Physical Sciences and Mathematics Commons^™

Enhancing The Forensic Comparison Process Of Common Trace Materials Through The Development Of Practical And Systematic Methods, Meghan Nicole Prusinowski

Graduate Theses, Dissertations, and Problem Reports (ETD)

An ongoing advancement in forensic trace evidence has driven the development of new and objective methods for comparing various materials. While many standard guides have been published for use in trace laboratories, different areas require a more comprehensive understanding of error rates and an urgent need for harmonizing methods of examination and interpretation. Two critical areas are the forensic examination of physical fits and the comparison of spectral data, which depend highly on the examiner’s judgment.

The long-term goal of this study is to advance and modernize the comparative process of physical fit examinations and spectral interpretation. This goal is …

Stability Properties Of A System Of Receptors In The Presence Of Attractive Domains, Basim Mohammed Al-Maliki

Graduate Theses, Dissertations, and Problem Reports (ETD)

I use mathematical modeling to understand aspects of molecular processes in living cells. Specifically, we look at the first few steps in cell signaling. Signal initiation requires that receptors located on the cell membrane bind together to form dimers. Microscopic imaging of receptors on the cell membrane revealed that receptors tend to accumulate in small areas (clusters). Studies also show that the membrane has a complex landscape consisting of domains and barriers of various origin.

Here we study the way receptor dimerization is influenced by domains on the cell membrane. Our underlying hypothesis is that the physical and chemical properties …

Enabling Technologies For Chemical Synthesis: I. Selective Microwave Heating; Ii. Synthesis And Regioselective Cyclotrimerizations Of Tethered 1,6-Diynes, Amir Tavakoli

Graduate Theses, Dissertations, and Problem Reports (ETD)

Reaction discoveries, method developments, and technology advancements lie at the heart of synthetic organic chemistry. These innovations are essential for creating and manipulating complex molecules, which are the building blocks of many important chemical compounds, including pharmaceuticals, materials, and agrochemicals. Here, we first describe new methods to prepare neopentylene-tethered (NPT) 1,6-diynes which are valuable substrates for reaction discovery and target-oriented synthesis, especially in benzannulation strategies toward illudalane natural products. NPT 1,6-diynes have been employed as coupling partners in cyclotrimerization reactions for the synthesis of highly substituted benzene rings which present a persistent challenge in chemical synthesis and are underrepresented scaffolds …

Clustering Hospital Performance Using Group-Based Multi-Trajectory Modeling With Singular Bayesian Information Criterion, Gaixin Du

Theses and Dissertations--Epidemiology and Biostatistics

Hospital performance is complex and patient-experience oriented. Currently, the Centers for Medicare and Medicaid Services (CMS) evaluate hospitals yearly with a single score of one to five ("Star Rating") using composite measures from five domains. However, a single composite score cannot fully describe it, and alternative measures should be considered. Healthcare quality improvement needs long-term data to validate effectiveness. Group-based multi-trajectory modeling (GBMTM) estimates probabilities of latent group membership based on longitudinal profiles from multiple outcomes. We use GBMTM to identify groups of hospitals with similar performance in SAS PROC TRAJ.

We downloaded Medicare-eligible hospitals (N=5,111) that provided patient care …

Potential Alzheimer's Disease Plasma Biomarkers, Taylor Estepp

Theses and Dissertations--Epidemiology and Biostatistics

In this series of studies, we examined the potential of a variety of blood-based plasma biomarkers for the identification of Alzheimer's disease (AD) progression and cognitive decline. With the end goal of studying these biomarkers via mixture modeling, we began with a literature review of the methodology. An examination of the biomarkers with demographics and other health factors found evidence of minimal risk of confounding along the causal pathway from biomarkers to cognitive performance. Further study examined the usefulness of linear combinations of biomarkers, achieved via partial least squares (PLS) analysis, as predictors of various cognitive assessment scores and clinical …

Active Learning For Efficient Soil Monitoring In Large Terrain With Heterogeneous Sensor Network, Hui Chen, Ju Wang

Publications and Research

Soils are a complex ecosystem that provides critical services, such as growing food, supplying antibiotics, filtering wastes, and maintaining biodiversity; hence monitoring soil health and domestication is required for sustainable human development. Low-cost and high-resolution soil monitoring systems are challenging to design and build. Compounded by the sheer size of the monitoring area of interest and the variety of biological, chemical, and physical parameters to monitor, naive approaches to adding or scheduling more sensors will suffer from cost and scalability problems. We investigate a multi-robot sensing system integrated with an active learning-based predictive modeling technique. Taking advantage of advances in …

