Physical Sciences and Mathematics Commons^™

A New Method To Compute The Hadamard Product Of Two Rational Functions, Ishan Kar

Rose-Hulman Undergraduate Mathematics Journal

The Hadamard product (denoted by∗) of two power series A(x) =a₀+a₁x+a₂x²+···and B(x) =b₀+b₁x+b₂x²+··· is the power series A(x)∗B(x) =a₀b₀+a₁b₁x+a₂b₂x²+···. Although it is well known that the Hadamard product of two rational functions is also rational, a closed form expression of the Hadamard product of rational functions has not been found. Since any rational power series can be expanded by partial fractions as a polynomial plus a sum of power series …

Sedimentation Processes In A Dredge Pit And Surrounding Environment In Northern Gulf Of Mexico, Adam M. Gartelman

LSU Master's Theses

Louisiana’s Coastal Protection and Restoration Authority has been using dredged sand from onshore and offshore sites for barrier island restoration and beach nourishment projects. Caminada dredge pit (CDP) located on eastern Ship Shoal in inner Louisiana shelf underwent two increments in 2014 and 2016, with material used to restore Caminada Headland and nearby areas. Multiple pits in East Terrebonne borrow areas (ET) right next to CDP were then used for East Timbalier Island and other barrier islands near Terrebonne Bay. ET1, north of CDP, was dredged in 2020, and ET2, west of CDP, was dredged in 2020 and 2021 used …

Malware And Memory Forensics On M1 Macs, Charles E. Glass

LSU Master's Theses

As malware continues to evolve, infection mechanisms that can only be seen in memory are increasingly commonplace. These techniques evade traditional forensic analysis, requiring the use of memory forensics. Memory forensics allows for the recovery of historical data created by running malware, including information that it tries to hide. Memory analysis capabilities have lagged behind on Apple's new M1 architecture while the number of malicious programs only grows. To make matters worse, Apple has developed Rosetta 2, the translation layer for running x86_64 binaries on an M1 Mac. As a result, all malware compiled for Intel Macs is theoretically functional …

New Chemoselective Dehydration And Cyclization Strategies Enabled By Triphosgene, Moshood Oreofeoluwa Ganiu

LSU Doctoral Dissertations

Since Friedrich Wöhler’s synthesis of urea in 1828, the techniques of organic synthesis have developed and advanced greatly. This advancement has facilitated the discovery of new organic synthetic methods, and enabled access to a more expansive chemical space. The purpose of this dissertation is to present the development of new organic synthetic reactions that were uncovered through previous discoveries. Additionally, the main theme of this work relies on exploiting the versatility of triphosgene in organic synthesis. To this end, the developed chemistries rely on the ability of triphosgene to serve as an activating agent, and a chloride source.

Chapter 1 …

New Multimedia Resources For Ecological Resilience Education In Modern University Classrooms, Katharine F. E. Hogan, Julie A. Fowler, Conor D. Barnes, Alison K. Ludwig, Dominic J. Cristiano, Daniel Morales, Rubi Quiñones, Dirac L. Twidwell Jr, Jenny Dauer

School of Natural Resources: Faculty Publications

Solutions to global problems such as climate change and biodiversity loss require educational frameworks and accompanying teaching resources that are theory-based, interdisciplinary, and accessible to broad undergraduate and graduate student audiences. Ecological resilience theory (ERT) is a framework with established interdisciplinary application to complex global problems, but despite an emphasis on the utility of resilience in national higher education frameworks, we found that many current ecology textbooks incorporate multiple definitions and highly variable amounts of discussion on core resilience concepts. To facilitate the use of innovative teaching resources in ERT in universities, this paper describes four free multimedia tools and …

The Biggest Loser: How Tanking In Professional Sports Impacts Fan Perception, Julia Ayres

Honors Projects in Mathematics

Professional sports teams are adored nationwide for their talents and the pride they bring to their city for their efforts. However, not all teams take this responsibility seriously and will lose on purpose, or tank, to gain a higher draft pick in the future. Although the long-term goals of tanking are to help the organization, many people take issue with athletes not putting in their best efforts in every game. Teams in both the NBA and NFL are guilty of tanking to gain better draft picks but not all have found success in this process. This leads to important questions …

