Physical Sciences and Mathematics Commons^™

High Performance Liquid Chromatography Monitoring Reaction Kinetics, Ken Overway, Mary Ruth Shifflett

Chemistry Faculty Scholarship

To develop a chromatographic method to characterize enantioselective kinetics, the reaction between aromatic aldehydes and ephedrine will be monitored with High Performance Liquid Chromatography (HPLC). First, develop kinetics analysis procedure with the HPLC, the decomposition of aspartame was observed with citrate and phosphate buffers. The procedure produced an activation energy in the presence of phosphate buffer of 71.9 kJ/mol with a -0.126 % error. The aromatic aldehyde, benzaldehyde, and ephedrine were run through a stereospecific column to separate peaks with various mobile phases. A more nonpolar mobile phase is required for better peak and retention time separation.

First Test Of Lepton Flavor Universality In The Charmed Baryon Decays Ωc0 → Ω-ℓ+Νℓ Using Data Of The Belle Experiment, Y. B. Li, C. P. Shen, I. Adachi, H. Aihara, S. Al Said, D. M. Asner, H. Atmacan, T. Aushev, R. Ayad, V. Babu, S. Bahinipati, P. Behera, K. Belous, J. Bennett, F. Bernlochner, M. Bessner, B. Bhuyan, T. Bilka, A. Bobrov

Faculty and Student Publications

We present the first observation of the ωc0→ω-μ+νμ decay and present measurements of the branching fraction ratios of the ωc0→ω-ℓ+νℓ decays compared to the reference mode ωc0→ω-π+, (ℓ=e or μ). This analysis is based on 89.5 fb-1, 711 fb-1, and 121.1 fb-1 data samples collected with the Belle detector at the KEKB asymmetric-energy e+e- collider at the center-of-mass energies of 10.52 GeV, 10.58 GeV, and 10.86 GeV, respectively. The ωc0 signal yields are extracted by fitting Mωℓ and Mωπ spectra. The branching fraction ratios B(ωc0→ω-e+νe)/B(ωc0→ω-π+) and B(ωc0→ω-μ+νμ)/B(ωc0→ω-π+) are measured to be 1.98±0.13(stat)±0.08(syst) and 1.94±0.18(stat)±0.10(syst), respectively. The ratio of B(ωc0→ω-e+νe)/B(ωc0→ω-μ+νμ) is …

Nessie Notation: A New Tool In Sequential Substitution Systems And Graph Theory For Summarizing Concatenations, Colton Davis

Student Research

While doing research looking for ways to categorize causal networks generated by Sequential Substitution Systems, I created a new notation to compactly summarize concatenations of integers or strings of integers, including infinite sequences of these, in the same way that sums, products, and unions of sets can be summarized. Using my method, any sequence of integers or strings of integers with a closed-form iterative pattern can be compactly summarized in just one line of mathematical notation, including graphs generated by Sequential Substitution Systems, many Primitive Pythagorean Triplets, and various Lucas sequences including the Fibonacci sequence and the sequence of square …

Comparing Composite Severe Weather Indices Of Thunderstorm Activity On Sea-Breeze And Non-Sea-Breeze Days In The Mobile, Alabama Area, Elizabeth Seiler

Poster Presentations

Poster for the Honors Thesis project.

Sea breezes (SB) occur frequently from May through October along the U.S. Gulf of Mexico Coast. One reason why SBs interest forecasters is their ability to spawn summertime thunderstorms, which can cause flash flooding, lightning, and hail. However, forecasting the exact timing and location of SB-driven convection can be challenging. This thesis will focus on Mobile and Baldwin Counties in southwest Alabama, which experience two types of phenomena – SBs along the Gulf of Mexico Coast and bay breezes on either side of Mobile Bay. Over the past years, multiple undergraduate students have analyzed …

Computational Approaches To Facilitate Automated Interchange Between Music And Art, Rao Hamza Ali

Computational and Data Sciences (PhD) Dissertations

Recently, there has been a tremendous increase in generating and synthesizing music and art using various computational techniques. An area that is still under-researched, however, is how one medium can be converted into the other, while maintaining the overall aesthetics. Over the last few centuries, artists, composers, and scholars, have attempted to use substitute one form of art for the other: by proposing techniques where music notes are synonymous to colors, by inventing instruments that combine the aesthetics of music and visual art, and by incorporating the two media in live performances. A widely accepted computational approach, for the conversion, …

