Physical Sciences and Mathematics Commons^™

The Chemistry And Catalytic Activity Of Dehydrogenative Silylation And Hydroboration Of Complexes Bearing Semirigid Ligands With Group 14 Elements, Niroshani S. Abeynayake

Theses and Dissertations

Incorporation of silicon in the ligand backbone would yield electron-rich metal complexes upon coordination to transition metal complexes. The coordination chemistry of semirigid benzyl phosphines bearing a single or multiple phosphorus atoms and varying number of Si−H moieties has gained interest in recent years. This dissertation focuses on synthesizing silyl and germyl transition metal complexes of groups 9 and 10. Chapter II presents the synthesis of a family of four coordinated 14-electron rhodium complexes. The newly synthesized complexes were characterized in solution by multinuclear NMR spectroscopy and in the solid-state by single-crystal X-ray diffraction. These d⁶ complexes possess sawhorse …

Augmented Reality Fonts With Enhanced Out-Of-Focus Text Legibility, Mohammed Safayet Arefin

Theses and Dissertations

In augmented reality, information is often distributed between real and virtual contexts, and often appears at different distances from the viewer. This raises the issues of (1) context switching, when attention is switched between real and virtual contexts, (2) focal distance switching, when the eye accommodates to see information in sharp focus at a new distance, and (3) transient focal blur, when information is seen out of focus, during the time interval of focal distance switching. This dissertation research has quantified the impact of context switching, focal distance switching, and transient focal blur on human performance and eye fatigue in …

Assessing Wood Failure In Plywood By Deep Learning/Semantic Segmentation, Ramon Ferreira Oliveira

Theses and Dissertations

The current method for estimating wood failure is highly subjective. Various techniques have been proposed to improve the current protocol, but none have succeeded. This research aims to use deep learning/semantic segmentation using SegNet architecture to estimate wood failure in four types of three-ply plywood from mechanical shear strength specimens. We trained and tested our approach on custom and commercial plywood with bio-based and phenol-formaldehyde adhesives. Shear specimens were prepared and tested. Photographs of 255 shear bonded areas were taken. Forty photographs were used to solicit visual estimates from five human evaluators, and the remaining photographs were used to train …

Geologic Mapping Of The Sparta 7.5-Minute Quadrangle In Northern Mississippi Via Remote Sensing, Traditional Geologic Survey, And Applied Geospatial Information Systems Methods, Rayford Dean Parnell

Theses and Dissertations

Traditional geologic mapping involves substantial time and labor in the field as geologic contacts are manually examined and interpreted. The processes of mapping geologic contacts can be condensed into a quicker and less laborious process using advances in remote sensing and GIS (geospatial information systems), including increased resolution and computerized data management and interpretation. Application of these advances reduces the costs and time of geologic mapping. The Sparta 7.5-minute quadrangle provides a mostly unaltered view of regional Paleocene and Upper Cretaceous geology due to its rural locale, lack of development, and stream topography. Recently LiDAR (Light Detection And Ranging) survey …

Dynamics Of Redox-Driven Molecular Processes In Local And Systemic Plant Immunity, Philip Berg

Theses and Dissertations

The work here presents two main parts. In the first part, chapters 1 – 3 focus on dynamical systems modeling in plant immunity, whereas chapters 4 – 6 describe contributions to computational modeling and analysis of proteomics and genomics data. Chapter 1 investigates dynamical and biochemical patterns of reversibly oxidized cysteines (RevOxCys) during effector-triggered immunity (ETI) in Arabidopsis, examines the regulatory patterns associated with Arabidopsis thimet oligopeptidase 1 and 2’s (TOP1 and TOP2), roles in the RevOxCys events during ETI, and analyzes the redox phenotype of the top1top2 mutant. The second chapter investigates the peptidome dynamics during ETI …

Towards Structured Planning And Learning At The State Fisheries Agency Scale, Caleb A. Aldridge

Theses and Dissertations

Inland recreational fisheries has grown philosophically and scientifically to consider economic and sociopolitical aspects (non-biological) in addition to the biological. However, integrating biological and non-biological aspects of inland fisheries has been challenging. Thus, an opportunity exists to develop approaches and tools which operationalize planning and decision-making processes which include biological and non-biological aspects of a fishery. This dissertation expands the idea that a core set of goals and objectives is shared among and within inland fisheries agencies; that many routine operations of inland fisheries managers can be regimented or standardized; and the novel concept that current information and operations can …

