Use Of Interlaboratory Studies For The Development Of Consensus-Based Criteria For The Elemental Analysis Of Electrical Tapes, Lacey M. Leatherland

Graduate Theses, Dissertations, and Problem Reports (ETD)

Tape evidence is often used in criminal cases involving violent crimes, kidnappings, improvised explosive devices (IEDs), and drug trafficking. This evidence can reveal potential links between suspects, items, or scenes. The forensic examination of electrical tape can provide investigative leads or offer support to alternative hypotheses evaluated in the courtroom. A conventional analytical scheme includes microscopic examination, Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy Energy Dispersive Spectrometry (SEM-EDS), and Pyrolysis Gas Chromatography Mass Spectrometry (Py-GC/MS). Elemental analysis of electrical tapes is commonly achieved using SEM-EDS; however, recent scientific literature suggests that this analysis can evolve from using SEM-EDS to …

Fluid-Rock And Fluid-Steel Interaction In Geothermal Energy Development In The Appalachain Basin, Samuel H. Bowman

Graduate Theses, Dissertations, and Problem Reports (ETD)

The ever-increasing demand for clean energy requires creative solutions. In the United States, unconventional energy sources such as geothermal are conventionally limited to the western half of the country. The Appalachian Basin in the Eastern United States is one such possible creative solution, although the comparatively low temperature gradient presents a significant challenge to delivering economically feasible geothermal energy. An emerging technology is enhanced geothermal systems, these are engineered reservoirs where a working fluid (typically water) is cycled between the subsurface energy source and the energy collection facility at the surface. The liquid water interacts with the geothermal reservoir rock …

Measuring And Modeling Riparian Wetland Saturated Hydraulic Conductivity, Nutrient Concentrations And Shallow Groundwater Dynamics In An Appalachian Mixed Land Use Catchment, Bidisha Faruque Abesh

Graduate Theses, Dissertations, and Problem Reports (ETD)

The paucity of research on accurate predictions of saturated hydraulic conductivity (Ksat), spatiotemporal analysis of nutrient concentrations relative to water source types (stream and shallow groundwater (SGW)), water flow directions, and land use in riparian wetlands of Appalachian mixed land use catchments underscored the need for this study. Additionally, the lack of SGW flow simulations and stream-SGW interactions using three-dimensional (3D) numerical models (i.e., MODFLOW) in these riparian wetlands further highlighted the research gap. Observed data including soil properties, Ksat, surface water (SW) and SGW levels, and nutrient concentrations, including nitrate (NO3-N), nitrite (NO2-N), ammonium (NH4-N), orthophosphate (PO43-P), total nitrogen …

Reconstructing Δ14c Production Events Using Tree Rings: Does Tree Physiology Affect Estimates Of Atmospheric Δ14c?, Meagan Rory Walker

Graduate Theses, Dissertations, and Problem Reports (ETD)

Cosmic rays and solar energetic particles (SEP) bombard the Earth’s geomagnetic field, posing a threat to satellites, space stations, and human space exploration. These rays and particles also produce radiocarbon (¹⁴C) in Earth’s atmosphere, thus records of past ¹⁴C concentration in the atmosphere may be indicative of past cosmic and solar activity. Rapid increases in the concentration of atmospheric radiocarbon ¹⁴C, (Miyake events) first identified in tree rings, are thought to be a result of solar eruptive activity triggering the release of solar energetic particles, though the precise nature of past events remains unresolved. The first …

Ung: A Diagnostic Standard C Library, Jakob Knute Kaivo

Graduate Theses, Dissertations, and Problem Reports (ETD)

Undefined behavior in C programs is a major source of unreliable software. Many of the most common exploitable software vulnerabilities can be traced directly to undefined behavior. In the increasingly connected world, a successful attack can cost the victim millions of dollars to recover from. While static program analysis aids in identifying undefined behavior, testing indicates that even the best static analysis tools correctly identifies about 35% of these defects. This dissertation introduces UNG’s Not GNU (UNG), a standard C library designed to mitigate undefined behavior. Where others have seen opportunities for optimization, UNG makes every effort to identify undefined …