Social Science Research To Help Advance Regional Coordination And Collaboration Of Sea Level Rise Planning And Adaptation On Humboldt Bay, Kristen Orth-Gordinier

Student Projects

Humboldt Bay is experiencing the fastest rate of relative sea level rise in California and is likely to experience severe sea level rise (SLR) flooding within the next two decades. The Humboldt Bay shoreline is owned and governed by a patchwork of entities with different missions and jurisdictions so coordination of SLR planning will be critical because flooding of hydrologic areas from tidal waters can cross political boundaries. The goal of this project was to conduct social science research that can inform and advance the development of regional coordination and collaboration related to SLR in Humboldt Bay. To do this, …

Synthesis, Characterization, And Functionality Of Novel 2d Material Sn3p2, Cory Stephenson

Physics Undergraduate Honors Theses

In recent years, two-dimensional (2D) materials have gained a lot of attention due to their potential applications in devices and their promise to revolutionize technology. In our group, we are capable of synthesizing such materials and study their properties. I have discovered a new material of the tin-phosphorus family that displays the 2D layered structure and therefore shows potential to be used in future devices due to this reduced dimensionality from the typical three-dimensional counterpart. This 2D structure may allow for new phenomena to emerge as there is no longer any interatomic interactions along the z- axis. Under this motivation, …

Monitoring The M-Dwarf Host Stars Of Tess Exoplanet Candidates: Stellar Flares And Habitability, Ashley Lieber

Physics Undergraduate Honors Theses

In the search for life beyond our solar system, the study of M-dwarfs has become increasingly important due to their unique characteristics including their small size, flaring capabilities, and long lifespans. Their small size allows for exoplanet detection due to observable gravitational interactions, and the stellar flares could potentially trigger prebiotic life on exoplanets in the system. Lastly, their long lifespans may provide the conditions necessary to foster prebiotic life and the development of more complex organisms over time. Flare rate is a critical factor in determining the habitability of the exoplanet due to its potential to damage or incubate …

Forecasting Razorback Baseball Game Outcomes, Austin Raabe

Information Systems Undergraduate Honors Theses

Despite the disappointing end to the 2021 Arkansas Razorback baseball year, the team’s success provided hog fans something to look forward to next season. While they will be without the 2021 Golden Spikes Award winner, Kevin Kopps, and four All-SEC team selections, the 2022 roster has promising new and returning talent. With fifty percent of the players who played significant time last year coming back (minimum ten hits or ten innings pitched), the arrival of several impact transfers from major conferences, and a recruiting class ranked in the top five according to Perfect Game, there is reason to believe that …

Spectral Signatures Of Hydrogen Thioperoxide (Hosh) And Hydrogen Persulfide (Hssh): Possible Molecular Sulfur Sinks In The Dense Ism, Charles Z. Palmer, Ryan C. Fortenberry, Joseph S. Francisco

Faculty and Student Publications

For decades, sulfur has remained underdetected in molecular form within the dense interstellar medium (ISM), and somewhere a molecular sulfur sink exists where it may be hiding. With the discovery of hydrogen peroxide (HOOH) in the ISM in 2011, a natural starting point may be found in sulfur-bearing analogs that are chemically similar to HOOH: hydrogen thioperoxide (HOSH) and hydrogen persulfide (HSSH). The present theoretical study couples the accuracy in the anharmonic fundamental vibrational frequencies from the explicitly correlated coupled cluster theory with the accurate rotational constants provided by canonical high-level coupled cluster theory to produce rovibrational spectra for use …

Search For Charged Lepton Flavor Violating Decays Of ϒ (1s), S. Patra, V. Bhardwaj, K. Trabelsi, I. Adachi, H. Aihara, S. Al Said, D. M. Asner, H. Atmacan, T. Aushev, R. Ayad, V. Babu, S. Bahinipati, P. Behera, K. Belous, J. Bennett, M. Bessner, B. Bhuyan, T. Bilka, A. Bobrov

Faculty and Student Publications

We present a search for the charged lepton-flavor-violating decays ϒ(1S) →ℓ±ℓ′∓ and radiative charged lepton-flavour-violating decays ϒ(1S) → γℓ±ℓ′∓ [ℓ,ℓ′ = e, μ, τ] using the 158 million ϒ(2S) sample collected by the Belle detector at the KEKB collider. This search uses ϒ(1S) mesons produced in ϒ(2S) → π+π− ϒ(1S) transitions. We do not find any significant signal, so we provide upper limits on the branching fractions at the 90% confidence level. [Figure not available: see fulltext.]

