Physical Sciences and Mathematics Commons^™

Bookworm: A Home Library Aid, Johnny Quach

Student Academic Conference

This project involved the design and development of a website intended to allow users to create a personal inventory of their purchased media with a primary focus on books. The goal of the project was to create a website that is both user-friendly, convenient, and both personally and professionally useful. The project began with an analysis of existing personal inventory websites and apps which identified many different aspects that are included in the finished website, as well as aspects that fell short. Utilizing Python and Flask, the design includes a number of easy-to-use features, such as the ability to create …

Reduction Of E-Waste With Multi Generational Clustering Of Obsolete Computers, Tyler Sather, Judah Nava

Student Academic Conference

The rise of E-waste is a growing concern as there are many toxic materials or toxic chemicals created with mishandling of the waste. Even in the school system we see obsolete computers systems laying around in closets collecting dust ready to be sent to the landfill. Our aim is to see if by clustering these old systems together we can give them new life thus reducing the need to add them to the worlds e-waste problem. Often these obsolete systems have lower powered CPUs which makes them less desirable for computing, if we cluster these systems together we can potentially …

Traversing Through A Graph, Andrew Selvig

Student Academic Conference

Software such as Google Maps or flight path routes utilize algorithms which find the most optimal path between two points or locations. These optimal routes are based on existing paths between nodes (locations). These kinds of software have made our lives much more convenient when we want to go somewhere. However, there are situations in which nodes and their paths have not been established. Nonetheless, there are two points that need to be connected with barriers in between. ;The purpose of this project is to tap into a way to create and traverse nodes between two points while refusing to …

Creating With Generative Ai, Gudrun Hall, Zeitun Abdinoor

Student Academic Conference

CustomGPT is a framework that utilizes advanced natural language processing techniques to generate customized versions of ChatGPT, adapting conversational agents to various contexts, domains, or individual preferences. This project demonstrates how ChatGPT serves as a powerful tool for creating chatbots with actionable features and dynamic mobile games. By showcasing its versatility in empowering users to innovate and drive creative content generation, we highlight ChatGPT's potential to shape the future of interactive mobile experiences.

Assigning A Dynamic Personality To Ai, Austin Jeral

Student Academic Conference

In today's world where artificial intelligence capabilities are advancing the potential for custom, and tailor made chatbots are similarly advancing. Such artificial intelligence chatbots could be particularly useful in many fields from the entertainment industry in the form of video game characters with dynamic dialog that stay true to their characters, to the world of psychology where such chatbots may be useful in helping budding psychologists train and be exposed to a vast array of different personalities that they may not be exposed to. Such artificial intelligence chatbots require however to have a believable and dynamic personality. Personality is a …

Effects Of Sensory Processing Impairments On Social Language Skills In Children With Autism Spectrum Disorder, Sara Stier

Student Academic Conference

Autism Spectrum Disorder (ASD) is a neurodevelopmental disorder that is commonly characterized by impairments in social communication, language, and other cognitive skills, behavior and emotional challenges, sensory processing issues, and feeding challenges (ASHA, n.d.). Sensory processing refers to the process of the central nervous system receiving input from the senses and integrating this information to generate an appropriate behavioral response (Kojovic et al., 2019). A highly regulated sensory system is a vital piece that is needed in order to be able to communicate wants, needs, and ideas effectively and appropriately (Sensory Issues, n.d.). The main sensory systems that individuals with …

Water Quality Analysis Of Red River Valley's Municipal And Rural Water Supply: A Collaboration Between Local High School Science Classes And Geosciences At Msum, Abigail Von Bank, Reed Wilke, Ally Peters

Student Academic Conference

Declining water quality is an environmental issue that has been around for decades now. As pipes decay and waterways become more polluted, these pollutants are becoming more present in water. This region, unlike other places, does not have a problem with water scarcity, but water quality is increasingly problematic. We are focusing on the study, collection, and analysis of Fargo, Moorhead, and the Red River Valley's water quality throughout the community. This project is a collaboration with local high school students by engaging in modern environmental dilemmas all while creating an in-depth analysis of the water samples taken to see …

