impact the DA dynamically. While …

Spatiotemporal Variability Of Snow Depth On Arctic Sea Ice In Cmip6 Models And Satellite Data, Shengzhe Chen

Legacy Theses & Dissertations (2009 - 2024)

The Arctic has experienced rapid environmental changes in recent decades. Motivated by the important role of snow over sea ice in influencing Arctic climate variability and change, this dissertation aims to improve our knowledge of spatiotemporal variability of snow depth and processes over Arctic sea ice in the observations and model simulations.First, we evaluate snow depth over Arctic sea ice during 1993–2014 simulated by the models from the Coupled Model Intercomparison Project phase 6 (CMIP6) against recent satellite retrievals. The CMIP6 models capture some aspects of the observed snow depth climatology and variability. The observed variability lies in the middle …

X Ray Phase And Coherent Scatter Imaging Measurements, Pikting Cheung

Legacy Theses & Dissertations (2009 - 2024)

Traditional x-ray images are good for distinguishing between materials with very different absorption coefficients. However, detecting breast cancer using conventional x-ray imaging is hard because cancer tissue has similar absorption coefficients as normal tissue. Annually 43,600 women will die from breast cancer. The odds of survival are better if the cancer is diagnosed at an early stage, but mammography tends to have high rates of missed cancers. Mammography also tends to have a high false-positive rate, which leads to unnecessary biopsies. Two techniques with potential to add additional information to breast imaging have been investigated. X-ray phase imaging has been …

X Ray Phase And Coherent Scatter Imaging Measurements, Mahboob Ur Rehman

Legacy Theses & Dissertations (2009 - 2024)

In conventional radiography, anatomical information of the patients can be obtained, distinguishing different tissue types, e.g. bone and soft tissue. However, it is difficult to obtain appreciable contrast between two different types of soft tissues. Instead, coherent x-ray scattering can be utilized to obtain images which can differentiate between normal and cancerous cells of breast. An x-ray system using a conventional source and simple slot apertures was tested. Materials with scatter signatures that mimic breast cancer were buried in layers of fat of increasing thickness and imaged. The result showed that the contrast and signal to noise ratio (SNR) remained …

Photopolymers : Environmentally Benign Technology For A Variety Of Industries, Tatyana Tarasevich

Legacy Theses & Dissertations (2009 - 2024)

Photopolymerization is a well-known process with applications in a variety of industries. Photopolymers are formed by a reaction of monomers or oligomers, photoinitiators and in some cases crosslinkers. Upon irradiation with UV or visible light, monomers undergo conformational change to form polymers via a photochemical process. Several photopolymerization types will be discussed in this thesis. End products of photopolymerizations included epoxies, inks, coatings, photoresists, etc.

Synthesis Of Oligonucleotides Containing Unnatural Backbone And Regulation Of Crispr Activity Using Inverse Electron Demand Diels-Alder Chemistry, Alyssa Hoy

Legacy Theses & Dissertations (2009 - 2024)

This thesis describes the synthesis of an oligonucleotide containing an unnatural neutralbackbone. The backbone was constructed using bio-orthogonal inverse electron demand Diels- Alder chemistry between trans-cyclooctene (TCO) and tetrazine (Tz). A TCO phosphoramidite was synthesized and attached to solid support for strand propagation. Uridine monomers containing either bis-TCO or bis-Tz were also synthesized. The oligonucleotide strand was formed by sequential ligation of the bis-Tz and bis-TCO monomers. The oligonucleotide was analyzed using mass spectrometry. This thesis also describes the synthesis of sgRNAs containing non-canonical nucleobases, m1A, m6A, s2U and s4U using the ‘split-and-click’ methodology. The synthetic sgRNAs were assembled using …

Trace Elements In Nails And Anemia In Children Living Along The Interoceanic Highway, Madre De Dios, Peru / Narrative Competence And Cognitive Mapping As A Culturally Sustaining Pedagogy In The Education Of Emergent Bilinguals, Tia Marks

Legacy Theses & Dissertations (2009 - 2024)

