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Full-Text Articles in Physical Sciences and Mathematics

Nebraska Test #2275: Case Ih Steiger 475 Quadtrac, Nebraska Tractor Test Lab Jan 2024

Nebraska Test #2275: Case Ih Steiger 475 Quadtrac, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

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Nebraska Test #2290: Case Ih Steiger 555 Quadtrac, Nebraska Tractor Test Lab Jan 2024

Nebraska Test #2290: Case Ih Steiger 555 Quadtrac, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

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Nebraska Test #2276: Case Ih Steiger 525 Quadtrac, Nebraska Tractor Test Lab Jan 2024

Nebraska Test #2276: Case Ih Steiger 525 Quadtrac, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

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Nebraska Test #2278: Case Ih Steiger 475, Nebraska Tractor Test Lab Jan 2024

Nebraska Test #2278: Case Ih Steiger 475, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

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Nebraska Test #2277: Case Ih Steiger 425, Nebraska Tractor Test Lab Jan 2024

Nebraska Test #2277: Case Ih Steiger 425, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

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Use Of Hydroxychloroquine In Multidrug Protocols For Sars-Cov-2, Eleftherios Gkioulekas, Peter A. Mccullough Jan 2024

Use Of Hydroxychloroquine In Multidrug Protocols For Sars-Cov-2, Eleftherios Gkioulekas, Peter A. Mccullough

School of Mathematical & Statistical Sciences Faculty Publications

We review the available evidence supporting the use of hydroxychloroquine-based multidrug protocols in the treatment of COVID-19, in response to a recently published editorial in the Tasman Medical Journal.

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Novel Re-Crosslinkable Preformed Particle Gels (Rppg) For Parent- And Infill-Well-Fracture Interactions Mitigation, Xiaojing Ge, Adel Alotibi, Ahmed Al-Hlaichi, Yanbo Liu, Tao Song, Junchen Liu, Baojun Bai, Thomas P. Schuman Jan 2024

Novel Re-Crosslinkable Preformed Particle Gels (Rppg) For Parent- And Infill-Well-Fracture Interactions Mitigation, Xiaojing Ge, Adel Alotibi, Ahmed Al-Hlaichi, Yanbo Liu, Tao Song, Junchen Liu, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Hydraulic fracturing treatments in unconventional infill (or "child") wells can be significantly affected by depletion from existing parent-well, resulting in asymmetrical fracture growth. These issues may lead to excessive load-water production, proppant deposition, casing deformation in the parent well, and unbalanced stimulation of infill wells. To mitigate these effects, various strategies have been proposed, including the use of far-field diverters in child wells and repressurization of parent wells. Additionally, an increasingly popular strategy involves injecting near-wellbore diverters to temporarily plug entry points into the parent wellbores during frac operations on infill wells. To achieve better application, a novel low-cost, self-degradable, …

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Comparative Analysis Of Critical Bond Strength Parameters Of Neat Class G Cement And Fly Ash Enhanced Cement To Steel, C. M. Potter, Andreas Eckert, James A. Jones, Z. Weicheng, M. Meng Jan 2024

Comparative Analysis Of Critical Bond Strength Parameters Of Neat Class G Cement And Fly Ash Enhanced Cement To Steel, C. M. Potter, Andreas Eckert, James A. Jones, Z. Weicheng, M. Meng

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

In subsurface engineering applications, such as wellbore integrity, the interface between cement and steel is integral to expected functionality. The interface between steel and cement is often a structural weak point in many systems, however, the critical parameters for debonding evaluation are poorly understood and derived from outdated experimental procedures. Through experimental debonding tests, this study aims to analyze the tensile bond strength and fracture parameters and their sensitivity to cement composition with a pozzolanic additive (fly ash). Neat Class G cement testing resulted in an average tensile bond strength of 0.223 MPa, an average contact stiffness of 2.94x108 N/m3, …

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Improving The Robustness Of Neural Networks To Adversarial Patch Attacks Using Masking And Attribution Analysis, Atandra Mahalder Jan 2024

Improving The Robustness Of Neural Networks To Adversarial Patch Attacks Using Masking And Attribution Analysis, Atandra Mahalder

Honors Undergraduate Theses

Computer vision algorithms, including image classifiers and object detectors, play a pivotal role in various cyber-physical systems, spanning from facial recognition to self-driving vehicles and security surveillance. However, the emergence of real-world adversarial patches, which can be as simple as stickers, poses a significant threat to the reliability of AI models utilized within these systems. To address this challenge, several defense mechanisms such as PatchGuard, Minority Report, and (De)Randomized Smoothing have been proposed to enhance the resilience of AI models against such attacks. In this thesis, we introduce a novel framework that integrates masking with attribution analysis to robustify AI …

