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Articles 64531 - 64560 of 294411
Full-Text Articles in Physical Sciences and Mathematics
Grassland Landscape Design: Working With Land-Managers, C. J. Pearson, R. K. Mann, I. G. Mann
Grassland Landscape Design: Working With Land-Managers, C. J. Pearson, R. K. Mann, I. G. Mann
IGC Proceedings (1977-2023)
We are entering an era of landscape design in order to simultaneously tackle largescale issues such as salinity and rising water tables, whole-farm profitability and the maintenance or enhancement of rural communities. In Australia, an important element of landscape design will be the reintroduction or broadening of the base of perennial grasses within farm systems. The goal of this project was to accelerate awareness and adoption of perennial grasses in a large but ecologically-specific area, namely the already-cleared steep uplands in the high rainfall recharge areas of the Murray-Darling Basin. We used a participatory model, in which land-managers made monthly …
Results With Methods For Measuring Herbage Mass In Situ, G. Nagy, I. Vinczeffy, K. Petõ
Results With Methods For Measuring Herbage Mass In Situ, G. Nagy, I. Vinczeffy, K. Petõ
IGC Proceedings (1977-2023)
Two indirect methods for estimating herbage mass in situ were investigated in a research programme. Electric capacitance and spectral reflectance measurements were made and estimated values were compared with cut herbage mass results. Vegetation indexes (VI) measured by spectroradiometer showed a high correlation with fresh herbage mass, but there was no correlation observed between VI and dry matter results. Equations installed in electric capacitance meter were not feasible for Hungarian conditions. The change of electric capacitance in the sward (CMR) gave no correlation with cut DM yields. The investigated indirect methods are not suitable for research or production use yet.
Application Of Municipal Biosolids To Bahiagrass Pasture: Trace Metals In Harvested Forage, R. M. Muchovej, J. E. Rechcigl
Application Of Municipal Biosolids To Bahiagrass Pasture: Trace Metals In Harvested Forage, R. M. Muchovej, J. E. Rechcigl
IGC Proceedings (1977-2023)
Municipal biosolids (sewage sludge) are the by-products of wastewater treatment plants and their production, worldwide, has steadily increased over the past years. Florida is one of the fastest growing states in the USA. Biosolids are readily and increasingly available throughout the state. Pasture fertilization has been shown to increase biomass and quality of bahiagrass (Paspalum notatum Flugge) dramatically in Florida sandy soils. Nevertheless, with low cattle prices, ranchers are forced to reduce fertilizers inputs. Biosolids contain considerable amounts of nutrients, especially nitrogen (N), phosphorus (P), sulphur (S), calcium (Ca), and micronutrients, and are inexpensive when compared with commercial fertilizers. …
Rangelands Vegetation Mapping At Species Composition Level Using The Spicla Method: SDm Based PiXel ClaSsification And Fuzzy Accuracy. A New Approach Of Map Making, A. G. Toxopeus, C. A. J. M. De Bie, E. H. Kloosterman, J. K. Mbaluka, P. K. Mwangi, L. G. J. Boerboom
Rangelands Vegetation Mapping At Species Composition Level Using The Spicla Method: SDm Based PiXel ClaSsification And Fuzzy Accuracy. A New Approach Of Map Making, A. G. Toxopeus, C. A. J. M. De Bie, E. H. Kloosterman, J. K. Mbaluka, P. K. Mwangi, L. G. J. Boerboom
IGC Proceedings (1977-2023)
Vegetation maps have been made since centuries. The vegetation cover was represented as homogeneous mapping units (polygons), representing different vegetation types, where each type consists a combination of different plant species (floristic composition). More recent, with the use of satellite imagery, the polygons have been replaced by pixels with similar content as the polygon maps. In both approaches, field-observations were linked to the mapping units (polygons or pixels) often resulting in a complex of different vegetation types per mapping unit. In our new approach field data (sample points) on presence and abundance of individual grass species are spatially extrapolated based …
Forensic Discoverability Of Ios Vault Applications, Alissa Gilbert, Kathryn C. Seigfried-Spellar
Forensic Discoverability Of Ios Vault Applications, Alissa Gilbert, Kathryn C. Seigfried-Spellar
Journal of Digital Forensics, Security and Law
Vault Applications are used to store potentially sensitive information on a smartphone; and are available on Android and iOS. The purpose of using these applications could be used to hide potential evidence or illicit photos. After comparing five different iOS photo vaults, each vault left evidence and photos behind. However, of the three forensic toolkits used, each produced different results in their scans of the phone. The media left behind was due to the photo vaults not protecting their information as claimed, and using basic obfuscation techniques in place of security controls. Future research will look at how newer security …