Anthropogenic changes in the Peruvian Amazon, including deforestation, highway development, agriculture, and artisanal and small-scale gold mining (ASGM), have increased community concern about potential exposures toxic trace elements (TTE) including arsenic (As), cadmium (Cd), mercury (Hg), and lead (Pb). Such exposures can lead to detrimental health effects in children, such as developmental delays and anemia. The overarching goal of my dissertation was to understand exposure to both toxic and essential (manganese (Mn), selenium (Se), and zinc (Zn)) trace elements, anemia prevalence, and the associations between hemoglobin (Hb) levels and trace elements. To do this, I leveraged existing data from a …

First Homoleptic Rare Rarth Metal Complexes With Doubly-Reduced Dibenzocyclooctatetraene, James C. Mahoney

Legacy Theses & Dissertations (2009 - 2024)

A set of novel complexes of rare earth elements, M(III) = Y, La, Gd, Tb, and Dy, with the doubly-reduced dibenzo[a,e]cyclooctatetraene (DBCOT) anion has been synthesized and crystallographically characterized for the first time. Preparation of new complexes has been accomplished through the ligand-metathesis reaction of M(III) triiodides with K2(DBCOT) in THF at ambient conditions. Subsequent crystallization via slow solvent evaporation afforded single crystals of good quality. X-ray diffraction technique confirmed that all complexes are isomorphous and conform to the [M(DBCOT)(THF)4][M(DBCOT)2] composition. In their crystal structures, the monoanionic double-decker sandwiches, [M(DBCOT)2], weakly interact with the cationic counterparts, [M(DBCOT)(THF)4]+. In both parts, …

Understanding Changes In Precipitation, Wildfires, And Possible Governing Factors Over Central Equatorial Africa, Yan Jiang

Legacy Theses & Dissertations (2009 - 2024)

Tropical rainforests are global epicenters of biodiversity and modulators of climate. A long-term drying trend has occurred in the Congo Basin since the 1980s and this raises great concerns for sustaining the Congolese rainforest and local rain-fed agriculture. Motivated by documented rainfall changes and the need to improve understanding of main factors influencing precipitation variability and changes in Central Equatorial Africa (CEA), this dissertation conducts synthesized studies on 1) quantifying variations in precipitation seasonality by focusing on dry season duration, 2) estimating cascading wildfire risks associated with changes in precipitation patterns, and estimating impacts of 3) the tropical Indian Ocean …

The Mountain Gap Wind Of The Isthmus Of Tehuantepec And Its Impact On Tropical Cyclogenesis In The Eastern Pacific, Adolfo Lugo Rios

Legacy Theses & Dissertations (2009 - 2024)

In this dissertation we research two aspects of the mountain gap wind northerlies of the Isthmus of Tehuantepec in Southern Mexico. The causes of extreme gap wind northerlies, emphasizing the causes by tropical weather systems, like easterly waves troughs or hurricanes, and the impacts of an extreme gap wind events on tropical cyclogenesis.Through the use of an index to diagnose the mountain gap wind strength, its evolution through the year and the mechanisms leading to extreme mountain gap winds was highlighted. The index revealed that the gap wind is strongly related to high surface pressure anomalies over the GoM throughout …

A Synoptic-Dynamic Analysis Of The Structure And Evolution Of Persistent North Pacific Wintertime Ridge Regimes, Tyler Christopher Leicht

Legacy Theses & Dissertations (2009 - 2024)

Along the west coast of North America (NA), a majority of the precipitation for the entire year falls during winter as a result of approximately a dozen cyclones or atmospheric rivers. However, persistent upper-level ridges can prevent the occurrence of wintertime precipitation events and lead to extended drought, significant water shortages, and adverse economy-wide impacts for major population centers in California. An increased understanding of the dynamical and thermodynamical processes that govern upper-level ridge formation, persistence, and dissipation during the rainy season along western NA would allow decision makers to better manage water resources and motivates this thesis. Persistent upper-level …

The Surface Heating Efficiency Of Atmospheric Energy Flux Events During Arctic Winter, Christopher Joseph Cardinale

Legacy Theses & Dissertations (2009 - 2024)