Surficial Geologic Mapping Of The Starkville 7.5-Minute United States Geological Survey Quadrangle 33088d-7 In Oktibbeha County, Mississippi, Jonathan Leard

Theses and Dissertations

The Starkville Quadrangle is a hotspot for geological research. The Late Cretaceous is represented by the Demopolis Formation in the northeast corner of the quadrangle, followed by the Ripley Formation, and the Prairie Bluff Formation. The K-Pg boundary is exposed in the quadrangle, and the remarkable paleontology is of global importance. The Clayton Formation is the first Paleocene unit. Where the Clayton Formation channel sands are in contact with the underlying Prairie Bluff Formation, springs occur. Springs were a rare source of water in the Black Prairie and spurred the settlement of the area over 10,000 years ago. The Paleocene …

Performance Analysis: Using The Northern Sea Route As An Alternative To Traditional Routes, Liangkun Xu, Qing Yu

Journal of Marine Science and Technology–Taiwan

The grounding accident of M/V EVER GIVEN in the Suez Canal causes a catastrophic loss on shipping companies. Alternatively, previous studies have presented encouraging findings of the remarkable benefits of time and cost saving in the Northern sea route (NSR) due to extend the ice-free time and shorten the distance. Ships using the NSR could shorten as much as 40% of the sailing distance from China (Shanghai) to Europe (Rotterdam) compared with the traditional route via the Suez Canal. This paper investigates the economic potential of using the NSR as a cost-effective route in comparison with Suez Canal Route (SCR) …

Numerical And Approximate Analytic Solutions Of Second- Order Nonlinear Boundary Value Problems, Chein-Shan Liu, Jian-Hung Shen, Yung-Wei Chen

Journal of Marine Science and Technology–Taiwan

The shooting method consists of guessing unknown initial values, transforming a second-order nonlinear boundary value problem (BVP) to an initial value problem and integrating it to obtain the values at the right end to match the specified boundary condition, which acts as a target equation. In the shooting method, the key issue is accurately solving the target equation to obtain highly precise initial values. Due to the implicit and nonlinear property, we develop a generalized derivative-free Newton method (GDFNM) to solve the target equation, which offers very accurate initial values. Numerical examples are examined to show that the shooting method …

Optimization Of Circular Silencers Internally Hybridized With Multiple Reverse Chambers Using The Ga Method, Min-Chie Chiu, Ying-Chun Chang, Tian-Syung Lan, Ho-Sheng Chen

Journal of Marine Science and Technology–Taiwan

A noise abatement method using an eigen function in conjunction with an optimizer (Genetic Algorithm) under a space-constrain situation is proposed in this study concerning a high order wave propagation effect. An eigen function is used to describe an acoustical field and shorten the acoustical model in a four-pole transfer matrix form. The system’s four-pole matrix estimates the Transmission Loss (TL) for the silencers by multiplying individual four-pole matrices.

Additionally, a case study of an air compressor’s broadband noise elimination is introduced. Three types of circular reverse silencers (silencers A-C) internally hybridized with multiple straight chambers are adopted to efficiently …

Numerical Investigation Of The Uncertainty Of Typhoon Wave Parameters Retrieval Using Hf Radar, Toan Duy Dao, Hwa Chien

Journal of Marine Science and Technology–Taiwan

The aim of this study was to identify the sources of uncertainties of typhoon wave field monitoring using HF radar and to quantitatively assess the bias of the wave parameters, such as significant wave height and mean period, retrieved under various conditions. The strategy was to apply a purely numerical simulation of the Doppler-range spectra and then compare the estimation results to the target. For the quantitative investigation, a numerical test-bed was established. The test-bed was used to simulate the Doppler spectra based on Barrick’s (1972) theory by using the input of the directional wave spectra. The typhoon wave spectra …

A Fused Data Based Real-Time Collision Warning System For Ferries In The Yangtze River, Xiaojia Liu, Ke Zhang, Han Xue, Yingtang Li