Mathematical Modeling For Dental Decay Prevention In Children And Adolescents, Mahdiyeh Soltaninejad

Dissertations

The high prevalence of dental caries among children and adolescents, especially those from lower socio-economic backgrounds, is a significant nationwide health concern. Early prevention, such as dental sealants and fluoride varnish (FV), is essential, but access to this care remains limited and disparate. In this research, a national dataset is utilized to assess sealants' reach and effectiveness in preventing tooth decay, particularly focusing on 2nd molars that emerge during early adolescence, a current gap in the knowledge base. FV is recommended to be delivered during medical well-child visits to children who are not seeing a dentist. Challenges and facilitators in …

Assessing Social Vulnerabilities Of Salivary Gland Cancer Care, Prognosis, And Treatment In The United States, Govind S. Bindra, David J. Fei-Zhang, Atharva Desai, John Maddalozzo, Stephanie S. Smith, Urjeet A. Patel, Daniel C. Chelius, Jill N. D'Souza, Jeffrey C. Rastatter, M. Boyd Gillespie, Anthony M. Sheyn

School of Medicine Faculty Publications

Background: Salivary gland cancers (SGC)-social determinants of health (SDoH) investigations are limited by narrow scopes of SGC-types and SDoH. This Social Vulnerability Index (SVI)-study hypothesized that socioeconomic status (SES) most contributed to SDoH-associated SGC-disparities. Methods: Retrospective cohort of 24 775 SGCs assessed SES, minority-language status (ML), household composition (HH), housing-transportation (HT), and composite-SDoH measured by the SVI via regressions with surveillance and survival length, late-staging presentation, and treatment (surgery, radio-, chemotherapy) receipt. Results: Increasing social vulnerability showed decreases in surveillance/survival; increased odds of advanced-presenting-stage (OR: 1.12, 95% CI: 1.07, 1.17), chemotherapy receipt (OR: 1.13, 95% CI: 1.03, 1.23); decreased odds …

Head Tail Open: Open Tailed Classification Of Imbalanced Document Data, Chetan Joshi

Theses and Dissertations

Deep learning models for scanned document image classification and form understand- ing have made significant progress in the last few years. High accuracy can be achieved by a model with the help of copious amounts of labelled training data for closed-world classification. However, very little work has been done in the domain of fine-grained and head-tailed(class imbalance with some classes having high numbers of data points and some having a low number of data points) open-world classification for documents. Our proposed method achieves a better classification results than the baseline of the head-tail-novel/open dataset. Our techniques include separating the head-tail …

Drone-Based Bug Detection In Orchards With Nets: A Novel Orienteering Approach, Francesco Betti Sorbelli, Federico Coró, Sajal K. Das, Lorenzo Palazzetti, Cristina M. Pinotti

Computer Science Faculty Research & Creative Works

The Use of Drones for Collecting Information and Detecting Bugs in Orchards Covered by Nets is a Challenging Problem. the Nets Help in Reducing Pest Damage, But They Also Constrain the Drone's Flight Path, Making It Longer and More Complex. to Address This Issue, We Model the Orchard as an Aisle-Graph, a Regular Data Structure that Represents Consecutive Aisles Where Trees Are Arranged in Straight Lines. the Drone Flies Close to the Trees and Takes Pictures at Specific Positions for Monitoring the Presence of Bugs, But its Energy is Limited, So It Can Only Visit a Subset of Positions. to …

Li2mp2s6: Building-Block Approach To A Family Of 2d Non-Van Der Waals-Layered Materials And Their Water, Ammonia, And Ion Intercalation Properties, Santhoshkumar Sundaramoorthy, Nikolay Gerasimchuk, Kartik Ghosh, Steven P. Kelley, Amitava Choudhury