The flux of moist static energy (MSE) into the polar regions plays a key role in the energy budget and climate of the polar regions. While usually studied from a vertically integrated perspective (Fwall), this dissertation examines its vertical structure, using the NASA-MERRA-2 reanalysis to compute climatological and anomalous fluxes of sensible, latent, and potential energy across 70◦N and 65◦S. This dissertation applies an energy budget analysis to winter-season synoptic periods of increased tropospheric (Ftrop) and stratospheric (Fstrat) energy flux convergence events and examines the processes that drive Arctic anoma lous surface warming and sea ice loss during Ftrop events. …

Sampling Distribution Of Non-Overlap Indices Using Bootstrapping Procedure : A Monte Carlo Simulation Study And Empirical Demonstration, Xinyun Xu

Legacy Theses & Dissertations (2009 - 2024)

Statistics can be either parametric or non-parametric, depending on whether distributional assumptions about the data and sampling distributions are required. Parametric and non-parametric approaches each include a variety of inferential methods. These methods can be seen in the field of single-case experimental design (SCED). By reviewing one of the most used groups of statistics for SCED research (Jamshidi et al., 2022; Maggin et al., 2011), the non-overlap indices, one major issue arose. It is challenging to make inferences and interpretations about non-overlap indices. The main reason for this issue is that non-overlap indices have inconsistent and unknown sampling distributions (under …

Municipal Solutions To Climate Change ; A Case Study Of Stream Daylighting In Suffolk County, New York, Madison Hrysko

Legacy Theses & Dissertations (2009 - 2024)

During the 1950’s and 1960’s Suffolk County, New York experienced rapid urbanization and development. To pave way for infrastructure, hydrological modifications were made to the land including the burial of naturally flowing streams. Daylighting streams is the nature-based process of bringing buried streams back to the surface. In turn, restoring ecosystem services, increasing local resilience to climate change impacts, and expanding biodiversity. Minimal research has been done using GIS technology alongside a set of criteria to select best fit streams for daylighting. This thesis aims to fill that gap by identifying best and second-best fit streams for daylighting in Suffolk …

Uio-Type Metal-Organic Framework Derivatives As Sorbents For The Detection Of Gas-Phase Explosives, Matthew Ryan Sherrill

Legacy Theses & Dissertations (2009 - 2024)

The detection of energetic compounds – better known to the public as explosives – has is an important cornerstone of counterterrorism and homeland security . While significant advances have been achieved for the detection of trace explosives in various matrices such as soil, wastewater, and clothing, the detection of explosives in the gas phase remains challenging due to their infamously low vapor pressures. In this thesis, we leverage the high sensitivity of direct analysis in real-time mass spectrometry (DART-MS) and the microporosity of metal-organic frameworks (MOFs) to adsorb and therefore concentrate explosives from the vapor phase and subsequently detect them …

New York City Micronet : Comprehensive Site Metadata And Classifications And Characteristics Of The Urban Heat Island, Ashley Williamson

Legacy Theses & Dissertations (2009 - 2024)

The New York City Micronet (NYC Micronet), comprised of 17 stations, was installed in the Fall of 2020 for the purpose of long-term monitoring of climate change, and to provide support to utility operations for Consolidated Edison, Inc. (Con Edison). There are five additional standard NYS Mesonet stations located in NYC installed in late 2017. Co-located at the standard stations are three flux, and three profiler stations from sub-networks within the NYS Mesonet. With 22 different locations collecting 5-minute averaged data, this network becomes the highest spatial and temporal resolution urban meteorological network (UMN) of this quality in NYC. This …

Development And Applications Of Touch Chemistry Biometrics Analysis Of Latent Fingermarks By Maldi-Ms, Cameron M. Longo

Legacy Theses & Dissertations (2009 - 2024)

Fingerprint evidence has long been a pillar of forensic science and has been used for over a century as a means of identifying an individual. This is accomplished through the comparison of friction ridge patterns, which are inherently unique to each individual, and the practice of visualizing fingerprints and comparing them has become a well-studied field. While these techniques have been optimized and improved over time, they generally rely only on the physical pattern to provide information about the donor, and not the content of the fingerprint material itself. In the modern era, steps have been made to extract from …