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Estimating Modeling Parameters For Covid-19 Spread On Campus, Aviel S. Crigger Jan 2024

Estimating Modeling Parameters For Covid-19 Spread On Campus, Aviel S. Crigger

Honors Undergraduate Theses

Understanding the true burden of community transmission of communicable diseases like COVID-19 is crucial for effective public health response. Clinical cases, while important, only represent a fraction of the actual disease prevalence within a population. In this thesis, we investigate methods to estimate parameters that link clinical cases to the true disease prevalence using a modified compartmental model known as SICR (Susceptible, Infected, Cases, Recovered). We employ Bayesian inference and ensemble Markov chain Monte Carlo (MCMC) simulations to analyze clinical case data provided by the University of Central Florida Health Center from 2020 to 2022. Our goal is to estimate …

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Tracking The Reaction Networks Of Criegee Intermediates Formed In The Ozone-Assisted Oxidation Reactions Of C5 Acyclic And Endocyclic Alkenes, Arden M. Floyd Jan 2024

Tracking The Reaction Networks Of Criegee Intermediates Formed In The Ozone-Assisted Oxidation Reactions Of C5 Acyclic And Endocyclic Alkenes, Arden M. Floyd

Honors Undergraduate Theses

Uni- and bi-molecular reactions involving Criegee intermediates (CIs), characteristic to alkene-ozone reactions, play an important role in synthetic organic, atmospheric, and combustion chemistry. However, difficulty in detecting key intermediates has prevented a thorough understanding of the details of the ozonolysis mechanism. To gain new insights into how alkene structure affects the CI network, the ozone assisted oxidation reactions of trans-2-pentene and cyclopentene are investigated between 320 K and 760 K in an atmospheric pressure jet stirred reactor (JSR). Molecular-beam mass spectrometry in conjunction with single photon tunable synchrotron VUV radiation is used to identify elusive intermediates by means of …

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Music Recommendation Using Exemplars And Contrastive Learning, Tina Tran Jan 2024

Music Recommendation Using Exemplars And Contrastive Learning, Tina Tran

Honors Undergraduate Theses

The popularity of AI audio applications is growing, it is used in chatbots, automated voice translation, virtual assistants, and text-to-speech translation. Audio classification is crucial in today’s world with a growing need to sort and classify millions of existing audio data with increasing amounts of new data uploaded over time. In the area of classification lies the difficult and lucrative problem of music recommendation. Research in music recommendation has trended over time towards collaborative-based approaches utilizing large amounts of user data. These approaches tend to deal with the cold-start problem of insufficient data and are costly to train. We look …

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Multicolor Bipartite Ramsey Number Of Double Stars, Gregory M. Decamillis Jan 2024

Multicolor Bipartite Ramsey Number Of Double Stars, Gregory M. Decamillis

Honors Undergraduate Theses

The core idea of Ramsey theory is that complete disorder is impossible. Given a large structure, no matter how complex it is, we can always find a smaller substructure that has some sort of order. For positive integers $n, m$, the double star $S(n,m)$ is the graph consisting of the disjoint union of two stars $K_{1,n}$ and $K_{1,m}$ together with an edge joining their centers. The $k$-color bipartite Ramsey number of $ S(n,m)$, denoted by $r_{bip}(S(n,m);k)$, is the smallest integer $N$ such that, in any $k$-coloring of the edges of the complete bipartite graph $K_{N,N}$, there is a monochromatic copy …

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L3dml: Facilitating Geo-Distributed Machine Learning In Network Layer, Xindi Hou, Shuai Gao, Ningchun Liu, Fangtao Yao, Bo Lei, Hongke Zhang, Sajal K. Das Jan 2024

L3dml: Facilitating Geo-Distributed Machine Learning In Network Layer, Xindi Hou, Shuai Gao, Ningchun Liu, Fangtao Yao, Bo Lei, Hongke Zhang, Sajal K. Das

Computer Science Faculty Research & Creative Works

Geo-Distributed Machine Learning (GDML) aims to train large-scale machine learning models across geographically dispersed datacenters. However, the performance of GDML systems is constrained by the limited Wide Area Network (WAN) bandwidth and the presence of the straggler problem. Existing GDML designs often show contradictory effects in addressing these challenges, while in-network computing attempts are typically restricted to single datacenter environments rather than the more complex GDML scenarios. To overcome these limitations, this paper proposes L3DML to facilitate GDML using the P4-based Software-defined Network (SDN). Our approach incorporates three key innovations. Firstly, we introduce a novel network addressing scheme that enables …

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Message From The Phd Dissertation Showcase Chairs, Panos K. Chrysanthis, Sanjay Madria Jan 2024

Message From The Phd Dissertation Showcase Chairs, Panos K. Chrysanthis, Sanjay Madria

Computer Science Faculty Research & Creative Works

No abstract provided.

