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Articles 42121 - 42150 of 294413

Full-Text Articles in Physical Sciences and Mathematics

Record High Room Temperature Resistance Switching In Ferroelectric-Gated Mott Transistors Unlocked By Interfacial Charge Engineering, Yifei Hao, Xuegang Chen, Le Zhang, Myung-Geun Han, Wei Wang, Yue-Wen Fang, Hanghui Chen, Yimei Zhu, Xia Hong May 2023

Record High Room Temperature Resistance Switching In Ferroelectric-Gated Mott Transistors Unlocked By Interfacial Charge Engineering, Yifei Hao, Xuegang Chen, Le Zhang, Myung-Geun Han, Wei Wang, Yue-Wen Fang, Hanghui Chen, Yimei Zhu, Xia Hong

Department of Physics and Astronomy: Faculty Publications

The superior size and power scaling potential of ferroelectric-gated Mott transistors makes them promising building blocks for developing energyefficientmemory and logic applications in the post-Moore’s Law era. The close to metallic carrier density in the Mott channel, however, imposes the bottleneck for achieving substantial field effect modulation via a solid-state gate. Previous studies have focused on optimizing the thickness, charge mobility, and carrier density of single-layer correlated channels, which have only led to moderate resistance switching at room temperature. Here, we report a record high nonvolatile resistance switching ratio of 38,440% at 300 K in a prototype Mott transistor consisting …


Neutrosophic Mcdm Methodology For Risk Assessment Of Autonomous Underwater Vehicles, Shimaa S. Mohamed, Ahmed Abdel-Monem, Alshaimaa A. Tantawy May 2023

Neutrosophic Mcdm Methodology For Risk Assessment Of Autonomous Underwater Vehicles, Shimaa S. Mohamed, Ahmed Abdel-Monem, Alshaimaa A. Tantawy

Neutrosophic Systems with Applications

Due to its usefulness in several industries and the military, researchers have concentrated on developing autonomous underwater vehicles (AUVs). However, AUV navigation continues to be a difficult challenge to solve owing to the variety of underwater settings. The usage of AUVs, or autonomous underwater vehicles, is not without dangers like malfunction, ecological risks, loss of communications, cybersecurity risks, collisions, and others. There are many criteria to assess these risks technical, operational, economic, and regulatory. So, the methods of multi-criteria decision-making (MCDM) is used to deal with these various criteria. The analytical hierarchy process (AHP) method is an MCDM methodology, that …


Development Of Novel Hybrid Structures For Fast Dissolution Of Hydrophobic Drugs, Mohammad Saiful Islam May 2023

Development Of Novel Hybrid Structures For Fast Dissolution Of Hydrophobic Drugs, Mohammad Saiful Islam

Dissertations

Nanomaterials have proven to be highly effective in the design and development of biomedicine. Complementary nanostructured hybrid particles show great promise in drug delivery applications. By improving functionalization, the physicochemical properties of the particles can be enhanced resulting in a high surface area, tunable hydrophilicity and porosity. These characteristics can provide a suitable environment for drug encapsulation, biocompatibility, high drug loading, and customizable release capabilities.

The formulation of drugs with poor water solubility faces multiple challenges, such as insufficient dissolution and inconsistent therapeutic efficacy, particularly when administered orally over an extended period. To overcome these challenges, some of the beneficial …


Dimensions Of Vaccination Attitudes In Nigeria: A Study Of The Impacts Of Covid-19 Vaccine Risk Perception And Acceptance, Abiodun Musbau Lawal, Babatola Dominic Olawa, Ikenna Maximillian Odoh, Ayodeji Olorunfemi Olawole, Olubukola Ajayi, Judith Chineye Azikiwe, Israel Oluwatosin Ayodele, Emmanuel Kolawole Odusina, Thomas Attah, Ezekiel Adeyemi Odedokun, Stephen Ishola Babatunde, Teslim Alabi Oladejo, Confidence Chioma Otoghile, Saheed Abiola Saka May 2023

