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Articles 33151 - 33180 of 291657

Full-Text Articles in Physical Sciences and Mathematics

Synthesis Of Chiral Amino Acids Via Direct Amination Of Diazo Ester With A Rhodium-Based Catalyst, Steven J. Boyles Jan 2024

Synthesis Of Chiral Amino Acids Via Direct Amination Of Diazo Ester With A Rhodium-Based Catalyst, Steven J. Boyles

Honors College Theses

Amino acids are critical molecules within living organisms as they are the building blocks of proteins. In organisms, proteins serve as regulators of necessary processes, structural components in tissue, hormones, and neurotransmitters. Amino acid therapy is an emerging treatment in the medical field used to treat symptoms of diseases such as Alzheimer’s disease, Parkinson’s disease, and multiple sclerosis. Amino acid therapies have also shown promising effects when it comes to treating mood disorders and weight management. In order to increase the number of amino acids available and increase the potential treatments for other ailments, there is a drive to increase …

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Investigating The Relationship Between Inherited Geologic Framework And Saltwater Intrusion On St. Catherines Island, Georgia, Juliet Talaber, Jacque Kelly, Robert Vance Jan 2024

Investigating The Relationship Between Inherited Geologic Framework And Saltwater Intrusion On St. Catherines Island, Georgia, Juliet Talaber, Jacque Kelly, Robert Vance

Honors College Theses

Since the late 1800s, the oldest cities on the Georgia coast have been withdrawing water from the confined Floridan Aquifer System. As the population has grown, a cone of depression has formed extending from Savannah, GA to St. Catherines Island, GA, a barrier island 50 km southeast of Savannah. On St. Catherines Island, the cone of depression has reversed the lateral and horizontal groundwater flow gradients causing saltwater intrusion into the Upper Floridan Aquifer from the Lower Floridan Aquifer through joints, faults, or solution collapse features. Previous studies from the southern and central areas of the island have found evidence …

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Enhancing Flight Delay Predictions Using Network Centrality Measures, Joseph Ajayi Jan 2024

Enhancing Flight Delay Predictions Using Network Centrality Measures, Joseph Ajayi

College of Graduate Studies: Theses & Dissertations

Accurate prediction of flight delays remains a formidable challenge within the aviation industry, owing to its inherent complexity and the interconnectivity of its operations. Traditional flight prediction methods frequently utilize meteorological conditions—such as temperature, humidity, and dew point—alongside flight-specific data like departure and arrival times. However, these predictors often fall short of capturing the nuanced dynamics that lead to delays. This thesis introduces network centrality measures as novel predictors for enhancing the binary classification of flight arrival delays. Furthermore, it emphasizes the application of tree-based ensemble models, which are recognized for their superior ability to model complex relationships compared to …

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Hybridization And Duplex Stability Of Peptide Nucleic Acid Containing An Azobenzene Switch, Carmen J. Velasquez Jan 2024

Hybridization And Duplex Stability Of Peptide Nucleic Acid Containing An Azobenzene Switch, Carmen J. Velasquez

College of Graduate Studies: Theses & Dissertations

Light-driven molecular switches that can be turned on and off on demand have found many biological applications. For DNA, RNA, and synthetic derivatives, the switch can be used to interfere with a hybridization event with a complementary strand. To explore this potential, we have synthesized three light-sensitive PNA which have an azobenzene group (PNA-5azo5 and PNA-4azo4), and two azobenzene groups (PNA-2azo5azo2) as part of the PNA backbone. UV experiments were used to verify the conversion to the cis-isomer from the initial trans state for all of the single-stranded Azo-PNA ( PNA-5azo5, PNA-4azo4, and PNA-2azo5azo2) by irradiating at 365 nm …

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Scattering Of Electromagnetic Radiation By Bianisotropic Spheres, Maxwell A. Wallace Jan 2024

Scattering Of Electromagnetic Radiation By Bianisotropic Spheres, Maxwell A. Wallace

College of Graduate Studies: Theses & Dissertations

Modern developments in materials science have led to the increased demand for the ability to control electromagnetic radiation at scales smaller than ever. One of the most important areas of research for controlling the manipulation of electromagnetic radiation, has been the studying of novel optical metamaterials, including the most general and complex form, bianisotropic metamaterials (BAMs). With modern developments in nano- engineering, paired with the advancement of more robust theoretical studies of BAMs, the demand for more novel BAM technologies has increased. With the advent of research of unbounded BAM media, as well as the recent extensions of Mie theory …