Futures On Dry Ground: Anthropology And Coastal Planning, Theodore Hilton, Sheehan Moore

Publications and Research

Around the world, governments, industry, and other actors are creating plans to save coasts from environmental crisis. Louisiana is one prominent example: levees and other measures protect oil and gas infrastructure from inundation as the wetlands buffer rapidly erodes—in large part due to that same industry. The state’s primary answer to land loss is a $50 billion Coastal Master Plan. To illuminate such responses in Louisiana and globally, this article reviews emerging literature and frames an anthropology of coastal planning around three themes: (1) novel orientations toward time and space, (2) the reproduction of power and capital in the name …

Molecular Mechanism Behind The Safe Immunostimulatory Effect Of Withania Somnifera, Kriti Kalpana, Shen Yap, Moriya Tsuji, Akira Kawamura

Publications and Research

Withania somnifera (L.) Dunal (family Solanaceae) is a medicinal plant known for, among many pharmacological properties, an immune boosting effect. Our recent study revealed that its key immunostimulatory factor is lipopolysaccharide of plant-associated bacteria. This is peculiar, because, although LPS can elicit protective immunity, it is an extremely potent pro-inflammatory toxin (endotoxin). However, W. somnifera is not associated with such toxicity. In fact, despite the presence of LPS, it does not trigger massive inflammatory responses in macrophages. To gain insights into the safe immunostimulatory effect of W. somnifera, we conducted a mechanistic study on its major phytochemical constituent, …

Changes To Sea Surface Temperatures And Vertical Wind Shear And Their Influence On Tropical Cyclone Activity In The Caribbean And The Main Developing Region, Keneshia Hibbert, Equisha Glenn, Thomas M. Smith, Jorge E. González-Cruz

Publications and Research

Sea surface temperatures and vertical wind shear are essential to tropical cyclone formation. TCs need warm SSTs and low shear for genesis. Increasing SSTs and decreasing VWS influences storm development. This work analyzes SST and VWS trends for the Caribbean, surrounding region, and the Atlantic hurricane main developing region from 1982–2020. Storm intensity increases significantly during this period. Annual and seasonal trends show that regional SSTs in the MDR are warming annually at 0.0219 °C yr⁻¹ and, per season, 0.0280 °C yr⁻¹. Simultaneously, VWS decreases during the late rainfall season, at 0.056 m/s yr⁻¹ in the …

Ecological Niche Comparison Among Closely Related Tree Species Of Lauraceae Using Climatic And Edaphic Data, Laura J. Giraldo-Kalil, Gonzalo E. Pinilla Buitrago, Andrés Lira-Noriega, Francisco Lorea-Hernández, Juan Núñez-Farfán

Publications and Research

ABSTRACT:

Edaphic specialization is considered to promote ecological differentiation among closely related species of Damburneya (Lauraceae) occurring in sympatry. However, little is known about the effects of soil and other key environmental factors like climate on the ecological niche and distribution of these tree species. Here, we assessed the role of climate and soil on niche divergence and potential distribution of four Damburneya species whose distributions span Central America and Mexico. We performed ecological niche modeling with MaxEnt using three sets of environmental data: climatic-only, edaphic-only, and a combination of both, to characterize species niches and suitable distribution areas. Niche …

Hamiltonian Structure Of 2d Fluid Dynamics With Broken Parity, Gustavo Machado Monteiro, Alexander G. Abanov, Sriram Ganeshan

Publications and Research

Isotropic fluids in two spatial dimensions can break parity symmetry and sustain transverse stresses which do not lead to dissipation. Corresponding transport coefficients include odd viscosity, odd torque, and odd pressure. We consider an isotropic Galilean invariant fluid dynamics in the adiabatic regime with momentum and particle density conservation. We find conditions on transport coefficients that correspond to dissipationless and separately to Hamiltonian fluid dynamics. The restriction on the transport coefficients will help identify what kind of hydrodynamics can be obtained by coarse-graining a microscopic Hamiltonian system. Interestingly, not all parity-breaking transport coefficients lead to energy conservation and, generally, the …

Inclusive Random Sampling In Graphs And Networks, Yitzchak Novick, Amotz Bar-Noy

Publications and Research

It is often of interest to sample vertices from a graph with a bias towards higher-degree vertices. One well-known method, which we call random neighbor or RN, involves taking a vertex at random and exchanging it for one of its neighbors. Loosely inspired by the friendship paradox, the method is predicated on the fact that the expected degree of the neighbor is greater than or equal to the expected degree of the initial vertex. Another method that is actually perfectly analogous to the friendship paradox is random edge, or RE, where an edge is sampled at random, and then one …