Hydrolytically Degradable Thermosets With Tunable Degradation Profiles Via Ketal-Based Crosslinks, Benjamin Alameda

Dissertations

Thermoset polymer networks are ubiquitous in the construction of high-performance materials due to their excellent mechanical properties, solvent resistance, and thermomechanical performance. However, the crosslinked structure that instills these materials with favorable performance also makes them incredibly resistant to degradation and are nearly impossible to recycle – adding to the ever-growing problem of plastic pollution. Hydrolytically degradable thermosets have emerged as a potentially sustainable alternative to traditional thermosets by affording networks that are inherently degradable in aqueous environments. This dissertation focuses on the development of hydrolytically degradable thermoset networks with tunable degradation behavior through the implementation of ketal-based crosslinks. Given …

Unknowable Truths: The Incompleteness Theorems And The Rise Of Modernism, Caroline Tvardy

Honors Scholars Collaborative Projects

This thesis evaluates the function of the current history of mathematics methodologies and explores ways in which historiographical methodologies could be successfully implemented in the field. Traditional approaches to the history of mathematics often lack either an accurate portrayal of the social and cultural influences of the time, or they lack an effective usage of mathematics discussed. This paper applies a holistic methodology in a case study of Kurt Gödel’s influential work in logic during the Interwar period and the parallel rise of intellectual modernism. In doing so, the proofs for Gödel’s Completeness and Incompleteness theorems will be discussed as …

Controlling Unequal Surface Energy Results Caused By Test Liquids: The Case Of Uv/O3 Treated Pet, Bilge N. Altay, Paul D. Fleming, Md Arifur Rahman, Alexandra Pekarovicova, Bruce Myers, Cem Aydemir, Arif Karademir

Articles

Ultraviolet/ozone (UV/O3) treatment has been reported to be an effective method to modify properties such as wettability, adhesion or adsorption of plastic surfaces. The change in the surface is measured by contact angle analysis, which employs liquids and their surface tensions (ST) to estimate the surface energy (SE). We found two different practices in the scientific community: (1) the majority of researchers adopted the ST value of liquids from the literature, while (2) other researchers conducted real-time measurements in the lab under ambient conditions prior to SE estimation. To the best of our knowledge, there is no study that compares …

Using Machine Learning To Recognize Chronic Rhinosinusitis, Irene Liu '23

Student Publications & Research

Chronic Rhinosinusitis (CRS) is a nasal disease characterized by the inflammation of the mucosa and paranasal sinuses with a duration of at least 12 consecutive weeks. So, to diagnose CRS, one needs to keep a record of their symptoms for ~12 weeks before they are recommended to get a tomography which will allow physicians to classify them as a patient with CRS or without. This is a timely and costly process; thus, machine learning should be used to speed the process up. Since patients with CRS have more obstructed noses, the sound produced should be different than an individual without …

Lines On A Smooth Projective Surface, Jordan Demoura

Mathematics & Computer Science Student Scholarship

Jordan DeMoura ’22
Major: Mathematics
Faculty Mentor: Dr. Su-Jeong Kang, Math

This research is to investigate lines on a smooth projective surface. A quadric surface contains two families of planes that provide a ruling of the surface. A cubic surface contains twenty-seven lines, and we provide a complete description of these lines for a Fermat cubic surface. Furthermore, under the Plucker embedding, we show that each family of the lines on a quadric surface corresponds to plane conic curves lying on complementary planes in the projective space of dimension five.

Coevolutionary Analysis Implicates Toll-Like Receptor 9 In Papillomavirus Restriction, Kelly King, Brendan B. Larsen, Sophie Gryseels, Cécile Richet, Simona Kraberger, Robert Jackson, Michael Worobey, Joseph S. Harrison, Arvind Varsani, Koenraad Van Doorslaer

Pacific Faculty Work

Upon infection, DNA viruses can be sensed by pattern recognition receptors (PRRs), leading to the activation of type I and III interferons to block infection. Therefore, viruses must inhibit these signaling pathways, avoid being detected, or both. Papillomavirus virions are trafficked from early endosomes to the Golgi apparatus and wait for the onset of mitosis to complete nuclear entry. This unique subcellular trafficking strategy avoids detection by cytoplasmic PRRs, a property that may contribute to the establishment of infection. However, as the capsid uncoats within acidic endosomal compartments, the viral DNA may be exposed to detection by Toll-like receptor 9 …