Discrimination Between Human And Non-Human Blood Using Raman Spectroscopy And A Self-Reference Algorithm For Forensic Purposes : Method Expansion And Validation, Harrison Dickler

Legacy Theses & Dissertations (2009 - 2024)

Determining whether the origin of a bloodstain is human or non-human is an important capability of a forensic investigation. In their pioneering work, Bian et al. (Journal of biomedical optics, 2017) introduced a self-reference peak algorithm for the analysis of bloodstain Raman spectra and demonstrated a great potential of this approach for differentiating human and nonhuman blood. However, this work only used three non-human species in the creation of their model. This study investigates the capability of a self-referencing peak algorithm to discriminate between human and 18 non-human species based on the Raman spectra of blood samples. The intensity ratios …

Methodology Studies For Dearomatized Dimer And Beta-Lactone-Mediated Native Chemical Ligation In Organic Synthesis, Xinhao Fan

Legacy Theses & Dissertations (2009 - 2024)

Chapter 1: Dimers of naphthalenol derivatives were synthesized by photocatalysis, cobalt(II) acetylacetonate. Several functional groups were tolerant of its skeleton. This novel dimer was connected through a reversible sigma bond. Its reversibility was confirmed by chiral HPLC and 1H-NMR experiments. Through EPR and Stern-Volmer quenching experiments, we proposed the reaction mechanism. The reversibility property can be potentially beneficial in polymers, self-healing, and memory materials.Chapter 2: We report an epimerization-free native chemical ligation reaction by β-lactone-mediated peptides. This approach can achieve Thr-Xaa efficiently and rapidly. Besides, it has a broad side-chain tolerance. Through the competition reaction experiment, it was demonstrated that …

The Mountain Gap Wind Of The Isthmus Of Tehuantepec And Its Impact On Tropical Cyclogenesis In The Eastern Pacific, Adolfo Lugo Rios

Atmospheric and Environmental Sciences Theses and Dissertations

In this dissertation we research two aspects of the mountain gap wind northerlies of the Isthmus of Tehuantepec in Southern Mexico. The causes of extreme gap wind northerlies, emphasizing the causes by tropical weather systems, like easterly waves troughs or hurricanes, and the impacts of an extreme gap wind events on tropical cyclogenesis.

Through the use of an index to diagnose the mountain gap wind strength, its evolution through the year and the mechanisms leading to extreme mountain gap winds was highlighted. The index revealed that the gap wind is strongly related to high surface pressure anomalies over the GoM …

A Novel Phase And Spectroscopic Imaging Technique To Evaluate Cellular Functions, Ting Chean Khoo

Legacy Theses & Dissertations (2009 - 2024)

This thesis presents the application of Raman spectroscopy, digital holographic microscope (DHM) and transport intensity equation (TIE) in imaging biological samples. Raman spectroscopy is a non-destructive technique that can provide chemical structure, concentration, temperature, and molecular interactions. On the other hand, DHM and TIE provide physical measurements such as height, width, area and volume.We applied Raman spectroscopy to study iron-bound transferrin (Tf) in intact human breast cancer cells. Iron is an essential element required for human life and is highly regulated in the body. As the exact mechanisms of iron-bound Tf in cells are not well known, we developed a …

System Measurements For X-Ray Phase And Diffraction Imaging, Erik Wolfgang Tripi

Legacy Theses & Dissertations (2009 - 2024)

In medical imaging, X rays are used to look inside the body to find fractures in bones, abnormal masses, cavities in teeth, and so on. What makes X rays so good at looking at these types of structures is the X ray’s penetration power. When imaging soft tissue to search for tumors, X-ray images tend to have difficulty performing well. The reason for this is that the background structures, such as fat or fibro glandular tissue have similar absorption coefficients as the tumor. Mammography tends to have a high false positive rate and can miss tumors entirely as well. There …

The Urban Heat Island Of Bengaluru, India : Characteristics, Trends, And Mechanisms, Heather Samantha Sussman

