Physical Sciences and Mathematics Commons^™

Fuzzy Super-Twisting Second Order Sliding Mode Trajectory Tracking Control For Robotic Manipulator, Baolin Du, Dachang Zhu, Yihua Pan

Journal of System Simulation

Abstract: A fuzzy super-twisting second order sliding mode control method is proposed for the uncertainties of the model error and external disturbance on the trajectory tracking accuracy of robotic manipulator. Based on the dynamic model of the robotic, a new non-singular terminal sliding mode manifold is designed, and an improved super-twisting algorithm is used to design the second order sliding mode controller. In order to solve the problem that the matching disturbance can only be compensated under the condition of the known disturbance boundary in the sliding mode control, the fuzzy logic algorithm is used to carryout the online compensation …

Butte Priority Soils Operable Unit (Bpsou) Draft Final Insufficiently Reclaimed Sites – Field Sampling Plan (Fsp) Bres No. 38 – Sister Dump., Mike Mcanulty

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Luminescence And Scintillation In The Niobium Doped Oxyfluoride Rb4Ge5O9F6:Nb, Darren Carone, Vladislav V. Klepov, Scott T. Misture, Joseph C. Schaeperkoetter, Luiz G. Jacobsohn, Mina Aziziha, Juliano Schorne-Pinto, Stuart A. J. Thomson, Adrian T. Hines, Theodore M. Besmann, Hans Conrad Zur Loye

Faculty Publications

A new niobium-doped inorganic scintillating oxyfluoride, Rb₄Ge₅O₉F₆:Nb, was synthesized in single crystal form by high-temperature flux growth. The host structure, Rb₄Ge₅O₉F₆, crystallizes in the orthorhombic space group Pbcn with lattice parameters a = 6.98430(10) Å, b = 11.7265(2) Å, and c = 19.2732(3) Å, consisting of germanium oxyfluoride layers made up of Ge₃O₉ units connected by GeO₃F₃ octahedra. In its pure form, Rb₄Ge₅O₉F₆ shows neither luminescence nor scintillation but when doped …

On Approximating Total Variation Distance, Arnab Bhattacharyya, Sutanu Gayen, Kuldeep S. Meel, Dimitrios Myrisiotis, A. Pavan, N. V. Vinodchandran

School of Computing: Faculty Publications

Total variation distance (TV distance) is a fundamental notion of distance between probability distributions. In this work, we introduce and study the computational problem of determining the TV distance between two product distributions over the domain {0, 1}ⁿ. We establish the following results.

1. Exact computation of TV distance between two product distributions is #P-complete. This is in stark contrast with other distance measures such as KL, Chi-square, and Hellinger which tensorize over the marginals.

2. Given two product distributions P and Q with marginals of P being at least 1/2 and marginals of Q being at most …

Engaging Hard-To-Reach Audiences Through Internal Interdisciplinary And External Diverse Collaborations, Erin M. Garrett, Ashley J. Belle

Journal of Extension

Through a combination of internal and external collaborations, consumer-based energy education designed for hard-to-reach audiences was successfully delivered statewide by an interdisciplinary Extension team. Program participants representing rural residents, senior citizens, and low-income audiences demonstrated improvements in knowledge and increased intention to change their home electricity usage behaviors. This outreach work can serve as a model for other Extension services to combine interdisciplinary teams with community partnerships to reach underserved audiences statewide.

A Large-Scale Sentiment Analysis Of Tweets Pertaining To The 2020 Us Presidential Election, Rao Hamza Ali, Gabriela Pinto, Evelyn Lawrie, Erik J. Linstead

Engineering Faculty Articles and Research

We capture the public sentiment towards candidates in the 2020 US Presidential Elections, by analyzing 7.6 million tweets sent out between October 31st and November 9th, 2020. We apply a novel approach to first identify tweets and user accounts in our database that were later deleted or suspended from Twitter. This approach allows us to observe the sentiment held for each presidential candidate across various groups of users and tweets: accessible tweets and accounts, deleted tweets and accounts, and suspended or inaccessible tweets and accounts. We compare the sentiment scores calculated for these groups and provide key insights into the …

Evidence For Multiple Potential Drivers Of Increased Phosphorus In High-Elevation Lakes, J. Scholz, Janice Brahney

