Physical Sciences and Mathematics Commons^™

Development And Applications Of Novel And Practical Fluorination Reagents., Yuhao Yang

Electronic Theses and Dissertations

The fluorine (F) atom has distinctive properties such as the highest electronegativity, small size, low polarizability, and strong C–F bond strength. Not surprisingly, fluorinated organic compounds have garnered significant attention in the pharmaceutical, agrochemical, and material fields. Since organofluorides are very rare in nature, we need fluorination reagents to help us transfer fluorine into the organic molecules. In past decades, a vast number of fluorination reagents have been developed and many of them are commercially available now. However, there is still much room for the improvement of these reagents. Our target is to develop novel and practical fluorination reagents to …

New Species Of Dryolestoid From The Late Cretaceous Allen Formation And Implications For South American Faunal Diversity., Brigid Erin Connelly

Electronic Theses and Dissertations

Dryolestoids are extinct cladotherians mammals from the Jurassic and Cretaceous periods. I describe a collection of dryolestoid specimens from the Late Cretaceous localities of Cerro Tortuga (Allen Formation), Anfiteatro 1, and Shining (both La Colonia Formation) from Patagonia, Argentina. Using comparative morphology, I identify a new species of meridiolestidan dryolestoid based on eleven specimens across both formations. The new species’ recovery from La Colonia Formation represents the first dryolestoid connection between the two approximately contemporaneous formations. The species’ morphology may represent an ecological shift within Meridiolestida from insectivory to herbivory, showing a transition in characters between the plesiomorphic sharp-toothed meridiolestidans …

New Methodologies For Sustainable Organic Synthesis In Water., Sudripet Sharma

Electronic Theses and Dissertations

Water is stable, benign, and green solvent. Its usage as a solvent in organic synthesis is significantly enhanced by micellar catalysis. However, replacing water as a reaction medium in organic synthesis is not sufficient to meet the sustainability challenges—excessive organic solvents are still required for product isolation and purification. Notably, solvents used in syntheses contribute to more than 80% of waste generation. In addition to solvents, the use of palladium in large amounts is also a problem for the future as it is a precious, low-abundance metal, and its supply is dwindling. Therefore, this dissertation highlights the various sustainable protocols …

Insights Into The Structural And Electronic Properties Of 2d Polar Sic/Gec Heterostructures And Asxp1−X Alloys., Kazi Jannatul Tasnim

Electronic Theses and Dissertations

Due to the unique structural and electronic properties along with the practical applications in current and near future, investigations about the group-IV graphene-like two-dimensional (2D) sheets have been accelerated. Among them, 2D SiC and GeC sheets are polar materials with in-plane charge transfer from Si (Ge) to C atoms. An interesting question is how the electrostatic force, triggered by such in-plane charge transfer, plays a role in stabilizing the vertical heterostructures formed by 2D SiC and GeC sheets beyond vdW interaction. To answer this question, we have systematically investigated, in my PhD research projects, the effects of the electrostatic interaction …

Electromagnetic Simulations Of The Lansce Chopper Structure, Yusuf Sahin

Electrical and Computer Engineering ETDs

Particle accelerators are important for basic research as well as in applications such as ion implantation and cancer therapy. One important accelerator is the Los Alamos Neutron Science Center (LANSCE) located at Los Alamos National Laboratory (LANL) that primarily produces neutrons for research. The beam chopper simulation described here is a study to provide better modeling of this subsystem of LANSCE. A chopper is a device in which particles are intermittently sliced and directed to a target and/or experiment. The simulations in this thesis are used to analyze the correct operating parameters of the chopper. A good chopper model can …

Spectral Broadening Effects On Pulsed-Source Digital Holography, Steven A. Owens, Mark F. Spencer, Glen P. Perram

Faculty Publications

Using a pulsed configuration, a digital-holographic system is setup in the off-axis image plane recording geometry, and spectral broadening via pseudo-random bit sequence is used to degrade the temporal coherence of the master-oscillator laser. The associated effects on the signal-to-noise ratio are then measured in terms of the ambiguity and coherence efficiencies. It is found that the ambiguity efficiency, which is a function of signal-reference pulse overlap, is not affected by the effects of spectral broadening. The coherence efficiency, on the other hand, is affected. As a result, the coherence efficiency, which is a function of effective fringe visibility, is …

Per- And Polyfluoroalkyl Substances (Pfas) In Treated Sewage Sludge From Michigan Wastewater Treatment Plants, Garrett Wesley Link