Experimental And Chemical Modeling Of Applied Dc Electric Field Induced H2 – Air Axisymmetric Laminar Co-Flow Diffusion Flames With Low Carbon Impurities, Susith Dilshan Pathmasiri Gunamuni Halowitage

Graduate Theses, Dissertations, and Problem Reports (ETD)

The effect of externally applied DC electric fields on flame structure was investigated in a stationary atmospheric axisymmetric laminar H₂–Air flame with less than 100 ppm carbon equivalent impurities. Flame OH chemiluminescence signals were recorded using a UV-sensitive CCD array as a function of voltage (+10 to -10 kV) applied to a stainless-steel ring electrode placed around the burner nozzle. Changes in chemiluminescence signal are reported as a function of electrode height above the burner, airflow, and fuel composition. Significant changes in OH* distributions were observed for voltages below -5 kV. Under optimum conditions, the height of the …

Development Of Probabilistic Dynamic Model Building And Bayesian Machine Learning Approaches, Samuel Oladayo Adeyemo

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

Development of Probabilistic Dynamic Model Building and Bayesian Machine Learning Approaches

Samuel Adeyemo

The recent years have seen a tremendous increase in the use of artificial intelligence (AI) and machine learning (ML) for the development of data-driven mathematical models needed for performing real-time optimization, model-based control, performance optimization, dynamic data reconciliation, and process performance monitoring. However, the development of data-driven models is faced with some challenges including lack of model interpretability, sensitivity of algorithm to noise in training data, limited extrapolation capabilities and violation of conservation laws. Drawing motivation from these existing gaps, this work aims to develop robust …

Advanced Techniques In Time Series Forecasting: From Deterministic Models To Deep Learning, Xue Bai

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation discusses three instances of temporal prediction, applied to population dynamics and deep learning.

In population modeling, dynamic processes are frequently represented by systems of differential equations, allowing for the analysis of various phenomena. The first application explores modeling cloned hematopoiesis in chronic myeloid leukemia (CML) via a nonlinear system of differential equations. By tracking the evolution of different cell compartments, including cycling and quiescent stem cells, progenitor cells, differentiated cells, and terminally differentiated cells, the model captures the transition from normal hematopoiesis to the chronic and accelerated-acute phases of CML. Three distinct non-zero steady states are identified, representing …

Assessing Carbon Sequestration Of Mixed Hardwood Forests Through Optimizing Harvesting Strategies And Biomass Utilization For Biochar, Bibek Aryal

Graduate Theses, Dissertations, and Problem Reports (ETD)

This study investigated the long-term carbon stock of central Appalachian mixed hardwood forests under several harvesting strategies. The strategies were optimized to maximize both long-term carbon sequestration and timber supply during harvest using Mixed-Integer Linear Programming (MILP) models. Clear-cut (CC), Partial cut (PC), and mixed harvesting methods to unharvested conditions over 190 years were studied. Initially, harvested forests showed lower sequestration rates than unharvested forests but eventually surpassed them, with CC showing the highest rates over time. Younger forests, particularly those aged 85 to 130 years, exhibited peak carbon sequestration rates. Regarding carbon stock, the unharvested scenario initially had the …

Room Temperature Decarboxylative Amination Reactions Of Carboxylic Acids, Rabina Basnet

Graduate Theses, Dissertations, and Problem Reports (ETD)

Anilines are important structural motifs present in numerous natural products and pharmaceutically relevant compounds. Among the various synthetic strategies that have been developed, transition-metal-catalyzed cross-coupling reactions represent one of the most commonly employed methods for the formation of anilines. However, these approaches generally require pre-functionalized aryl coupling partners, and the utilization of more readily available, and structurally diverse coupling partners, such as carboxylic acids, would be desirable. Decarboxylative coupling reactions have garnered significant attention as an alternative approach to form new C-N bonds, and substantial progress has been made in this area. Nevertheless, these methods remain limited, with a predominant …

Three Essays On Energy Related To State Policies And Low Carbon Transitions, Pinky Thomas

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation consists of three essays on energy-related state policies and energy transition. Each paragraph below refers to the three abstracts for the three chapters in this dissertation, respectively.