Watershed Sciences Faculty Publications

Total phosphorus (TP) concentrations have increased in many remote mountain waterbodies across the western United States, and reports of algal blooms in these systems have increased in frequency. Explanations for observed TP increases are uncertain, and typical landscape drivers, such as agricultural/urban runoff, are implausible. We investigated multiple atmospheric and terrestrial-P loading mechanisms to explain the observed decadal increase in TP, including a novel hypothesis that warming soils may lead to elevated P fluxes to receiving water bodies. Using northern Utah mountains ranges as a case study, we measured prospective inputs of total and bioavailable P via dust deposition. Terrestrial …

Quantum Decoherence In Time-Dependent Anharmonic Systems, Ty Beus

Theses and Dissertations

This dissertation studies quantum decoherence in anharmonic oscillator systems to monitor and understand the way the systems evolve. It also explores methods to control the systems' evolution, and the effects of decoherence when applicable. We primarily do this by finding the time evolution of the systems using their Lie algebraic structures. We solve for a generalized Caldirola-Kanai Hamiltonian, and propose a general way to produce a desired evolution of the system. We apply the analysis to the effects of Dirac delta fluctuations in mass and frequency, both separately and simultaneously. We also numerically demonstrate control of the generalized Caldirola-Kanai system …

Policing By Proxy: Interrogating Big Tech's Role In Law Enforcement, Claire Elizabeth

University Honors Theses

Predictive policing, sometimes referred to as data-driven or actuarial policing, is a method of policing that uses a risk-based approach to law enforcement. For-profit technology companies market proprietary risk assessment algorithms to law enforcement organizations as tools meant to proactively mitigate crime. Using data collected from a vast array of sources, both personal and public, police are able to "predict" the likelihood of criminal activity in a given area using these algorithms. Proponents claim that risk assessment tools have the potential to fight crime with unbiased accuracy and speed by predicting when, where, and whom to police by relying on …

Draft Final 2021 Unreclaimed Sites Sampling Ur-35 Site Evaluation Summary Report, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Silver Bow Creek/Butte Area Npl Site Butte Priority Soils Operable Unit, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

2022 Final Unreclaimed Sites Quality Assurance Project Plan (Qapp), Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Revised Draft Final Butte Reclaimed Areas Maintenance And Monitoring (M&M) Plan In Accordance With Butte Reclamation Evaluation System (Bres), Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Shadows Of A Schwarzschild Black Hole Surrounded By A Spherically Symmetric Dark Matter, Ahmad Ibrahim

Theses and Dissertations

In this thesis, using general relativity, the null geodesics and black hole shadow of a spherically symmetric configuration of a black hole (surrounded by a dark matter shell) are studied. First, the standard

results of the photon sphere of Schwarzschild de-Sitter black hole is revisited and analyzed more carefully. Secondly, using an ansatz (piecewise metric function) commonly used in the literature to describe the mass distribution of the spherically symmetric black hole - dark matter configuration, the null geodesics through vacuum and dark matter are analyzed. Assuming an observer located at a finite distance from the black hole outside the …

Enhancing Vanadium Redox Battery Performance Using Tungsten-Bismuth-Based Oxide Nanostructures As Electrode Modifiers, Taher Al Najjar

Theses and Dissertations

Renewable energy power plants require high efficiency conversion and storage systems that can store high amounts of energy and can be integrated with the electrical grid. Vanadium redox flow batteries are very promising for this application. However, one major drawback of VRFBs is their low power density which means that right now they cannot replace non-renewable energy sources. Different carbon materials are used as electrodes in VRFBs and each carbon material affects the battery’s performance in a different way. Modification of these electrodes can increase the power density of the battery. Some metal oxides like tungsten oxide can enhance vanadium …

A Simplified Model For The Intermediate Structure Of Strong Fire Whirls, Forman A. Williams

Progress in Scale Modeling, an International Journal

A model is described for the overall structure of intense fire whirls, based on a spatially evolving vortex, with circulation enhancement driven by the axial acceleration of low-density gas in the core through the axial pressure gradient. The axial acceleration increases the entrainment rate into the core which, through mass conservation, increases the circulation if the angle between the tangential and radial velocity components remains fixed. The two-zone model employs general balance equations for regions inside and outside a cylinder of fixed radius, each inviscid, the inside region being presumed to have a constant density small compared with the (constant) …

Managing Risk And Knowledge: Frameworks To Guide Knowledge-Enabled Technology Transfer, Martin Lipa Dr, Anne Greene