Dimensions Of Vaccination Attitudes In Nigeria: A Study Of The Impacts Of Covid-19 Vaccine Risk Perception And Acceptance, Abiodun Musbau Lawal, Babatola Dominic Olawa, Ikenna Maximillian Odoh, Ayodeji Olorunfemi Olawole, Olubukola Ajayi, Judith Chineye Azikiwe, Israel Oluwatosin Ayodele, Emmanuel Kolawole Odusina, Thomas Attah, Ezekiel Adeyemi Odedokun, Stephen Ishola Babatunde, Teslim Alabi Oladejo, Confidence Chioma Otoghile, Saheed Abiola Saka

Kesmas

Nigeria has been affected by the COVID-19 pandemic, and vaccination is a key strategy. However, the country faces vaccination hesitancy, poor risk perception, and low acceptance. This study aimed to assess the direct and interactive impacts of COVID-19 vaccine risk perception and acceptability on COVID-19 vaccination attitudes in the general Nigerian population. In a cross-sectional approach, participants completed a structured questionnaire including demographics, COVID-19 vaccine risk perception, acceptance, and vaccination attitude from April 2-30, 2021. The sample included 1,026 participants from different ethnicities across four regions (Southwest, South, Southeast, and North Central) in Nigeria, which were selected using the convenience …


Extremely Hot Ambient Temperature And Injury-Related Mortality, Mien T N Nguyen, Man V M Nguyen, Huong V T Le, Hoai Viet Nguyen, Vu Anh Nguyen, Ngoan Tran Le May 2023

Extremely Hot Ambient Temperature And Injury-Related Mortality, Mien T N Nguyen, Man V M Nguyen, Huong V T Le, Hoai Viet Nguyen, Vu Anh Nguyen, Ngoan Tran Le

Kesmas

This pilot study aimed to evaluate the effects of extremely hot ambient temperatures on the total number of fatal injuries. Data were collected from a population-based mortality registry of Thanh Hoa, a province in the North Central region of Vietnam. This study qualified the distributed lag non-linear model and calculated the RR and 95% CI adjusted for long-term trend and absolute humidity. For the entire study population with 3,949 registered deaths due to injuries collected during 2005-2007, after the onset of extremely hot ambient temperatures, an increased risk of death was observed on the 9th day RR (95% CI) = …


Effects Of Using An Application For Postpartum Contraceptive Use In Family Planning Counseling During Pregnancy, Lia Nurcahyani, Dyah Widiyastuti, Arief Tarmansyah Iman, Yanti Cahyati, Yeni Fitrianingsih May 2023

Effects Of Using An Application For Postpartum Contraceptive Use In Family Planning Counseling During Pregnancy, Lia Nurcahyani, Dyah Widiyastuti, Arief Tarmansyah Iman, Yanti Cahyati, Yeni Fitrianingsih

Kesmas

A decision-making tool for family planning flipchart is used for contraceptive counseling, but the use of this flipchart is suboptimal. In this study, primary study resulted in innovative decision-making tools for family planning applications. “Si KB Pintar” was also developed, a tool that women can use to discuss contraceptives with their husbands after family planning counseling. This study analyzed the effectiveness of family planning counseling during pregnancy by applying postpartum contraceptive use. Analytical quantitative quasi-experimental methods were used with a control group design. The sampling method was two-stage sampling. In the first stage, from 22 primary health care (PHC) in …


Assessment Of Rabies Control Attitudes During The Covid-19 Pandemic Through Partial Least Square-Structural Equation Modeling, Sang Gede Purnama, Ni Wayan Arya Utami, Made Subrata, Putu Erma Pradnyani, Karang Agustina, Ibn Swacita May 2023

Assessment Of Rabies Control Attitudes During The Covid-19 Pandemic Through Partial Least Square-Structural Equation Modeling, Sang Gede Purnama, Ni Wayan Arya Utami, Made Subrata, Putu Erma Pradnyani, Karang Agustina, Ibn Swacita

Kesmas

The COVID-19 pandemic disrupts rabies control activities in the community. A new approach is needed to control rabies during the COVID-19 pandemic through digital health interventions by conducting digital surveillance and education. This study aimed to determine key attitude indicators in controlling rabies during the COVID-19 pandemic. A cross-sectional study on 166 participants in Denpasar City with a total of 31 indicators measuring five variables: perceptions of the benefits of rabies control (6 indicators), perceptions of rabies risk (6 indicators), perceptions of obstacles to rabies control (5 indicators), perceptions of the need for technology (7 indicators), and attitudes toward rabies …