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Railroad Condition Monitoring Using Distributed Acoustic Sensing And Deep Learning Techniques, Md Arifur Rahman Jan 2024

Railroad Condition Monitoring Using Distributed Acoustic Sensing And Deep Learning Techniques, Md Arifur Rahman

College of Graduate Studies: Theses & Dissertations

Proper condition monitoring has been a major issue among railroad administrations since it might cause catastrophic dilemmas that lead to fatalities or damage to the infrastructure. Although various aspects of train safety have been conducted by scholars, in-motion monitoring detection of defect occurrence, cause, and severity is still a big concern. Hence extensive studies are still required to enhance the accuracy of inspection methods for railroad condition monitoring (CM). Distributed acoustic sensing (DAS) has been recognized as a promising method because of its sensing capabilities over long distances and for massive structures. As DAS produces large datasets, algorithms for precise …

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Accessing And Assessing Components Of Elementary And Middle School Students’ Mathematical Disposition Through Metaphors, Emily Deal, Edward Mooney, Amanda Cullen, Neet Priya Bajwa, Allison M. Kroesch, Julien Corven, Beth Macdonald Jan 2024

Accessing And Assessing Components Of Elementary And Middle School Students’ Mathematical Disposition Through Metaphors, Emily Deal, Edward Mooney, Amanda Cullen, Neet Priya Bajwa, Allison M. Kroesch, Julien Corven, Beth Macdonald

Faculty Publications – Mathematics

This study examined student-generated metaphors comparing food to math as a means of accessing and assessing components of prekindergarten through Grade 8 students’ (N = 306) mathematical disposition. Previous research provided insight into predominantly affective components of older students’ mathematical disposition (i.e. Grade 4 through college). However, we extend these findings to include nonaffective components and younger students. Our study highlights the value in conceptualizing mathematical disposition as the sum of three mental functions, namely cognitive (e.g., mental processes such as reasoning), affective (e.g., attitudes, feelings, beliefs about mathematics or oneself as a learner), and conative (e.g., effort, grit, …

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A Comparison Of Adenosine Triphosphate With Other Metrics Of Microbial Biomass In A Gradient From The North Atlantic To The Chesapeake Bay, Alexander B. Bochdansky, Amber A. Beecher, Joshua R. Calderon, Alison N. Stouffer, Nyjaee N. Washington Jan 2024

A Comparison Of Adenosine Triphosphate With Other Metrics Of Microbial Biomass In A Gradient From The North Atlantic To The Chesapeake Bay, Alexander B. Bochdansky, Amber A. Beecher, Joshua R. Calderon, Alison N. Stouffer, Nyjaee N. Washington

OES Faculty Publications

A new, simplified protocol for determining particulate adenosine triphosphate (ATP) levels allows for the assessment of microbial biomass distribution in aquatic systems at a high temporal and spatial resolution. A comparison of ATP data with related variables, such as particulate carbon, nitrogen, chlorophyll, and turbidity in pelagic samples, yielded significant and strong correlations in a gradient from the tributaries of the Chesapeake Bay (sigma-t = 8) to the open North Atlantic (sigma-t = 29). Correlations varied between ATP and biomass depending on the microscopic method employed. Despite the much greater effort involved, biomass determined by microscopy correlated poorly with other …

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Nitrogen Fixation At The Mid-Atlantic Bight Shelfbreak And Transport Of Newly Fixed Nitrogen To The Slope Sea, C. R. Selden, M. R. Mulholland, K. E. Crider, S. Clayton, A. Macías-Tapia, P. Bernhardt, D. J. Mcgillicuddy Jr., W. G. Zhang, P. D. Chappell Jan 2024

Nitrogen Fixation At The Mid-Atlantic Bight Shelfbreak And Transport Of Newly Fixed Nitrogen To The Slope Sea, C. R. Selden, M. R. Mulholland, K. E. Crider, S. Clayton, A. Macías-Tapia, P. Bernhardt, D. J. Mcgillicuddy Jr., W. G. Zhang, P. D. Chappell