Chemistry Faculty Research & Creative Works

A Series of Non-Van Der Waals 2D Quaternary Thiophosphates with Nominal Composition, Li2MP2S6 (M = V, Mn, Fe, Co, Ni, and Zn), Has Been Successfully Synthesized through Solid-State Metathesis Reactions by a Building Block Approach as Well as Starting with a Stoichiometric Combination of Elements. Li4-NxMxn+P2S6 (M = V, Fe, Ni, Co, and Zn; X = 0.5-1, N = 2 or 3) Crystallize in the P3̅1m Space Group, While Li2MnP2S6 Crystallizes in R3̅. All the Compounds Form a 2D Layered Structure through Edge Sharing MS6 Octahedra and P2S6 Units with Li Atoms Occupying the Interlayer Spaces. X-Ray Diffraction and Thermogravimetric …

Li2mp2s6: Building-Block Approach To A Family Of 2d Non-Van Der Waals-Layered Materials And Their Water, Ammonia, And Ion Intercalation Properties, Santhoshkumar Sundaramoorthy, Nikolay Gerasimchuk, Kartik Ghosh, Steven P. Kelley, Amitava Choudhury

Chemistry Faculty Research & Creative Works

A series of non-van der Waals 2D quaternary thiophosphates with nominal composition, Li₂MP₂S₆ (M = V, Mn, Fe, Co, Ni, and Zn), has been successfully synthesized through solid-state metathesis reactions by a building block approach as well as starting with a stoichiometric combination of elements. Li4-nxMxn+P2S6 (M = V, Fe, Ni, Co, and Zn; x = 0.5-1, n = 2 or 3) crystallize in the P3̅1m space group, while Li₂MnP₂S₆ crystallizes in R3̅. All the compounds form a 2D layered structure through edge sharing MS6 octahedra and P₂S …

Maximizing Data Optimization: Analysis, Retention, And Website Accessibility, Selena Cade

Masters Projects

As a graduate assistant at Grand Valley, there is significant involvement with a program that assists middle and high school students with learning about college. As a preface, the information presented in this document will remain anonymous and confidential for the program's benefit.

Students receive a campus tour, eat at the dining halls, and obtain information about college. Before students arrive, a pre-visit survey is sent to gauge their college knowledge. After the visit, a post-visit survey with the same questions is sent out to determine if they gained more knowledge. This data has rarely been viewed in the past …

Molybdenum Alkylidyne Complexes With Phenoxide Ligands For Alkyne Metathesis, Marvin L. Stewart Jr

LSU Doctoral Dissertations

Abstract

Alkyne metathesis is a powerful synthetic tool, which provides easy access to complex organic molecules in a single-step. It is a dynamic covalent reaction that scrambles alkynes, carbon-carbon triple bonds (C≡C). Molybdenum- or tungsten-alkylidyne (Mo≡C, W≡C) complexes are typically used as catalyst to cleave and reform alkyne bonds. Our goal has been to gain a deeper understanding of the intrinsic differences between functional ligands by the development of novel phenoxide ligands.

In chapter 2 we explore the detailed synthesis of novel phenoxide podand ligands in an effort to identify their mo-alkylidyne complexes. We were able to synthesize a variety …

Cash For Conservation: Payments For Ecosystem Service Programs And Forest Loss, John Shandra

Sustainability Seminar Series

According to the World Bank, 1.1 million square miles of tree cover were cleared from 2001 to 2020. Approximately 90% of forests were cleared in low- and middle-income nations. This loss is equivalent to a 7% reduction in tree cover and corresponds with 107 trillion metric tons of carbon dioxide emissions being released into the atmosphere. To limit forest loss, low and middle-income nations often implement payment for ecosystem service programs. By 2020, over 550 programs were active globally, accounting for an estimated $36–42 billion in annual transactions between users and providers. However, we not aware of any cross-national research …

Predictors Of Student Success In College-Level General Chemistry, Elijah J. Engler, Clarice Ak Kelleher

