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Articles 60721 - 60750 of 294419
Full-Text Articles in Physical Sciences and Mathematics
Coastal Sediment Response To The Diel Oxygen Cycle, Kara Gadeken
Coastal Sediment Response To The Diel Oxygen Cycle, Kara Gadeken
Graduate Theses and Dissertations (2019 - present)
Shallow coastal sediments are sites of intense respiration and organic matter breakdown. Macroinfauna bioturbate and bioirrigate sediments which supplies microbes with oxygen and newly deposited organic material from surface sediments, facilitating microbial remineralization of organic matter. These processes depend heavily on the concentration of dissolved oxygen in overlying water. Shallow water oxygen patterns often follow a diel cycle as dissolved oxygen decreases at night due to respiration and then increases during the day with photosynthesis, creating recurring suboxic conditions that are potentially stressful to organisms. Sediment oxygen flux is known to depend on ambient dissolved oxygen concentration, but behavioral responses …
Enhancing System Security Using Dynamic Hardware, Sydney L. Davis
Enhancing System Security Using Dynamic Hardware, Sydney L. Davis
Graduate Theses and Dissertations (2019 - present)
Within the ever-advancing field of computing, there is significant research into the many facets of cyber security. However, there is very little research to support the concept of using a Field Programmable Gate Array (FPGA) to increase the security of a system. While its most common use is to provide efficiency and speedup of processes, this research considers the use of an FPGA to mitigate vulnerabilities in both software and hardware. This paper proposes circuit variance within an FPGA as a method of Moving Target Defense (MTD) and investigates its effect on side-channels. We hypothesize that although the functionality of …
Synthesis And Characterization Of Ternary Pt Nanoally Catalysts For Fuel Cells, Ylith Peck
Synthesis And Characterization Of Ternary Pt Nanoally Catalysts For Fuel Cells, Ylith Peck
Undergraduate Honors Theses
A hydrogen fuel cell is an electrochemical device that converts oxygen and hydrogen into electrical energy while producing water as the only by-product, which has attracted growing interest, especially in the automotive industry. This technology is efficient and has zero pollution to the environment, in contrast to the direct use of fossil fuels in combustion engines which produce pollution and greenhouse gas emissions. One of the key components for hydrogen fuel cells is the catalyst that operates at the cathode, which currently use platinum. Due to the scarce amount of platinum in the world, the manufacturing cost for fuel cells …
Investigation Of The Binding Domain Interfaces Of The C-Terminus Of The Albino3 Insertase And The 43kda Chloroplast Signal Recognition Particle Subunit Via Single Molecule Förster Resonance Energy Transfer, Amanda Tomanek
Chemistry & Biochemistry Undergraduate Honors Theses
Fluorescent labeling is a technique used for visualizing functional groups contained in biomolecules by fluorescence imaging. This technique was used in this project to analyze post-translational targeting of light-harvesting chlorophyll-binding proteins (LHCP), which are the core complexes that harvest sunlight to drive photosynthetic electron transfer. This protein is synthesized in the cytosol and post-translationally targeted to the stroma of chloroplasts. CpSRP43 is a signal recognition particle (SRP) subunit unique to chloroplasts, which has been shown to interact with the stroma-soluble C-terminus of the thylakoid-bound Albino3 insertase (Alb3-Cterm). In the chloroplast stroma, targeting to thylakoids is performed via the cpSRP pathway …
Diffusion Of A Salt In An Aqueous Media, Aldaly Pineda Hernandez
Diffusion Of A Salt In An Aqueous Media, Aldaly Pineda Hernandez
Chemical Engineering Undergraduate Honors Theses
Diffusion is defined as the net transfer of a molecule from a high concentration region to a low concentration region. The concept of diffusion is used in a very important process called "desalination." Desalination is a separation process used to reduce the salt content dissolved in brackish water to make it suitable for human consumption, irrigation, and industrial use.