Journal of Marine Science and Technology–Taiwan

The risks for ferries in the Yangtze River are relatively high, as they frequently cross the main traffic flows, leading to more intersections with other upwards and downwards ships. Although some studies have developed many models to assess collision risks in the Yangtze River, collision warning studies on ferries are scant. Meanwhile, most of the current collision studies evaluate risk based on AIS data, which are incapable of providing real-time ship information as they are discrete-time series data. In this work, fused data combining radar and AIS data are applied in a real-time ship collision warning model to assess the …

Experimental Study Of The Effect Of A Solid Wing Conveyor On Marine Debris Collection, Erik Sugianto, Jeng-Horng Chen

Journal of Marine Science and Technology–Taiwan

Marine debris is a global problem that has not been resolved. This has encouraged the emergence of marine debris cleaning technologies, one of which is a conveyor ship. However, how effective conveyors are in collecting waste has not been studied. In this paper, experimental research on conveyors as marine debris collectors is investigated. The capability of catamarans with or without solid wing conveyors to collect marine debris is explored. Three kinds of marine debris collection models are used: no-wing conveyor, a 12.5-cm-long wing conveyor, and an 18.75-cm-long wing conveyor. Artificial marine debris (AMD) is spread on the water surface in …

Solving Nonlinear Boundary Value Problems With Nonlinear Integral Boundary Conditions By Local And Nonlocal Boundary Shape Functions Methods, Chein-Shan Liu, Yung-Wei Chen, Jian-Hung Shen

Journal of Marine Science and Technology–Taiwan

The paper considers the second-order nonlinear boundary value problem (NBVP), which is equipped with nonlinear integral boundary conditions (BCs). Two novel iterative algorithms are developed to overcome the difficulty of NBVP with double nonlinearities involved. In the first iterative algorithm, two nonlocal shape functions incorporating the linear integral terms are derived, and a nonlocal boundary shape function (NBSF) is formulated to assist the solution. Let the solution be the NBSF so that the NBVP can be exactly transformed into an initial value problem. The new variable is a free function in the NBSF, and its initial values are given. For …

Interdisciplinary Convergence To God: A Supplement To The Big Bang & God– An Astro-Theology, Theodore Walker

Perkins Faculty Research and Special Events

Here is a December 2022 supplement to the 2015 book—The Big Bang and God: An Astro-Theology wherein an astronomer and a theologian offer a study of interdisciplinary convergences with natural theology both in the scientific researches of Sir Fred Hoyle and in the philosophical researches of Charles Hartshorne and Alfred North Whitehead, thereby illustrating a constructive postmodern trend (New York: Palgrave Macmillan, 2015) by Theodore Walker Jr. and Chandra Wickramasinghe, with editing and co-authoring by Alexander Vishio.

Biology, astronomy, astrobiology, cosmology, and theology converge when the word “God” refers to “that than which none greater can conceived” (St. Anselm), …

Iitd At The Wanlp 2022 Shared Task: Multilingual Multi-Granularity Network For Propaganda Detection, Shubham Mittal, Preslav Nakov

Natural Language Processing Faculty Publications

We present our system for the two subtasks of the shared task on propaganda detection in Arabic, part of WANLP'2022. Subtask 1 is a multi-label classification problem to find the propaganda techniques used in a given tweet. Our system for this task uses XLM-R to predict probabilities for the target tweet to use each of the techniques. In addition to finding the techniques, Subtask 2 further asks to identify the textual span for each instance of each technique that is present in the tweet; the task can be modeled as a sequence tagging problem. We use a multi-granularity network with …

Transfer Of Personality Through Text Style, Michael O'Mahony, Robert Ross

Other resources

The style of generated text is how something is said rather than what is said. We hypothesize that changing the style of generated text can change the perceived personality of the text generation agent. Dialogue systems that aim to imitate a human agent can appear to have a consistent personality through a consistent, controllable style of conversation. Some recent work on the style of generated text [1] performs impressively in the small number of domains selected for their experiments using transformer and LSTM-based models. Lin et al. [1] used weak supervised learning as their data set lacks parallel data. The …

2022 December 8 - Tennessee Weekly Drought Summary, Tennessee Climate Office, East Tennessee State University

Tennessee Climate Office Weekly Drought Summaries

No abstract provided.