Mathematically Modeling Prey-Catching Behavior Of The Tomato Frog, Conrad Tyler, Sarah Marzen, Jenna Monroy
Mathematically Modeling Prey-Catching Behavior Of The Tomato Frog, Conrad Tyler, Sarah Marzen, Jenna Monroy
Spora: A Journal of Biomathematics
Many microhylid frog species, such as the tomato frog, Dyscophus sp., have demonstrated the ability to aim their tongues independently of head and jaw movements. However, a trade-off between tongue-aiming and head-only aiming exists in which the former allows for crypsis but lacks speed whereas the latter is faster but less accurate and more noticeable to prey. For frogs that can move their tongues independently of their heads, under what circumstances will they utilize each strategy, and why? We derive a model, dependent on factors relevant for prey-catching, for the probability the frog will turn its head (and not …
Adoption And Influence: Industry Evaluation Of The GrassgroTm Decision Support Tool, E. M. Salmon, A. D. Moore
Adoption And Influence: Industry Evaluation Of The GrassgroTm Decision Support Tool, E. M. Salmon, A. D. Moore
IGC Proceedings (1977-2023)
The GrassGro Decision Support tool (DS tool) (Donnelly and Moore, 1999) was released for commercial use in Australia with a training package in late 1997. An assessment of its adoption was made by a survey of 53 registered users in March 1999. An evaluation of the software and training package was made at training workshops by 92 users between 1997 and December 1999. The response rates to the survey and the evaluation were 62% and 82% respectively. Seventy six percent of survey respondents had analysed at least one problem with GrassGro and 27% had applied GrassGro to five or more …
Digestibility Estimates Based On A Grass Growth Model Are Distributed Via Internet To Finnish Farmers, Marketta Rinne, J. Nousiainen, I. Mattila, H. Nikander, P. Huhtanen
Digestibility Estimates Based On A Grass Growth Model Are Distributed Via Internet To Finnish Farmers, Marketta Rinne, J. Nousiainen, I. Mattila, H. Nikander, P. Huhtanen
IGC Proceedings (1977-2023)
Optimising the harvesting time of grass in primary growth is difficult under Finnish climatic conditions, because the digestibility of grass decreases on average by 0.5 percentage units daily. We constructed a model based on cumulative temperature and geographical location which estimates the digestibility of grass. This model is used to produce estimates utilising real time weather information. The estimates are presented as a map, which is revised daily. Farmers have free access to the maps via Internet.
Reducing Tillage Affects Long-Term Yields But Not Grain Quality Of Maize, Soybeans, Oats, And Wheat Produced In Three Contrasting Farming Systems, Kirsten Ann Pearsons, Emmanuel Chiwo Omondi, Brad J. Heins, Gladis Zinati, Andrew Smith, Yichao Rui
Reducing Tillage Affects Long-Term Yields But Not Grain Quality Of Maize, Soybeans, Oats, And Wheat Produced In Three Contrasting Farming Systems, Kirsten Ann Pearsons, Emmanuel Chiwo Omondi, Brad J. Heins, Gladis Zinati, Andrew Smith, Yichao Rui
Agricultural and Environmental Sciences Faculty Research
Reducing tillage has been widely promoted to reduce soil erosion, maintain soil health, and sustain long-term food production. The effects of reducing tillage on crop nutritional quality in organic and conventional systems, however, has not been widely explored. One possible driver of crop nutritional quality might be the changing soil nitrogen (N) availability associated with reduced tillage in various management systems. To test how reducing tillage affects crop nutritional quality under contrasting conventional and organic farming systems with varied N inputs, we measured nutritional quality (protein, fat, starch, ash, net energy, total digestible nutrients, and concentrations of Ca, K, Mg, …
Parameter Estimation Based On Double Ranked Set Samples With Applications To Weibull Distribution, Mohamed Abd Elhamed Sabry, Hiba Zeyada Muhammed, Mostafa Shaaban, Abd El Hady Nabih
Parameter Estimation Based On Double Ranked Set Samples With Applications To Weibull Distribution, Mohamed Abd Elhamed Sabry, Hiba Zeyada Muhammed, Mostafa Shaaban, Abd El Hady Nabih
Journal of Modern Applied Statistical Methods
In this paper, the likelihood function for parameter estimation based on double ranked set sampling (DRSS) schemes is introduced. The proposed likelihood function is used for the estimation of the Weibull distribution parameters. The maximum likelihood estimators (MLEs) are investigated and compared to the corresponding ones based on simple random sampling (SRS) and ranked set sampling (RSS) schemes. A Monte Carlo simulation is conducted and the absolute relative biases, mean square errors, and efficiencies are compared for the different schemes. It is found that, the MLEs based on DRSS is more efficient than MLE using SRS and RSS for estimating …