Masters Theses

Concentrations, compositions, and variability of Per- and Polyfluoroalkyl Substances (PFAS) in sewage sludge are characterized using an extensive dataset of 350 samples from 190 wastewater treatment plants (WWTPs) across Michigan. All samples are comprised of final treated sewage sludge generated at the end of the wastewater treatment process. Concentrations of Σ₂₄ PFAS are log normally distributed with a range of 1 to 3200 ng/g dry wt. and of average 108 ± 277 ng/g dry wt. Compounds with carboxyl and sulfonic functional groups comprised 29% and 71% of Σ₂₄ PFAS concentrations, respectively, on average. Primary sample variability is associated …

Data Is The New Gold: A Singapore Perspective On The Duty Of Care Concerning A Dataset’S Role In Contributing To Bias And Ai Hallucinations, Daniel Seah

Research Collection College of Integrative Studies

Amidst the trends and advances in Artificial Intelligence (AI) techniques, the dataset’s key role in creating AI harms is a constant. Yet the literature’s attention is typically focussed on the machinelearning’s role, from which the dataset’s role is examined usually in terms of its potential for bias. Datasets also contribute to AI hallucinations. Again, the literature focuses on the composite roles of datasets and AI models in hallucinations, in isolation from a dataset’s contributory role in creating bias. Therefore, the overlapping and distinctive roles of datasets, as a dual contributor, are understudied in the literature. Through the legal concept of …

Outgassing Behavior And Heat Treatment Optimization Of Jsc-1a Lunar Regolith Simulant, Ryan P. Wilkerson, Mihail P. Petkov, Gerald E. Voecks, Catherine S. Lynch, Holly S. Shulman, Santhoshkumar Sundaramoorthy, Amitava Choudhury, Douglas L. Rickman, Michael R. Effinger

Chemistry Faculty Research & Creative Works

As NASA Strives towards a Long Duration Presence on the Moon, It Has Become Increasingly Important to Learn How to Better Utilize Resources from the Lunar Surface for Everything from Habitats, Vehicle Infrastructure, and Chemical Extraction. to that End, a Variety of Lunar Simulants Have Been Sourced from Terrestrially Available Volcanic Minerals and Glass as Apollo Regolith is Unavailable for Experimentation Needing Large Masses. However, While Mineralogy and Chemical Composition Can Approach that of Lunar Material in These Simulants, There Are Still Distinct Non-Lunar Phases Such as Hydrates, Carbonates, Sulfates, and Clays that Can Cause Simulants to Behave Distinctly Non-Lunar …

Enabling Affordances Of Blockchain In Agri-Food Supply Chains: A Value-Driver Framework Using The Q-Methodology, Pouyan Jahanbin, Stephen C. Wingreen, Ravishankar Sharma, Behrang Ijadi, Marlon M. Reis

All Works

The application of blockchain beyond cryptocurrencies has received increasing attention from industry and scholars alike. Given predicted looming food crises, some of the most impactful deployments of blockchains are likely to concern food supply chains. This study outlined how blockchain adoption can result in positive affordances in the food supply chain. Using Q methodology, this study explored the current status of the agri-food supply chain and how blockchain technology could be useful in addressing existing challenges. This theorization leads to the proposition of the 3TIC value-driver framework for determining the enabling affordances of blockchain that would increase shared value for …

Investigating The Effects Of E219 Mutations In M. Tuberculosis Indole-3-Glycerol Phosphate Synthase, Cinthya Moran

Theses, Dissertations and Culminating Projects

Tuberculosis (TB) is a serious infectious disease caused by Mycobacterium tuberculosis. Tuberculosis drug resistance is increasingly a problem, but recent research has provided results that suggest Indole-3-Glycerol Phosphate Synthase (IGPS) could be a potential drug target. IGPS is an enzyme that catalyzes the fourth step in the tryptophan biosynthesis pathway, a crucial process for optimal Mycobacterium tuberculosis growth. In this research, we studied IGPS from Mycobacterium tuberculosis (MtIGPS) to shed light on a particular conserved residue that has not been studied in depth in any IGPS homolog. My investigation focuses on understanding the role of the active site residue E219. …

Quantifying Local And Regional Effects Of Human Development On Centennial Barrier Island Evolution : Insights From Barnegat Inlet, New Jersey, Shane Nichols-O’Neill