Mining Themes In Clinical Notes To Identify Phenotypes And To Predict Length Of Stay In Patients Admitted With Heart Failure, Ankita Agarwal, Tanvi Banerjee, William Romine, Krishnaprasad Thirunarayan, Lingwei Chen, Mia Cajita May 2023

Mining Themes In Clinical Notes To Identify Phenotypes And To Predict Length Of Stay In Patients Admitted With Heart Failure, Ankita Agarwal, Tanvi Banerjee, William Romine, Krishnaprasad Thirunarayan, Lingwei Chen, Mia Cajita

Computer Science and Engineering Faculty Publications

Heart failure is a syndrome which occurs when the heart is not able to pump blood and oxygen to support other organs in the body. Identifying the underlying themes in the diagnostic codes and procedure reports of patients admitted for heart failure could reveal the clinical phenotypes associated with heart failure and to group patients based on their similar characteristics which could also help in predicting patient outcomes like length of stay. These clinical phenotypes usually have a probabilistic latent structure and hence, as there has been no previous work on identifying phenotypes in clinical notes of heart failure patients …


"I Think They're Poisoning My Mind": Understanding The Motivations Of People Who Have Voluntarily Adopted Secure Email, Warda Usman May 2023

"I Think They're Poisoning My Mind": Understanding The Motivations Of People Who Have Voluntarily Adopted Secure Email, Warda Usman

Theses and Dissertations

Secure email systems that use end-to-end encryption are the best method we have for ensuring user privacy and security in email communication. However, the adoption of secure email remains low, with previous studies suggesting mainly that secure email is too complex or inconvenient to use. However, the perspectives of those who have, in fact, chosen to use an encrypted email system are largely overlooked. To understand these perspectives, we conducted a semi-structured interview study that aims to provide a comprehensive understanding of the mindsets underlying adoption and use of secure email services. Our participants come from a variety of countries …


An Lp-Based Characterization Of Solvable Qap Instances With Chess-Board And Graded Structures, Lucas Waddell, Jerry Phillips, Tianzhu Liu, Swarup Dhar May 2023

An Lp-Based Characterization Of Solvable Qap Instances With Chess-Board And Graded Structures, Lucas Waddell, Jerry Phillips, Tianzhu Liu, Swarup Dhar

Faculty Journal Articles

The quadratic assignment problem (QAP) is perhaps the most widely studied nonlinear combinatorial optimization problem. It has many applications in various fields, yet has proven to be extremely difficult to solve. This difficulty has motivated researchers to identify special objective function structures that permit an optimal solution to be found efficiently. Previous work has shown that certain such structures can be explained in terms of a mixed 0-1 linear reformulation of the QAP known as the level-1 reformulation-linearization-technique (RLT) form. Specifically, the objective function structures were shown to ensure that a binary optimal extreme point solution exists to the continuous …


A Method Of Reconstructing Historical Destructive Landslides Using Bayesian Inference, Raelynn Wonnacott May 2023

A Method Of Reconstructing Historical Destructive Landslides Using Bayesian Inference, Raelynn Wonnacott

Theses and Dissertations

Along with being one of the most populated regions of the world, Indonesia has one of the highest natural disaster rates worldwide. One such natural disaster that Indonesia is particularly prone to are tsunamis. Tsunamis are primarily caused by earthquakes, volcanoes, landslides and debris flows. To effectively allocate resources and create emergency plans we need an understanding of the risk factors of the region. Understanding the source events of destructive tsunamis of the past are critical to understanding the these risk factors. We expand upon previous work focusing on earthquake-generated tsunamis to consider landslide-generated tsunamis. Using Bayesian inference and modern …


Recommending Answers To Math Questions Using Kl-Divergence And The Approximate Xml Tree Matching Approach, Siqi Gao May 2023

Recommending Answers To Math Questions Using Kl-Divergence And The Approximate Xml Tree Matching Approach, Siqi Gao

Theses and Dissertations

Mathematics is the science and study of quality, structure, space, and change. It seeks out patterns, formulates new conjectures, and establishes the truth by rigorous deduction from appropriately chosen axioms and definitions. The study of mathematics makes a person better at solving problems. It gives someone skills that (s)he can use across other subjects and apply in many different job roles. In the modern world, builders use mathematics every day to do their work, since construction workers add, subtract, divide, multiply, and work with fractions. It is obvious that mathematics is a major contributor to many areas of study. For …