Legacy Theses & Dissertations (2009 - 2024)

The urban heat island (UHI) effect refers to how urban surfaces tend to be warmer than nearby non-urban areas due to less vegetation and other processes. UHIs can increase the risk of heat and respiratory illnesses. Since every city is unique, UHIs should be studied on a local-scale. One particular city that has not had its UHI comprehensively evaluated is Bengaluru, India. Bengaluru was once known as the “Garden City” of India due to a wide presence of gardens and public parks, but is now known as the “Silicon City” of India due to the overwhelming presence of the information …

Spokane Climate Project: Chapter 1, Temperature Impact Study For Spokane, Washington, Rebecca Macmullen, Kara Odegard, Jim Simon, David Camp, Gonzaga University Climate Institute

Climate, Water, and the Environment Research

This chapter examines the effects that projected future temperature increases are likely to have on human health and safety in Spokane. Spokane’s annual Lilac Bloomsday Run (Bloomsday) is used as a case study to illustrate potential impacts to human health.

The full version of this report as well as a full list of the citations and methodologies employed for this analysis can be found at the Spokane Climate Project website: https://www.spokaneclimateproject.org/.

Spokane Climate Project: Executive Summary, Pacific Northwest Climate Impacts Research Consortium (Circ), Gonzaga University Climate Institute

Climate, Water, and the Environment Research

This executive summary was created as part of the Spokane Climate Project (SCP) and complies the key climate science finding of the project. This summary report is part of a larger climate and weather vulnerability and resilience assessment for Spokane, Washington. The full assessment is scheduled for completion sometime in 2021.

Under the guidance of the Pacific Northwest Climate Impacts Research Consortium (CIRC), Spokane Climate Project participants from Spokane used CIRC’s Climate Toolbox, a suite of online climate science tools and related datasets, to investigate how climate and weather-related impacts—including rising temperatures, wildfires, and the loss of snowpack—are projected to …

Image-Data-Driven Deep Learning For Slope Stability Analysis, Behnam Azmoon

Dissertations, Master's Theses and Master's Reports

Landslides cause major infrastructural issues, damage the environment, and cause socio-economic disruptions. Therefore, various slope stability analysis methods have been developed to evaluate the stability of slopes and the probability of their failure. This dissertation attempts to take advantage of the recent advancements in remote sensing and computer technology to implement a deep-learning-based landslide prediction method.

Considering the novelty of this approach, this dissertation leads with proof-of-concept studies to evaluate and establish the suitability of deep learning models for slope stability analysis. To achieve this, a simulated 2D dataset of slope images was created with different geometries and soil properties. …

Design And Analysis Of Marangoni-Driven Robotic Surfers, Mitchel L. Timm

Dissertations, Master's Theses and Master's Reports

We designed and experimentally studied the dynamics of two robotic systems that surf along the water-air interface. The robots were self-propelled by means of creating and maintaining a surface tension gradient resulting from an asymmetric release of isopropyl alcohol (IPA). The imbalance in the distribution of surface tension surrounding the robots generates a propulsive force commonly referred to as Marangoni propulsion. First, we considered a single surfer, which was custom-made with novel control mechanisms that allow for both forward motion and steering to be remotely adjusted solely through the manipulation of local surface stresses. We analyzed the performance of this …

The Photo-Transformation Of Free Methionine In The Presence Of Surrogate And Standard Isolate Dissolved Organic Matter Under Sunlit Irradiation, Benjamin J. Mohrhardt

Dissertations, Master's Theses and Master's Reports

Sulfur (S)-containing amino acids are key sources of carbon, nitrogen, and sulfur involved in protein synthesis, protein function, and providing energy for microbial growth. Dissolved free and combined methionine is one of two S-containing amino acids incorporated into proteins and has been attributed to their stability and function. The oxidation of methionine has received considerable attention given its ubiquitous presence in most biological systems and has been associated with losses in protein function and pathological disorders. In natural waters, methionine is rapidly and selectively taken up by microorganisms to achieve cellular requirements of carbon, nitrogen, and sulfur. The abiotic transformation …