OES Faculty Publications

Continental shelves contribute a large fraction of the ocean's new nitrogen (N) via N2 fixation; yet, we know little about how physical processes at the ocean's margins shape diazotroph biogeography and activity. Here, we test the hypothesis that frontal mixing favors N2 fixation at the Mid-Atlantic Bight shelfbreak. Using the 15N2 bubble release method, we measured N2 fixation rates on repeat cross-frontal transects in July 2019. N2 fixation rates in shelf waters (median = 5.42 nmol N L−1 d−1) were higher than offshore (2.48 nmol N L−1 d−1) …

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Characterization Of Nasa Cold Atom Laboratory Potentials Using Variational Techniques, Samuel O. Oni Jan 2024

Characterization Of Nasa Cold Atom Laboratory Potentials Using Variational Techniques, Samuel O. Oni

College of Graduate Studies: Theses & Dissertations

In a recent atom-interferometry (AI) experiment, conducted aboard the NASA Cold Atom Laboratory (CAL) deployed to the International Space Station (ISS), a Bose-Einstein condensate (BEC) was formed too near to the atom chip wall for the AI experiment to be carried out. To fix this the experimentalists tuned the CAL external magnetic field and atom-chip currents so as to move the BEC away from the atom-chip wall. They then planned to turn the trap off and allow it to expand in place (since there is no gravity on the ISS) in preparation for the AI experiment. Unfortunately, when the trap …

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The Distribution Of The Significance Level, Paul O. Monnu Jan 2024

The Distribution Of The Significance Level, Paul O. Monnu

College of Graduate Studies: Theses & Dissertations

Reporting the p-value is customary when conducting a test of hypothesis or significance. The likelihood of getting a fictitious second sample and presuming the null hypothesis is correct is the p-value. The significance level is a statistic that interests us to investigate. Being a statistic, it has a distribution. For the F-test in a one-way ANOVA and the t-tests for population means, we define the significance level, its observed value, and the observed significance level. It is possible to derive the significance level distribution. The t-test and the F-test are not without controversy. Specifically, we demonstrate that as sample size …

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Assessing Performance Optimization Strategies In Cloud-Native Environments Through Containerization And Orchestration Analysis, Daniel E. Ukene Jan 2024

Assessing Performance Optimization Strategies In Cloud-Native Environments Through Containerization And Orchestration Analysis, Daniel E. Ukene

College of Graduate Studies: Theses & Dissertations

This thesis comprises three distinct, yet interconnected studies addressing critical aspects of web infrastructure management. We begin by studying containerization via Docker and its impact on web server performance, focusing on Apache and Nginx hosted on virtualized environments. Through meticulous load testing and analysis, we provide insights into the comparative performance of these servers, adding users of this technology know which webservers to leverage when hosting their webservice along alongside the infrastructure to host it on. Next, we expand our focus to examine the performance of caching systems, namely Redis and Memcached, across traditional VMs and Docker containers. By comparing …

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Simulation Of Wave Propagation In Granular Particles Using A Discrete Element Model, Syed Tahmid Hussan Jan 2024

Simulation Of Wave Propagation In Granular Particles Using A Discrete Element Model, Syed Tahmid Hussan

College of Graduate Studies: Theses & Dissertations

The understanding of Bender Element mechanism and utilization of Particle Flow Code (PFC) to simulate the seismic wave behavior is important to test the dynamic behavior of soil particles. Both discrete and finite element methods can be used to simulate wave behavior. However, Discrete Element Method (DEM) is mostly suitable, as the micro scaled soil particle cannot be fully considered as continuous specimen like a piece of rod or aluminum. Recently DEM has been widely used to study mechanical properties of soils at particle level considering the particles as balls. This study represents a comparative analysis of Voigt and Best …

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Concentration Effects Of Ytterbium(Iii) Ions On The Physical, Structural, Thermal, And Optical Properties Of Barium Phosphate Glasses, Richard Amesimenu Jan 2024

Concentration Effects Of Ytterbium(Iii) Ions On The Physical, Structural, Thermal, And Optical Properties Of Barium Phosphate Glasses, Richard Amesimenu