Radical-Initiated Brown Carbon Formation In Sunlit Carbonyl–Amine–Ammonium Sulfate Mixtures And Aqueous Aerosol Particles, Natalie G. Jimenez, Kyle D. Sharp, Tobin Gramyk, Duncan Z. Ugland, Matthew-Khoa Tran, Antonio Rojas, Michael A. Rafla, Devoun Stewart, Melissa M. Galloway, Peng Lin, Alexander Laskin, Mathieu Cazaunau, Edouard Pangui, Jean-François Doussin, David O. De Haan
Radical-Initiated Brown Carbon Formation In Sunlit Carbonyl–Amine–Ammonium Sulfate Mixtures And Aqueous Aerosol Particles, Natalie G. Jimenez, Kyle D. Sharp, Tobin Gramyk, Duncan Z. Ugland, Matthew-Khoa Tran, Antonio Rojas, Michael A. Rafla, Devoun Stewart, Melissa M. Galloway, Peng Lin, Alexander Laskin, Mathieu Cazaunau, Edouard Pangui, Jean-François Doussin, David O. De Haan
Chemistry and Biochemistry: Faculty Scholarship
Brown carbon (BrC) formed from glyoxal+ammonium sulfate (AS) and methylglyoxal+AS reactions photobleaches quickly, leading to the assumption that BrC formed overnight by Maillard reactions will be rapidly destroyed at sunrise. Here, we tested this assumption by reacting glyoxal, methylglyoxal, glycolaldehyde, or hydroxyacetone in aqueous mixtures with reduced nitrogen species at pH 4–5 in the dark and in sunlight (>350 nm) for at least 10 h. The absorption of fresh carbonyl+AS mixtures decreased when exposed to sunlight, and no BrC formed, as expected from previous work. However, the addition of amines (either methylamine or glycine) allowed BrC to form in …
Investigating The Mechanical Performance Of Nano Additives Reinforced High-Performance Concrete, Mohamed Morsy
Investigating The Mechanical Performance Of Nano Additives Reinforced High-Performance Concrete, Mohamed Morsy
Nanotechnology Research Centre
It is known that nanomaterials have been broadly employed worldwide as reinforcements for the production of high-strength and high mechanical performance concrete-based structures. Hereinafter, high-performance concrete (HPC) modifed with three types of additives were synthesized: exfoliated nano clay (NC), nano-silica (NS), and hybrid particles [silica fume (SF) & limestone (LS)]. The compressive, splitting tensile and flexural strengths, were investigated at 28 days of hydration. The exfoliated NC was simply prepared via exfoliating the thermally activated ordinary clay with the aid of organic ammonium chloride. The results revealed that all types of the employed additives provided an augmentation in the mechanical …
Exploring South Korea’S Ocean Economy : The Korea National Ocean Economy Survey 2017-2019, Seokwoo Jake Choi Dr, Ju-Hyeoun Kim, Gi-Su Kim, Kwang Seo Park Dr
Exploring South Korea’S Ocean Economy : The Korea National Ocean Economy Survey 2017-2019, Seokwoo Jake Choi Dr, Ju-Hyeoun Kim, Gi-Su Kim, Kwang Seo Park Dr
Journal of Ocean and Coastal Economics
As the economic contribution of the ocean and fisheries industry increases, it is essential to identify industrial characteristics and propose specialized strategies based on data. However, there has been a lack of research on the establishment of an industrial classification system that reflects the characteristics of the ocean and fisheries industry in South Korea. Therefore, this study aims to introduce the specialized classification system of the ocean and fisheries industry and, further intends to analyze industry trends using the survey data based on the classification system. For the past three years (2017-2019) 9,000 businesses were surveyed annually to estimate industry …
Kentucky Alfalfa Conference: A Team Approach To Alfalfa Education And Technology Transfer, Garry D. Lacefield, Monroe Rasnake, Christi L. Forsythe, Jimmy C. Henning, Bill Talley
Kentucky Alfalfa Conference: A Team Approach To Alfalfa Education And Technology Transfer, Garry D. Lacefield, Monroe Rasnake, Christi L. Forsythe, Jimmy C. Henning, Bill Talley
IGC Proceedings (1977-2023)
Alfalfa has played an important role in providing farmers of Kentucky with a high yielding, high quality, persistent forage legume for many years. In 1980, a group of individuals under the leadership of University of Kentucky Forage Extension Specialists organized and implemented the first statewide educational event on alfalfa. This initial meeting gave rise to the Kentucky Alfalfa Conference that celebrated it’s twentieth anniversary in February 2000. This annual event has been co-sponsored by the University of Kentucky, Kentucky Forage and Grassland Council, along with other state and national groups including Certified Alfalfa Seed Council, Kentucky Department of Agriculture, Kentucky …