The Effects Copper Has On Casting Glass, K. Malika Haver

Honors Projects

The aim of this honors project was to discern the difference between how various types of copper reacted with glass. The two disciplines that were connected were chemistry and glassblowing. The basic components learned in chemistry were applied to glass with an end goal of a project installation that visualized the discoveries with copper. The glassblowing technique used was lost wax casting, and the two types of copper used were copper foil and fine copper metal powder. The copper was found to turn the glass into various blues with the intensity and darkness of the blues being dependent on the …

Metal Complexes Of Redox Active Ligands, Alexandra Chaparro, Parker Keller

Chemistry & Biochemistry Student Scholarship

Alexandra Chaparro ’22, Major: Biochemistry

Parker Keller ’24, Major: Chemistry

Mentor: Dr. Maria Carroll, Chemistry and Biochemistry

Our research focuses on synthesizing and studying the properties of metal complexes that contain redox active ligands. Ligands are molecules or ions that can bind to a metal ion, and this particular class of ligands is interesting because they can either accept or lose electrons. We synthesized zinc complexes, in order to measure the reduction potentials of the ligands, which provide information about the ease with which they accept electrons. We then synthesized iron complexes and determined their structures. These complexes are potentially …

Investigating Ionic Current Rectification As A Means Of Controllable Drug Delivery Using Silica Nanoparticles And Nano Porous Membranes, Katie L. Nolan

Honors College Theses

This project investigates a novel ionic current rectification (ICR) phenomenon created by the opening and closing of nanopores by charged silica nanoparticles (SNPs) under electrophoretic flow. This voltage-controlled opening and closing of the pores can be exploited to allow delivery of nicotine through the pores at programmable intervals. The ICR phenomenon was thoroughly investigated by varying pH, buffer concentration, SNP concentration, and applied voltage range. The mechanism was also verified by testing with a 2-, 3-, and 5-electrode system. Potential cake layer formation was demonstrated in a longer ICR test, and the implications of this on the drug delivery mechanism …

Impact Of Traditional Versus Alternative Assessment On Student Achievement, Beth Lustgarten

Honors Projects

The focus of this study looks at the effect of alternative assessment on student achievement in a high school science classroom. Within this action research, students have choices and are able to demonstrate creativity in their alternative assessments. By comparing student results from traditional and alternative assessments, the impact of assessment showed students had an overwhelming preference for completing alternative assessments, and a majority of students did better on the alternative assessment when compared to the traditional assessment.

The Synthesis And Purification Methodology Of An Intermolecular Pyrophosphate Sensor: Applications For The Quantitative Polymerase Chain Reaction, Ethan Gevedon

Honors Projects

The optimized synthesis and purification methodology for an intermolecular pyrophosphate sensor scaffold molecule was performed: high performance liquid chromatography afforded the scaffold in excellent purity and yield. The applications of the sensor assembly in the quantitative polymerase chain reaction were discussed, and preliminary results show that

Synthesis, Characterization And Activity Of Palladium Catalysts On The Dual Support Of Cerium And Aluminum Oxides, Jihyeon Park

Theses and Dissertations

The effects of sequence of impregnation (Pd on cerium oxides -alumina and cerium oxides on Pd-alumina) and calcination temperature (500 ℃ and 850 ℃) on the catalytic oxidation of methane under lean conditions were investigated. The catalysts were prepared by a combination of impregnation, slurry and vortexing methods. The catalysts had 4.7 wt.% Pd and 10.7 wt.% Ce based on inductively coupled plasma optical emission spectrometry (ICP-OES) analysis. The catalysts were characterized by pulse chemisorption, temperature programmed reduction (TPD), scanning transmission electron microscopy (STEM), and X-ray photoelectron spectroscopy (XPS). The activity of the catalysts for methane combustion was measured in …

Synthesis And Characterization Of Alkyne-Functionalized Photo-Cross-Linkable Polyesters, Warrick Ma, Xiaochu Ding, Ying Chen, Yadong Wang

Michigan Tech Publications, Part 1

An alkyne-functionalized elastomer derived from sebacic acid, 1,3-propanediol, and alkyne-functionalized serinol is synthesized via melt condensation. A low-power UV lamp triggers the cross-linking rapidly via thiol-yne click chemistry. The cross-linking behavior is studied by photorheology and NMR spectroscopy. The resultant elastomer possesses mechanical properties similar to those of human soft tissues and exhibits in vitro degradability and good cytocompatibility.