Theses, Dissertations and Culminating Projects

Societal benefits and ecosystem services provided by barrier islands are at risk as these landforms evolve rapidly in response to system changes including an increasing rate of sea-level rise and changing storm patterns. To prevent retreat or drowning, the expected response of natural barrier islands, and preserve benefits provided by barrier islands, significant investments are made at developed barrier islands to stabilize ocean and bay shorelines. Maintaining stable shorelines may not be sustainable in the future due to changing environmental, financial, and political conditions. Decadal to centennial-scale alongshore barrier island evolution at Long Beach Island, New Jersey is analyzed to …

Short-Term Response In Soil Health To Management Practices Within Large- And Small-Scale Cropping Systems In Arkansas, Torri Holder

Graduate Theses and Dissertations

Improving soil health is a growing area of interest within large- and small-scale agricultural systems in Arkansas as producers face increasing input costs, increased awareness of variability and intensity in extreme weather events, decreasing resource availability, and suboptimal productivity related to environmental degradation. Practices aimed at improving soil health such as cover cropping and the use of organic amendments are increasingly recommended and adopted; however, research on optimal management in the Mid-South is lacking. Two studies were conducted to evaluate the effectiveness of soil health management under both small- and large-scale farming operations in Arkansas. The objective of the small-scale …

Nutrient Responses To Hippuric Acid In Sheep Urine Applied To Pasture Soil Cores, Ethan Avery Collins

Graduate Theses and Dissertations

Hippuric acid is a breakdown product of tannins, which bind with proteins in the animal rumen and slow down protein metabolism, thus increasing nitrogen (N) retention in the animal. Increased hippuric acid concentration in bovine and ovine urine applied to soil may decrease rates of nitrification, denitrification, and nitrous oxide fluxes in pasture soils. Additionally, condensed tannins have increased rates of carbon mineralization when incorporated in humus and leaf litter. To evaluate effects of hippuric acid concentration, treatments of urine from sheep fed a tannin-supplemented diet, synthetic urine, or urea controls were applied to intact soil cores seeded with crabgrass …

Investigation Of The Flow Field In The Jack Rabbit Ii Mock Urban Environment Field Tests Using A 1:50 Scale Wind Tunnel Model, Paulo Victor De Freitas Lopes

Graduate Theses and Dissertations

Accidental release of toxic chemicals can put workers and nearby populations at significant risk. Consequence assessment of accidents in urban environments is of particular interest. Urban geometries create wind channels between buildings, along with particularly dangerous areas downwind of buildings, where near-stagnant flow is present. Furthermore, recirculation zones can be formed between buildings, trapping high concentrations of toxic gases at ground level, particularly for denser-than-air gases. In 2015, the Department of Homeland Security conducted the Jack Rabbit II Field Test (JR-II) at Dugway Proving Ground, UT. During JR-II, chlorine was released at the center of a Mock Urban Environment (MUE) …

Photon Counting Statistics Of Classical And Quantum Light Sources, Luis Felipe Morales Bultron

Graduate Theses and Dissertations

Multiple sources of light, including coherent light, thermal light, light from a degenerate parametric oscillation and resonance fluorescence from a two level coherently driven atom are considered for the analysis of their wait time statistics. We include the second order normalized correlation function and Mandel's Q parameter for brief discussion. A general framework to analyze the generalized conditional and unconditional wait time distributions is also obtained in order to understand the photo-count statistics of the light sources included in this work. Average and variance of wait times with respect to both unconditional and conditional wait time distribution are also obtained …

Circuitry And Semiconductor Studies For Making A Graphene Energy Harvesting Device, Ferdinand Harerimana

Graduate Theses and Dissertations

Freestanding graphene has constantly moving ripples. Due to its extreme flexibility, graphene responds to ambient vibrations and changes its curvature from concave to convex and vice versa. During a ripple inversion 10,000 atoms move together, suggesting the presence of kinetic energy which can be harvested. In this study we present circuitry and semiconductor studies for harvesting energy from graphene vibrations. The goal of the study is to develop a graphene energy harvesting chip which can serve as a battery replacement in low power electronics. In the first study we determined the best circuit for harvesting vibrational low power. To do …

Towards Multi-Modal Explainable Video Understanding, Kashu Yamazaki

Graduate Theses and Dissertations

This thesis presents a novel approach to video understanding by emulating human perceptual processes and creating an explainable and coherent storytelling representation of video content. Central to this approach is the development of a Visual-Linguistic (VL) feature for an interpretable video representation and the creation of a Transformer-in-Transformer (TinT) decoder for modeling intra- and inter-event coherence in a video. Drawing inspiration from the way humans comprehend scenes by breaking them down into visual and non-visual components, the proposed VL feature models a scene through three distinct modalities. These include: (i) a global visual environment, providing a broad contextual understanding of …