Quantity Of Questing Black-Legged Ticks And Associated Micro-Scale Environmental Data Collected From Four Suburban Parks Near New York City, Shipeng Sun, Chong Di, Li Li, Brian Sulkow, Weigang Qiu

Publications and Research

During 2017 and 2018, we collected the quantity of questing black-legged ticks (Ixodes scapularis), also known as deer ticks, in 124 sampling sites of 5m by 5m in four state parks—Caumsett State Historic Park, Connetquot River State Park, Rockefeller State Park, and Fire Island National Seashore—around New York City. The black-legged tick is the primary vector for the spirochete Borrelia burgdorferi, the pathogen of Lyme disease, in Northeastern United States. Using the flagging method, we collected and counted the numbers of adult and nymphal black-legged ticks at each site. Along with these quantities, we also recorded the …

Aligning Retrograde Nuclear Cluster Orbits With An Active Galactic Nucleus Accretion Disc, Syeda S. Nasim, Gaia Fabj, Freddy Caban, Amy Secunda, K. E. Saavik Ford, Barry Mckernan, Jillian M. Bellovary, Nathan W. C. Leigh, Wladimir Lyra

Publications and Research

Stars and stellar remnants orbiting a supermassive black hole (SMBH) can interact with an active galactic nucleus (AGN) disc. Over time, prograde orbiters (inclination i < 90°) decrease inclination, as well as semimajor axis (a) and eccentricity (e) until orbital alignment with the gas disc (‘disc capture’). Captured stellar-origin black holes (sBH) add to the embedded AGN population that drives sBH–sBH mergers detectable in gravitational waves using LIGO–Virgo–KAGRA or sBH–SMBH mergers detectable with Laser Interferometer Space Antenna. Captured stars can be tidally disrupted by sBH or the SMBH or rapidly grow into massive ‘immortal’ stars. Here, we investigate the behaviour of polar and retrograde orbiters …

Identity-Based Edge Computing Anonymous Authentication Protocol, Naixin Kang, Zhenhu Ning, Shiqiang Zhang, Sadaqat Ur Rehman, Muhammad Waqas

Research outputs 2022 to 2026

With the development of sensor technology and wireless communication technology, edge computing has a wider range of applications. The privacy protection of edge computing is of great significance. In the edge computing system, in order to ensure the credibility of the source of terminal data, mobile edge computing (MEC) needs to verify the signature of the terminal node on the data. During the signature process, the computing power of edge devices such as wireless terminals can easily become the bottleneck of system performance. Therefore, it is very necessary to improve efficiency through computational offloading. Therefore, this paper proposes an identity-based …

Photocatalytic Reforming Of Lignocellulose: A Review, Xinyuan Xu, Lei Shi, Shu Zhang, Zhimin Ao, Jinqiang Zhang, Shaobin Wang, Hongqi Sun

Research outputs 2022 to 2026

Biomass has been considered as a promising energy resource to combat the exhaustion of fossil fuels, as it is renewable, sustainable, and clean. Photocatalytic reforming is a novel technology to utilize solar energy for upgrading biomass in relatively mild conditions. This process efficiently reforms and recasts biomass into hydrogen and/or valuable chemicals. To date, lignocellulose, including cellulose, hemicellulose and lignin, has attracted extensive studies in facile photocatalytic valorisation. This review summarizes and analyzes the most recent research advances on photoreforming of lignocellulose to provide insights for future research, with a particular emphasis on the reformation of lignin because of its …

Utilizing Proteomics To Identify And Optimize Microalgae Strains For High-Quality Dietary Protein: A Review, Sara Hamzelou, Damien Belobrajdic, James A. Broadbent, Angéla Juhász, Kim L. Chang, Ian Jameson, Peter Ralph, Michelle L. Colgrave

Research outputs 2022 to 2026

Algae-derived protein has immense potential to provide high-quality protein foods for the expanding human population. To meet its potential, a broad range of scientific tools are required to identify optimal algal strains from the hundreds of thousands available and identify ideal growing conditions for strains that produce high-quality protein with functional benefits. A research pipeline that includes proteomics can provide a deeper interpretation of microalgal composition and biochemistry in the pursuit of these goals. To date, proteomic investigations have largely focused on pathways that involve lipid production in selected microalgae species. Herein, we report the current state of microalgal proteome …

Edna Metabarcoding Of Avocado Flowers: ‘Hass’ It Got Potential To Survey Arthropods In Food Production Systems?, Joshua H. Kestel, Philip W. Bateman, David L. Field, Nicole E. White, Rose Lines, Paul Nevill