Approval Letter For The Revised Residential Metals Abatement Program (Rmap), Interior School Soils Remedial Action Work Plan (Rawp), Butte High School (Dated November 17, 2022), Nikia Greene

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Evidence-Based Study: The Effect Of The Covid-19 Pandemic On Post-Secondary Enrollment And Chosen Fields Of Study, Hannah Fields '25

Student Research

The onset of the COVID-19 pandemic in the United States in March of 2020 derailed educational systems at all levels. Specifically, at the post-secondary level, the pandemic sent many students online or forced them to take a fifth year to complete their degrees. As a result, post-secondary enrollment rates are likely to have dropped to reflect these changing post-COVID views surrounding education. Additionally, changing viewpoints about the essentiality of certain jobs and roles changed the chosen fields of study of these same students. Data for this study was collected by way of a short-scale meta-analysis, and enrollment rates were split …

The Design, Synthesis, And Investigation Into Small Molecule Modulators Of The Src Homology 2 Domain-Containing Inositol 5’-Phosphatase (Ship), Shea Thomas Meyer

Dissertations - ALL

The PI3K pathway is a major cell signaling pathway that influences survival and longevity in eukaryotic cells. Abnormal signaling of this pathway has been implicated in a number of disorders, including Alzheimer's disease and cancer. The PI3K pathway utilizes the inositolphospholipid PI(3,4,5)P3 as a key secondary messenger in the transmission of signals from outside the cell to the nucleus. The SRC Homology 2 containing Inositol 5’-Phosphatase (SHIP) also plays a key role in the PI3K pathway, mediating hydrolysis of the inositol phospholipid PI(3,4,5)P3 to PI(3,4)P2. Early testing has shown modulation of SHIP activity through the use of small molecule modulators …

Multifrequency Scintillation In The Polar Caps, Tate Colby

Doctoral Dissertations and Master's Theses

In the ionosphere, plasma density structures with scales sizes ranging from a few centimeters to hundreds of kilometers are capable of modifying the phase and amplitude of a radio signal in a rapid random manner in a process called scintillation. The Coherent Electromagnetic Radio Tomography (CERTO) and the Canadian High Arctic Ionospheric Network (CHAIN) are two different networks of scintillation receivers, each with a station in Resolute Bay, Canada. CERTO measures amplitude and phase signals in VHF and UHF while CHAIN measures amplitude and phase signals in the L-band. Through these measurements we can calculate the scintillation indexes, S_4 and …

Improving Spatial Resolution Of Time Reversal Focusing Using Arrays Of Acoustic Resonators, Adam David Kingsley

Theses and Dissertations

Using a near-field array of acoustic resonators, it is possible to modify a focused pressure field and enforce a spatial frequency corresponding to the resonator array spacing. This higher spatial frequency makes it possible to focus and image with a resolution that is better than if the focusing were in free space. This near-field effect is caused by the phase shifting properties of resonators and, specifically, the delayed phase found in waves with a temporal frequency lower than that of the resonators in the array. Using time reversal, arrays of resonators are explored and the subwavelength focusing is used to …

Enhanced Neurologic Concept Recognition Using A Named Entity Recognition Model Based On Transformers, Sima Azizi, Daniel B. Hier, Donald C. Wunsch

Chemistry Faculty Research & Creative Works

Although Deep Learning Has Been Applied to the Recognition of Diseases and Drugs in Electronic Health Records and the Biomedical Literature, Relatively Little Study Has Been Devoted to the Utility of Deep Learning for the Recognition of Signs and Symptoms. the Recognition of Signs and Symptoms is Critical to the Success of Deep Phenotyping and Precision Medicine. We Have Developed a Named Entity Recognition Model that Uses Deep Learning to Identify Text Spans Containing Neurological Signs and Symptoms and Then Maps These Text Spans to the Clinical Concepts of a Neuro-Ontology. We Compared a Model based on Convolutional Neural Networks …

A Maturity Model Of Data Modeling In Self-Service Business Intelligence Software, Anna Kurenkov

