Physical Sciences and Mathematics Commons^™

Cover Crops And Irrigation Impacts On Corn And Soybean Production In The Mid-Southern Usa, Dillon Aaron Russell

Theses and Dissertations

Reducing groundwater withdrawals from the Mississippi River Valley Alluvial Aquifer is imperative to sustain future irrigated cropping systems in the mid-southern USA. This research was conducted to determine the impacts of cover crops and irrigation sensor thresholds on corn (Zea mays L.) and soybean (Glycine max L.) production, water productivity, irrigation water use efficiency, and soil physical properties in the Mississippi Delta. The cover crop treatments included cereal rye (Secale cereale L.), hairy vetch (Vicia villosa R.), wheat (Triticum aestivum L.)-radish (Raphanus sativus L.)-turnip (Brassica rapa L.) mix, and no cover crop. The irrigation thresholds included -40 kPa, -90 kPa, …

Insights Into Molecular Recognition And Reactivity From Molecular Simulations Of Protein-Ligand Interactions Using Md And Qm/Mm, Jerrano L. Bowleg

Theses and Dissertations

In this thesis, we have employed two computational methods, molecular dynamics (MD) and hybrid quantum mechanics/molecular mechanics (QM/MM) MD simulations with umbrella sampling (US), to gain insights into the molecular mechanism governing the molecular recognition and reactivity in several protein-ligand complexes. Three systems involving protein-ligand interactions are examined in this dissertation utilizing well-established computational methodologies and mathematical modeling. The three proteins studied here are acetylcholinesterase (AChE), butyrylcholinesterase (BChE), and peptidyl-prolyl cis-trans isomerase NIMA-interacting 1 (PIN1). These enzymes are known to interact with a variety of ligands. AChE dysfunction caused by organophosphorus (OP) chemicals is a severe hazard since AChE is …

Synthesis Of Conjugated Polymers From Xanthene And Alkenyl Flanked Diketopyrrolopyrrole Monomers For High-Performance Electronic Applications., Ranganath Wijesinghe Wahalathantrige Don

Theses and Dissertations

In traditional electronics, inorganic materials such as silicon and germanium are used as semiconductors due to their outstanding semiconducting properties. Unfortunately, inorganic materials are rigid due to their high crystalline nature, and processing these materials is complex and expensive. Furthermore, traditional semiconducting materials do not have favorable mechanical properties in applications such as wearable devices and large-area applications with complicated shapes. Conjugated conducting polymers (CCPs) are being explored as alternative materials to conventional semiconductors due to their mechanical properties and high conductivity. CCPs offer properties such as solution and low-temperature processability, flexibility, thermal and optical properties that traditional semiconductors could …

Rooted In The Earth: An Igbo Sacramental Nature Of The Universe, A Model For Igbo Christian Ecological Ethics, Kenneth Oguzie

Electronic Theses and Dissertations

The contemporary Igbo society faces a lot of challenges. These include political, religious, and moral crises. These crises affect the environment in many ways. They threaten the peace and harmony of the Igbo society. As a result, it touches on faith. The Igbo society holds a holistic view of life. Whatever affects one aspect of life affects the other areas. Ecologically, various factors are responsible for the crises. These include changes in lifestyle from the traditional way of living to modern style of life with its penchant on consumerism. Also, colonialism and its lingering residues, civil unrests, politics, population growth, …

Relational Graph Convolutional Networks For Predicting Blood-Brain Barrier Penetration Of Drug Molecules

Faculty, Staff and Student Publications

MOTIVATION: Evaluating the blood-brain barrier (BBB) permeability of drug molecules is a critical step in brain drug development. Traditional methods for the evaluation require complicated in vitro or in vivo testing. Alternatively, in silico predictions based on machine learning have proved to be a cost-efficient way to complement the in vitro and in vivo methods. However, the performance of the established models has been limited by their incapability of dealing with the interactions between drugs and proteins, which play an important role in the mechanism behind the BBB penetrating behaviors. To address this limitation, we employed the relational graph convolutional …

Impact Of Climate Oscillations/Indices On Hydrological Variables In The Mississippi River Valley Alluvial Aquifer., Meena Raju