An Evaluation Of Security In Blockchain-Based Sharing Of Student Records In Higher Education, Timothy Arndt, Angela Guercio, Yonghun Chae

Information Systems

Blockchain has recently taken off as a disruptive technology, from its initial use in cryptocurrencies to wider applications in areas such as property registration and insurance due to its characteristic as a distributed ledger which can remove the need for a trusted third party to facilitate transactions. This spread of the technology to new application areas has been driven by the development of smart contracts – blockchain-based protocols which can automatically enforce a contract by executing code based on the logic expressed in the contract. One exciting area for blockchain is higher education. Students in higher education are ever more …

Teaching Assembly Programming Through Video Games, Kaden Ven Gryphon

Honors Capstone Projects and Theses

No abstract provided.

Length-Based Risk Analysis Of Management Options For The Southern Florida Usa Multispecies Coral Reef Fish Fishery, Jerald Ault, Steven G. Smith, Matthew W. Johnson, Laura Jay W. Grove, James A. Bohnsack, Gerard T. Dinardo, Caroline Mclaughlin, Nelson M. Ehrhardt, Vanessa Mcdonough, Michael P. Seki, Steven Miller, Jiangang Luo, Jeremiah Blondeau, Michael P. Crosby, Glenn Simpson, Mark E. Monaco, Clayton G. Pollock, Michael W. Feeley, Alejandro Acosta

Marine & Environmental Sciences Faculty Articles

Exploitation impacts and management options for 15 coral reef fish species central to the commercial and recreational fisheries of the southern Florida USA coral reef ecosystem were evaluated using a length-based risk analysis (LBRA) framework. Population abundance-at-length composition data were obtained from several regional federal-state sampling programs. These and updated life history demographic data were integrated into a length-based numerical cohort model to generate LBRA fishery sustainability metrics from a probabilistic perspective. Three of five groupers, eight of eight snappers, and two of two grunts were below the 40% spawning potential ratio (SPR) stock sustainability minimum; ten of these …

Gauging The State-Of-The-Art For Foresight Weight Pruning On Neural Networks, Noah James

Computer Science and Computer Engineering Undergraduate Honors Theses

The state-of-the-art for pruning neural networks is ambiguous due to poor experimental practices in the field. Newly developed approaches rarely compare to each other, and when they do, their comparisons are lackluster or contain errors. In the interest of stabilizing the field of pruning, this paper initiates a dive into reproducing prominent pruning algorithms across several architectures and datasets. As a first step towards this goal, this paper shows results for foresight weight pruning across 6 baseline pruning strategies, 5 modern pruning strategies, random pruning, and one legacy method (Optimal Brain Damage). All strategies are evaluated on 3 different architectures …

Fair Bankruptcy Solutions Under Interval Uncertainty, Uyen Pham, Olga Kosheleva, Vladik Kreinovich

Departmental Technical Reports (CS)

If the overall amount of the company's assets is smaller than its total debts, then a fair solution is to give, to each creditor, the amount proportional to the corresponding debt, e.g., 10 center for each dollar or 50 cents for each dollar. But what if the debt amounts are not known exactly, and for some creditors, we only know the lower and upper bounds on the actual debt amount? What division will be fair in such a situation? In this paper, we show that the only fair solution is to make payments proportional to an appropriate convex combination of …

How Probable Is A Revolution? A Natural Relu-Like Formula That Fits The Historical Data, Olga Kosheleva, Vladik Kreinovich

Departmental Technical Reports (CS)

In his recent book "Principles for Dealing with the Changing World Order", Ray Dalio considered many historical crisis situations, and came up with several data points showing how the probability of a revolution or a civil war depends on the number of economic red flags. In this paper, we provide a simple empirical formula that is consistent with these data points.