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Smart Connected Farms And Networked Farmers To Improve Crop Production, Sustainability And Profitability, Asheesh K. Singh, Behzad J. Balabaygloo, Barituka Bekee, Samuel W. Blair, Suzanne Fey, Fateme Fotouhi, Ashish Gupta, Amit Jha, Jorge C. Martinez-Palomares, Kevin Menke, Aaron Prestholt, Vishesh K. Tanwar, Xu Tao, Anusha Vangala, Matthew E. Carroll, Sajal K. Das, Guilherme Depaula Jan 2024

Smart Connected Farms And Networked Farmers To Improve Crop Production, Sustainability And Profitability, Asheesh K. Singh, Behzad J. Balabaygloo, Barituka Bekee, Samuel W. Blair, Suzanne Fey, Fateme Fotouhi, Ashish Gupta, Amit Jha, Jorge C. Martinez-Palomares, Kevin Menke, Aaron Prestholt, Vishesh K. Tanwar, Xu Tao, Anusha Vangala, Matthew E. Carroll, Sajal K. Das, Guilherme Depaula

Computer Science Faculty Research & Creative Works

To meet the grand challenges of agricultural production including climate change impacts on crop production, a tight integration of social science, technology and agriculture experts including farmers are needed. Rapid advances in information and communication technology, precision agriculture and data analytics, are creating a perfect opportunity for the creation of smart connected farms (SCFs) and networked farmers. a network and coordinated farmer network provide unique advantages to farmers to enhance farm production and profitability, while tackling adverse climate events. the aim of this article is to provide a comprehensive overview of the state of the art in SCF including the …

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Protecting Activity Sensing Data Privacy Using Hierarchical Information Dissociation, Guangjing Wang, Hanqing Guo, Yuanda Wang, Bocheng Chen, Ce Zhou, Qiben Yan Jan 2024

Protecting Activity Sensing Data Privacy Using Hierarchical Information Dissociation, Guangjing Wang, Hanqing Guo, Yuanda Wang, Bocheng Chen, Ce Zhou, Qiben Yan

Computer Science Faculty Research & Creative Works

Smartphones and wearable devices have been integrated into our daily lives, offering personalized services. However, many apps become overprivileged as their collected sensing data contains unnecessary sensitive information. For example, mobile sensing data could reveal private attributes (e.g., gender and age) and unintended sensitive features (e.g., hand gestures when entering passwords). To prevent sensitive information leakage, existing methods must obtain private labels and users need to specify privacy policies. However, they only achieve limited control over information disclosure. In this work, we present Hippo to dissociate hierarchical information including private metadata and multi-grained activity information from the sensing data. Hippo …

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Interlude: Interactions Between Labeled And Unlabeled Data To Enhance Semi-Supervised Learning, Zhe Huang, Xiaowei Yu, Dajiang Zhu, Michael C. Hughes Jan 2024

Interlude: Interactions Between Labeled And Unlabeled Data To Enhance Semi-Supervised Learning, Zhe Huang, Xiaowei Yu, Dajiang Zhu, Michael C. Hughes

Computer Science Faculty Research & Creative Works

Semi-supervised learning (SSL) seeks to enhance task performance by training on both labeled and unlabeled data. Mainstream SSL image classification methods mostly optimize a loss that additively combines a supervised classification objective with a regularization term derived solely from unlabeled data. This formulation often neglects the potential for interaction between labeled and unlabeled images. In this paper, we introduce InterLUDE, a new approach to enhance SSL made of two parts that each benefit from labeled-unlabeled interaction. The first part, embedding fusion, interpolates between labeled and unlabeled embeddings to improve representation learning. The second part is a new loss, grounded in …

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Core-Periphery Multi-Modality Feature Alignment For Zero-Shot Medical Image Analysis, Xiaowei Yu, Lu Zhang, Zihao Wu, Dajiang Zhu Jan 2024