In desalination plants, it is important to monitor the constantly changing salt content of water, partly due to the diffusive effect. The main purpose of this experiment was to study the diffusion of NaCl in water at two NaCl concentrations. The …
The Effect Of Changing Land Use On Streamflow Statistics And Flood Flows Across Select Gages In Northwest Arkansas, Timothy Mcmullen
The Effect Of Changing Land Use On Streamflow Statistics And Flood Flows Across Select Gages In Northwest Arkansas, Timothy Mcmullen
Civil Engineering Undergraduate Honors Theses
Since 1901, heavy rainfall events have increased in the United States in both intensity and frequency, and population in the United States has increased, resulting in significant land use changes. Both of these trends could explain an increase in observed flood magnitude and frequency. In order to determine if a relationship exists between land use/land cover and changing stream flows in northwest Arkansas, this study analyzed temporal changes in various flow statistics for fourteen stream gages and compared the rates of change in flow statistics from gages on streams with watersheds that have varying land uses, i.e. urban, agricultural, and …
The Impact Of Inclination-Dependent Attenuation On Ultraviolet Star Formation Rate Tracers, Keith Doore, Rafael T. Eufrasio, Bret D. Lehmer, Erik B. Monson, Antara Basu-Zych, Kristen Garofali
The Impact Of Inclination-Dependent Attenuation On Ultraviolet Star Formation Rate Tracers, Keith Doore, Rafael T. Eufrasio, Bret D. Lehmer, Erik B. Monson, Antara Basu-Zych, Kristen Garofali
Physics Faculty Publications and Presentations
We examine and quantify how hybrid (e.g., UV+IR) star formation rate (SFR) estimators and the AFUV–β relation depend on inclination for disk-dominated galaxies using spectral energy distribution modeling that utilizes the inclination-dependent attenuation curves described in Doore et al. We perform this analysis on a sample of 133 disk-dominated galaxies from the CANDELS fields and 18 disk galaxies from the Spitzer Infrared Nearby Galaxies Survey and Key Insights on Nearby Galaxies: A Far-Infrared Survey with Herschel samples. We find that both the hybrid SFR estimators and the AFUV–β relation present clear dependencies on inclination. To quantify …
Hands-On Stem: Chemistry, Physics, And Other Science Resources For K-12 Education, Lisa Ahlberg, G. Brendan Cross
Hands-On Stem: Chemistry, Physics, And Other Science Resources For K-12 Education, Lisa Ahlberg, G. Brendan Cross
Faculty Publications
No abstract provided.
Relative Palatability And Efficacy Of Brodifacoum-25d Conservation Rodenticide Pellets For Mouse Eradication On Midway Atoll, Peter J. Kappes, Shane R. Siers, Israel L. Leinbach, Robert T. Sugihara, Wesley J. Jolley, Jonathan H. Plissner, Elizabeth N. Flint, Kelly L. Goodale, Gregg R. Howald
Relative Palatability And Efficacy Of Brodifacoum-25d Conservation Rodenticide Pellets For Mouse Eradication On Midway Atoll, Peter J. Kappes, Shane R. Siers, Israel L. Leinbach, Robert T. Sugihara, Wesley J. Jolley, Jonathan H. Plissner, Elizabeth N. Flint, Kelly L. Goodale, Gregg R. Howald
United States Department of Agriculture Wildlife Services: Staff Publications
Invasive mice (Mus spp.) can negatively impact island species and ecosystems. Because fewer island rodent eradications have been attempted for mice compared to rats (Rattus spp.), less is known about efficacy and palatability of rodenticide baits for mouse eradications. We performed a series of bait acceptance and efficacy cage trials using a standard formulation of brodifacoum-based rodenticide on wild-caught mice from Sand Island, Midway Atoll, to help inform a proposed eradication there. Mice were offered ad libitum brodifacoum pellets along with various alternative food sources, and a “no choice” treatment group received only bait pellets. Mortality in the no choice …
Simple Groups And Related Topics, Simrandeep Kaur
Simple Groups And Related Topics, Simrandeep Kaur
Electronic Theses, Projects, and Dissertations
Since every nonabelian simple group is a homomorphic image of an involutory progenitor 2^(*n):N where N ≤ S_n is transitive, our motivation for the thesis has been to seek finite homomorphic images of such progenitors and construct them using our technique of double coset enumeration. We have constructed U_3 (3):2 over 5^2:S_3, 2x(A_5 x A_5) over D_5 x D_5, S_6 over S_5, 2^5:S_5 over S_5, and 3^3: 2^3 over 3^2:2 . We have discovered original symmetric presentations numerous group as homomorphic images various progenitors. We have also found new monomial representations of groups and given monomial progenitors. We have given …
Lexglue: A Benchmark Dataset For Legal Language Understanding In English, Ilias Chalkidis, Abhik Jana, Dirk Hartung, Michael Bommarito, Ion Androutsopoulos, Daniel Katz, Nikolaos Aletras
Lexglue: A Benchmark Dataset For Legal Language Understanding In English, Ilias Chalkidis, Abhik Jana, Dirk Hartung, Michael Bommarito, Ion Androutsopoulos, Daniel Katz, Nikolaos Aletras
Research Collection Yong Pung How School Of Law