College of Graduate Studies: Theses & Dissertations

Ytterbium(III)-doped glasses are widely known for their application in near-infrared (NIR) lasers and nowadays attract attention for solar spectral conversion in photovoltaic cells. In this study, the effects of ytterbium(III) concentration on the physical, structural, optical, and thermal characteristics of Yb-doped phosphate glasses were investigated. The glasses were synthesized using the melt-quenching technique with nominal compositions of 50P2O5:(50 – xBaO):xYb2O3 (x = 0, 0.5, 1.0, 2.0, 3.0 and 4 mol%). The properties were then examined by density and related parameters, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform-infrared …

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Antibiotic Resistance In A Coastal River In Mississippi, Usa – Potential Drivers, Shuo Shen, Wei Wu, Eric A. Saillant, Darrell Jay Grimes Jan 2024

Antibiotic Resistance In A Coastal River In Mississippi, Usa – Potential Drivers, Shuo Shen, Wei Wu, Eric A. Saillant, Darrell Jay Grimes

Gulf and Caribbean Research

Wastewater treatment plants (WWTPs) are major sources of antibiotic resistant bacteria (ARB) and antibiotic resistance genes (ARGs) in water bodies. Most studies on the impact of WWTPs on antibiotic resistance have focused on freshwater systems, with little information on coastal and estuarine waters with variable salinity. This study monitored seasonal levels of ARGs at the effluent and downstream of the Pascagoula— Moss Point WWTP in the lower Pascagoula River, a coastal river in southeastern Mississippi, USA. Surface water samples were collected seasonally at upstream, outflow, and 3 downstream sites from February to November 2016. Bacterial resistance to sulfamethazine, tetracycline, and …

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Assessing Tax Revenue Implications Of Environmental Policy: A Case Study Of China’S Channel City Policy, Yongwen Yang, Juhee Lee Jan 2024

Assessing Tax Revenue Implications Of Environmental Policy: A Case Study Of China’S Channel City Policy, Yongwen Yang, Juhee Lee

School of Earth, Environmental, & Marine Sciences Faculty Publications

Recent studies suggest that while environmental policies yield positive environmental effects, they also incur costs for various entities. However, there is a gap in research regarding these policies’ financial impact from the government's perspective. To investigate the extent to which government tax revenue is affected by environmental policies, we employ the Difference-inDifferences (DID) method to estimate the impact of a regional air pollution control policy in China known as the Channel City Policy on the tax revenue of city governments. Our findings indicate that the Channel City Policy (CCP) enhances air quality by reducing PM2.5, SO2, and NOx concentrations by …

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Exploring International Educators' Learning About Local And Global Social Justice In A Virtual Community Of Practice, Bima Sapkota, Xuwei Luo, Muna Sapkota, Murat Akarsu, Emmanuel Deogratias, Daphne Fauber, Rose Mbewe, Fidelis Mumba, Ram Krishna Panthi, Jill Newton Jan 2024

Exploring International Educators' Learning About Local And Global Social Justice In A Virtual Community Of Practice, Bima Sapkota, Xuwei Luo, Muna Sapkota, Murat Akarsu, Emmanuel Deogratias, Daphne Fauber, Rose Mbewe, Fidelis Mumba, Ram Krishna Panthi, Jill Newton

School of Mathematical & Statistical Sciences Faculty Publications

In this chapter, the authors report themes that emerged when a cross-cultural team of researchers involved in a virtual international community of practice (Global Social Justice in Education-GSJE) investigated reflections on activities focused on social justice in local and global contexts. The findings suggested that the activities elicited GSJE community members' understandings of the complexities of social justice associated with naming practices, privilege, and the arts within their own and across contexts. The authors discuss implications of the activities to advance diverse educators' understanding of social justice in global and local contexts. They also unpack the opportunities and challenges that …

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Stereocontrolled Synthesis Of Lactam-Fused Tetrahydropyrans As Potential Antidiabetic Agents, Ifeyinwa Stella Anosike Jan 2024

Stereocontrolled Synthesis Of Lactam-Fused Tetrahydropyrans As Potential Antidiabetic Agents, Ifeyinwa Stella Anosike