Core-Periphery Multi-Modality Feature Alignment For Zero-Shot Medical Image Analysis, Xiaowei Yu, Lu Zhang, Zihao Wu, Dajiang Zhu

Computer Science Faculty Research & Creative Works

Multi-modality learning, exemplified by the language-image pair pre-trained CLIP model, has demonstrated remarkable performance in enhancing zero-shot capabilities and has gained significant attention recently. However, simply applying language-image pre-trained CLIP to medical image analysis encounters substantial domain shifts, resulting in severe performance degradation due to inherent disparities between natural (non-medical) and medical image characteristics. To address this challenge and uphold or even enhance CLIP's zero-shot capability in medical image analysis, we develop a novel approach, Core-Periphery feature alignment for CLIP (CP-CLIP), to model medical images and corresponding clinical text jointly. To achieve this, we design an auxiliary neural network whose …

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Enhancing Group-Wise Consistency In 3-Hinge Gyrus Matching Via Anatomical Embedding And Structural Connectivity Optimization, Chao Cao, Xiaowei Yu, Lu Zhang, Tong Chen, Yanjun Lyu, Tianming Liu, Dajiang Zhu Jan 2024

Enhancing Group-Wise Consistency In 3-Hinge Gyrus Matching Via Anatomical Embedding And Structural Connectivity Optimization, Chao Cao, Xiaowei Yu, Lu Zhang, Tong Chen, Yanjun Lyu, Tianming Liu, Dajiang Zhu

Computer Science Faculty Research & Creative Works

Recently, a novel cortical folding pattern known as the 3-hinge gyrus (3HG) has been identified. 3HGs are defined as the convergence of the gyri coming from three distinct directions on gyral crests. In contrast to cortical regions, 3HGs are defined at a finer scale and they widely exist across different individuals, representing both commonalities and individualities of cortical folding patterns. It is important to note that 3HGs are identified in individual spaces, lacking natural cross-subject correspondences. To address this issue, we have developed a learning-based method to encode anatomical features of 3HGs into a set of embedding vectors that can …

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The Perils Of Wi-Fi Spoofing Attack Via Geolocation Api And Its Defense, Xiao Han, Junjie Xiong, Wenbo Shen, Mingkui Wei, Shangqing Zhao, Zhuo Lu, Yao Liu Jan 2024

The Perils Of Wi-Fi Spoofing Attack Via Geolocation Api And Its Defense, Xiao Han, Junjie Xiong, Wenbo Shen, Mingkui Wei, Shangqing Zhao, Zhuo Lu, Yao Liu

Computer Science Faculty Research & Creative Works

Location spoofing attack deceiving a Wi-Fi positioning system has been studied for over a decade. However, it has been challenging to construct a practical spoofing attack in urban areas with dense coverage of legitimate Wi-Fi APs. This paper identifies the vulnerability of the Google Geolocation API, which returns the location of a mobile device based on the information of the Wi-Fi access points that the device can detect. We show that this vulnerability can be exploited by the attacker to reveal the black-box localization algorithms adopted by the Google Wi-Fi positioning system and easily launch the location spoofing attack in …

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Soci+: An Enhanced Toolkit For Secure Outsourced Computation On Integers, Bowen Zhao, Weiquan Deng, Xiaoguo Li, Ximeng Liu, Qingqi Pei, Robert H. Deng Jan 2024

Soci+: An Enhanced Toolkit For Secure Outsourced Computation On Integers, Bowen Zhao, Weiquan Deng, Xiaoguo Li, Ximeng Liu, Qingqi Pei, Robert H. Deng

Research Collection School Of Computing and Information Systems

Secure outsourced computation is critical for cloud computing to safeguard data confidentiality and ensure data usability. Recently, secure outsourced computation schemes following a twin-server architecture based on partially homomorphic cryptosystems have received increasing attention. The Secure Outsourced Computation on Integers (SOCI) [1] toolkit is the state-of-the-art among these schemes which can perform secure computation on integers without requiring the costly bootstrapping operation as in fully homomorphic encryption; however, SOCI suffers from relatively large computation and communication overhead. In this paper, we propose SOCI+ which significantly improves the performance of SOCI. Specifically, SOCI+ employs a novel (2,2)-threshold Paillier cryptosystem with fast …

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A Unified Framework For Contextual And Factoid Question Generation, Chenhe Dong, Ying Shen, Shiyang Lin, Zhenzhou Lin, Yang Deng Jan 2024

A Unified Framework For Contextual And Factoid Question Generation, Chenhe Dong, Ying Shen, Shiyang Lin, Zhenzhou Lin, Yang Deng