The Plant Water Management Experiments, Marc Benjamin Wasserman

Dissertations and Theses

A simple means of watering plants in the low-g environment aboard orbiting spacecraft is not obvious. Since the beginning of spaceflight, numerous approaches have been pursued to water plants that seek to maximize plant viability and system reliability, while minimizing crew time and system complexity. The Plant Water Management experiments (PWM) seek to apply recent advances in low-gravity capillary fluidics to the challenges faced during plant growth operations aboard spacecraft. One primary challenge encountered in such applications is to establish Earth-like flows, minimizing the low-g specific adaptations required by the plants. This is difficult due to the fluid physics challenges …

Using Supervised Learning Algorithms As A Follow-Up Method In The Search Of Gravitational Waves From Core-Collapse Supernovae, Javier M. Antelis, Marco Cavaglia, Travis Hansen, Mannuel D. Morales, Claudia Moreno, Soma Mukherjee, Marek J. Szczepańczyk, Michele Zanolin

Physics & Astronomy Faculty Publications

We present a follow-up method based on supervised machine learning (ML) to improve the performance in the search of gravitational wave (GW) bursts from core-collapse supernovae (CCSNe) using the coherent WaveBurst (cWB) pipeline. The ML model discriminates noise from signal events by using a set of reconstruction parameters provided by cWB as features. Detected noise events are discarded yielding a reduction in the false alarm rate (FAR) and the false alarm probability thus enhancing the statistical significance. We tested the proposed method using strain data from the first half of the third observing run of advanced LIGO, and CCSNe GW …

Lattice Dynamics, Mechanical Properties, Electronic Structure And Magnetic Properties Of Equiatomic Quaternary Heusler Alloys Crticoz (Z = Al, Si) Using First Principles Calculations, Eesha Andharia, Hind Alqurashi, Bothina Hamad

Physics Faculty Publications and Presentations

First principles calculations are performed to investigate the thermodynamical stability, dynamical, mechanical, electronic and magnetic properties of CrTiCoZ (Z = Al/Si) novel quaternary Heusler alloys. A Y-type III atomic configuration is found to be the most stable structure for both compounds. The lattice constant values obtained using GGA-PBE approach are 5.9368 Å and 5.7853 Å for CrTiCoAl and CrTiCoSi, respectively. Using the value of elastic moduli for both the compounds, the computed Pugh’s ratio value is 2.5 and 2.7 for CrTiCoAl and CrTiCoSi, respectively, which is higher than 1.75, indicating both the compounds are ductile in nature. The melting temperatures …

Collision-Induced Dissociation And Ion Mobility Mass Spectrometry Of Au30(S-Tbu)18 Nanoclusters, Christopher Hood

Honors Theses

Collision Induced Dissociation (CID) and Ion Mobility Mass Spectrometry (IM-MS) are methods used to understand the structural arrangement and stability of large molecules. In this study, the gold nanocluster Au₃₀(S-tBu)₁₈ was dissociated at varying Trap collision energies, and drift time vs mass spectrometry data was plotted to determine the order of cluster fragmentation. Comparing Au₃₀(S-tBu)₁₈ data to that of Au₂₅(SCH₂CH₂Ph)₁₈, the only current nanocluster published with IM-MS data, two distinctly different dissociation patterns were seen. Unlike the linear CID fragmentation of Au …

Search For Electroweak Production Of Charginos And Neutralinos In Proton-Proton Collisions At √S = 13 Tev, A. Tumasyan

Department of Physics and Astronomy: Faculty Publications

A direct search for electroweak production of charginos and neutralinos is presented. Events with three or four leptons, with up to two hadronically decaying τ leptons, or two same-sign light leptons are analyzed. The data sample consists of 137 fb⁻¹ of proton-proton collisions with a center of mass energy of 13TeV, recorded with the CMS detector at the LHC. The results are interpreted in terms of several simplified models. These represent a broad range of production and decay scenarios for charginos and neutralinos. A parametric neural network is used to target several of the models with large backgrounds. In …