All Master's Theses

Functionalized tetrahydropyrans are structural motifs in diverse natural products, including polyether antibiotics, marine toxins, pheromones, and pharmaceuticals. They are frequently used as versatile building blocks for accessing stereochemically sophisticated biologically active compounds. Specifically, functionalized bicyclic tetrahydropyrans bearing contiguous stereocenters have garnered interest in the synthesis and medicinal chemistry communities. Thus far, some synthetic methods have been developed for their construction and functionalization. These methods include Prins' cyclization reactions, intramolecular oxa-Michael reactions, hetero-Diels-Alder cyclization, ring-closing metathesis, radical cyclization, and halocycloetherification. However, these methods have some drawbacks such as the need for expensive reagents and catalysts, substrate limitations, and environmentally unfriendly conditions. …

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Gnss Radio Propagation Through Trapped Atmospheric Lee Waves In The San Bernardino Valley, Ca, Logan Grey Jan 2024

Gnss Radio Propagation Through Trapped Atmospheric Lee Waves In The San Bernardino Valley, Ca, Logan Grey

All Master's Theses

Atmospheric lee waves, also known as mountain waves, are a type of gravity wave that form as air that is forced over a mountain creates turbulence downstream. Trapped, or stationary, lee waves located directly over a Global Navigation Satellite System (GNSS) receiver on Earth’s surface appear to lead to anomalies in the receiver’s position estimate, usually skewed toward the neighboring mountain range. The exact mechanism by which trapped lee waves might cause these anomalies is not known, and so my research aims to understand this. GNSS station P612 located in the lee of the San Bernardino Mountains in southern California …

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Contrasting Nitrogen Dynamics Across The Mid-Atlantic Bight Shelfbreak Front: Insights From Nitrate Dual Isotopes And Nitrifier Gene Abundance, Yifan Zhu, Margaret R. Mulholland, Corday R. Selden, Dennis J. Mcgillicuddy Jr., Josie Mottram, P. Dreux Chappell, Weifang Gordon Zhang, Julie Granger, Katherine E. Crider, Meredith G. Meyer, Peter W. Bernhardt, Hilde Oliver, Sophie Clayton Jan 2024

Contrasting Nitrogen Dynamics Across The Mid-Atlantic Bight Shelfbreak Front: Insights From Nitrate Dual Isotopes And Nitrifier Gene Abundance, Yifan Zhu, Margaret R. Mulholland, Corday R. Selden, Dennis J. Mcgillicuddy Jr., Josie Mottram, P. Dreux Chappell, Weifang Gordon Zhang, Julie Granger, Katherine E. Crider, Meredith G. Meyer, Peter W. Bernhardt, Hilde Oliver, Sophie Clayton

OES Faculty Publications

Observations and model studies suggest that front dynamics can enhance phytoplankton productivity. This study tested whether frontal systems also increase the abundance of nitrifying microbes and nitrogen recycling during repeat sampling transects across the Mid‐Atlantic Bight shelfbreak in July 2019. We measured ammonium concentrations, nitrate dual isotopes (δ15N, δ18O), and ammonia monooxygenase subunit A (amoA) genes of ammonia‐oxidizing archaea (AOA) and bacteria (AOB). In subsurface shelf waters, ammonium concentrations exceeded 2 μmol L−1, due to a temporary imbalance in regeneration from sinking particles and subsequent nitrification. The inverse correlation between nitrate δ15 …

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A Scoping Review On Mobile Health Technology For Assessment And Intervention Of Upper Limb Motor Function In Children With Motor Impairments, Md Raihan Mia, Sheikh Iqbal Ahamed, Alissa V. Fial, Samuel Nemanich Jan 2024

A Scoping Review On Mobile Health Technology For Assessment And Intervention Of Upper Limb Motor Function In Children With Motor Impairments, Md Raihan Mia, Sheikh Iqbal Ahamed, Alissa V. Fial, Samuel Nemanich

Computer Science Faculty Research and Publications

Upper limb (UL) motor dysfunctions impact residual movement in hands/shoulders and limit participation in play, sports, and leisure activities. Clinical and laboratory assessments of UL movement can be time-intensive, subjective, and/or require specialized equipment and may not optimally capture a child's motor abilities. The restrictions to in-person research experienced during the COVID-19 pandemic have inspired investigators to design inclusive at-home studies with child participants and their families. Relying on the ubiquity of mobile devices, mobile health (mHealth) applications offer solutions for various clinical and research problems. This scoping review article aimed to aggregate and synthesize existing research that used health …