Lawsandtheirinterpretations, legal arguments and agreements are typically expressed in writing, leading to the production of vast corpora of legal text. Their analysis, which is at the center of legal practice, becomes increasingly elaborate as these collections grow in size. Natural language understanding (NLU) technologies can be a valuable tool to support legal practitioners in these endeavors. Their usefulness, however, largely depends on whether current state-of-the-art models can generalize across various tasks in the legal domain. To answer this currently open question, we introduce the Legal General Language Understanding Evaluation (LexGLUE) benchmark, a collection of datasets for evaluating model performance across …
Fabrication And Characterization Of Superparamagnetic Nickel Ferrite Ferrofluid, D. Karthickraja, S. Karthi, G. Ajith Kumar, D. K. Sardar, Gamage Chamath Dannangoda, Karen S. Martirosyan, Niroj Kumar Sahu, M. Prasath, R. Arunima, E. L. Girija
Fabrication And Characterization Of Superparamagnetic Nickel Ferrite Ferrofluid, D. Karthickraja, S. Karthi, G. Ajith Kumar, D. K. Sardar, Gamage Chamath Dannangoda, Karen S. Martirosyan, Niroj Kumar Sahu, M. Prasath, R. Arunima, E. L. Girija
Physics & Astronomy Faculty Publications
Because of their unique magnetic characteristics, magnetic nanoparticles are being used in various applications. We used a two-step method to create nickel ferrite ferrofluid in this study. The first step included hydrothermal preparation of oleic acid-capped nickel ferrite nanoparticles, followed by surface functionalization of the particles with citric acid, which made the nanoparticles hydrophilic. The materials' phase purity, functional groups, and magnetic behaviour were investigated. The production of mono-dispersed spherical nanoparticles with an average diameter of 9 ± 3.6 nm was shown by TEM images. With a blocking temperature of 53 K, ZFC-FC measurements verified the sample's …
Hybrid Machine And Deep Learning-Based Cyberattack Detection And Classification In Smart Grid Networks, Adedayo Aribisala
Hybrid Machine And Deep Learning-Based Cyberattack Detection And Classification In Smart Grid Networks, Adedayo Aribisala
Electronic Theses and Dissertations
Power grids have rapidly evolved into Smart grids and are heavily dependent on Supervisory Control and Data Acquisition (SCADA) systems for monitoring and control. However, this evolution increases the susceptibility of the remote (VMs, VPNs) and physical interfaces (sensors, PMUs LAN, WAN, sub-stations power lines, and smart meters) to sophisticated cyberattacks. The continuous supply of power is critical to power generation plants, power grids, industrial grids, and nuclear grids; the halt to global power could have a devastating effect on the economy's critical infrastructures and human life.
Machine Learning and Deep Learning-based cyberattack detection modeling have yielded promising results when …
Finding A Representative Distribution For The Tail Index Alpha, Α, For Stock Return Data From The New York Stock Exchange, Jett Burns
Electronic Theses and Dissertations
Statistical inference is a tool for creating models that can accurately display real-world events. Special importance is given to the financial methods that model risk and large price movements. A parameter that describes tail heaviness, and risk overall, is α. This research finds a representative distribution that models α. The absolute value of standardized stock returns from the Center for Research on Security Prices are used in this research. The inference is performed using R. Approximations for α are found using the ptsuite package. The GAMLSS package employs maximum likelihood estimation to estimate distribution parameters using the CRSP data. The …
Community Structure Analysis Of Mammals Found At The Gray Fossil Site, Tn, Sarah Clark
Community Structure Analysis Of Mammals Found At The Gray Fossil Site, Tn, Sarah Clark
Electronic Theses and Dissertations
The early Pliocene Gray Fossil Site (GFS) is a biodiverse site with a unique faunal assemblage that represents one of few sites of its age in eastern North America. A community structure analysis of the mammals at GFS was done to characterize species and better understand the paleoenvironment. Data and was gathered from twenty modern communities and five late Neogene sites to compare with GFS. Species from these 26 sites were categorized by body size, locomotor mode, cheek tooth crown height, and diet to characterize niches occupied. Descriptive statistics contrasted proportions of species within categories across communities. Discriminant function analyses …
Water Quality Assessment Of Karst Spring Water As A Private Water Supply Source In Northeast Tennessee, Lukman Fashina
Water Quality Assessment Of Karst Spring Water As A Private Water Supply Source In Northeast Tennessee, Lukman Fashina
Electronic Theses and Dissertations
Karst springs are an essential source of private water supply for about 10% of households in Tennessee. However, these springs, which can be easily polluted, are unregulated. This study, therefore, assesses water quality spatial patterns and water quality rating of roadside springs in northeast Tennessee.