The first essay is entitled: “Impacts of State Tax and Resource Ownership Policies on Extraction: Evidence from U.S. Natural Gas Production”. The innovation of combined use of horizontal drilling and hydraulic fracturing technologies during the 2000s has allowed natural gas producers in the United States to extract natural gas and liquids from deep shale formations in a cost-efficient manner. This essay evaluates whether unconventional gas production responds to tax changes, and …

Photoinduced Alpha-Hydroxy C–H Alkylation Of Mono-Alcohols Via Hydrogen Atom Transfer (Hat) Of An Activated Boron-Containing Complex, Courtney Deanna Glenn

Graduate Theses, Dissertations, and Problem Reports (ETD)

Hydroxy (-OH) groups are one of the most abundant functional groups found in natural products and pharmaceuticals with many of these compounds containing multiple alcohol classes. The ability to selectively functionalize a specific α-OH C–H bond in the presence of other competitive sites would provide straightforward access to new, potentially bioactive compounds. In recent literature, photoredox catalysis has been implemented to perform site and stereoselective α-OH C–H functionalization of cis-diol containing substrates. Incorporating an organoboron cocatalyst into these systems have proven to be crucial in decreasing the bond dissociation energy (BDE) and increasing hydricity of the α-OH C–H bond …

Evaluating Land Cover Change And Opportunities For Bioenergy Crop Development On Surface Mine Sites In West Virginia, U.S.A., Kenzie D. Kohrs

Graduate Theses, Dissertations, and Problem Reports (ETD)

Surface mining can impact land cover, forests, and water quality. Current reclamation strategies include revegetation with herbaceous species due to the ease and speed of cover establishment. Herbaceous and woody biomass crops have been used in various studies to reclaim surface mines and act as an alternative to nonrenewable energy sources. The objectives of this study were to quantify the state of vegetation growth on former surface mines in West Virginia over a 9-year period and identify suitable acreage for bioenergy production. During 2011 to 2020, we found that over 40,000 acres had been converted to forest and 40,000 acres …

Utilizing Suas-Based Remote Sensing For Sustainable Outdoor Recreational Trail Design And Monitoring, Isaac C. Kinder

Graduate Theses, Dissertations, and Problem Reports (ETD)

This study utilizes sUAS-based remote sensing and hydrologic models to analyze and predict locations susceptible to water-based trail erosion. Erosion is frequently cited as the most significant environmental impact of trails and often requires costly design and management considerations. A professionally designed trail totaling 4 km in length was segmented based on presence or absence of water-based erosion for analyses and then flown with sUAS technology. Three Logistic regression (LR) models were generated utilizing several hydrologic terrain models of varying resolutions to determine the effects of spatial resolution on the models’ predictive accuracies. Receiver operator characteristics, kappa, and overall accuracy …

Implementing Unmanned Aerial Vehicles To Collect Human Gait Data At Distance And Altitude For Identification And Re-Identification, Donn E. Bartram

Graduate Theses, Dissertations, and Problem Reports (ETD)

Gait patterns are a class of biometric information pertaining to the way a person moves and poses. Gait information is unique to each person and can be used to identify and reidentify people. Historically, this task has been achieved through the use of multiple ground-based imaging sensors. However, as Unmanned Aerial Vehicles (UAVs) advance, they present the opportunity to evolve the process of persons identification and re-identification. Collecting human gait data using UAVs at distances ranging from 20m to 500m and altitudes ranging from 0m to 120m is a challenging task. The current biometric data collection methods, primarily designed for …