Shape Of An Egg: Towards A Natural Simple Universal Formula, Sofia Holguin, Vladik Kreinovich

Departmental Technical Reports (CS)

Eggs of different bird species have different shapes. There exists formulas for describing the usual egg shapes -- e.g., the shapes of chicken eggs. However, some egg shapes are more complex. A recent paper proposed a general formula for describing all possible egg shapes; however this formula is purely empirical, it does not have any theoretical foundations. In this paper, we use the theoretical analysis of the problem to provide an alternative -- theoretically justified -- general formula. Interestingly, the new general formula is easier to compute than the previously proposed one.

Freedom Of Will, Non-Uniqueness Of Cauchy Problem, Fractal Processes, Renormalization, Phase Transitions, And Stealth Aircraft, Miroslav Svitek, Olga Kosheleva, Vladik Kreinovich

Departmental Technical Reports (CS)

We all know that we can make different decisions, decisions that change -- at least locally -- the state of the world. This is what is known as freedom of will. On the other hand, according to physics, the future state of the world is uniquely pre-determined by its current state, so there is no room for freedom of will. How can we resolve this contradiction? In this paper, we analyze this problem, and we show that many physical phenomena can help resolve this contradiction: fractal character of equations, renormalization, phase transitions, etc. Usually, these phenomena are viewed as somewhat …

How To Estimate The Present Serviceability Rating Of A Road Segment: Explanation Of An Empirical Formula, Edgar Daniel Rodriguez Velasquez, Vladik Kreinovich

Departmental Technical Reports (CS)

An accurate estimation of the road quality requires a lot of expertise, and there is not enough experts to provide such estimates for all the road segments. It is therefore desirable to estimate this quality based on easy-to-estimate and easy-to-measure characteristics. Recently, an empirical formula was proposed for such an estimate. In this paper, we provide a theoretical explanation for this empirical formula.

Education In The Era Of Google, Wikipedia, And Deep Learning: Are We Humans Still Needed And If Yes For What?, Miroslav Svitek, Olga Kosheleva, Vladik Kreinovich

Departmental Technical Reports (CS)

One of the main purposes of education is to teach skills needed in future life and future jobs. What is important and what is useful changes with time. Before the industrial revolution, routine mechanical work was an important part of human activity – now machines can do it (and do it better). Before printing, copying was an important activity – now copy machines do it. Before computers, humans were needed for computing – now computer do it better. With Wikipedia and Google, there is not much need for scholars being erudite. Even extracting dependencies from data – one of the …

Economy-Related Emotional Attitudes Towards Other People: How Can We Explain Them?, Christopher Reyes, Vladik Kreinovich, Chon Van Le

Departmental Technical Reports (CS)

Research has shown that to properly understand people's economic behavior, it is important to take into account their emotional attitudes towards each other. Behavioral economics shows that different attitudes results in different economy-related behavior. A natural question is: where do these emotional attitudes come from? We show that, in principle, such emotions can be explained by people's objective functions. Specifically, we show it on the example of a person whose main objective is to increase his/her country's GDP: in this case, the corresponding optimization problem leads exactly to natural emotions towards people who contribute a lot or a little towards …

How Blockchain Solutions Enable Better Decision Making Through Blockchain Analytics, Sammy Ter Haar

Information Systems Undergraduate Honors Theses

Since the founding of computers, data scientists have been able to engineer devices that increase individuals’ opportunities to communicate with each other. In the 1990s, the internet took over with many people not understanding its utility. Flash forward 30 years, and we cannot live without our connection to the internet. The internet of information is what we called early adopters with individuals posting blogs for others to read, this was known as Web 1.0. As we progress, platforms became social allowing individuals in different areas to communicate and engage with each other, this was known as Web 2.0. As Dr. …

A Versatile Python Package For Simulating Dna Nanostructures With Oxdna, Kira Threlfall