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Contribution Of High Turbidity To Tidal Dynamics In A Curved Channel In Zhoushan Islands, China, Li Li, Fangzhou Shen, Zhiguo He, Gangfeng Ma, Jiachen Wang, Kailong Huangfu Jan 2024

Contribution Of High Turbidity To Tidal Dynamics In A Curved Channel In Zhoushan Islands, China, Li Li, Fangzhou Shen, Zhiguo He, Gangfeng Ma, Jiachen Wang, Kailong Huangfu

Civil & Environmental Engineering Faculty Publications

The curved tidal channel, Luotou Deep-water Navigational Channel, is the main channel of the Ningbo Zhoushan Port, which is ranked first in the world. Tidal dynamics in the channel are spatially and temporally asymmetric. In this study, the three-dimensional tidal dynamics in the channel were analyzed using field data and simulated using FVCOM. The results show that the tides in the channel flood/ebb along the northern/southern bank near the bottom/surface layer and these asymmetries are due to the imbalanced Coriolis force, centrifugal force, sea-level gradient, and density gradient. Residual current velocity peaks (0.7 m/s) in the middle of the channel …

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Investigating The Viability Of Low Frequency Mhvsr Estimates Using Deep Shear Wave Velocity Profile, T. Mai, C. C. Nweke, P. Wang, F. J. Ornelas Jan 2024

Investigating The Viability Of Low Frequency Mhvsr Estimates Using Deep Shear Wave Velocity Profile, T. Mai, C. C. Nweke, P. Wang, F. J. Ornelas

Civil & Environmental Engineering Faculty Publications

Site response describes the alterations of seismic energy due to its interaction with subsurface geological interfaces and structures, which is usually estimated by one dimensional (1D) ground response analysis (GRA). However, 1D GRA requires subsurface information (e.g., shear wave velocity profile), which makes it not widely applicable, particularly for the sites where subsurface information is unavailable. Alternatively, the microtremor horizontal-to-vertical spectral ratio (mHVSR) from three-component recordings of ambient noise on the ground surface is easily measured and is believed to have the potential for site response prediction (the peaks in mHVSR are strongly associated with the site resonant frequencies). However,the …

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Accelerating Cavity Fault Prediction Using Deep Learning At Jefferson Laboratory, Md M. Rahman, A. Carpenter, K. Iftekharuddin, C. Tennant Jan 2024

Accelerating Cavity Fault Prediction Using Deep Learning At Jefferson Laboratory, Md M. Rahman, A. Carpenter, K. Iftekharuddin, C. Tennant

Electrical & Computer Engineering Faculty Publications

Accelerating cavities are an integral part of the continuous electron beam accelerator facility (CEBAF) at Jefferson Laboratory. When any of the over 400 cavities in CEBAF experiences a fault, it disrupts beam delivery to experimental user halls. In this study, we propose the use of a deep learning model to predict slowly developing cavity faults. By utilizing pre-fault signals, we train a long short-term memory-convolutional neural network binary classifier to distinguish between radio-frequency (RF) signals during normal operation and RF signals indicative of impending faults. We optimize the model by adjusting the fault confidence threshold and implementing a multiple consecutive …

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Improving The Robustness Of Neural Networks To Adversarial Patch Attacks Using Masking And Attribution Analysis, Atandra Mahalder Jan 2024

Improving The Robustness Of Neural Networks To Adversarial Patch Attacks Using Masking And Attribution Analysis, Atandra Mahalder

Honors Undergraduate Theses

Computer vision algorithms, including image classifiers and object detectors, play a pivotal role in various cyber-physical systems, spanning from facial recognition to self-driving vehicles and security surveillance. However, the emergence of real-world adversarial patches, which can be as simple as stickers, poses a significant threat to the reliability of AI models utilized within these systems. To address this challenge, several defense mechanisms such as PatchGuard, Minority Report, and (De)Randomized Smoothing have been proposed to enhance the resilience of AI models against such attacks. In this thesis, we introduce a novel framework that integrates masking with attribution analysis to robustify AI …

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Tracking The Reaction Networks Of Criegee Intermediates Formed In The Ozone-Assisted Oxidation Reactions Of C5 Acyclic And Endocyclic Alkenes, Arden M. Floyd Jan 2024

