Physical Sciences and Mathematics Commons^™

In Quest Of A Shared Planet: Negotiating Climate From The Global South, Naveeda Khan

Literary Studies

Based on the author’s eight years of fieldwork with the United Nations-led Conference of Parties (COP), In Quest of a Shared Planet offers an illuminating first-person ethnographic perspective on climate change negotiations. Focusing on the Paris Agreement, anthropologist Naveeda Khan introduces readers to the only existing global approach to the problem of climate change, one that took nearly thirty years to be collectively agreed upon. She shares her detailed descriptions of COP21 to COP25 and growing understanding of the intricacies of the climate negotiation process, leading her to ask why countries of the Global South invested in this slow-moving process …

Revisiting The Definition Of Field Capacity As A Functional Parameter In A Layered Agronomic Soil Profile Beneath Irrigated Maize, Paolo Nasta, Trenton E. Franz, Justin P. Gibson, Nunzio Romano

School of Natural Resources: Faculty Publications

The soil water content at the condition of field capacity (θ_FC) is a key parameter in irrigation scheduling and has been suggested to be determined by running a synthetic drainage experiment until the flux rate (q) at the bottom of the soil profile achieves a predefined negligible value (q_FC). We question the impact of q_FC on the assessment of field capacity. Moreover, calculating θ_FC as the integral mean of the water content profile when q is equal to q_FC is strictly valid only for uniform soil profiles. By contrast, …

Cms Pythia 8 Colour Reconnection Tunes Based On Underlying-Event Data, A. Tumasyan

Department of Physics and Astronomy: Faculty Publications

New sets of parameter tunes for two of the colour reconnection models, quantum chromodynamics-inspired and gluon-move, implemented in the pythia 8 event generator, are obtained based on the default CMS pythia 8 underlying-event tune, CP5. Measurements sensitive to the underlying event performed by the CMS experiment at centre-of-mass energies √ s = 7 and 13 TeV, and by the CDF experiment at 1.96 TeV are used to constrain the parameters of colour reconnection models and multiple-parton interactions simultaneously. The new colour reconnection tunes are compared with various measurements at 1.96, 7, 8, and 13 TeV including measurements of the underlying-event, …

Final Rmap Park Soil Sampling Field Sampling Plan (Fsp) Submittal #7 [Covering Gold Hill Lutheran Church, Peoples Park, Sioux Park, Charlie Judd Park, Emma Park, Mandan Park, And Walkerville Park (Daly And Dunn)], Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

A Gridded Co2 Emissions Inventory For Portland, Or, James E. Powell

Dissertations and Theses

Here we develop a new high resolution inventory of CO₂ emissions for the three Oregon counties which comprise the bulk of the City of Portland, Oregon, USA. Locally curated and long-running data collection efforts for on-road traffic activity and emission rates are used to model on-road emissions, and a new survey of the area's natural gas network informs the building energy model. The inventory estimates total emissions of CO₂ for each hour of the year 2018 in the on-road, residential, and commercial building sectors at 1 km² resolution. The onroad inventory compares to within 3% with an …

Implementing A Functional Logic Programming Language Via The Fair Scheme, Andrew Michael Jost

Dissertations and Theses

This document presents a new compiler for the Functional Logic programming language Curry based on a novel pull-tabbing evaluation strategy called the Fair Scheme. A simple version of the Fair Scheme is proven sound, complete, and optimal. An elaborated version is also developed, which supports narrowing computations and other features of Curry, such as constraint programming, equational constraints, and set functions.

The Fair Scheme is used to develop a new Curry system called Sprite, a high-quality, performant implementation whose aims are to promote practical uses of Curry and to serve as a laboratory for further research. An important aspect of …

Evaluation Of Temperature-Index And Energy-Balance Snow Models For Hydrological Applications In Operational Water Supply Forecasts, Tian Gan, David G. Tarboton, Tseganeh Z. Gichamo