Investigation Of Deoxyfluorination Of Alkyl Alcohols Using Pentafluoropyridines Through A Covalent Intermediate, Christopher Allen Bias

Graduate Theses, Dissertations, and Problem Reports (ETD)

Organofluorines are an omnipresent class of organic molecules, especially in pharmaceuticals. Selective fluorination of drug molecules allows for the influence of properties including metabolic activity, solubility, and intrinsic potency. Deoxyfluorinations are typically performed via generation of nucleophilic fluoride from a deoxyfluorination agent. Traditionally, diethylaminosulfur trifluoride (DAST) is the reagent of choice for these reactions, and it remains a popular reagent today. However, it has a propensity to form elimination side products and explode. Several research groups have recently developed new classes of deoxyfluorination agents including imidazole-based reagents (PhenoFluor) and sulfonyl fluorides (PyFluor) that exhibit better functional group tolerance and much …

Modeling The Dynamics Of Radiation Belt Electrons And Ring Current Protons, Xingzhi Lyu

Graduate Theses, Dissertations, and Problem Reports (ETD)

Earth’s inner magnetosphere is a highly dynamic region with various charged particle populations and current systems. The radiation belts, composed of relativistic electrons and protons, is an environment that can pose significant risks to both spacecraft and humans in space; while the fluctuations of ring current, an electric current flowing around the earth consisting of energetic electrons and ions, can lead to severe disruptions in ground-based electrical systems. In this dissertation, we first modeled the long-term evolution of ring current protons based on the measurements of Van Allen Probes. By implementing a 1D radial diffusion model with charge exchange loss, …

Machine Learning And Rna Bioinformatics, Jason Rafe Miller

Graduate Theses, Dissertations, and Problem Reports (ETD)

The applied science of bioinformatics encompasses computational analysis of molecular biology data. Advances in genomics and DNA sequencing technology have enabled computational analysis of ribonucleic acids (RNAs), which play diverse and critical roles in most cells. To assist the study of human RNA, we trained machine learning models on RNA nucleotide sequences, devoid of domain knowledge. We built models that distinguish long non-coding lncRNA from protein-coding mRNA, and models that predict the cytoplasmic vs. nuclear preferences of lncRNAs. In a review of published lncRNA subcellular localization classifiers, we show that the commonly used validation protocol generates optimistic performance measures, and …

Exploring Crystal Polymorphism In Additive-Assisted Chemical Vapor-Deposited Transition Metal Chalcogenides And Oxides, Lawrence Kirimi Mubwika

Graduate Theses, Dissertations, and Problem Reports (ETD)

Crystal polymorphism is a phenomenon in which compounds with the same chemical formula can be crystallized into different crystal structures. This phenomenon can be observed in elemental materials, such as diamond and graphite, as well as in compounds, such as the trigonal (1H) or octahedral (1T) prismatic MoS₂. Crystals can also exhibit polytypism by stacking different polymorphs in a certain order, with the stacking sequence determining the variation between polytypes. Although all polymorphs and polytypes have the same chemical composition, each polymorph and polytype possesses unique electronic and physical properties.

This study explores the additive-assisted chemical vapor deposition …

A Multi-Wavelength Determination Of The Total Luminosity And Star Formation Rate Of The Milky Way, Joshua L. Mascoop

Graduate Theses, Dissertations, and Problem Reports (ETD)

The star formation rate (SFR) of the Milky Way is poorly understood in comparison to the SFR of other galaxies. In order to better find the Galaxy's place in the universe, it is imperative to understand the star formation activity occurring within it. We characterize the Galactic \hii\ region luminosity function (LF) at multiple infrared and radio wavelengths using a sample of 797 first Galactic quadrant \hii regions compiled from the WISE Catalog of Galactic \hii Regions. This sample is statistically complete for all regions powered by single stars of type O9.5V and earlier.