Tracking The Reaction Networks Of Criegee Intermediates Formed In The Ozone-Assisted Oxidation Reactions Of C5 Acyclic And Endocyclic Alkenes, Arden M. Floyd

Honors Undergraduate Theses

Uni- and bi-molecular reactions involving Criegee intermediates (CIs), characteristic to alkene-ozone reactions, play an important role in synthetic organic, atmospheric, and combustion chemistry. However, difficulty in detecting key intermediates has prevented a thorough understanding of the details of the ozonolysis mechanism. To gain new insights into how alkene structure affects the CI network, the ozone assisted oxidation reactions of trans-2-pentene and cyclopentene are investigated between 320 K and 760 K in an atmospheric pressure jet stirred reactor (JSR). Molecular-beam mass spectrometry in conjunction with single photon tunable synchrotron VUV radiation is used to identify elusive intermediates by means of …

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An Investigation Of Students' Modes Of Thinking Concerning Linearity In Linear Algebra, Noa Levy Jan 2024

An Investigation Of Students' Modes Of Thinking Concerning Linearity In Linear Algebra, Noa Levy

Honors Undergraduate Theses

The intent of this thesis is to investigate student approaches to linearity within a linear algebra context, focusing on definitional, computational, and theoretical skills. Linear algebra’s abstract nature constitutes a major challenge for a significant sector of STEM students, with the course often serving as undergraduates’ first encounter with mathematical proofs and extrapolations. The current student struggle is reflected through the prominent gap in knowledge derived from a lack of a concrete understanding of rudimentary concepts (like linearity), pivotal to student success. As such, this investigation aimed to bridge this gap by considering students’ modes of thinking regarding the elementary …

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Searching For Black Holes In The Galactic Center, Caden Zaccardi Jan 2024

Searching For Black Holes In The Galactic Center, Caden Zaccardi

Honors Undergraduate Theses

Due to the high extinction along the plane of the Milky Way towards the Galactic Center (GC), it is useful to look at objects that are bright in the near-infrared (near-IR) to obtain data with Earth-based instruments. To identify X-ray Binary (XRB) counterparts towards the GC, we used near-IR spectra from the Large Binocular Telescope (LBT). After reducing the LUCI/LBT spectra with the superFATBOY (sFB) pipeline, we compared our near-IR spectra to previously matched IR and X-ray sources in the GC (DeWitt, 2011). Particularly, we looked for H and He emission lines, which indicate signs of a hard radiation field …

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A Signal Injection Attack Against Zero Involvement Pairing And Authentication For The Internet Of Things, Isaac Ahlgren, Jack West, Kyuin Lee, George K. Thiruvathukal, Neil Klingensmith Jan 2024

A Signal Injection Attack Against Zero Involvement Pairing And Authentication For The Internet Of Things, Isaac Ahlgren, Jack West, Kyuin Lee, George K. Thiruvathukal, Neil Klingensmith

Computer Science: Faculty Publications and Other Works

Zero Involvement Pairing and Authentication (ZIPA) is a promising technique for auto-provisioning large networks of Internet-of-Things (IoT) devices. In this work, we present the first successful signal injection attack on a ZIPA system. Most existing ZIPA systems assume there is a negligible amount of influence from the unsecured outside space on the secured inside space. In reality, environmental signals do leak from adjacent unsecured spaces and influence the environment of the secured space. Our attack takes advantage of this fact to perform a signal injection attack on the popular Schurmann & Sigg algorithm. The keys generated by the adversary with …

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Actionpoint: An App To Combat Cyberbullying By Strengthening Parent-Teen Relationships, Maddie Juarez, Natali Barragan, Deborah Hall, George K. Thiruvathukal, Yasin Silva Jan 2024

Actionpoint: An App To Combat Cyberbullying By Strengthening Parent-Teen Relationships, Maddie Juarez, Natali Barragan, Deborah Hall, George K. Thiruvathukal, Yasin Silva

Computer Science: Faculty Publications and Other Works

Overview: Urgent need for intervention tools to mitigate increase in cyberbullying • ActionPoint is based on parent-teen relationship research • App includes interactive modules to improve family communication and online behavior to combat cyberbullying effects • To be presented in the IEEE World Forum on Public Safety Technology 2024.

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