Dd Slug Migration: Mathematical Model And Numerical Results, Joy Song May 2023

Dd Slug Migration: Mathematical Model And Numerical Results, Joy Song

Theses and Dissertations

Amoebae are commonly studied to understand embryogenesis, and the best-characterized amoebozoan species is Dictyostelium discoideum (Dd). Dd has a very simple life cycle with a range of developmental stages, among which we are most interested in the stage of a migrating slug. It has been observed that different sizes of Dd slugs maintain a proportional distribution of prestalk cells and prespore cells: prestalk cells occupy the anterior 20% of the slug, while prespore cells occupy the posterior 80%. However, it remains unknown how the migrating slug forms and preserves this anterior-posterior proportional pattern under so many different dynamics including cell …


Ten‐Year Cardiovascular Disease Risk Score And Cognitive Function Among Older Adults: The National Health And Nutrition Examination Survey 2011 To 2014, Jingkai Wei, Hanzhang Xu, Angela D. Liese, Anwar T. Nerchant Sc.D, Mph, Dmd, Liang Wang, Chih-Hsiang Yang, Matthew C. Lohman, Monique J. Brown Ph.D., Mph, Tiansheng Wang, Daniela B. Friedman Ph.D. May 2023

Ten‐Year Cardiovascular Disease Risk Score And Cognitive Function Among Older Adults: The National Health And Nutrition Examination Survey 2011 To 2014, Jingkai Wei, Hanzhang Xu, Angela D. Liese, Anwar T. Nerchant Sc.D, Mph, Dmd, Liang Wang, Chih-Hsiang Yang, Matthew C. Lohman, Monique J. Brown Ph.D., Mph, Tiansheng Wang, Daniela B. Friedman Ph.D.

Faculty Publications

BACKGROUND: The Framingham 10-year cardiovascular disease risk score, which is based on age, sex, smoking, total cholesterol, high-density lipoprotein-cholesterol, blood pressure, and diabetes, has been found to be associated with cognitive health, but these findings have not been validated in a representative sample in the United States. We aimed to examine the associations of Framingham risk score with cognitive function among older adults in a nationally representative sample, as well as by race or ethnicity, education, and family income.

METHODS AND RESULTS: A total of 2254 older adults ≥60years (57% female, 79% non-Hispanic White) in the National Health and Nutrition …


Post-Harvest Eucalyptus Residue Removal Reduces Soil Aggregation And Biological Activities In Central-West Brazil, Karla Nascimento Sena, Thaís Soto Boni, Kátia Luciene Maltoni, Ana Maria Rodrigues Cassiolato, Engil Isadora Pujol Pereira May 2023

Post-Harvest Eucalyptus Residue Removal Reduces Soil Aggregation And Biological Activities In Central-West Brazil, Karla Nascimento Sena, Thaís Soto Boni, Kátia Luciene Maltoni, Ana Maria Rodrigues Cassiolato, Engil Isadora Pujol Pereira

School of Earth, Environmental, & Marine Sciences Faculty Publications

Tree residue removal from Eucalyptus plantations after timber harvest can reduce soil functioning by reducing the organic matter input. To assess the effects of residue management systems (RMS) on soil aggregation, carbon (C) and nitrogen (N) content, and biological activities, a field trial was conducted in a commercial Eucalyptus plantation (loamy sand soil) in Mato Grosso do Sul, Brazil. The study assessed three RMS: cut-to-length (CTL), tree-length (TL), and bare litter (BL), respectively. After 21 months, undisturbed soil samples were collected and physically isolated into three aggregate-size fractions: large macroaggregates (LM), medium macroaggregates (SM), and microaggregates (MI). Results showed that …


Towards Generalizable Machine Learning Models For Computer-Aided Diagnosis In Medicine, Yiyang Wang May 2023

Towards Generalizable Machine Learning Models For Computer-Aided Diagnosis In Medicine, Yiyang Wang

College of Computing and Digital Media Dissertations

Hidden stratification represents a phenomenon in which a training dataset contains unlabeled (hidden) subsets of cases that may affect machine learning model performance. Machine learning models that ignore the hidden stratification phenomenon--despite promising overall performance measured as accuracy and sensitivity--often fail at predicting the low prevalence cases, but those cases remain important. In the medical domain, patients with diseases are often less common than healthy patients, and a misdiagnosis of a patient with a disease can have significant clinical impacts. Therefore, to build a robust and trustworthy CAD system and a reliable treatment effect prediction model, we cannot only pursue …