Binghamton University Undergraduate Journal

Success in college-level general chemistry is important because it is a required course for many different STEM majors and student success in early STEM classes correlates with retention of students in STEM. Identifying factors associated with success and failure can give educators a better understanding of the warning signs to look out for in struggling students. This paper compares factors and behaviors with final grades in general chemistry courses at Binghamton University, including adjectives selected from a word bank (“valued,” “supported,” etc.), resources used, and opinion on group work as it relates to learning. Correlations were found between student adjective …

One-Pot Synthesis Green Zinc Oxide Nanoparticles Immobilized On Activated Carbon Derived From Pineapple Peel For Adsorption Of Pb(Ii), Vienna Saraswaty, Evyka Setya Aji, Ardi Ardiansyah, Ayu Hanifah, Nathania Puspitasari, Shella Permatasari Santoso, Sandy Budi Hartono, Chandra Risdian, Elsy Rahimi Chaldun, Henry Setiyanto

Karbala International Journal of Modern Science

The current study introduces a one-pot technique for synthesizing an environmentally benign and cheap composite adsorbent, namely ZnO-PPAC, for the adsorption of Pb(II). The designated adsorbent was prepared by incorporating green synthesized zinc oxide (ZnO) nanoparticles on activated carbon-derived from pineapple peel. The prepared adsorbents were characterized using XRD, SEM, EDS, FTIR, and BET techniques. The XRD pattern verifies that the ZnO was successfully synthesized and immobilized onto the PPAC in a one pot synthesis system. The surface areas of ZnOPPAC and PPAC adsorbents were 13.62 m2/g and 961.96 m2/g, respectively. The FTIR evaluation of the ZnO-PPAC adsorbent revealed several …

Sgd-Od: Investigating The Potential Oxygen Demand Of Submarine Groundwater Discharge In Coastal Systems., Willard S Moore, Claudia Benitez-Nelson, Charles Schutte, Amy Moody, Alan Shiller, Ryan J Sibert, Samantha Joye

School of Earth & Environment Departmental Research

Submarine groundwater discharge (SGD) supplies nutrients, carbon, metals, and radionuclide tracers to estuarine and coastal waters. One aspect of SGD that is poorly recognized is its direct effect on dissolved oxygen (DO) demand in receiving waters, denoted here as SGD-OD. Sulfate-mediated oxidation of organic matter in salty coastal aquifers produces numerous reduced byproducts including sulfide, ammonia, dissolved organic carbon and nitrogen, methane, and reduced metals. When these byproducts are introduced to estuarine and coastal systems by SGD and are oxidized, they may substantially reduce the DO concentration in receiving waters and impact organisms living there. We consider six estuarine and …

Unique K3 Surfaces With Purely Non-Symplectic Automorphism: Insights From Weighted Projective Spaceunique K3 Surfaces With Purely Non-Symplectic Automorphism:\\Insights From Weighted Projective Space, Elizabeth Melville

Theses and Dissertations

K3 surfaces have garnered attention across various fields, from optics and dynamics to high energy physics, making them a subject of extensive study for many decades. Recent work by mathematicians, including Brandhorst [1], has focused on non-symplectic automorphisms, aiming to categorize K3 surfaces that admit such automorphisms. Brandhorst made a list of unique K3 surfaces with purely non-symplectic automorphisms and established specific criteria for a K3 surface to be isomorphic to one on his list. This thesis aims to provide an alternative representation of select K3 surfaces from Brandhorst's list. While Brandhorst predominantly characterizes these surfaces as elliptic K3 surfaces, …

Optimal Molecular Dynamics System Size For Increased Precision And Efficiency For Epoxy Materials, Khatereh Kashmari, Sagar Patil, Josh Kemppainen, Shankara Gowtham, Gregory Odegard