Karst spring water samples collected from 50 springs were assessed using EPA Standard methods for pathogens, nutrients, radon, and physicochemical parameters. Springs generally met federal and state standards for physicochemical parameters, 90% of samples contained E. coli, and all samples contained fecal coliform. High E. coli was spatially clustered causing a fecal contamination hot …
Numerical Study Of Cahn-Hilliard Equations, Oula Khouzam
Numerical Study Of Cahn-Hilliard Equations, Oula Khouzam
Open Access Theses & Dissertations
In this thesis we study the well-known first-order Eyre's convex splitting numerical scheme for solving the Cahn-Hilliard equation and theoretically prove and numerically demonstrate the key properties of the scheme namely: mass conservation, unique solvability and unconditional stability. While the convex splitting scheme has been around for over two decades, explicit proofs for these important properties for the fourth order Cahn-Hillard equation are not directly available in the existing literature. This thesis aims to bridge this gap by providing the complete proofs of the aforementioned key properties of the scheme and numerically demonstrating the performance of the scheme.
A Central Compact Hybrid-Variable Method With Spectral-Like Resolution, Md Mahmudul Hasan
A Central Compact Hybrid-Variable Method With Spectral-Like Resolution, Md Mahmudul Hasan
Open Access Theses & Dissertations
Numerical methods for hyperbolic conservation laws have been a driving force for theresearch in scientific computing and simulation science in the past decades, as many physical, biological, and engineering systems are governed by these equations, such as fluid mechanics, tumor growth, and virtual wind tunnel simulations. Despite the existence of many schemes in the literature, people have never stopped searching for more accurate and efficient methods for these problems. Indeed, the increasing complexity of systems in emerging applications demands better resolution of sub-grid scale phenomenon whereas classical methods usually fail to deliver high-fidelity simulation results of such systems within realistic …
Exploring Tunable Magnetization And High-Temperature Ferromagnetism In Ternary Transition Metal-Based Chalcogenides, Hector Iturriaga
Exploring Tunable Magnetization And High-Temperature Ferromagnetism In Ternary Transition Metal-Based Chalcogenides, Hector Iturriaga
Open Access Theses & Dissertations
The discovery of long-range magnetic ordering in ultrathin transition metal-based compounds shows great promise for the development of nanoscale memory and spintronic devices. Composed of cost-effective materials and boasting from strong chemical and thermal stability at low dimensions, van der Waals (vdW) ternary transition metal chalcogenide magnets like CrSiTe3 (CST), Fe2.7GeTe2 (FGT), and Mn3Si2Te6 (MST), provide not only possible energy solutions, but also a broad platform to explore the versatile magnetic character of this family of compounds. Although they have great potential, it has been found that their long-range magnetic ordering exists at temperatures far too low (the highest of …
Characterization And Evolution Of The Professor Valley Pennsylvanian Salt Body (Paradox Basin, Ut) Using Gravity And Magnetotellurics, Derek Scott
Open Access Theses & Dissertations
Syndepositional halokinetic movement of the Pennsylvanian Paradox Formation in the Paradox Basin, UT & CO behaved as a control over the development of depositional systems during the Late Paleozoic and early Mesozoic periods (Trudgill, 2011). Understanding the controls on halokinetic evolution in the area serves as an invaluable outcrop analogue for similar subsurface salt bodies in petroleum-bearing basins and provides key insights for hydrocarbon exploration in salt basins world wide. Professor Valley, located 15 miles Northeast of Moab, UT is situated between the Fisher Valley (Onion Creek) and Cache/Salt Valley salt walls. It includes an anomalous, isolated 0.5 km² outcrop …
Grid-Connected Renewable Energy Systems For Residential Hvac Load Management, Oscar Samuel Acosta
Grid-Connected Renewable Energy Systems For Residential Hvac Load Management, Oscar Samuel Acosta