Civil and Environmental Engineering Faculty Publications

In the western United States, snow accumulation, storage, and ablation affect seasonal runoff. Thus, the prediction of snowmelt is essential to improve the reliability of water supply forecasts to guide water allocation and operational decisions. The current method used at the Colorado Basin River Forecast Center (CBRFC) couples the SNOW-17 temperature index snow model and the Sacramento Soil Moisture Accounting (SAC-SMA) runoff model in a lumped approach. Limitations in parameter transferability and calibration requirements for changing conditions with the temperature-index model motivated this research, in which new avenues were investigated to assess and prototype the application of an energy-balance snow …

Effective Non-Hermiticity And Topology In Markovian Quadratic Bosonic Dynamics, Vincent Paul Flynn

Dartmouth College Ph.D Dissertations

Recently, there has been an explosion of interest in re-imagining many-body quantum phenomena beyond equilibrium. One such effort has extended the symmetry-protected topological (SPT) phase classification of non-interacting fermions to driven and dissipative settings, uncovering novel topological phenomena that are not known to exist in equilibrium which may have wide-ranging applications in quantum science. Similar physics in non-interacting bosonic systems has remained elusive. Even at equilibrium, an "effective non-Hermiticity" intrinsic to bosonic Hamiltonians poses theoretical challenges. While this non-Hermiticity has been acknowledged, its implications have not been explored in-depth. Beyond this dynamical peculiarity, major roadblocks have arisen in the search …

Synthesis And Characterization Of Porphyrin-Encapsulated Nanoparticles: Investigations With Scanning Probe Microscopy, Olajumoke Helen Olubowale

LSU Doctoral Dissertations

Scanning probe microscopy (SPM) encompasses a family of surface measurements that use a sharp probe to “feel” a surface. The tip is scanned point-by-point to build a map of the sample topography, which can be correlated with local measurements of surface properties. This dissertation outlines the history of SPM and describes techniques, operational modes, and applications. A review of force volume mapping (FVM), a 3D characterization mode of SPM used to map material properties detailed. Force volume mapping can be achieved by measuring multiple force measurements point-by-point in a grid pattern. Local properties such as chemical forces, dielectric properties, nanomechanical …

Method Of Evanescently Coupling Whispering Gallery Mode Optical Resonators Using Liquids, Hengky Chandrahalim, Kyle T. Bodily

AFIT Patents

The present invention relates to evanescently coupling whispering gallery mode optical resonators having a liquid coupling as well as methods of making and using same. The aforementioned evanescently coupling whispering gallery mode optical resonators having a liquid couplings provide increased tunability and sensing selectivity over current same. The aforementioned. Applicants’ method of making evanescent-wave coupled optical resonators can be achieved while having coupling gap dimensions that can be fabricated using standard photolithography. Thus economic, rapid, and mass production of coupled WGM resonators-based lasers, sensors, and signal processors for a broad range of applications can be realized.

A Hörmander–Fock Space, Daniel Alpay, Fabrizio Colombo, Kamal Diki, Irene Sabadini, Daniele C. Struppa

Mathematics, Physics, and Computer Science Faculty Articles and Research

In a recent paper we used a basic decomposition property of polyanalytic functions of order 2 in one complex variable to characterize solutions of the classical ∂-problem for given analytic and polyanalytic data. Our approach suggested the study of a special reproducing kernel Hilbert space that we call the Hörmander-Fock space that will be further investigated in this paper. The main properties of this space are encoded in a specific moment sequence denoted by η= (η_n)_n≥0 leading to a special entire function E(z) that is used to express the kernel function of the Hörmander-Fock space. We …

Visible Light Photoacid Generator Catalyzed Michael Additions & In-Situ Photoredox Generated Carbocation Catalysis, Zena M. Salem

Seton Hall University Dissertations and Theses (ETDs)

Proton transfer is essential in many natural and chemical processes, and photoacids that undergo proton dissociation or generation upon photoirradiation can be beneficial for use in acid-sensitive reactions. This work describes the use of photoacid generators (PAGs) as tools for organic synthesis, generating strong acids upon light absorption catalyzing Michael addition reactions. Specifically, visible-light-induced PAGs were used to facilitate the 1,4-conjugate addition between indoles and vinyl ketones. Furthermore, carbocations have gained attention as Lewis acid catalysts in a variety of reactions providing good selectivity and yields. We also demonstrate the viability of in-situ photoredox-generated carbocation catalysis in the context of …