Michigan Tech Publications

Molecular dynamics (MD) simulation is an important tool for predicting thermo-mechanical properties of polymer resins at the nanometer length scale, which is particularly important for efficient computationally driven design of advanced composite materials and structures. Because of the statistical nature of modeling amorphous materials on the nanometer length scale, multiple MD models (replicates) are typically built and simulated for statistical sampling of predicted properties. Larger replicates generally provide higher precision in the predictions but result in higher simulation times. Unfortunately, there is insufficient information in the literature to establish guidelines between MD model size and the resulting precision in predicted …

Modern Approaches To Treating Hospital Acquired Infections: An Overview Of Current Treatments Using Antibiotics And New Therapies Centered Around Photo-Activated Porphyrins, Meghan Johns

Senior Honors Theses

Annually, hospital-acquired infections (HAIs) affect hundreds of thousands of people in the U.S. and impose a great economic burden. The current problem is further exacerbated due to the failure of traditional treatment strategies considering the rise in antimicrobial resistance rates. Besides the fact that antimicrobial resistances complicates clinical treatment strategies, patients are also more vulnerable to secondary infections and complications from prolonged antibiotic use. As a result, research investigating novel treatment strategies for bacterial infections has recently increased. A strategy using porphyrin-based compounds is showing promise. Porphyrins and their derivatives have exhibited bactericidal effects against Gram-positive bacteria by the destruction …

Methods For Computing Rovibrational Spectral Data With Applications To Inorganic Oxides And Hydrocarbons, Alexandria Watrous

Honors Theses

Computational chemistry focuses on finding solutions to the time-independent Schrödinger equation for systems of interest to study their molecular properties such as rovibrational spectral data. Any molecule containing more than one electron cannot be solved explicitly but coupled cluster theory offers one of the best approximations. One such application of this method is to molecules of astrochemical interest to support observation and experimental data. Chapters 2, 3, and 4 look at the performance of new couple cluster theory methods including composite and hybrid methods for ground and excited state rovibrational data. Chapters 5 - 9 use the previously mentioned methods …

The Effect Of Fixed Time Delays On The Synchronization Phase Transition, Shaizat Bakhytzhan

USF Tampa Graduate Theses and Dissertations

Nature is full of synchronization phenomena, which are essential to many scientific fields like biology, chemistry, physics, and neuroscience. The Kuramoto model is a well-known theoretical model that helps explain the fundamental ideas behind synchronization dynamics [6]. Nevertheless, in practical situations, systems frequently display intrinsic latency, which can greatly impact their behavior during synchronization. This insight inspired our work, which looks at the results of adding temporal delays to the Kuramoto model. In particular, we investigate how the system’s synchronization dynamics are affected by delays. We shed light on the mechanisms underpinning synchronization in the face of temporal delays and …

Gate-Controlled Supercurrent Effect In Dry-Etched Dayem Bridges Of Non-Centrosymmetric Niobium Rhenium, Jennifer Koch, Carla Cirillo, Sebastiano Battisti, Leon Ruf, Zahra Makhdoumi Kakhaki, Alessandro Paghi, Armen Gulian, Serafim Teknowijoyo, Giorgio De Simoni, Francesco Giazotto, Carmine Attanasio, Elke Scheer, Angelo Di Bernardo

Mathematics, Physics, and Computer Science Faculty Articles and Research

The application of a gate voltage to control the superconducting current flowing through a nanoscale superconducting constriction, named as gate-controlled supercurrent (GCS), has raised great interest for fundamental and technological reasons. To gain a deeper understanding of this effect and develop superconducting technologies based on it, the material and physical parameters crucial for the GCS effect must be identified. Top-down fabrication protocols should also be optimized to increase device scalability, although studies suggest that top-down fabricated devices are more resilient to show a GCS. Here, we investigate gated superconducting nanobridges made with a top-down fabrication process from thin films of …

Kinematic And Dynamic Structure Of The 18 May 2020 Squall Line Over South Korea, Wishnu Agum Swastiko, Chia-Lun Tsai, Seung Hee Kim, Gyuwon Lee