Open Access Theses & Dissertations
With an ongoing mission of utility operators to maintain a resilient and reliable power grid in the face of continuously increasing load demand, it is essential that advancements be made in developing both technology and methodology to help account for the increasing energy requirements. According to the U.S. Department of Energy (DOE) and Energy Information Administration (EIA), the residential end-use sector alone counted for 22% of all electricity used in the U.S. in 2020. Of this, approximately 32% of household electricity load is the direct result of air conditioning and space heating units (HVAC). One way to account for this …
Rational Design Of Composite Nanomaterials For Water Treatment Applications, Mariana Marcos-Hernandez
Rational Design Of Composite Nanomaterials For Water Treatment Applications, Mariana Marcos-Hernandez
Open Access Theses & Dissertations
Water quantity and quality have been affected in communities all around the world due to population growth, pollution, changes in land use, and climate change. In order to cope with existing and anticipated water demands and shortages, the use of treated or reclaimed water is an ongoing alternative that has helped communities all over the world address this problem. The adaptation of nanotechnology to traditional water and wastewater treatment processes offers new opportunities in technological developments. Unique size-dependent properties such as: high surface to mass ratio, high reactivity, high sorption capacities, fast dissolution, superparamagnetism, among others, provide high-tech efficient materials …
Mathematical Modeling Of Potassium Modulated Viral Infection, Zaira Elizabeth Mather
Mathematical Modeling Of Potassium Modulated Viral Infection, Zaira Elizabeth Mather
Open Access Theses & Dissertations
In recent years, there is a growing interest in the investigation of using potassium to treat virus infections. In the region of infection, there is a biological observation of extracel- lular potassium level being typically very low whereas the intracellular potassium levels are much higher. There are numerous biological studies showing that elevated potassium levels in the extracellular membrane tends to block virus infections. A recent effort in this direction is a collaborative research conducted by mathematicians and biologists from the University of Texas at El Paso, New Mexico State University, and the University of New Mexico, where we develop …
Game-Theoretic Deception Modeling For Distracting Network Adversarie, Mohammad Sujan Miah
Game-Theoretic Deception Modeling For Distracting Network Adversarie, Mohammad Sujan Miah
Open Access Theses & Dissertations
In this day and age, adversaries in the cybersecurity space have become alarmingly capable of identifying network vulnerabilities and work out various targets to attack where deception is becoming an increasingly crucial technique for the defenders to delay these attacks. For securing computer networks, the defenders use various deceptive decoy objects to detect, confuse, and distract attackers. By trapping the attackers, these decoys gather information, waste their time and resources, and potentially prevent future attacks. However, we have to consider that an attacker with the help of smart techniques may detect the decoys and avoid them. One of the well-known …
Evolution Of The Magnetic Properties On Van Der Waals Layered Magnets Via Pressure And Proton Irradiation, Rubyann Olmos
Evolution Of The Magnetic Properties On Van Der Waals Layered Magnets Via Pressure And Proton Irradiation, Rubyann Olmos
Open Access Theses & Dissertations
Probing the magnetism in quasi two-dimensional materials has the potential in driving their properties towards future use in spin electronic based devices. Studying such layered magnets will enable the scientific community to uncover tunable exotic phases such as superconductivity, quantum paramagnetism, etc. This work examines the influence of two types of external perturbations, namely, the pressure and proton irradiation, on the magnetic properties of several compounds in the van der Waals crystal family.