Developing A National Alfalfa Information System, David B. Hannaway, K. J. Hannaway, P. Sohn, S. Griffith, B. E. Avery, E. Nowick, W. F. Wedin, L. R. Vough, S. C. Bosworth, Garry D. Lacefield, Gary E. Bates, D. Undersander, N. P. Martin, J. Caddel, G. L. Kilgore, S. B. Orloff, A. M. Gray, R. Ditterline, T. Griggs, D. H. Putnam, M. J. Ottman
Developing A National Alfalfa Information System, David B. Hannaway, K. J. Hannaway, P. Sohn, S. Griffith, B. E. Avery, E. Nowick, W. F. Wedin, L. R. Vough, S. C. Bosworth, Garry D. Lacefield, Gary E. Bates, D. Undersander, N. P. Martin, J. Caddel, G. L. Kilgore, S. B. Orloff, A. M. Gray, R. Ditterline, T. Griggs, D. H. Putnam, M. J. Ottman
IGC Proceedings (1977-2023)
Using state-of-the-art telecommunication technologies, this project is developing a comprehensive knowledge resource for alfalfa (Medicago sativa L.); the National Alfalfa Information System (NAIS). This project will serve as an improved model for Extension educational programs. Alfalfa is the most important forage crop in the USA and grown worldwide for feeding millions of livestock and in many cropping systems. As a legume, it is important in sustaining the environment and the productivity of agriculture. Information needs are present in every state and internationally. The NAIS is being developed through national and international cooperation, putting the best science-based alfalfa information and …
Main-Stem Seepage And Base-Flow Recession Time Constants In The Niobrara National Scenic River Basin, Nebraska, 2016–18, Kellan R. Strauch, Philip J. Soeksen
Main-Stem Seepage And Base-Flow Recession Time Constants In The Niobrara National Scenic River Basin, Nebraska, 2016–18, Kellan R. Strauch, Philip J. Soeksen
United States Geological Survey: Water Reports and Publications
The Niobrara River of northern Nebraska is a valuable water resource that sustains irrigated agriculture and recreation, as well as a diverse ecosystem. Large-quantity withdrawals from the source aquifer system have the potential to reduce the flow into the river and to adversely affect the free-flowing condition of the Niobrara National Scenic River (NSR). Therefore, to understand the magnitude and characteristics of those flows, the United States Geological Survey (USGS), in cooperation with the National Park Service, began a study to quantify seepage gains/losses along the eastern half of the Niobrara NSR and to create a map characterizing the base-flow …
A Deep Neural Network For Early Detection And Prediction Of Chronic Kidney Disease, Vijendra Singh, Vijayan K. Asari, Rajkumar Rajasekaran
A Deep Neural Network For Early Detection And Prediction Of Chronic Kidney Disease, Vijendra Singh, Vijayan K. Asari, Rajkumar Rajasekaran
Electrical and Computer Engineering Faculty Publications
Diabetes and high blood pressure are the primary causes of Chronic Kidney Disease (CKD). Glomerular Filtration Rate (GFR) and kidney damage markers are used by researchers around the world to identify CKD as a condition that leads to reduced renal function over time. A person with CKD has a higher chance of dying young. Doctors face a difficult task in diagnosing the different diseases linked to CKD at an early stage in order to prevent the disease. This research presents a novel deep learning model for the early detection and prediction of CKD. This research objectives to create a deep …
Upregulation Of Cd36, A Fatty Acid Translocase, Promotes Colorectal Cancer Metastasis By Increasing Mmp28 And Decreasing E-Cadherin Expression, James Drury, Piotr G. Rychahou, Courtney O. Kelson, Mariah E. Geisen, Yuanyuan Wu, Daheng He, Chi Wang, Eun Y. Lee, B. Mark Evers, Yekaterina Y. Zaytseva
Upregulation Of Cd36, A Fatty Acid Translocase, Promotes Colorectal Cancer Metastasis By Increasing Mmp28 And Decreasing E-Cadherin Expression, James Drury, Piotr G. Rychahou, Courtney O. Kelson, Mariah E. Geisen, Yuanyuan Wu, Daheng He, Chi Wang, Eun Y. Lee, B. Mark Evers, Yekaterina Y. Zaytseva
Surgery Faculty Publications
Altered fatty acid metabolism continues to be an attractive target for therapeutic intervention in cancer. We previously found that colorectal cancer (CRC) cells with a higher metastatic potential express a higher level of fatty acid translocase (CD36). However, the role of CD36 in CRC metastasis has not been studied. Here, we demonstrate that high expression of CD36 promotes invasion of CRC cells. Consistently, CD36 promoted lung metastasis in the tail vein model and GI metastasis in the cecum injection model. RNA-Seq analysis of CRC cells with altered expression of CD36 revealed an association between high expression of CD36 and upregulation …
Hadamard’S Variational Formula In Terms Of Stress And Strain Tensors, Björn Gustafsson, Ahmed Sebbar