Master of Science in Information Technology Theses

Although Self-Service Business Intelligence (SSBI) is continually being adopted in various industries, there is a lack of research focused on data modeling in SSBI. This research aims to fill that research gap and propose a maturity model for SSBI data modeling which is generalizeable between different software and applicable for users of all technical backgrounds. Through extensive literature review, a five-tier maturity model was proposed, explained, and instantiated in PowerBI and Tableau. The testing of the model was found to be simple and intuitive, and the research concludes that the model is applicable to enterprise SSBI environments. This research is …

Focusing Of High-Amplitude Sound Waves Using The Time Reversal Process, Brian D. Patchett

Theses and Dissertations

Time reversal is a method often used to focus sound to a desired location, and works best in a reverberant environment. The effect of focus location within a reverberant environment is presented first, revealing that proximity to reflecting surfaces has a significant effect on the amplitude of the focus both experimentally and when using a modal summation model. These effects are a primary component to creating focus signals at high amplitudes. High-amplitude focusing experiments show that when multiple sources are used simultaneously to generate a focus, a peak amplitude pressure spike of 200 dB can be achieved in air. A …

Galaxy And Mass Assembly (Gama): The Dependence Of Star Formation On Surface Brightness In Low-Redshift Galaxies, S Phillipps, S Bellstedt, M N. Bremer, R De Propris, P A. James, S Casura, J Liske, B W. Holwerda

Faculty and Staff Scholarship

The star-formation rate in galaxies is well known to correlate with stellar mass (the ‘star-forming main sequence’). Here, we extend this further to explore any additional dependence on galaxy surface brightness, a proxy for stellar mass surface density. We use a large sample of low-redshift (z ≤ 0.08) galaxies from the Galaxy And Mass Assembly survey which have both spectral energy distribution (SED) derived star-formation rates and photometric bulge-disc decompositions, the latter providing measures of disc surface brightness and disc masses. Using two samples, one of galaxies fitted by a single component with Sérsic index below 2 and one …

Hate-Clipper: Multimodal Hateful Meme Classification Based On Cross-Modal Interaction Of Clip Features, Gokul Karthik Kumar, Karthik Nandakumar

Computer Vision Faculty Publications

Hateful memes are a growing menace on social media. While the image and its corresponding text in a meme are related, they do not necessarily convey the same meaning when viewed individually. Hence, detecting hateful memes requires careful consideration of both visual and textual information. Multimodal pretraining can be beneficial for this task because it effectively captures the relationship between the image and the text by representing them in a similar feature space. Furthermore, it is essential to model the interactions between the image and text features through intermediate fusion. Most existing methods either employ multimodal pre-training or intermediate fusion, …

2022 Fall Engr333 Project Section A Final Report, Dat Cao, Sam Hoover, Sawyer Masselink, Ian Vanderkooi, Matthew Carlson, Jacob Heeres, Anthony Nykamp, Jacob Wyngarden, Nate Anderson, Anna Giboney, Gia Mien Le, Jonathan Washburn, Jess Camp, Aubree Peters, Alin Stoica, Drew Stoneburner, Claire Sheppard, Alayna Spiering, Reid Veneman, James Viel

ENGR 333

Calvin University has committed to being carbon neutral by 2057. This entails removing all the natural gas consumption for heating, converting to electrical heating options, and then making carbon free electricity. This project looked into four different options: air source heat pumps, ground source heat pumps, renewable natural gas, and the efficiency of current equipment. Each option was examined throughout the course of the semester to determine feasibility of each solution, and which ones would be best to implement. As a class, section A decided ground source heat pumps along with thermostatic valves and the implementation of double pane windows …

Free Radical-Based Sequencing For Native Top-Down Mass Spectrometry, Carolina Rojas Ramírez, Rayan Murtada, Jinshan Gao, Brandon T. Ruotolo

Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works

Native top-down proteomics allows for both proteoform identification and high-order structure characterization for cellular protein complexes. Unfortunately, tandem MS-based fragmentation efficiencies for such targets are low due to an increase in analyte ion mass and the low ion charge states that characterize native MS data. Multiple fragmentation methods can be integrated in order to increase protein complex sequence coverage, but this typically requires use of specialized hardware and software. Free-radical-initiated peptide sequencing (FRIPS) enables access to charge-remote and electron-based fragmentation channels within the context of conventional CID experiments. Here, we optimize FRIPS labeling for native top-down sequencing experiments. Our labeling …