Target Cell-Specific Synaptic Dynamics Of Excitatory To Inhibitory Neuron Connections In Supragranular Layers Of Human Neocortex, Thomas Chartrand, Nikolas L Jorstad, Joseph T Mahoney, Michael J Taormina, Brian Long, Katherine Baker, Trygve E Bakken, Luke Campagnola, Tamara Casper, Michael Clark, Nick Dee, Florence D'Orazi, Clare Gamlin, Brian E Kalmbach, Sara Kebede, Brian R Lee, Lindsay Ng, Jessica Trinh, Charles Cobbs, Ryder P Gwinn, C Dirk Keene, Andrew L Ko, Jeffrey G Ojemann, Daniel L Silbergeld, Staci A Sorensen, Jim Berg, Kimberly A Smith, Philip R Nicovich, Tim Jarsky, Hongkui Zeng, Jonathan T Ting, Boaz P Levi, Ed Lein May 2023

Target Cell-Specific Synaptic Dynamics Of Excitatory To Inhibitory Neuron Connections In Supragranular Layers Of Human Neocortex, Thomas Chartrand, Nikolas L Jorstad, Joseph T Mahoney, Michael J Taormina, Brian Long, Katherine Baker, Trygve E Bakken, Luke Campagnola, Tamara Casper, Michael Clark, Nick Dee, Florence D'Orazi, Clare Gamlin, Brian E Kalmbach, Sara Kebede, Brian R Lee, Lindsay Ng, Jessica Trinh, Charles Cobbs, Ryder P Gwinn, C Dirk Keene, Andrew L Ko, Jeffrey G Ojemann, Daniel L Silbergeld, Staci A Sorensen, Jim Berg, Kimberly A Smith, Philip R Nicovich, Tim Jarsky, Hongkui Zeng, Jonathan T Ting, Boaz P Levi, Ed Lein

Faculty, Staff and Student Publications

Rodent studies have demonstrated that synaptic dynamics from excitatory to inhibitory neuron types are often dependent on the target cell type. However, these target cell-specific properties have not been well investigated in human cortex, where there are major technical challenges in reliably obtaining healthy tissue, conducting multiple patch-clamp recordings on inhibitory cell types, and identifying those cell types. Here, we take advantage of newly developed methods for human neurosurgical tissue analysis with multiple patch-clamp recordings, post-hoc fluorescent in situ hybridization (FISH), machine learning-based cell type classification and prospective GABAergic AAV-based labeling to investigate synaptic properties between pyramidal neurons and PVALB- …


Patterns Of Hiv Disclosure And Its Impact On The Hiv Care Continuum Among Black Men Who Have Sex With Men In South Carolina, Xueying Yang Ph.D., Titilayo A. James, Monique J. Brown Ph.D., Mph, Tony Brown, Sydney Zarsadias, Ran Zhang, Fanghui Shi, Xiaoming Li Ph.D. May 2023

Patterns Of Hiv Disclosure And Its Impact On The Hiv Care Continuum Among Black Men Who Have Sex With Men In South Carolina, Xueying Yang Ph.D., Titilayo A. James, Monique J. Brown Ph.D., Mph, Tony Brown, Sydney Zarsadias, Ran Zhang, Fanghui Shi, Xiaoming Li Ph.D.

Faculty Publications

Addressing the psychosocial concerns of Black men who have sex with men (MSM), such as HIV disclosure, is critical for effective HIV treatment efforts. Black MSM living with HIV experience multiple psychosocial challenges, such as “triple stigma” due to their sexual orientation, racial minority status, and HIV status, which hinder their HIV disclosure and subsequent HIV care-seeking behavior. Our study sought to examine the HIV disclosure patterns and their impact on the HIV care continuum among Black MSM using a qualitative approach. Semi-structured interviews were carried out among 28 Black MSM aged ≥18 years old living in South Carolina. A …


Draft Final Annual Operations And Maintenance (O&M) Report Butte Treatment Lagoon (Btl) System – 2022, Pioneer Technical Services, Inc. May 2023

Draft Final Annual Operations And Maintenance (O&M) Report Butte Treatment Lagoon (Btl) System – 2022, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.