Level 3

Technology transfer is not only about the transfer of technology, but also about the transfer of knowledge, as evidenced by definitions of KM within the biopharma industry and beyond. However, knowledge transfer is often not well structured and its effectiveness – in particular for tacit knowledge (i.e., know how) – is an opportunity for improvement which can lead to many benefits. This article profiles recent research into the topic of improving knowledge transfer during technology transfer and presents several recently developed frameworks for improving such. The article furthermore explains how the frameworks can be co-deployed in support of robust knowledge …

Steps Towards Digital Transformation In The Pharmaceutical Manufacturing Landscape Knowledge-Enabled Technology Transfer, Anne Greene Professor, Martin Lipa Dr

Level 3

No abstract provided.

Grotthuss Molecular Dynamics Simulations For Modeling Proton Hopping In Electrosprayed Water Droplets., Lars Konermann, Scott Kim

Chemistry Publications

Excess protons in water exhibit unique transport properties because they can rapidly hop along H-bonded water wires. Considerable progress has been made in unraveling this Grotthuss diffusion mechanism using quantum mechanical-based computational techniques. Unfortunately, high computational cost tends to restrict those techniques to small systems and short times. Molecular dynamics (MD) simulations can be applied to much larger systems and longer time windows. However, standard MD methods do not permit the dissociation/formation of covalent bonds, such that Grotthuss diffusion cannot be captured. Here, we bridge this gap by combining atomistic MD simulations (using Gromacs and TIP4P/2005 water) with proton hopping. …

Stereocontrolled Access To Δ-Lactone-Fused-Γ-Lactams Bearing Angular Benzylic Quaternary Stereocenters, Timothy K. Beng, Morgan J. Rodriguez, Claire Borg

All Faculty Scholarship for the College of the Sciences

C-fused γ-lactam-lactones are resident in several bioactive molecules, including anticancer agents such as omuralide. In this embodiment, we report mild conditions for the catalytic halolactonization of lactam-tethered 5-aryl-4(E)-pentenoic acids. The use of dichloromethane as the solvent and Ph₃PS as the catalyst led to predominant 6-endo-trig cyclization and furnished the trans-fused-γ-lactam-δ-lactones. The transformation is modular, regioselective, chemoselective, and diastereoselective. The γ-lactam-δ-lactones bear angular quaternary benzylic stereocenters, which is noteworthy since the presence of a quaternary carbon in bioactive small molecules often promotes an element of conformational restriction that imparts potency, selectivity, and metabolic stability. The …

Towards Color-Based Two-Hand 3d Global Pose Estimation, Fanqing Lin

Theses and Dissertations

Pose estimation and tracking is essential for applications involving human controls. Specifically, as the primary operating tool for human activities, hand pose estimation plays a significant role in applications such as hand tracking, gesture recognition, human-computer interaction and VR/AR. As the field develops, there has been a trend to utilize deep learning to estimate the 2D/3D hand poses using color-based information without depth data. Within the depth-based as well as color-based approaches, the research community has primarily focused on single-hand scenarios in a localized/normalized coordinate system. Due to the fact that both hands are utilized in most applications, we propose …

An Absence Of Elephants In The Room: Religion, Philosophy, And Negative Numbers In Albert Girard’S A New Discovery In Algebra, Ethan Wilmes

Lawrence University Honors Projects

In early seventeenth-century Europe, the lines separating theology, science, and humanism were thin; what the modern reader understands as three distinct spheres of knowledge considerably overlapped with one another. Scientific discoveries and innovations coming from new technologies and foreign lands were laden with implications about theology and the human condition. While bland to all but the most fringe historians of mathematics today, the discovery of negative numbers led to a passionate and occasionally fierce epistemological debate throughout Europe. Falling outside of traditional mathematical knowledge, negative numbers found themselves in a sort of existential limbo; however useful they proved themselves to …

Calcium Bistriflimide-Mediated Sulfur(Vi)–Fluoride Exchange (Sufex): Mechanistic Insights Toward Instigating Catalysis, Brian Han, Samuel R. Khasnavis, Matthew Nwerem, Michael Bertagna, Nicholas D. Ball, O. Maduka Ogba