Institute for ECHO Articles and Research

The diagonal squall line that passed through the Korean Peninsula on the 18 May 2020 was examined using wind data retrieved from multiple Doppler radar synthesis focusing on its kinematic and dynamic aspects. The low-level jet, along with warm and moist air in the lower level, served as the primary source of moisture supply during the initiation and formation process. The presence of a cold pool accompanying the squall line played a role in retaining moisture at the surface. As the squall line approached the Korean Peninsula, the convective bands in the northern segment (NS) and southern segment (SS) of …

Benthic Community Response To The Impacts Of Proposed Sediment Diversions In Louisiana Estuaries, Jillian C. Tupitza

LSU Doctoral Dissertations

Sediment diversions designed to mitigate land loss in coastal Louisiana will likely cause ecosystem-wide shifts. The first diversion, planned for Barataria Bay, will divert fresh water and sediment from the Mississippi River into the surrounding wetlands to help them keep pace with high rates of relative sea-level rise (RSLR). Estuarine benthic communities were used in this study as tools to characterize ecological patterns in the context of anticipated salinity changes. I reviewed relevant literature, conducted a two-year survey of Barataria Bay benthos, executed a reciprocal transplant experiment to describe changes that might occur in both community composition and trophic dynamics, …

Demonstration Of High-Impedance Superconducting Nbre Dayem Bridges, S. Battisti, J. Koch, A. Paghi, L. Ruf, Armen Gulian, Serafim Teknowijoyo, C. Cirillo, Z. Makhdoumi Kakhaki, C. Attanasio, E. Scheer, A. Di Bernardo, G. De Simoni, F. Giazotto

Mathematics, Physics, and Computer Science Faculty Articles and Research

Here, we demonstrate superconducting Dayem-bridge weak-links made of different stoichiometric compositions of NbRe. Our devices possess a relatively high critical temperature, normal-state resistance, and kinetic inductance. In particular, the high kinetic inductance makes this material a good alternative to more conventional niobium-based superconductors (e.g., NbN or NbTiN) for the realization of superinductors and high-quality factor resonators, whereas the high normal-state resistance yields a large output voltage in superconducting switches and logic elements realized upon this compound. Moreover, out-of-plane critical magnetic fields exceeding 2 T ensure that possible applications requiring high magnetic fields can also be envisaged. Altogether, these features make …

Evaluating Appropriate Participant Training Period For Anuran Auditory Surveys, Evianna Goebel

Honors Projects

Auditory surveys are common in anuran research as they can tell a lot about a species without being intensely laborious or costly. There has not been much research on training periods for those taking part in the surveys. Proper training is necessary and improper training can hinder a project and lead to skewed results. In this study, we took students from several biology 2040 classes and had them study the calls of 11 frog species in NW Ohio. From the data, we can conclude that 2 weeks of roughly 100 minutes of study time is not enough for successful results …

Deep Selenium Donors In Zngep2 Crystals: An Electron Paramagnetic Resonance Study Of A Nonlinear Optical Material, Timothy D. Gustafson, Larry E. Halliburton, Nancy C. Giles, Peter G. Schunemann, Kevin T. Zawilski, J. Jesenovec, Kent L. Averett, Jonathan E. Slagle [*]

Faculty Publications

Zinc germanium diphosphide (ZnGeP₂) is a ternary semiconductor best known for its nonlinear optical properties. A primary application is optical parametric oscillators operating in the mid-infrared region. Controlled donor doping provides a method to minimize the acceptor-related absorption bands that limit the output power of these devices. In the present study, a ZnGeP₂ crystal is doped with selenium during growth. Selenium substitutes for phosphorus and serves as a deep donor. Significant concentrations of native defects (zinc vacancies, germanium-on-zinc antisites, and phosphorous vacancies) are also present in the crystal. Electron paramagnetic resonance (EPR) is used to establish the …