Theses and Dissertations

The Mississippi River Valley Alluvial Aquifer (MRVAA) is one of the most productive agricultural regions in the United States. The main objectives of this research are to identify long term trends and change points in hydrological variables (streamflow and rainfall), to assess the relationship between hydrological variables, and to evaluate the influence of global climate indices on hydrological variables. Non-parametric tests, MMK and Pettitt’s tests were used to analyze trend and change points. PCC and Streamflow elasticity analysis were used to analyze the relationship between streamflow and rainfall and the sensitivity of streamflow to rainfall changes. PCC and MLR analysis …

Development And Evaluation Of Seasonal, Continental-Scale Streamflow Forecasts, Elissa Marie Yeates

Theses and Dissertations

Methods of forecasting streamflow using atmospheric ensembles and hydrologic routing have greatly improved over the past decades. These forecasts anticipate the timing and magnitude of streamflow peaks, enabling early warning of floods. Recent advances in atmospheric modeling have enabled production of forecasts months ahead, which are less precise but give a useful sense of trends.

The purpose of this study is to produce and evaluate a seasonal streamflow forecast model using a Muskingum routing hydrologic model coupled with runoff from a land surface model, and atmospheric input from a medium-term atmospheric and precipitation model. To evaluate the skill of the …

Step-Growth Polymerization Of Perfluoro-Vinyl Ether, -Cycloalkenes, And -Acyclic Alkenes With Bisphenols Containing Variable Polycyclic Aromatic Cores, Karl Mpumbwa Mukeba

Theses and Dissertations

This dissertation reports the synthesis and characterization of semi-fluorinated polymers derived from the polymerization of bisphenols with fluoroalkenes. A series of diverse bisphenols were chosen from popular commercial bisphenols and new polycyclic aromatic hydrocarbon (PAH) derived bisphenols requiring synthesis. Step-growth condensation polymerization of bisphenols with three different fluoroalkene types was performed while probing polymerization conditions and the structure/properties relationship of the resulting fluoropolymers. The fluoroalkene monomers were chosen from bis(trifluorovinyloxy)biphenyl (TFVE), perfluorocyclohexene (PFCH), and perfluoro acyclic monomers, namely, perfluoro(4-methyl-2-pentene) and 1-perfluoroheptene to undergo this chemistry.

This work is divided into four parts based on the polymerization methodology.

The first …

Developing A Model Of Driver Performance, Situation Awareness, And Cognitive Load Considering Different Levels Of Partial Vehicle Autonomy, Jessie E. Cossitt

Theses and Dissertations

To fully utilize the abilities of current autonomous vehicles, it is necessary to understand the interactions between vehicles and their operators. Since the current state of the art of autonomous vehicles is partial autonomy that requires operators to perform parts of the driving task and be alert and ready to take over full control of the vehicle, it is necessary to know how operators' abilities are impacted by the amount of autonomy present in the system. Autonomous systems have known effects on performance, cognitive load, and situation awareness, but little is known about how these effects change in relation to …

A Novel Chebyshev Wavelet Method For Solving Fractional-Order Optimal Control Problems, Ghodsieh Ghanbari

Theses and Dissertations

This thesis presents a numerical approach based on generalized fractional-order Chebyshev wavelets for solving fractional-order optimal control problems. The exact value of the Riemann– Liouville fractional integral operator of the generalized fractional-order Chebyshev wavelets is computed by applying the regularized beta function. We apply the given wavelets, the exact formula, and the collocation method to transform the studied problem into a new optimization problem. The convergence analysis of the proposed method is provided. The present method is extended for solving fractional-order, distributed-order, and variable-order optimal control problems. Illustrative examples are considered to show the advantage of this method in comparison …

Bio-Based Antibacterial Packaging From Decorated Bagasse Papers With Natural Rosin And Synthesised Go-Ag Nanoparticles, Mohamed Morsy

Nanotechnology Research Centre

No abstract provided.