Hydrolysis-Directed Vapor-Phase Synthesis And Solution Processing Of Nanostructured Conducting Polymers, Haoru Yang

Arts & Sciences Graduate Student Theses and Dissertations

Conducting polymers are a class of organic material that possesses semiconducting properties. Their unique molecular structure facilitates charge transport via delocalized π-electron network in the polymer backbone. Creating nanostructures in a conducting polymer increases its surface area to volume ratio and promotes molecular interaction at the surface of the polymer, resulting in enhanced physical and chemical properties, such as ion transfer, adsorption/desorption efficiency, and electrical conductivity. This dissertation focuses on synthesizing nanostructured conducting polymers and their composites from the vapor phase. The mechanisms in a novel synthetic strategy that utilizes iron corrosion products to initiate polymerization and template nanostructure formation …

New Methods Of Selectivity Using Electrochemistry, Qiwei Jing

Arts & Sciences Graduate Student Theses and Dissertations

This project has been working on introducing new type of method to induce chemoselectivity into electrochemical reactions by modifying the surface of an electrode and then confining chemical reactions to the region of the reaction close to that surface. The goal is to translate the extremely high levels of site-selectivity seen in chemical reactions on a microelectrode array into a tool for preparative synthetic reactions.As a proof-of-principle experiment, Pt-anode was coated with a diblock copolymer that is known to have an affinity for pyrene groups. The electrode is then used in the oxidation of two alcohol substrates: one having the …

Experimental Investigation Of Non-Hermiticity In Quantum Systems, Maryam Abbasi

Arts & Sciences Graduate Student Theses and Dissertations

The investigation of quantum systems in experimental setups involves interaction with the environment, which introduces channels of dissipation. These systems can be described by a non-Hermitian Hamiltonian, capturing the effect of gain and loss. Realizing these systems in classical cases demonstrates interesting phenomena such as topological features in the optical and mechanical domain, energy transfer, and enhancement in sensing. The primary focus of this thesis is the realization of the non-Hermiticity in a quantum system. To accomplish this, we harness multiple energy levels of an anharmonic superconducting circuit with coupling to an engineered bath to investigate the static and dynamic …

Ptmtorrent: A Dataset For Mining Open-Source Pre-Trained Model Packages, Wenxin Jiang, Nicholas Synovic, Purvish Jajal, Taylor R. Schorlemmer, Arav Tewari, Bhavesh Pareek, George K. Thiruvathukal, James C. Davis

Computer Science: Faculty Publications and Other Works

Due to the cost of developing and training deep learning models from scratch, machine learning engineers have begun to reuse pre-trained models (PTMs) and fine-tune them for downstream tasks. PTM registries known as “model hubs” support engineers in distributing and reusing deep learning models. PTM packages include pre-trained weights, documentation, model architectures, datasets, and metadata. Mining the information in PTM packages will enable the discovery of engineering phenomena and tools to support software engineers. However, accessing this information is difficult — there are many PTM registries, and both the registries and the individual packages may have rate limiting for accessing …

Downstream Gradients In Unit Stream Power Influence Log Jam Location And Process Domain, Eliza H. Malakoff

Dartmouth College Master’s Theses

Growing calls for the use of natural materials and processes to meet management goals have positioned artificial log jams as a compelling alternative to hard engineering instream and floodplain habitat. Deep uncertainties remain, however, about where and how wood should be placed to best mimic natural river processes. In this study, I test whether at-a-point or downstream gradients in unit stream power, an estimate of a river’s ability to do work, exert control over where and how log jams form. Using field observations of 360 log jams in New Hampshire and Vermont and an additional 320 previously published locations of …

An Assistive Interface For Displaying Novice's Code History, Ruiwei Xiao

McKelvey School of Engineering Graduate Student Theses & Dissertations

As Teaching Assistant (TA) programs grow in number and size in introductory CS courses, TAs play a significant role in novice programmers' experience and contribute to their success. However, many TAs are also relative beginners themselves and thus have limited experience in programming and teaching. Thus the effectiveness and consistency of their guidance can vary significantly. To improve interaction quality and assist TAs in providing better support, we examine the difficulties encountered by inexperienced TAs in previous literature and then identify the potential for the high cognitive load as an unaddressed difficulty that may prevent new TAs from initiating effective …