Computer Science and Computer Engineering Undergraduate Honors Theses

The ability to synthesize custom DNA molecules has led to the feasibility of DNA nanotechnology. Synthesis is time-consuming and expensive, so simulations of proposed DNA designs are necessary. Open-source simulators, such as oxDNA, are available but often difficult to configure and interface with. Packages such as oxdna-tile-binding pro- vide an interface for oxDNA which allows for the ability to create scripts that automate the configuration process. This project works to improve the scripts in oxdna-tile-binding to improve integration with job scheduling systems commonly used in high-performance computing environments, improve ease-of-use and consistency within the scripts compos- ing oxdna-tile-binding, and move …

An Investigation Into, And The Construction Of, An Operable Windows Notifier, Grey Hixson

Computer Science and Computer Engineering Undergraduate Honors Theses

The Office of Sustainability at the University of Arkansas identified that building occupants that have control over operable windows may open them at inappropriate times. Windows opened in a building with a temperature and air differential leads to increased HVAC operating costs and building occupant discomfort. This led the Associate Vice Chancellor of Facilities at the University of Arkansas to propose the construction of a mobile application that a building occupant can use to make an informed decision before opening their window. I have formulated a series of research objectives in conjunction with the Director of the Office of Sustainability …

Demonstration Of Cyberattacks And Mitigation Of Vulnerabilities In A Webserver Interface For A Cybersecure Power Router, Benjamin Allen

Computer Science and Computer Engineering Undergraduate Honors Theses

Cyberattacks are a threat to critical infrastructure, which must be secured against them to ensure continued operation. A defense-in-depth approach is necessary to secure all layers of a smart-grid system and contain the impact of any exploited vulnerabilities. In this undergraduate thesis a webserver interface for smart-grid devices communicating over Modbus TCP was developed and exposed to SQL Injection attacks and Cross-Site Scripting attacks. Analysis was performed on Supply-Chain attacks and a mitigation developed for attacks stemming from compromised Content Delivery Networks. All attempted attacks were unable to exploit vulnerabilities in the webserver due to its use of input sanitization …

Analysis Of Gpu Memory Vulnerabilities, Jarrett Hoover

Computer Science and Computer Engineering Undergraduate Honors Theses

Graphics processing units (GPUs) have become a widely used technology for various purposes. While their intended use is accelerating graphics rendering, their parallel computing capabilities have expanded their use into other areas. They are used in computer gaming, deep learning for artificial intelligence and mining cryptocurrencies. Their rise in popularity led to research involving several security aspects, including this paper’s focus, memory vulnerabilities. Research documented many vulnerabilities, including GPUs not implementing address space layout randomization, not zeroing out memory after deallocation, and not initializing newly allocated memory. These vulnerabilities can lead to a victim’s sensitive data being leaked to an …

Using A Bert-Based Ensemble Network For Abusive Language Detection, Noah Ballinger

Computer Science and Computer Engineering Undergraduate Honors Theses

Over the past two decades, online discussion has skyrocketed in scope and scale. However, so has the amount of toxicity and offensive posts on social media and other discussion sites. Despite this rise in prevalence, the ability to automatically moderate online discussion platforms has seen minimal development. Recently, though, as the capabilities of artificial intelligence (AI) continue to improve, the potential of AI-based detection of harmful internet content has become a real possibility. In the past couple years, there has been a surge in performance on tasks in the field of natural language processing, mainly due to the development of …

Final Inversion Of The Midcontinent Rift During The Rigolet Phase Of The Grenvillian Orogeny, Mark D. Schmitz

Geosciences Faculty Publications and Presentations

Despite being a prominent continental-scale feature, the late Mesoproterozoic North American Midcontinent Rift did not result in the break-up of Laurentia, and subsequently underwent structural inversion. The timing of inversion is critical for constraining far-field effects of orogenesis and processes associated with the rift's failure. The Keweenaw fault in northern Michigan (USA) is a major thrust structure associated with rift inversion; it places ca. 1093 Ma rift volcanic rocks atop the post-rift Jacobsville Formation, which is folded in its footwall. Previous detrital zircon (DZ) U-Pb geochronology conducted by laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) assigned a ca. 950 Ma maximum …

Progression Magazine, 2022 Spring, Coastal Carolina University

Progression Magazine

Magazine of the College of Science at Coastal Carolina University.