Lepton Flavor Violation And Lepton Flavor Universality Violation: Opportunity For New Physics Beyond The Standard Model, Fang Xu

Arts & Sciences Graduate Student Theses and Dissertations

The Standard Model (SM) of Particle Physics has been remarkably successful in explaining the fundamental forces and classifying elementary particles. However, there are various experimental and theoretical indications that suggest the need to go beyond the SM (BSM) and expand our understanding of the fundamental nature of the universe. From a theoretical perspective, there are several limitations of the SM that suggest the existence of a more fundamental theory. For example, the SM does not incorporate gravity, and it fails to explain the hierarchy problem. Additionally, the nature of dark matter and the origin of the mass hierarchy of elementary …

Heterochiral Dna Nanotechnology For Biomedical Applications, Tracy L. Mallette

Biomedical Engineering ETDs

In the past 30 years, there have been major advancements on how to treat and diagnose disease because of the improvement and increase in accessibility of sequencing technology. Nucleic acid-based therapeutics can manipulate protein expression. Likewise, pathogens can be identified and detected with single nucleotide specificity. However, the underlying oligonucleotide technology requires protection against natural defense systems that have evolved to destroy foreign nucleic acids. Many chemical modifications that can protect nucleotides also have significant cytotoxic side effects and must be carefully designed into the strands. A novel way to protect against nuclease-mediated degradation is through the use of mirror-image, …

Evolve Path Tracer: Early Detection Of Malicious Addresses In Cryptocurrency, Ling Cheng, Feida Zhu, Yong Wang, Ruicheng Liang, Huiwen Liu

Research Collection School Of Computing and Information Systems

With the boom of cryptocurrency and its concomitant financial risk concerns, detecting fraudulent behaviors and associated malicious addresses has been drawing significant research effort. Most existing studies, however, rely on the full history features or full-fledged address transaction networks, both of which are unavailable in the problem of early malicious address detection and therefore failing them for the task. To detect fraudulent behaviors of malicious addresses in the early stage, we present Evolve Path Tracer, which consists of Evolve Path Encoder LSTM, Evolve Path Graph GCN, and Hierarchical Survival Predictor. Specifically, in addition to the general address features, we propose …

The Future Of Cryptocurrency And Blockchain Technology In Finance, Wanyi Wong, Alan @ Ali Madjelisi Megargel

Research Collection School Of Computing and Information Systems

Cryptocurrencies have been all the rage in recent years, with many being drawn to their appeal as speculative investment assets. Its proponents also champion the secure and decentralised nature of the technology it is based on, called the blockchain. Given the secure nature of blockchain technology, the idea of adopting cryptocurrencies as legal tender currency has also been mooted and experimented with – with the most famous example being the Central American nation of El Salvador’s bold move to adopting the cryptocurrency Bitcoin as legal tender in September 2021. In theory, this would provide a solution to the high transaction …

Generalization Through Diversity: Improving Unsupervised Environment Design, Wenjun Li, Pradeep Varakantham, Dexun Li

Research Collection School Of Computing and Information Systems

Agent decision making using Reinforcement Learning (RL) heavily relies on either a model or simulator of the environment (e.g., moving in an 8x8 maze with three rooms, playing Chess on an 8x8 board). Due to this dependence, small changes in the environment (e.g., positions of obstacles in the maze, size of the board) can severely affect the effectiveness of the policy learned by the agent. To that end, existing work has proposed training RL agents on an adaptive curriculum of environments (generated automatically) to improve performance on out-of-distribution (OOD) test scenarios. Specifically, existing research has employed the potential for the …

Context-Aware Event Forecasting Via Graph Disentanglement, Yunshan Ma, Chenchen Ye, Zijian Wu, Xiang Wang, Yixin Cao, Tat-Seng Chua

Research Collection School Of Computing and Information Systems

Event forecasting has been a demanding and challenging task throughout the entire human history. It plays a pivotal role in crisis alarming and disaster prevention in various aspects of the whole society. The task of event forecasting aims to model the relational and temporal patterns based on historical events and makes forecasting to what will happen in the future. Most existing studies on event forecasting formulate it as a problem of link prediction on temporal event graphs. However, such pure structured formulation suffers from two main limitations: 1) most events fall into general and high-level types in the event ontology, …