Unraveling The Quantum Hall Effects: From Conformal Field Theory Inspired Tensor Networks To Interacting Many-Body Simulations, Matheus Schossler

Arts & Sciences Graduate Student Theses and Dissertations

Systems confined in the two-dimensional world have long played a major role in physics. Under a quantizing magnetic field, these systems can exhibit phases of matter described by beautiful trial wave functions. Although there are numerous solvable models for fractional quantum Hall (FQH) physics, they are primarily developed and studied from the viewpoint of clustering properties of these wave functions in first quantization. Here we investigate frustration-free Hamiltonians of FQH states and their connection with 1D tensor networks, or matrix product state (MPS), based on the conformal field theory (CFT) representation of their ground and excited states. Examining these Hamiltonians …

Deformation Of Hydrous Magnesium Silicates In Subduction Zone Environments, Charis Madeleine Horn

Arts & Sciences Graduate Student Theses and Dissertations

Hydrous magnesium silicates form primarily from the interaction of seawater with the oceanic lithosphere and are drawn down into the mantle by subducting slabs at convergent margins. It is thought that they hold an important control over several aspects of the subduction multisystem, with implications for many different subduction zone processes. In particular, the hydrous magnesium silicates serpentine and talc exhibit unusual rheological and anisotropic properties. To explore the effects of these minerals on global subduction zones, we conducted three separate studies on talc (Mg3Si4O10(OH)2) and two of the serpentine group minerals (Mg3Si2O5(OH)4), lizardite and antigorite. Firstly, to understand the …

Draft Final Bpsou Unreclaimed Sites Ur-06 Temporary Best Management Practice Work Plan, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Butte Reduction Works (Brw) Smelter Area Mine Waste Remediation And Contaminated Groundwater Hydraulic Control Site Quality Assurance Project Plan (Qapp) For Microbial Analysis And Biotreatability; Request For Change Brw-2023-02, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Expressive Marks: Art In The Age Of Augmented Reality, Carson G. Levine

Dartmouth College Master’s Theses

Augmented reality (AR) and non-fungible tokens (NFTs) introduce new considerations for the long-standing debate of what it means for digital art to be “real.” However, the ability to create AR experiences is limited to those who are technically skilled or who can afford to consult someone else. This paper addresses the need for an accessible tool that enables artists of all technical backgrounds to expressively create marks in AR. The solution includes a mobile application called CrayonAR. The system was designed to be modular, minimal, and physically engaging, and was developed in Unity using ARFoundation and Firebase Storage and Realtime …

Artificial Intelligence In Neuroradiology: A Scoping Review Of Some Ethical Challenges, Pegah Khosravi, Mark Schweitzer

Publications and Research

Artificial intelligence (AI) has great potential to increase accuracy and efficiency in many aspects of neuroradiology. It provides substantial opportunities for insights into brain pathophysiology, developing models to determine treatment decisions, and improving current prognostication as well as diagnostic algorithms. Concurrently, the autonomous use of AI models introduces ethical challenges regarding the scope of informed consent, risks associated with data privacy and protection, potential database biases, as well as responsibility and liability that might potentially arise. In this manuscript, we will first provide a brief overview of AI methods used in neuroradiology and segue into key methodological and ethical challenges. …

Development And Validation Of A Uplc-Ms/Ms Method To Investigate The Plasma Pharmacokinetics Of A KCa2.2/KCa2.3 Positive Allosteric Modulator In Mice, Mohammad Asikur Rahman, Devaraj Venkatapura Chandrashekar, Young-Woo Nam, Basir Syed, David Salehi, Hamidreza Montazeri Aliabadi, Miao Zhang, Reza Mehvar

Pharmacy Faculty Articles and Research

Rationale

There is currently no treatment for spinocerebellar ataxias (SCAs), which are a group of genetic disorders that often cause a lack of coordination, difficulty walking, slurred speech, tremors, and eventually death. Activation of K_Ca2.2/K_Ca2.3 channels reportedly exerts beneficial effects in SCAs. Here, we report the development and validation of an analytical method for quantitating a recently-developed positive allosteric modulator of K_Ca2.2/K_Ca2.3 channels (compound 2q) in mouse plasma.