The Ecology And Evolution Of Phenotypic Plasticity: Insights From Amphibians, Rick Relyea

Sustainability Seminar Series

Nearly every species on the planet exhibits traits that are the product of the genes they possess and the environments in which they live. Dr. Relyea will examine the ecological and evolutionary insights from more than two decades of studying amphibians as a model system, including the many different predator, competitor, and contaminant environments that induce changes in behavior, morphology, and life history. He will also explore the phylogenetic patterns in how plastic traits have evolved, including how traits and trait plasticities can exhibit dramatically different evolutionary patterns.

Urban Forests And Their Potential To Combat Food Insecurity: Analyzing Street Trees In Baltimore, Md For Their Edibility, Victoria Bearden

Environment and Sustainability Honors Papers

Food insecure environments, in which residents lack consistent access to nutritious food materials, can occur in urban settings. Literature on urban forests suggests that trees can provide a range of provisioning ecosystem services, including edible uses. We consider this to determine if street trees in Baltimore, Maryland have the potential to provide nutritious food materials to address food insecurity in Healthy Food Priority Areas (HFPA), designated by Johns Hopkins Center for a Livable Future. Our analysis utilizes the Plants For a Future database and the geospatial hotspot analysis tool in Esri’s ArcMap to determine the edible quality ratings (EQR) of …

A Descriptive Pilot Study On Travel Nurses' Risk Of Burnout During The Covid- 19 Pandemic, Lashanda Head

ATU Theses and Dissertations 2021 - Present

Burnout is a state of emotional, physical, and mental exhaustion that results from long-term involvement in work situations that are difficult (Schaufeli & Greenglass, 2001). Burnout leads to a significant occupational problem in various professions that involve people who work with others, including nurses who work with COVID- 19 patients. This pilot study aims to determine if travel nurses who have worked or are currently working during the COVID-19 pandemic in acute care hospitals are at increased risk for nurse burnout. A convenience sample (N=9) of travel nurses working at CHRISTUS St Michael Health System were asked to …

Fighting Food Insecurity In New York City: What Role For Street Trees?, Kristen Cooney

Environment and Sustainability Honors Papers

There is growing recognition that urban forests have the potential to combat food insecurity via their edible parts, namely fruits, berries, and nuts. I researched New York City’s street trees, by locating trees with edible parts within food insecure communities, to analyze this potential.

The Geology Of The Mt. Simon Sandstone Storage Complex At The Wabash #1 Well, Vigo Co., Indiana (Subtask 7.2, Technical Report), Jared T. Freiburg, Franck Delpomdor, John H. Mcbride, Hannes E. Leetaru, David H. Malone, Nate Grigsby, Mansour Khosravi, Scott Frailey, James R. Damico, Charles Monson, Zohreh Askari, Yaghoob Lasemi, Donna Willette, Oladipupo Babarinde, Chris Korose, Mingyue Yu, Lauren Gardiner

Faculty Publications - Geography, Geology, and the Environment

The Wabash CarbonSAFE project drilled the Wabash #1 stratigraphic test well (ID# 168045) at the Wabash Valley Resources (WVR) IGCC facility in Vigo County, Indiana, to characterize and evaluate the basal Cambrian Mt. Simon Sandstone for commercial-scale CO2 storage near the site. This report presents an extensive geologic characterization of the Mt. Simon storage complex and relevant data collected from the Wabash #1 well, such as lithologic data collected from cuttings and core, geophysical logging, geomechanical analysis of core samples, and well testing and fluid sampling within the Mt. Simon Sandstone. The Mt. Simon storage complex comprises two major sections: …

Analytical Study To Determine Significant Causes Of Increased No-Hitters In The 2021 Major League Baseball Season, Joel Robison

Honors Projects

Why were there so many no-hitters in the 2021 MLB season? This project focuses on possible significant causes to the record-breaking number of no-hitters pitched in the 2021 Major League Baseball season. Specifically, this project takes an analytical look at the recent trends in launch angles and spin rates to determine if there are any significant causes to the increased number of no-hitters in baseball. The random nature and unpredictability of the game of baseball make it almost impossible to come to any solid conclusions.