Hadamard’S Variational Formula In Terms Of Stress And Strain Tensors, Björn Gustafsson, Ahmed Sebbar
Mathematics, Physics, and Computer Science Faculty Articles and Research
Starting from a Lagrangian action functional for two scalar fields we construct, by variational methods, the Laplacian Green function for a bounded domain and an appropriate stress tensor. By a further variation, imposed by a given vector field, we arrive at an interior version of the Hadamard variational formula, previously considered by P. Garabedian. It gives the variation of the Green function in terms of a pairing between the stress tensor and a strain tensor in the interior of the domain, this contrasting the classical Hadamard formula which is expressed as a pure boundary variation.
Deep Extragalactic Visible Legacy Survey: Data Release 1 Blended Spectra Search For Candidate Strong Gravitational Lenses, Benne Holwerda, S Knabel, J E. Thorne, S Bellstedt, M Siudek, L J M Davies
Deep Extragalactic Visible Legacy Survey: Data Release 1 Blended Spectra Search For Candidate Strong Gravitational Lenses, Benne Holwerda, S Knabel, J E. Thorne, S Bellstedt, M Siudek, L J M Davies
Faculty and Staff Scholarship
Here, we present a catalogue of blended spectra in Data Release 1 of the Deep Extragalactic VIsible Legacy Survey (DEVILS) on the Anglo-Australian Telescope. Of the 23 197 spectra, 181 showed signs of a blend of redshifts and spectral templates. We examine these blends in detail for signs of either a candidate strong lensing galaxy or a useful overlapping galaxy pair. One of the three DEVILS target fields, COSMOS (D10), is close to complete and it is fully imaged with Hubble Space Telescope Advanced Camera for Surveys, and we visually examine the 57 blended spectra in this field in the …
Isolated Objects And Their Evolution: A Derivation Of The Propagator’S Path Integral For Spinless Elementary Particles, Domenico Napoletani, Daniele Carlo Struppa
Isolated Objects And Their Evolution: A Derivation Of The Propagator’S Path Integral For Spinless Elementary Particles, Domenico Napoletani, Daniele Carlo Struppa
Mathematics, Physics, and Computer Science Faculty Articles and Research
We formalize the notion of isolated objects (units), and we build a consistent theory to describe their evolution and interaction. We further introduce a notion of indistinguishability of distinct spacetime paths of a unit, for which the evolution of the state variables of the unit is the same, and a generalization of the equivalence principle based on indistinguishability. Under a time reversal condition on the whole set of indistinguishable paths of a unit, we show that the quantization of motion of spinless elementary particles in a general potential field can be derived in this framework, in the limiting …
Map Based Www Tool For Recommending Forage Species, M. H. Hall, D. A. Miller, J. H. Cherney
Map Based Www Tool For Recommending Forage Species, M. H. Hall, D. A. Miller, J. H. Cherney
IGC Proceedings (1977-2023)
Selecting the “best” forage species or species mixture requires a knowledge and understanding of the consuming animal, soil characteristics, and forage species. The multivariate nature of the problem presents challenges to those interested in solving the practical problem of maximizing available resources. Earlier work at Cornell University resulted in a WWW-based interface that allowed the user to provide a soil type or zip code and additional management factors to initiate the species selection. This approach relies on either user knowledge of soil series or an implied relationship between zip code and soil series that may often be wrong. To improve …
Remote Sensing Application To Grassland Monitoring, Z. B. Nan
Remote Sensing Application To Grassland Monitoring, Z. B. Nan
IGC Proceedings (1977-2023)
Application of remote sensing to the management of grassland resources, the role this plays in developing sustainable grassland farming systems and opportunities for further development are outlined. Use of remote sensing technologies in grassland monitoring has a history of more than 30 years. Both fine- and coarse-grained remote sensing techniques are used to monitor and study grasslands. Fine-grained techniques are used to study landscape scale processes through the use of sensors providing spatial resolution of a few meters, whereas coarse-grained techniques are used to study catchment scale areas, and even entire biomes, using satellite-based sensors with a spatial resolution of …
Modelling Grassland Ecosystems, J. H. M. Thornley
Modelling Grassland Ecosystems, J. H. M. Thornley
IGC Proceedings (1977-2023)
In this contribution a view of the promise and difficulties of modelling grassland is given. This is largely centred around work with a grassland ecosystem simulator known as the Hurley Pasture Model.