Scalable Deeper Graph Neural Networks For High-Performance Materials Property Prediction, Sadman Sadeed Omee, Steph-Yves Louis, Nihang Fu, Lai Wei, Sourin Dey, Rongzhi Dong, Qinyang Li, Jianjun Hu

Faculty Publications

Machine-learning-based materials property prediction models have emerged as a promising approach for new materials discovery, among which the graph neural networks (GNNs) have shown the best performance due to their capability to learn high-level features from crystal structures. However, existing GNN models suffer from their lack of scalability, high hyperparameter tuning complexity, and constrained performance due to over-smoothing. We propose a scalable global graph attention neural network model DeeperGATGNN with differentiable group normalization (DGN) and skip connections for high-performance materials property prediction. Our systematic benchmark studies show that our model achieves the state-of-the-art prediction results on five out of six …

The Impact Of Academic Tracking And Mathematics Self-Concept On Mathematics Achievement., Kain M. Schow

Dissertations, Theses, and Projects

ABSTRACT

This study examines the effects of academic tracking, in high school math, on students’ mathematics self-concept (MSC) and how that correlates to students’ mathematics achievement. This study measured students’ MSC through a mathematics self-concept questionnaire and measured mathematics achievement by the students’ latest grade report. Participants included 60 students in grades 10-12 who had been or were currently enrolled in math courses in the researcher’s school district. The data collected will direct the researcher and school administration on the effects of academic tracking on students, allowing for further discussion about continuing tracking in the district.

Sheltered Math Curriculum For Middle School English Learners, Jasmine Ercink

Dissertations, Theses, and Projects

Language barriers have shown a need for differentiation and sheltered instruction in the classroom for English Learners (ELs) to be successful in the United States public school system. This project proposes a mathematics curriculum using SIOP so that both groups of students in the middle school level can increase their proficiency in the mathematics content area as well as experience opportunities for academic and social language development. The purpose of this report is to describe the processes, methods, data, and intent of the mathematics curriculum for these learners. The curriculum acts as an effective intervention to fill gaps in both …

The Nature Of Environmental Planning In The Carnué Land Grant, Desiree Loggins

Geography ETDs

In 1819, the Spanish Crown established Cañón de Carnué land grant as a buffer between the colonial settlement of Albuquerque and raids from Plains Apache and other nomadic tribal nations. Upon entering the U.S. period of Manifest Destiny, Carnué land grant heirs lost much of the land they stewarded as a collective to the Cibola National Forest. While the state generates laws and policies that complicate the prioritization of subsistence land uses by land grant communities, Carnué’s presence is felt as grantees reform relationships to their environment and assert their personal stake in stewardship and care. I argue that Carnué’s …

An Evidence-Based Lexical Pattern Approach For Quality Assurance Of Gene Ontology Relations, Licong Cui

Faculty, Staff and Student Publications

Gene Ontology (GO) is widely used in the biological domain. It is the most comprehensive ontology providing formal representation of gene functions (GO concepts) and relations between them. However, unintentional quality defects (e.g. missing or erroneous relations) in GO may exist due to the large size of GO concepts and complexity of GO structures. Such quality defects would impact the results of GO-based analyses and applications. In this work, we introduce a novel evidence-based lexical pattern approach for quality assurance of GO relations. We leverage two layers of evidence to suggest potentially missing relations in GO as follows. We first …

Needs Assessment Of Southeastern United States Vector Control Agencies: Capacity Improvement Is Greatly Needed To Prevent The Next Vector-Borne Disease Outbreak, Kyndall C. Dye-Braumuller, Jennifer R. Gordon, Danielle John, Josie Morrissey, Kaci Mccoy, Rhoel R. Dinglasan, Melissa Nolan Ph.D., Mph

Faculty Publications

A national 2017 vector control capacity survey was conducted to assess the United States’ (U.S.’s) ability to prevent emerging vector-borne disease. Since that survey, the southeastern U.S. has experienced continued autochthonous exotic vector-borne disease transmission and establishment of invasive vector species. To understand the current gaps in control programs and establish a baseline to evaluate future vector control efforts for this vulnerable region, a focused needs assessment survey was conducted in early 2020. The southeastern U.S. region was targeted, as this region has a high probability of novel vector-borne disease introduction. Paper copies delivered in handwritten envelopes and electronic copies …

A Two-Layer Model Explains Higher-Order Feature Selectivity Of V2 Neurons, Timothy D. Oleskiw, Justin D. Lieber, J. Anthony Movshon, Eero P. Simoncelli

MODVIS Workshop

Neurons in cortical area V2 respond selectively to higher-order visual features, such as the quasi-periodic structure of natural texture. However, a functional account of how V2 neurons build selectivity for complex natural image features from their inputs – V1 neurons locally tuned for orientation and spatial frequency – remains elusive.