We find that neither a single …

Advances In Machine Learning Aided Seismic Interpretation And Inversion For Subsurface Characterization, Tobi Micheal Ore

Graduate Theses, Dissertations, and Problem Reports (ETD)

Geophysical data are used to “remotely sense” the subsurface to illuminate structures, stratigraphy, and features that are of interest in the exploration for energy, suitable storage for carbon dioxide, geothermal development, and environmental considerations. The interpretations of these data typically are regarded as partially an art, as it depends on the experience of the interpreter. This is further exacerbated with the big data era as this data is large and takes several days, even longer, to manually interpret. To bridge this gap of speed and subjective bias, machine learning has been successfully applied to automate the geophysical interpretation process. This …

Estimating Home Range Size And Density Of White-Tailed Deer (Odocoileus Virginianus) In West Virginia, Sarah M. Pesi

Graduate Theses, Dissertations, and Problem Reports (ETD)

Big game hunting is an important source of revenue and recreation in the United States. Of big game species, white-tailed deer (Odocileus virginianus) are the most heavily pursued. White-tailed deer are a widespread generalist species, capable of existing at high densities. Hunting is often used as the primary method of managing deer populations, particularly in the eastern United States, where there is a lack of large predators. When populations reach high densities, there can be negative effects on the environment and conflicts with humans. Managers must consider both creating adequate hunting opportunities and reducing negative impacts when managing …

A Hyperbolic Relaxation Solver For Numerical Relativity, Thiago Assumpcao

Graduate Theses, Dissertations, and Problem Reports (ETD)

Numerical relativity (NR) simulations are essential for self-consistently modeling compact binary mergers, whose observations form the heart of gravitational-wave science. Stable NR simulations are the result of mathematical and computational breakthroughs spanning several decades: early attempts to numerically solve the two-body problem in General Relativity (GR) date back to the 1960s, while the first successful black-hole binary merger simulations were performed in 2005 with the generalized harmonic coordinates, and in 2006 using the moving-puncture gauge.

Today, NR continues to drive progress in gravity research, with ongoing efforts focused on increasing physical realism in simulations containing matter, exploring alternative theories of …

X-Ray Absorption And Related Studies In Superconducting Devices And Magnetic Thin Films, Ghadendra Bahadur Bhandari

Graduate Theses, Dissertations, and Problem Reports (ETD)

Superconducting and magnetic thin films are commonly used in sensors for analytical detectors, especially those that operate at very low temperatures, often below 1 Kelvin. These highly sensitive detectors, capable of functioning across a broad range of wavelengths, have garnered significant interest in scientific research. The focus of this thesis is to address a material challenge associated with an emerging technology known as microwave kinetic inductance detectors (MKIDs). The research involves the study of Al/Si and Al-Mn/Si-based thin films, as well as an investigation into the magnetic properties of LaMnO₃ thin films. LaMnO₃, a perovskite thin film that plays a …

Conformational Investigation Of Biopolymers Through Molecular Dynamics (Md) Simulations And In-Droplet Hdx-Ms Utilizing Cvssi, Samira Hajian Foroushani

Graduate Theses, Dissertations, and Problem Reports (ETD)

Over the last two decades, mass spectrometry (MS) has received significant interest in biological study platforms, especially in the areas of proteomics and metabolomics. With the development of soft ionization methods like electrospray ionization (ESI), mass spectrometry has emerged as a potent method for directly characterizing proteins in their native state. The recent invention of capillary vibrating sharp-edge spray ionization has opened new avenues for the study of biopolymer native structure including the usage of droplet charge tuning and in-droplet hydrogen-deuterium exchange (HDX) labeling. With this new technique comes the opportunity to study biopolymer ion structure preservation with molecular dynamics …

A Floquet Solver For Time Periodic Open Quantum Systems, Fenton Ross Clawson

Graduate Theses, Dissertations, and Problem Reports (ETD)