Search For Heavy Resonances And Quantum Black Holes In Eμ, Eτ, And Μτ Final States In Proton-Proton Collisions At √S = 13 Tev, A. Tumasyan May 2023

Search For Heavy Resonances And Quantum Black Holes In Eμ, Eτ, And Μτ Final States In Proton-Proton Collisions At √S = 13 Tev, A. Tumasyan

Department of Physics and Astronomy: Faculty Publications

A search is reported for heavy resonances and quantum black holes decaying into eμ, eτ, and μτ final states in proton-proton collision data recorded by the CMS experiment at the CERN LHC during 2016–2018 at √s = 13TeV, corresponding to an integrated luminosity of 138 fb−1. The eμ, eτ, and μτ invariant mass spectra are reconstructed, and no evidence is found for physics beyond the standard model. Upper limits are set at 95% confidence level on the product of the cross section and branching fraction for lepton flavor violating signals. Three benchmark signals are studied: resonant τ sneutrino …


Toxicological Effects Assessment For Wildlife In The 21st Century: Review Of Current Methods And Recommendations For A Path Forward, Thomas G. Bean, Val R. Beasley, Philippe Berny, Karen M. Eisenreich, John E. Elliott, Margaret L. Eng, Phyllis C. Fuchsman, Mark S. Johnson, Mason D. King, Rafael Mateo, Carolyn B. Meyer, Christopher J. Salice, Barnett A. Rattner May 2023

Toxicological Effects Assessment For Wildlife In The 21st Century: Review Of Current Methods And Recommendations For A Path Forward, Thomas G. Bean, Val R. Beasley, Philippe Berny, Karen M. Eisenreich, John E. Elliott, Margaret L. Eng, Phyllis C. Fuchsman, Mark S. Johnson, Mason D. King, Rafael Mateo, Carolyn B. Meyer, Christopher J. Salice, Barnett A. Rattner

United States Geological Survey: Staff Publications

Model species (e.g., granivorous gamebirds, waterfowl, passerines, domesticated rodents) have been used for decades in guideline laboratory tests to generate survival, growth, and reproductive data for prospective ecological risk assessments (ERAs) for birds and mammals, while officially adopted risk assessment schemes for amphibians and reptiles do not exist. There are recognized shortcomings of current in vivo methods as well as uncertainty around the extent to which species with different life histories (e.g., terrestrial amphibians, reptiles, bats) than these commonly used models are protected by existing ERA frameworks. Approaches other than validating additional animal models for testing are being developed, but …


Vibrational, Rotational And Electronic Spectroscopy For Possible Interstellar Detection Of Alnh2 And Halnh, Tarek Trabelsi, Vincent J. Esposito, Joseph S. Francisco May 2023

Vibrational, Rotational And Electronic Spectroscopy For Possible Interstellar Detection Of Alnh2 And Halnh, Tarek Trabelsi, Vincent J. Esposito, Joseph S. Francisco

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

We obtained accurate vibrational frequencies, rotational constants, and vertical transition energy for AlNH2(X1A1) and HAlNH(X1A′) isomers using ab initio calculations at various levels of theory. These two isomers are potential candidates for astronomical observation. AlNH2 and HAlNH are thermodynamically stable, with Al-NH2 and HAl-NH bond dissociation energies predicted to be 4.39 and 3.60 eV, respectively. The two isomers are characterized by sizable dipole moments of 1.211 and 3.64 D, respectively. The anharmonic frequencies and spectroscopic constants reported for the two isomers should facilitate their experimental differentiation. In addition, we evaluated …


Ionic Nanomaterials And Doped Carbon Materials: Synthesis, Characterization, And Application In Cancer, Energy, And Environment, Samantha Paige Macchi May 2023

Ionic Nanomaterials And Doped Carbon Materials: Synthesis, Characterization, And Application In Cancer, Energy, And Environment, Samantha Paige Macchi