Research Collection School Of Computing and Information Systems

Question generation (QG) aims to automatically generate fluent and relevant questions, where the two most mainstream directions are generating questions from unstructured contextual texts (CQG), such as news articles, and generating questions from structured factoid texts (FQG), such as knowledge graphs or tables. Existing methods for these two tasks mainly face challenges of limited internal structural information as well as scarce background information, while these two tasks can benefit each other for alleviating these issues. For example, when meeting the entity mention “United Kingdom” in CQG, it can be inferred that it is a country in European continent based on …

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Demonstrating Canvas-Based Processing Of Multiple Camera Streams At The Edge, Ila Gokarn, Hemanth Sabbella, Yigong Hu, Tarek Abdelzaher, Archan Misra Jan 2024

Demonstrating Canvas-Based Processing Of Multiple Camera Streams At The Edge, Ila Gokarn, Hemanth Sabbella, Yigong Hu, Tarek Abdelzaher, Archan Misra

Research Collection School Of Computing and Information Systems

We demonstrate criticality-aware canvas-based processing of multiple concurrent camera streams at the resource constrained edge to show substantial improvement in the accuracy-throughput trade-off. The proposed system focuses the available computation resources on select Regions of Interest (RoI) across all the camera streams by (i) extracting RoI from the input camera stream (ii) 2D bin packing the RoI on a canvas frame and (iii) batching and inferring upon these constructed composite canvas frames with a YOLOv5 object detection model. Our experiments show that such canvas-based processing can (i) sustain real-time processing throughput of 23 FPS per camera across 6 concurrent input …

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Societal Impacts Of Artificial Intelligence: Ethics, Legal, And Governance Issues, Yuzhou Qian, Keng Siau, Fiona Fui-Hoon Nah Jan 2024

Societal Impacts Of Artificial Intelligence: Ethics, Legal, And Governance Issues, Yuzhou Qian, Keng Siau, Fiona Fui-Hoon Nah

Research Collection School Of Computing and Information Systems

Artificial intelligence (AI) is quickly changing the way we work and the way we live. The emergence of ChatGPT has thrust AI, especially Generative AI, into the spotlight. The societal impact of AI is on most people's minds. This article presents several research projects on how AI impacts work and society. Three research works are discussed in this article. The first study develops a theoretical framework structuring the legal and ethical objectives that are needed and the means to achieve them. The second study concentrates on bias and discrimination issues embedded in AI applications. It focuses on enhancing the collaboration …

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Big Code Search: A Bibliography, Kisub Kim, Sankalp Ghatpande, Dongsun Kim, Xin Zhou, Kui Liu, Tegawende F. Bissyande, Jacques Klein, Traon Yves Le Jan 2024

Big Code Search: A Bibliography, Kisub Kim, Sankalp Ghatpande, Dongsun Kim, Xin Zhou, Kui Liu, Tegawende F. Bissyande, Jacques Klein, Traon Yves Le

Research Collection School Of Computing and Information Systems

Code search is an essential task in software development. Developers often search the internet and other code databases for necessary source code snippets to ease the development efforts. Code search techniques also help learn programming as novice programmers or students can quickly retrieve (hopefully good) examples already used in actual software projects. Given the recurrence of the code search activity in software development, there is an increasing interest in the research community. To improve the code search experience, the research community suggests many code search tools and techniques. These tools and techniques leverage several different ideas and claim a better …

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Clearspeech: Improving Voice Quality Of Earbuds Using Both In-Ear And Out-Ear Microphones, Dong Ma, Ting Dang, Ming Ding, Rajesh Krishna Balan Jan 2024

Clearspeech: Improving Voice Quality Of Earbuds Using Both In-Ear And Out-Ear Microphones, Dong Ma, Ting Dang, Ming Ding, Rajesh Krishna Balan

Research Collection School Of Computing and Information Systems

Wireless earbuds have been gaining increasing popularity and using them to make phone calls or issue voice commands requires the earbud microphones to pick up human speech. When the speaker is in a noisy environment, speech quality degrades significantly and requires speech enhancement (SE). In this paper, we present ClearSpeech, a novel deep-learningbased SE system designed for wireless earbuds. Specifically, by jointly using the earbud’s in-ear and out-ear microphones, we devised a suite of techniques to effectively fuse the two signals and enhance the magnitude and phase of the speech spectrogram. We built an earbud prototype to evaluate ClearSpeech under …