A brief introduction sets forth possible reasons for building a large ecosystem model, and stresses the importance of modelling objectives. It is suggested that a model is de rigeur for any research programme which aims to take a firm grasp of the complex responses of grassland. Mechanistic models are required to provide the understanding needed for intelligent and flexible management of grassland, whatever the prevailing environmental or economic …
Estimating Herbage Mass In Stargrass (Cynodon Nlenfuensis Var Nlenfuensis) Using Sward Surface Height And The Rising Plate Meter, D. E. Oliveira, S. R. Medeiros, L. J. M. Aroeira, L. G. Barioni, D. P. D. Lanna
Estimating Herbage Mass In Stargrass (Cynodon Nlenfuensis Var Nlenfuensis) Using Sward Surface Height And The Rising Plate Meter, D. E. Oliveira, S. R. Medeiros, L. J. M. Aroeira, L. G. Barioni, D. P. D. Lanna
IGC Proceedings (1977-2023)
Estimation of herbage mass is necessary both in research and farm management. Methods for such estimations should be inexpensive, rapid and reliable. Since estimations through hand clipping are time consuming, a range of indirect methods have been developed and tested in the literature. This study had the aim of comparing precision of two indirect methods, sward surface height (SSH) and the rising plate meter (RPM), to estimate herbage mass in stargrass pastures (Cynodon nlenfuensis var. nlenfuensis). Pre-grazing measurements of SSH and RPM readings were taken and compared with the paddock herbage mass. RPM readings were converted into centimeters. Average …
Tropical Cyclones Negatively Impact The Tourism Economy In Coastal Regions, Sergio Alvarez, Arthur Huang
Tropical Cyclones Negatively Impact The Tourism Economy In Coastal Regions, Sergio Alvarez, Arthur Huang
Rosen Research Review
Tropical cyclones can have a devastating effect on communities, causing loss of property, businesses, and life. In areas that rely on tourism, these effects can be long-lasting. In their recent work, Dr. Sergio Alvarez and Dr. Arthur Huang from UCF Rosen College of Hospitality Management have examined the impact that tropical cyclones have on the tourism economy in Florida. The results suggest that these cyclones negatively impact the economy, especially in coastal regions, and that policy changes are needed to help the tourism sector recover
Synthesis Of Methanediol [Ch2(Oh)2]: The Simplest Geminal Diol, Cheng Zhu, N. Fabian Kleimeier, Andrew M. Turner, Santosh K. Singh, Ryan C. Fortenberry, Ralf I. Kaiser
Synthesis Of Methanediol [Ch2(Oh)2]: The Simplest Geminal Diol, Cheng Zhu, N. Fabian Kleimeier, Andrew M. Turner, Santosh K. Singh, Ryan C. Fortenberry, Ralf I. Kaiser
Faculty and Student Publications
Geminal diols—organic molecules carrying two hydroxyl groups at the same carbon atom—have been recognized as key reactive intermediates by the physical (organic) chemistry and atmospheric science communities as fundamental transients in the aerosol cycle and in the atmospheric ozonolysis reaction sequence. Anticipating short lifetimes and their tendency to fragment to water plus the aldehyde or ketone, free geminal diols represent one of the most elusive classes of organic reactive intermediates. Here, we afford an exceptional glance into the preparation of the previously elusive methanediol [CH2(OH)2] transient—the simplest geminal diol—via energetic processing of low-temperature methanol–oxygen ices. Methanediol was identified in the …
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