Theses and Dissertations

Materials is a crucial area of science which encompasses the design, synthesis, and application of various chemicals or other materials. Determining the relationship between materials’ physical, chemical, and photophysical properties on their performance is crucial to design the most optimal materials. This dissertation is focused on two types of materials: ionic liquids and heteroatom doped carbons as well as their various applications. Part A of this dissertation is focused on the development of various frozen ionic liquids (ionic materials, IMs) and nanoparticles derived from IMs as cancer therapeutics. The effect of various counterions on the photophysical and cytotoxic properties of …


Significance Of Storage Conditions On The Flow Properties Of Wheat Flours, Jared Lou Rivera, Jikai Zhao, Aminu Owonikoko, Kaliramesh Siliveru May 2023

Significance Of Storage Conditions On The Flow Properties Of Wheat Flours, Jared Lou Rivera, Jikai Zhao, Aminu Owonikoko, Kaliramesh Siliveru

School of Earth, Environmental, & Marine Sciences Faculty Publications

Flow properties of wheat flours are influenced by their intrinsic properties and environmental conditions during handling. This study evaluated the effects of environmental conditions (temperature and relative humidity- %RH) and flour properties (particle size and wheat class) on the flow properties of wheat flours. Size fractions from hard red winter (HRW) and soft red winter (SRW) wheat were produced through sieving. Flour fractions were then exposed to various temperature (25 and 35 oC) and relative humidity (50, 60, and 70%RH) combinations (t = 3 h) to evaluate the effects of environmental conditions. Flow indicators (Hausner ratio – HR and compressibility …


Biopolymer-Coated Magnetite Nanoparticles For The Removal Of Emerging Contaminants From Aqueous Solutions, Hebatullah Farghal May 2023

Biopolymer-Coated Magnetite Nanoparticles For The Removal Of Emerging Contaminants From Aqueous Solutions, Hebatullah Farghal

Theses and Dissertations

Abstract

Biopolymers are gaining interest as promising materials for water purification due to their functionality, biodegradability, abundance, and safe use. In this work, three biopolymer-based systems were developed as adsorbents for removing emerging contaminants from water. The first system of biopolymeric nanocomposites was synthesized by coating chitosan/xylan biopolymeric nanocomposites on magnetite nanoparticles (CsXM) to facilitate their separation from water via a magnetic field. The prepared mesoporous CsXM nanocomposite was thermally stable and possessed a particle size of 11 nm and a neutral to slightly negative charge over the studied pH range of about 3 to 10. The nanocomposite efficiently removed …


A Strong-Type Furstenberg–Sárközy Theorem For Sets Of Positive Measure, Polona Durcik, Vjekoslav Kovač, Mario Stipčić May 2023

A Strong-Type Furstenberg–Sárközy Theorem For Sets Of Positive Measure, Polona Durcik, Vjekoslav Kovač, Mario Stipčić

Mathematics, Physics, and Computer Science Faculty Articles and Research

For every β ∈ (0,∞), β ≠ 1, we prove that a positive measure subset A of the unit square contains a point (x0, y0) such that A nontrivially intersects curves y − y0 = a(x −x0)β for a whole interval I ⊆ (0,∞) of parameters a ∈ I . A classical Nikodym set counterexample prevents one to take β = 1, which is the case of straight lines. Moreover, for a planar set A of positive density, we show that the interval I can be arbitrarily large on the logarithmic scale. These results can …


Electronically Modulated Feni Composite By Ceo2 Porous Nanosheets For Water Splitting At Large Current Density, Ming-Yu Ding, Wen-Jie Jiang, Tian-Qi Yu, Xiao-Yan Zhuo, Xiao-Jing Qin, Shi-Bin Yin May 2023

Electronically Modulated Feni Composite By Ceo2 Porous Nanosheets For Water Splitting At Large Current Density, Ming-Yu Ding, Wen-Jie Jiang, Tian-Qi Yu, Xiao-Yan Zhuo, Xiao-Jing Qin, Shi-Bin Yin

Journal of Electrochemistry

Exploiting highly active and non-noble metal bifunctional catalysts at large current density is significant for the advancement of water electrolysis. In this work, CeO2 electronically structure modulated FeNi bimetallic composite porous nanosheets in-situ grown on nickel foam (NiFe2O4-Fe24N10-CeO2/NF) is synthesized. Electrochemical experiments show that the NiFe2O4-Fe24N10-CeO2/NF exhibited the outstanding activities toward both oxygen and hydrogen evolution reactions (OER and HER) (η1000 = 352 mV and η1000 = 429 mV, respectively). When assembled into a two-electrode system for …