Research outputs 2022 to 2026

In the face of global biodiversity declines, surveys of beneficial and antagonistic arthropod diversity as well as the ecological services that they provide are increasingly important in both natural and agro-ecosystems. Conventional survey methods used to monitor these communities often require extensive taxonomic expertise and are time-intensive, potentially limiting their application in industries such as agriculture, where arthropods often play a critical role in productivity (e.g. pollinators, pests and predators). Environmental DNA (eDNA) metabarcoding of a novel substrate, crop flowers, may offer an accurate and high throughput alternative to aid in the detection of these managed and unmanaged taxa. Here, …

Camdec: Advancing Axis P1435-Le Video Camera Security Using Honeypot-Based Deception, Leslie F. Sikos, Craig Valli, Alexander E. Grojek, David J. Holmes, Samuel G. Wakeling, Warren Z. Cabral, Nickson M. Karie

Research outputs 2022 to 2026

The explosion of online video streaming in recent years resulted in advanced services both in terms of efficiency and convenience. However, Internet-connected video cameras are prone to exploitation, leading to information security issues and data privacy concerns. The proliferation of video-capable Internet of Things devices and cloud-managed surveillance systems further extend these security issues and concerns. In this paper, a novel approach is proposed for video camera deception via honeypots, offering increased security measures compared to what is available on conventional Internet-enabled video cameras.

Strengthening The Interpretation Of Glass And Paint Evidence Through The Study Of Random Frequency Of Occurrence And Analytical Information, Lauryn C. Alexander

Graduate Theses, Dissertations, and Problem Reports (ETD)

Glass and paint particles are frequently discovered at crime scenes as valuable trace evidence. Often, these fragments are transferred from a crime scene to a victim or person-of-interest, and can subsequently be evaluated, analyzed, and classified according to their physical and optical measurements, and chemical properties, each of which can provide important information to the analyst to assist in the determining if a recovered particle is distinguishable or indistinguishable from a known source. Moreover, these minute materials can provide information about how the events took place, leading to the reconstruction of crime scenes and the identification of valuable clues for …

Enantioselective Dearomatization Facilitated By Non-Covalent Interactions Of N-Heterocyclic Carbene Catalysts And Pyridinium Salts, Jack A. Patterson

Graduate Theses, Dissertations, and Problem Reports (ETD)

Dihydropyridines are a practical organic scaffold commonly used for their pharmaceutical properties. Nucleophilic dearomatization of pyridines has proven to be a useful method in obtaining dihydropyridines. By using N-heterocyclic carbene (NHC) organocatalysts, dihydropyridines can be synthesized with high regioselectivity of the 1,4 regioisomer over the 1,2- regioisomer but often with low enantioselectivity. By incorporating non-covalent interaction contact points, we hypothesize that enantioselectivity can be enhanced. By synthesizing numerous NHCs, each proposed to exhibit a different type of non-covalent interaction (i.e., hydrogen bonding or ion pairing), an understanding of the secondary interactions within this reaction system can be studied and …

Effects Of Invasive Species On Ohio River Zooplankton, Samuel John Johnston

Graduate Theses, Dissertations, and Problem Reports (ETD)

Invasive species have the potential to dramatically change both aquatic and terrestrial ecosystems with rates of introduction only expected to increase across the Globe. In the Mississippi River basin filter feeding silver (Hypophthalmichthys molitrix) and bighead carp (Hypophthalmichthys nobilis) collectively known as invasive carp were introduced into aquaculture ponds where they subsequently escaped and spread to interconnected basins. Invasive carp have not yet completely established throughout the entire Ohio River. Managers recognize three distinct phases of carp invasion: establishment front, invasion front and presence front. In the Illinois River invasive carp are very well established and …

Longest Path And Cycle Transversal And Gallai Families, James A. Long Jr

Graduate Theses, Dissertations, and Problem Reports (ETD)

A longest path transversal in a graph G is a set of vertices S of G such that every longest path in G has a vertex in S. The longest path transversal number of a graph G is the size of a smallest longest path transversal in G and is denoted lpt(G). Similarly, a longest cycle transversal is a set of vertices S in a graph G such that every longest cycle in G has a vertex in S. The longest cycle transversal number of a graph G is the size of a smallest longest cycle transversal in G and …

A Study Of Accidental Daughter Crystals In Fluid Inclusions In Bedded Halite From The Permian Opeche Shale And Cedar Hills Sandstone Of The Midcontinental United States, Ryan James Prchlik

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ancient acid-saline lakes of the midcontinental United States deposited bedded halite during Permian time. These deposits are not typically preserved at the surface, but drill cores of the Opeche Shale of North Dakota and Cedar Hills Sandstone of Kansas contain preserved beds of halite. Halite from these ancient lakes have primary fluid inclusions that contain Permian lake water. Also included are accidental daughter crystals that were trapped inside the fluid inclusions at time of halite precipitation. Both the fluid and daughter crystals inside bedded halite can tell us about the geochemistry of original lake waters of Pangea.