We made single-unit recordings in area V2 in two fixating rhesus macaques. We presented stimuli composed of multiple superimposed grating patches that localize contrast energy in space, orientation, and scale. V2 activity is modeled via a two-layer linear-nonlinear network, optimized to use a sparse combination of V1-like outputs to account …

Elektrisidad Sa Pagsikad: Feasibility Study Of Amalgamated Bicycle With Piezoelectric Power Generator, Nichole P. Bombio, Florence B. De La Serna, Nestor Luis M. Tappa Jr.

DLSU Senior High School Research Congress

The rapid increase in energy demand has created worries about supply challenges, depletion of energy resources, and severe environmental effects. This study incorporated Goal 7 of the 2030 UN Agenda for Sustainable Development to achieve clean and affordable energy sources. As a result, this research designed, built, and tested an amalgamated bicycle that can generate voltages from applied pressure on tires using piezoelectric transducers. The main goal of this study is to test if there is a significant difference between the generated energy when an amalgamated bicycle is moving or not and if there is a significant relationship between the …

Smart Grid Control: Demand Side Management In Household Refrigerators As A Tool For Load Shifting, Anogh Utkalika Zaman, James Doyle

Macalester Journal of Physics and Astronomy

With improved supply of renewable sources of energy the focus has shifted away from simply producing clean energy to efficient consumption of energy. Until cheaper methods of energy storage are developed, Demand Side Management (DSM) is the best option for maximising energy efficiency. This paper proposes a method of turning regular refrigerators into smart demand response fridges. First, we develop an algorithm that accounts for small fluctuations in price and switches the device for optimal performance and lowered running cost. Then, we use longer price fluctuations to predict suitable times for pre-cooling and investigate the reduction in price as a …

Twisting Lasers With The Faraday Effect, Harrison Werrell

Macalester Journal of Physics and Astronomy

Our objective with this project was to create a system and procedure to quantify the magnetization of a material with polarized light by using the Faraday Effect, where the light is rotated according to the magnetization. This type of system has seen use in technologies such as magneto-optical drives and optical isolators, and is part of the study of optical materials, along with the similar MagnetoOptical Kerr Effect. Our system, specifically, is intended to be used as part of an advanced Physics Lab in the future. It uses an electromagnet to magnetize a sample, and a laser to observe the …

Electrical Analysis Of A Pem Electrolysis Cell, Joey Wehrley, James Doyle

Macalester Journal of Physics and Astronomy

Polymer Electrolyte Membrane (PEM) electrolysis is a form of electrolysis that is heavily used in commercial capacities. It functions by using a membrane and an electric charge in order to perform electrolysis water, splitting it into its component parts - Hydrogen and Oxygen. These parts can then be used in a number of different applications, including reversing the electrolysis process to regenerate some energy in the form of electricity. During this experiment, multiple currents were run through a PEM cell, and voltages across the membrane were measured. It was found that a standard R/C charging model can be fit to …

The Interaction Of Topological Defects In Anisotropically-Elastic Nematic Liquid Crystals, Carter J. Swift

Macalester Journal of Physics and Astronomy

Topological defects are very well understood so long as the medium in which they exist is isotropically-elastic. They lead to director fields which are easy to calculate and superpose linearly so that a system with any number of defects is analytically treatable. They also have an interaction which is simple in form and can be accurately described by the Peach-Koehler force. In an anisotropically-elastic medium, however, such defects are very poorly understood outside of the single-defect case which was solved by Dzyaloshinskii. In this project, numerical and approximate analytical techniques are applied in order to better understand the interaction between …