P-Doped Ru-Pt Alloy Catalyst Toward High Performance Alkaline Hydrogen Evolution Reaction, Rong-Qin Huang, Wei-Ping Liao, Meng-Xuan Yan, Shi Liu, Yuan-Ming Li, Xiong-Wu Kang May 2023

P-Doped Ru-Pt Alloy Catalyst Toward High Performance Alkaline Hydrogen Evolution Reaction, Rong-Qin Huang, Wei-Ping Liao, Meng-Xuan Yan, Shi Liu, Yuan-Ming Li, Xiong-Wu Kang

Journal of Electrochemistry

Electrocatalytic water splitting represents grand promise for hydrogen fuel in modern energy equipment, and the design and fabrication of higher performance catalysts are at the central. Herein, we report the sequential phosphorus (P)-doping into ruthenium (Ru) nanoparticles (Ru-P/C) by thermal annealing of Ru nanoparticles in phosphine (PH3) atmosphere and deposition of extremely low concentration of platinum (Pt) to obtain P-doped Ru-Pt alloy catalyst supported on carbon nanotubes (CNTs), which is denoted as (Ru-P)#Pt/C. The data by X-ray diffraction spectroscopy and transmission electron microscopy show that the Ru nanoparticles existed in the form of hexagonal close-packed (hcp) phase with …


Rapid Assessment Of Fish Freshness For Multiple Supply-Chain Nodes Using Multi-Mode Spectroscopy And Fusion-Based Artificial Intelligence, Angelis Tzouchas, Alireza Akhbardeh, Insuck Baek, Chansong Hwang, Jianwei Qin, Amanda M Tabb, Rosalee S Hellberg, Shereen Ismail, Hassan Reza, Fartash Vasefi, Moon Kim, Kouhyar Tavakolian, Christopher T Elliott May 2023

Rapid Assessment Of Fish Freshness For Multiple Supply-Chain Nodes Using Multi-Mode Spectroscopy And Fusion-Based Artificial Intelligence, Angelis Tzouchas, Alireza Akhbardeh, Insuck Baek, Chansong Hwang, Jianwei Qin, Amanda M Tabb, Rosalee S Hellberg, Shereen Ismail, Hassan Reza, Fartash Vasefi, Moon Kim, Kouhyar Tavakolian, Christopher T Elliott

Faculty, Staff and Student Publications

This study is directed towards developing a fast, non-destructive, and easy-to-use handheld multimode spectroscopic system for fish quality assessment. We apply data fusion of visible near infra-red (VIS-NIR) and short wave infra-red (SWIR) reflectance and fluorescence (FL) spectroscopy data features to classify fish from fresh to spoiled condition. Farmed Atlantic and wild coho and chinook salmon and sablefish fillets were measured. Three hundred measurement points on each of four fillets were taken every two days over 14 days for a total of 8400 measurements for each spectral mode. Multiple machine learning techniques including principal component analysis, self-organized maps, linear and …


Deep Euteceic Solvents-Assisted Synthesis Of Novel Network Nanostructures For Accelerating Formic Acid Electrooxidation, Jun-Ming Zhang, Xiao-Jie Zhang, Yao Chen, Ying-Jian Fan, You-Jun Fan, Jian-Feng Jia May 2023

Deep Euteceic Solvents-Assisted Synthesis Of Novel Network Nanostructures For Accelerating Formic Acid Electrooxidation, Jun-Ming Zhang, Xiao-Jie Zhang, Yao Chen, Ying-Jian Fan, You-Jun Fan, Jian-Feng Jia

Journal of Electrochemistry

Deep eutectic solvents (DESs) have been reported as a type of solvent for the controllable synthesis of metal nanostructures. Interestingly, flower-like palladium (Pd) nanoparticles composed of staggered nanosheets and nanospheres are spontaneously transformed into three-dimensional (3D) network nanostructures in choline chloride-urea DESs using ascorbic acid as a reducing agent. Systematic studies have been carried out to explore the formation mechanism, in which DESs itself acts as a solvent and soft template for the formation of 3D flower-like network nanostructures (FNNs). The amounts of hexadecyl trimethyl ammonium bromide and sodium hydroxide also play a crucial role in the anisotropic growth and …