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

We report a mechanistic investigation of calcium bistriflimide-mediated sulfur(VI)–fluoride exchange (SuFEx) between sulfonyl fluorides and amines. We determine the likely pre-activation resting state─a calcium bistriflimide complex with ligated amines─thus allowing for corroborated calculation of the SuFEx activation barrier at ∼21 kcal/mol, compared to 21.5 ± 0.14 kcal/mol derived via kinetics experiments. Transition state analysis revealed: (1) a two-point calcium-substrate contact that activates the sulfur(VI) center and stabilizes the leaving fluoride and (2) a 1,4-diazabicyclo[2.2.2]octane additive that provides Brønsted-base activation of the nucleophilic amine. Stable Ca–F complexes upon sulfonamide formation are likely contributors to inhibited catalytic turnover, and a proof-of-principle redesign …

Draft Final 2022 Residential Metals Abatement Program (Rmap) Park Soil Sampling Field Sampling Plan (Fsp) Submittal #4 [Covering Tot Lot, Clark Park, Huron Tennis Courts, Father Sheehan Park, Community Garden, And Lexington Gardens], Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

A Room-Temperature Ferroelectric Resonant Tunneling Diode, Zhijun Ma,, Qi Zhang, Lingling Tao, Yihao Wang, Daniel Sando, Jinling Zhou, Yizhong Guo, Michael Lord, Peng Zhou, Yongqi Ruan, Zhiwei Wang, Alex Hamilton, Alexei Gruverman, Evgeny Y. Tsymbal, Tianjin Zhang, Nagarajan Valanoor

Department of Physics and Astronomy: Faculty Publications

Resonant tunneling is a quantum-mechanical effect in which electron transport is controlled by the discrete energy levels within a quantum-well (QW) structure. A ferroelectric resonant tunneling diode (RTD) exploits the switchable electric polarization state of the QW barrier to tune the device resistance. Here, the discovery of robust room-temperature ferroelectric-modulated resonant tunneling and negative differential resistance (NDR) behaviors in all-perovskite-oxide BaTiO₃/SrRuO₃/BaTiO₃ QW structures is reported. The resonant current amplitude and voltage are tunable by the switchable polarization of the BaTiO₃ ferroelectric with the NDR ratio modulated by ≈3 orders of magnitude and an OFF/ON …

Emerging Technologies: Empowering People To Capture, Share And Transfer Tacit Knowledge, Donncadh J. Nagle, Melanie J. Adams

Level 3

ICH Q10 was published in 2008, and presented a model for an effective Pharmaceutical Quality System (PQS). However, the industry still has some way to go in embracing and implementing its principles in order to achieve greater product realisation, to establish and maintain a state of control, and to facilitate continual improvement.

ICH Q10 introduced us to two key enablers: Knowledge Management (KM) and Quality Risk Management (QRM).^[1] While the pharmaceutical industry has made progress in implementing the principles of QRM since 2008, there has been significantly slower progress in implementing knowledge management practices. However, there may be solutions …

A Westerly Wind Dominated Puna Plateau During Deposition Of Upper Pleistocene Loessic Sediments In The Subtropical Andes, South America, Alex Pullen, David L. Barbeau Jr, Andrew Leier, Madison Ward, Austin Bruner, Mary Kate Fidler

Faculty Publications

The Tafí del Valle depression (~27° S) in the eastern Andes of Argentina provides a record of late Pleistocene dust deposition in the subtropics of South America. We present large-n U-Pb geochronology data for detrital zircons from upper Pleistocene loess-paleosol deposits. When compared to regional data, the age spectra from the Tafí del Valle samples are most like the southern Puna Plateau, supporting derivation largely from the west and northwest. This runs counter to hypotheses suggesting these loessic sediments were derived from the low elevation plains to the east or extra-Andean Patagonia. Mapping of linear wind erosion features on …

Approval Letter For The Butte Priority Soils Operable Unit (Bpsou) 2022 Revised Draft Final Unreclaimed Sites Quality Assurance Project Plan (Dated June 8, 2022), Nikia Greene

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Draft Final Rmap Park Soil Sampling Field Sampling Plan (Fsp) Submittal #2 [Covering Scown Field, Cherokee Park, Copper/Emmet, West Side Subdivision Park, Chester Steele Park, And Cinders Field], Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Draft Final 2022 Residential Metals Abatement Program (Rmap) Park Soil Sampling Field Sampling Plan (Fsp) Submittal #6 [Covering Stodden Park, Baptist Student Union, Minor Park, Blacktail Lane, Earth Lane, Fleecer Drive, Boulevard (Josette), Boulevard (Lasalle), And Sesame- Sage], Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.