Neutrino Oscillations In The Presence Of A Magnetic Field, Chinhsan Sieng

Macalester Journal of Physics and Astronomy

We calculate oscillation probabilities in the presence of an external magnetic field in a one-generation neutrino framework that includes both Majorana and Dirac mass terms. First, we write down the Euler-Lagrange equations and obtain a system of eight differential equations coupling together eight different neutrino states that can be distinguished by helicity, chirality, and particle/antiparticle-ness. We then solve this system of differential equations in various special cases, exhibiting different types of oscillations. When the magnetic field is in the direction of momentum, there are only four oscillation channels as helicity flip is forbidden. We observe that chirality flips are suppressed …

The Impact Of Initial Abundances On Modeling The Weak S-Process, Lev S. Serxner

Macalester Journal of Physics and Astronomy

No abstract provided.

The Survey Of Hi In Extremely Low-Mass Dwarfs: New Results From Vla Imaging, Francesco Pecere, John M. Cannon, Damen Beverlin, Jackson Codd

Macalester Journal of Physics and Astronomy

We present new HI spectral line imaging of 19 galaxies in the “Survey of HI in Extremely Low-mass Dwarfs” (SHIELD) acquired for Large Program VLA/ 20A-330. Using the National Radio Astronomy Observatory’s Karl G. Jansky Very Large Array (VLA) in the C configuration, we produce images of the neutral interstellar medium (HI) on angular scales of 15 to 20 arcseconds (corresponding to physical resolutions of 200 to 1100 parsecs). The three-dimensional cubes probe the morphology and kinematics of the gas at a range of spatial and spectral resolutions. The cubes were collapsed to produce two-dimensional moment maps (representing HI mass …

Hunting For Fast Radio Bursts From Messier 82: Exploring The Frb--Magnetar Connection, Susie Paine

Macalester Journal of Physics and Astronomy

Fast radio bursts (FRBs) are short-duration radio pulses of cosmological origin. Among the most common sources predicted to explain this phenomenon are bright pulses from a class of extremely highly magnetized neutron stars known as magnetars. In 2020, a Galactic magnetar produced an FRB-like burst, allowing researchers to constrain the Galactic magnetar burst rate. We assume that the magnetar burst rate scales with star formation rate and test an important prediction for similar bursts in nearby galaxies. Messier 82 (M82) has a star formation rate 40 times that of the Milky Way, implying that the magnetar burst rate would be …

Finite-Difference-Time-Domain Simulation Of Ultrafast Experiments, Alpha Ma

Macalester Journal of Physics and Astronomy

The Finite-Difference-Time-Domain (FDTD) method is a numerical method that calculates electric fields or magnetic fields by interleaving them in space and time. Using a python package called “MEEP”, I was able to write optical simulations of ultrafast experiments, especially the Terahertz Pump-Probe experiments. The goal of this project was to use FDTD simulation to measure the transmission of an electro-magnetic pulse passing through a thin film of conducting material on a dielectric substrate in order to study the characteristic conductivity of potential solar cell materials.

Molecular Line Search In Archival Alma Imaging Of M87, Xueyi Li

Macalester Journal of Physics and Astronomy

We present a molecular line search in spectral imaging of the elliptical galaxy M87 using archival data from the Atacama Large Millimeter/sub-millimeter Array (ALMA). The primary goal of this project is to verify and characterize possible CO transition lines, which can be used for future studies to determine the dynamics of the system, or the mass of the supermassive black hole (BH) in the center of the galaxy. After performing extensive atmospheric modeling, we found that most of the absorption features have a corresponding atmospheric ozone transition, so it is unlikely that these features are either Galactic or extragalactic. We …

Lie Algebras And The Poincare Group, Jack Hempel Costello

Macalester Journal of Physics and Astronomy

This paper will discuss my research with
Professor Tonnis ter Veldhuis on the Poincare Group
and other similar algebraic approaches based on the
Minkowski Metric. This paper will begin with an
introduction discussing group theory and expand on its
specific applications in theoretical physics.