Petrography and laser …

Sequence Checking And Deduplication For Existing Fingerprint Databases, Tahsin Islam Sakif

Graduate Theses, Dissertations, and Problem Reports (ETD)

Biometric technology is a rapidly evolving field with applications that range from access to devices to border crossing and entry/exit processes. Large-scale applications to collect biometric data, such as border crossings result in multimodal biometric databases containing thousands of identities. However, due to human operator error, these databases often contain many instances of image labeling and classification; this is due to the lack of training and throughput pressure that comes with human error. Multiple entries from the same individual may be assigned to a different identity. Rolled fingerprints may be labeled as flat images, a face image entered into a …

Synthesis And Pharmacology Of Illudalic Acid And Analogous Chemical Structures, Robert Gaston Jr

Graduate Theses, Dissertations, and Problem Reports (ETD)

Natural products are the foundation of modern medicine and an inspiration for chemical innovation. Developing new synthetic strategies to complex natural products drives synthetic innovation and promotes pharmacological exploration. As bioactive secondary metabolites of fungi, illudalic acid and associated analogs have unrealized medicinal potential due to synthetic limitations. Illudalic acid is notably the first selective covalent inhibitor of the LAR-PTPs, a class of enzymes linked to many human illnesses, including stimulant addiction. The chemistry herein focuses on optimizing synthetic routes to illudalic acid and associated analogs toward exploring their pharmaceutical potential. We report a second-generation synthesis of illudinine (55% overall …

Machine Learning Prediction Of Dod Personal Property Shipment Costs, Tiffany Tucker, Torrey J. Wagner, Paul Auclair, Brent T. Langhals

Faculty Publications

U.S. Department of Defense (DoD) personal property moves account for 15% of all domestic and international moves - accurate prediction of their cost could draw attention to outlier shipments and improve budget planning. In this work 136,140 shipments between 13 personal property shipment hubs from April 2022 through March 2023 with a total cost of $1.6B were analyzed. Shipment cost was predicted using recursive feature elimination on linear regression and XGBoost algorithms, as well as through neural network hyperparameter sweeps. Modeling was repeated after removing 28 features related to shipment hub location and branch of service to examine their influence …

Ambient Ammonia Synthesis Via Microwave-Catalytic Materials And Plasma Chemistry, Siobhan Brown

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ammonia is critical to supporting human life on earth because of its use as fertilizer. The Haber-Bosch process to produce ammonia has been practiced for over 100 years. This process operates at high pressure and temperature to overcome the thermodynamic and kinetic limitations of the ammonia synthesis reaction thus researchers have tried to overcome it for decades. At present this process represents 1% of global energy usage and 2.5% of global CO₂ emissions. The proposed chemical looping ammonia synthesis approach seeks to reduce the environmental impact of this critical process and to elucidate microwave-catalytic principles.

This research aims to …

Optimal Design And Operation Of Integrated Hydrogen Generation And Utilization Plants, Ijiwole Solomon Ijiyinka

Graduate Theses, Dissertations, and Problem Reports (ETD)

There are considerable efforts worldwide for reducing the use of fossil fuel for energy production. While renewable energy sources are being increasingly used, fossil fuel still contribute about 80% of the energy used worldwide. As a result, the level of CO₂ is still increasing fast in the atmosphere currently exceeding about 410 parts per million (ppm). For reducing CO₂ build up in the atmosphere, various approaches are being investigated. For the electric power generation sector, two key approaches are post-combustion CO₂ capture and use of hydrogen as a fuel for power generation. These two solutions can also …

Generative Prior For Unsupervised Image Restoration, Ahmed Cheikh Sidiya

Graduate Theses, Dissertations, and Problem Reports (ETD)

The challenge of restoring real world low-quality images is due to a lack of appropriate training data and difficulty in determining how the image was degraded. Recently, generative models have demonstrated great potential for creating high- quality images by utilizing the rich and diverse information contained within the model’s trained weights and learned latent representations. One popular type of generative model is the generative adversarial network (GAN). Many new methods have been developed to harness the information found in GANs for image manipulation. Our proposed approach is to utilize generative models for both understanding the degradation of an image and …