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A Comparative Study Of Cationic Copper(I) Reagents Supported By Bipodal Tetramethylguanidinyl-Containing Ligands As Nitrene-Transfer Catalysts, Suraj Kumar Sahoo, Brent Harfmann, Himanshu Bhatia, Harish Singh, Srikanth Balijapelly, Amitava Choudhury, Pericles Stavropoulos Jan 2024

A Comparative Study Of Cationic Copper(I) Reagents Supported By Bipodal Tetramethylguanidinyl-Containing Ligands As Nitrene-Transfer Catalysts, Suraj Kumar Sahoo, Brent Harfmann, Himanshu Bhatia, Harish Singh, Srikanth Balijapelly, Amitava Choudhury, Pericles Stavropoulos

Chemistry Faculty Research & Creative Works

The Bipodal Compounds [(TMG2biphenN-R)CuI-NCMe](PF6) (R = Me, Ar (4-CF3Ph-)) And [(TMG2biphenN-Me)CuI-I] Have Been Synthesized With Ligands That Feature A Diarylmethyl- And Triaryl-Amine Framework And Superbasic Tetramethylguanidinyl Residues (TMG). The Cationic Cu(I) Sites Mediate Catalytic Nitrene-Transfer Reactions Between The Imidoiodinane PhI = NTs (Ts = Tosyl) And A Panel Of Styrenes In MeCN, To Afford Aziridines, Demonstrating Comparable Reactivity Profiles. The Copper Reagents Have Been Further Explored To Execute C-H Amination Reactions With A Variety Of Aliphatic And Aromatic Hydrocarbons And Two Distinct Nitrene Sources PhI = NTs And PhI = NTces (Tces = 2,2,2-Trichloroethylsulfamate) In Benzene/HFIP (10:2 V/v). Good Yields …

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Perfect Polar Alignment Of Parallel Beloamphiphile Layers: Improved Structural Design Bias Realized In Ferroelectric Crystals Of The Novel “Methoxyphenyl Series Of Acetophenone Azines”, Harmeet Bhoday, Nathan Knotts, Rainer Glaser Jan 2024

Perfect Polar Alignment Of Parallel Beloamphiphile Layers: Improved Structural Design Bias Realized In Ferroelectric Crystals Of The Novel “Methoxyphenyl Series Of Acetophenone Azines”, Harmeet Bhoday, Nathan Knotts, Rainer Glaser

Chemistry Faculty Research & Creative Works

An Improved Design Is Described For Ferroelectric Crystals And Implemented With The "Methoxyphenyl Series" Of Acetophenone Azines, (MeO−Ph, Y)-Azines With Y=F (1), Cl (2), Br (3), Or I (4). The Crystal Structures Of These Azines Exhibit Polar Stacking Of Parallel Beloamphiphile Monolayers (PBAMs). Azines 1, 3, And 4 Form True Racemates Whereas Chloroazine 2 Crystallizes As A Kryptoracemate. Azines 1–4 Are Helical Because Of The N−N Bond Conformation. In True Racemates The Molecules Of Opposite Helicity (M And P) Are Enantiomers A(M) And A*(P) While In Kryptoracemates They Are Diastereomers A(M) And B*(P). The Stacking Mode Of PBAMs Is Influenced …

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Solar Enhanced Oxygen Evolution Reaction With Transition Metal Telluride, Harish Singh, Taishi Higuchi-Roos, Fabrice Roncoroni, David Prendergast, Manashi Nath Jan 2024

Solar Enhanced Oxygen Evolution Reaction With Transition Metal Telluride, Harish Singh, Taishi Higuchi-Roos, Fabrice Roncoroni, David Prendergast, Manashi Nath

Chemistry Faculty Research & Creative Works

The Photo-Enhanced Electrocatalytic Method of Oxygen Evolution Reaction (OER) Shows Promise for Enhancing the Effectiveness of Clear Energy Generation through Water Splitting by using Renewable and Sustainable Source of Energy. However, Despite Benefits of Photo electrocatalytic (PEC) Water Splitting, its Uses Are Constrained by its Low Efficiency as a Result of Charge Carrier Recombination, a Large overpotential, and Sluggish Reaction Kinetics. Here, We Illustrate that Nickel Telluride (NiTe) Synthesized by Hydrothermal Methods Can Function as an Extremely Effective Photo-Coupled Electrochemical Oxygen Evolution Reaction (POER) Catalyst. in This Study, NiTe Was Synthesized by Hydrothermal Method at 145°C within Just an Hour …

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