Computational physics has been a backbone of experimental and theoretical physics since the 1940’s, when the first nuclear bomb and ballistic simulations were per- formed at Los Alamos Laboratory. Nowadays, however, simulation of open quan- tum systems has been formalized into coding packages and user-friendly functions, such as QuTiP or Qiskit, which allow users to simulate these systems without hav- ing the in-depth knowledge required to build the computational backbone from the ground-up. With the shift in modern quantum physics towards the realization of quantum computation, a strong computational background is still necessary to lend validity to theoretical results and …

Α-Hydroxy C–H Functionalization Of Alcohols Via Boronic Acid, Hat, Photoredox Triad Catalytic System, Seth Christopher Cowan

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation explores the research that I have conducted in my time at West Virginia University. Most of my work has focused on the development of methods and studies to further understand the α-OH C–H functionalization of alcohols. This work involves a system of catalysts including photocatalysts, HAT catalysts, and boronic acid catalysts. Chapter 1 highlights a background for each of these areas. Photoredox catalysis has been an increasing area of chemistry over the past two decades as this technique can be used to design conditions to form new bonds in a selective manner through the utilization of light energy. …

Characterizing Prescribed Fire With Terrestrial Lidar In The New Jersey Pine Barrens, Samuel Rhule Stockton

Graduate Theses, Dissertations, and Problem Reports (ETD)

Prescribed burning has become a commonly used tool in the mitigation of wildfire, though monitoring the way it changes ecosystems has historically been a time-intensive process. Rapid change across ecosystems has necessitated advancements in remote sensing technologies to quantify the changes taking place. Single-scan terrestrial LiDAR scanning is one such method of monitoring these changes through the quantification of ecosystem structural characteristics. Acute disturbance events such as fire can transform the structure of an ecosystem, and by extension, change the way that ecosystem functions. The purpose of this study is to analyze the changes in vegetation density and distribution following …

Experimental Verification And Time-Resolved Bispectral Analysis Of Nonlinear Coupling In The Toroidicity-Induced Alfv´En Eigenmode Spectrum, Gregory Allen Riggs

Graduate Theses, Dissertations, and Problem Reports (ETD)

In magnetically-confined fusion devices, the toroidicity-induced Alfv´en eigenmode (TAE) is a well-studied, weakly stable solution of the linearized ideal magnetohydrodynamic (MHD) equations. Due to intrinsic coupling of poloidal harmonics of the shear Alfv´en wave (SAW) in toroidal geometry, the rotational transform of magnetic field lines modulates the effective index of refraction, ensuring gaps in the so-called “Alfv´en continuum.” Experimental verification of theoretical predictions for various parameters of interest (i.e., frequency, mode structure, instability threshold, etc.) is established in the literature.

We present the first systematic study of TAE-TAE phase coherence in an experimental device, using the DIII-D tokamak. Crucially, nonlinear …

Synthesis, Characterization, And Reactivity Studies Of Pyridine Dipyrrolide Iron-Carbene Complexes With Electronically Distinct Carbene Moieties, Jose G. Rodriguez

Graduate Theses, Dissertations, and Problem Reports (ETD)

First, three (^MesPDP^Ph) iron carbene complexes with electronically distinct carbene moieties were synthesized. These transitional iron carbene complexes were first characterized by ¹H nuclear magnetic resonance (NMR) spectroscopy as their spectra showed paramagnetically shifted resonances. Additionally, their respected solid state structures were collected via X-ray diffraction. The two donor/acceptor iron carbene complexes [(^MesPDP^Ph)Fe(C(CO₂Me)(4-FPh) and (^MesPDP^Ph)Fe(C(CO₂Me)(4-MeOPh)] demonstrated a weak Fe-O interaction between the iron center and ester function group while the (^MesPDP^Ph)Fe(IMe) displayed a C_2v symmetric structure in the …