Pressure has been found to induce structural and magnetic phase transitions in many of these materials. Using hydrostatic pressure as a disorderless approach to manipulate the interlayer …
Material Synthesis And Machine Learning For Additive Manufacturing, Jaime Eduardo Regis
Material Synthesis And Machine Learning For Additive Manufacturing, Jaime Eduardo Regis
Open Access Theses & Dissertations
The goal of this research was to address three key challenges in additive manufacturing (AM), the need for feedstock material, minimal end-use fabrication from lack of functionality in commercially available materials, and the need for qualification and property prediction in printed structures. The near ultraviolet-light assisted green reduction of graphene oxide through L-ascorbic acid was studied with to address the issue of low part strength in additively manufactured parts by providing a functional filler that can strengthen the polymer matrix. The synthesis of self-healing epoxy vitrimers was done to adapt high strength materials with recyclable properties for compatibility with AM …
Context Dependence Of Warming Induced Shifts In Alpine Soil Microbial Functions, Sydne Rose Spinella
Context Dependence Of Warming Induced Shifts In Alpine Soil Microbial Functions, Sydne Rose Spinella
Open Access Theses & Dissertations
Atmospheric warming is occurring due to anthropogenic release of carbon dioxide. Climate change has the potential to increase microbial activity in soil, where a significant amount of terrestrial carbon is stored, which may lead to release of this soil carbon into the atmosphere, positively feeding back to global temperature rise. Understanding how the indirect impacts of climate warming, like shifts in plant community composition, affect soil microbes can improve predictions of ecosystem functions and services under climate change. This project examined direct and indirect consequences of warming on microbial processes using independent and combined treatments of experimental warming and dominant …
Integration Of Genetic Isothermal Amplification On Low-Cost Hybrid Paper/Polymer Microfluidic Biochips For High Sensitivity Point-Of-Care Disease Diagnosis, Hamed Tavakoli
Open Access Theses & Dissertations
Infectious diseases and cancer have been two main causes of global death and disability, leading to a significant impact on public health and economies globally. Early diagnosis of these diseases can improve prevention, treatment, and prognosis in clinical practice. However, current laboratory diagnostic approaches require expensive and bulky equipment, well-trained personnel, and time-consuming processes, which puts a great challenge to conventional methods to address, especially in resource-limited settings. Microfluidic lab-on-a-chip presents a unique opportunity for various biomedical applications due to multiple advantages such as low reagent consumption, integration, miniaturization, portability, and automation. Since different microfluidic platform substrates have their advantages …
Developing And Applying Computational Algorithms To Reveal Health-Related Biomolecular Interactions, Yixin Xie
Developing And Applying Computational Algorithms To Reveal Health-Related Biomolecular Interactions, Yixin Xie
Open Access Theses & Dissertations
Computational biology is an interdisciplinary area that applies computational approaches in biological big data, including protein amino acid sequences, genetic sequences, etc., which is widely used to analyze protein-protein interactions, make predictions in drug discovery, develop vaccines, etc. Popular methods include mathematical modeling, molecular dynamics simulations, data science mythology, etc. With the help of computational algorithms and applications, drug development is much faster than traditional processes, as it reduces risks early on in a drug discovery process and helps researchers select target candidates that have the highest potential for success. In my doctoral research, I applied multi-scale computational approaches to …
Single Particle Electrochemical Oxidation Of Polyvinylpyrrolidone-Capped Silver Nanospheres, Nanocubes, And Nanoplates In Potassium Nitrate And Potassium Hydroxide Solutions, Jazlynn C. Sikes, Isabelle I. Niyonshuti, Kannasoot Kanokkanchana, Jingyi Chen, Kristina Tschulik, Ingrid Fritsch
Single Particle Electrochemical Oxidation Of Polyvinylpyrrolidone-Capped Silver Nanospheres, Nanocubes, And Nanoplates In Potassium Nitrate And Potassium Hydroxide Solutions, Jazlynn C. Sikes, Isabelle I. Niyonshuti, Kannasoot Kanokkanchana, Jingyi Chen, Kristina Tschulik, Ingrid Fritsch
Chemistry & Biochemistry Faculty Publications and Presentations
Single particle electrochemical oxidation of polyvinylpyrrolidone-capped silver nanoparticles at a microdisk electrode is investigated as a function of particle shape (spheres, cubes, and plates) in potassium nitrate and potassium hydroxide solutions. In potassium nitrate, extreme anodic potentials (≥ 1500 mV vs Ag/AgCl (3 M KCl)) are necessary to achieve oxidation, while lower anodic potentials are required in potassium hydroxide (≥ 900 mV vs Ag/AgCl (saturated KCl)). Upon oxidation, silver oxide is formed, readily catalyzing water oxidation, producing a spike-step current response. The spike duration for each particle is used to probe effects of particle shape on the oxidation mechanism, and …