Numgpt: Improving Numeracy Ability Of Generative Pre-Trained Models, Zhihua Jin, Xin Jiang, Xiangbo Wang, Qun Liu, Yong Wang, Xiaozhe Ren, Huamin Qu

Research Collection School Of Computing and Information Systems

Existing generative pre-trained language models (e.g., GPT) focus on modeling the language structure and semantics of general texts. However, those models do not consider the numerical properties of numbers and cannot perform robustly on numerical reasoning tasks (e.g., math word problems and measurement estimation). In this paper, we propose NumGPT, a generative pre-trained model that explicitly models the numerical properties of numbers in texts. Specifically, it leverages a prototype-based numeral embedding to encode the mantissa of the number and an individual embedding to encode the exponent of the number. A numeral-aware loss function is designed to integrate numerals into the …

A Certificateless Designated Verifier Sanitizable Signature, Yonghua Zhan, Bixia Yi, Yang Yang, Renjie He, Rui Shi

Research Collection School Of Computing and Information Systems

Sanitizable Signature is a digital signature variant that enables modification operations, allowing sanitizers to alter the signed data in a regulated manner without requiring any interaction with the original signer. It is widely used in scenarios such as healthcare data privacy protection, social networks, secure routing, etc. In existing sanitizable signature schemes, anyone can verify the validity and authenticity of the sanitized message, which results in costly certificate management overhead or complicated key escrow problems. To address these challenges, a designated verifier certificateless sanitizable signature scheme is proposed. This scheme introduces the concept of a designated verifier into sanitizable signatures, …

Towards Intelligent Runtime Framework For Distributed Heterogeneous Systems, Polykarpos Thomadakis

Computer Science Theses & Dissertations

Scientific applications strive for increased memory and computing performance, requiring massive amounts of data and time to produce results. Applications utilize large-scale, parallel computing platforms with advanced architectures to accommodate their needs. However, developing performance-portable applications for modern, heterogeneous platforms requires lots of effort and expertise in both the application and systems domains. This is more relevant for unstructured applications whose workflow is not statically predictable due to their heavily data-dependent nature. One possible solution for this problem is the introduction of an intelligent Domain-Specific Language (iDSL) that transparently helps to maintain correctness, hides the idiosyncrasies of lowlevel hardware, and …

Application Of Quantum Mechanical Techniques To Optical Waveguide Structures, Stuart Ward

Physics & Astronomy ETDs

The focus of this dissertation is on the application of supersymmetric quantum mechanics to the problem of microbending in optical waveguides and on the analysis of soliton decay due solely to quantum mechanical effects.

The techniques of supersymmetric quantum mechanics are applied to the equation of motion describing light propagation in an optical waveguide which is undergoing microbending. Based on these supersymmetric techniques, given a particular refractive index profile, one may derive a new refractive index profile which results in less loss due to the microbending -- the particular example of the monomial index profile is analyzed in detail. An …

Near- And Far- Field Optical Response Of Ensembles Of Nanostructures, Lauren Zundel

Physics & Astronomy ETDs

The ability of metallic nanostructures to support collective oscillations of their conduction electrons, known as surface plasmons, makes them attractive candidates for a wide range of applications in areas as diverse as cancer therapy, biosensing, and solar energy harvesting. These applications are especially promising for periodic arrays of nanostructures, which can support collective modes known as lattice resonances, and for nanostructures with extreme aspect ratios that give rise to enhanced light-matter interaction. In this Thesis, we employ a coupled dipole model to theoretically explore the lattice resonances supported by complex arrays of nanoparticles containing multiple nanoparticles per unit cell. We …

High-Power Laser Cooling And Temperature-Dependent Fluorescence Studies Of Ytterbium Doped Silica, Brian Topper

Optical Science and Engineering ETDs

Experimental observation of optical refrigeration using ytterbium doped silica glass in recent years has created a new solution for heat mitigation in high-power laser systems, nonlinear fiber experiments, integrated photonics, and precision metrology. Current efforts of different groups focus on compositional optimization, fiber fabrication, and investigating how much silica can be cooled with a laser. At the start of this work, the best effort in laser cooling ytterbium doped silica saw cooling by 6 K from room temperature. This dissertation follows the experimental efforts that culminated in the increase of this initial record by one order of magnitude. Comprehensive spectroscopic …