Methods

Mouse plasma samples (10 μL) containing various concentrations of 2q were subjected to protein precipitation in the presence of a structurally similar internal …

Application Of Advanced Mathematical Approaches To The Interpretation Of Remote Sensing Observations Of The Surface Of Mars, John Randall Christian

Arts & Sciences Graduate Student Theses and Dissertations

Spectroscopic imagers have been used to analyze the surface of Mars at varying spatial scales in several distinct modalities, each of which provides different information about surface geology and geochemistry. In this dissertation, we take a closer look at two such spectroscopic imagers: the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) on board the Mars Reconnaissance Orbiter and the Planetary Instrument for X-ray Lithochemistry (PIXL) on board the Mars 2020 rover Perseverance. We apply new mathematical models to data collected by CRISM to infer physical properties from a complex (and therefore underutilized) portion of the spectrum, and to data collected …

Non-Adjacent Anti Cyclobutane Pyrimidine Dimers As Intrinsic Probes Of Non-B Form Secondary Structures Of Dna, Natalia Eugenia Gutierrez Bayona

Arts & Sciences Graduate Student Theses and Dissertations

G-quadruplexes are four-stranded structures of DNA composed of G-quartets that have been proposed to play an extremely important role in replication, transcription, and translation. It has, however, been extremely difficult to unequivocally demonstrate that G-quadruplexes form in living cells due to the lack of probes that would allow for their unambiguous detection and location without disrupting the DNA or the cellular environment. To circumvent these problems, it was proposed that DNA itself could be used as an intrinsic photoprobe for certain classes of G-quadruplex structures and other non-B DNA conformations in vivo. Recently, we discovered that UVB irradiation of human …

A Torsion Balance Search For Long-Range Interactions Coupling To Baryons And Leptons And Cosmic Ray Transport For Spatially And Temporally Continuous And Discrete Sources, Dawson Huth

Arts & Sciences Graduate Student Theses and Dissertations

Part I: The expectation of new physics motivates more stringent tests of our current best understanding of gravitation, General Relativity (GR). Many theories proposing new physics predict the violation of Einstein’s equivalence principle, a set of criteria which must hold for GR to be valid. A torsion balance instrument was designed and operated to detect any violation of the equivalence principle. The motivations for performing such an experi- ment, instrument design, operational principles, data collected and subsequent analysis are described in detail in this thesis. After 51 days of continuous data collection experimental upper bounds on the violation of the …

Studying Quantum Memory Effects Of The Environment With Superconducting Circuits, Daria Kowsari

Arts & Sciences Graduate Student Theses and Dissertations

The presence of the environment in real-world experiments which strive to harness quantum mechanical effects is inevitable. This results in dissipation, which is known to be the main source of errors that prevent us from building a practical quantum computer. Nevertheless, one can employ the environment as a resource, especially when there is a strong coupling between the system and its environment. In this regime, the dynamics of the system is governed by the generalized Nakajima-Zwanzig master equation incorporating all the memory effects induced by the environment. The existence of memory allows us to investigate intriguing phenomena, such as the …

Studies And Applications Of Two-Phase Ligand Exchanges On Cadmium Selenide Nanoplatelets, Chenguang Ji

Arts & Sciences Graduate Student Theses and Dissertations

This dissertation presents two-phase ligand exchanges on CdSe NPLs, and the applications of two-phase ligand exchanges to achieve interchange between L-type, Z-type and bound-ion-pair X type ligation on wurtzite CdSe NPLs. Post-synthetic ligand exchange is an important emerging method for optimizing the physical, catalytic, and spectroscopic properties of semiconductor nanocrystals. However, ligand exchanges conducted with small, polar, or charged ligands produce nanocrystals that are not dispersible in nonpolar liquids. Two-phase ligand exchange with immiscible polar and nonpolar liquids allows transfer of the nanocrystals from the nonpolar to the polar phase upon ligand exchange, in which stable nanocrystal dispersions are formed. …