Physical Sciences and Mathematics Commons^™

Robust Prediction Of Charpy Toughness Of Additively Manufactured Kovar Using Deep Convolutional Neural Networks, Nathan R. Bianco

Mathematics & Statistics ETDs

Understanding the reason for mechanical failures of manufactured parts in their operating environments is critical to prevention of future failures. However, in-situ post-mortem evaluation of physical properties, such as fracture toughness, is time consuming and alters the condition of the material, leading to potentially misleading findings. In this study, additively manufactured test coupons were produced over a wide range of process conditions to test the impact toughness of a material. The Charpy V-Notch toughness was measured on over 200 samples alongside corresponding optical images of both sides of the fracture surface. Convolutional neural network models were trained to correlate fracture …

The Environmental Craftsfolk: Making Things In A World Full Of Stuff, Zoey Ballard

Graduate Student Portfolios, Professional Papers, and Capstone Projects

This Civic Engagement Project (CEP) proposes a transformative approach to addressing the complex challenges of environmental degradation and disconnection from nature through the establishment of the Eco-Craft Cabal in Missoula, Montana. The project seeks to reframe environmental consciousness through the lens of craft, fostering improved connections with the local environment and promoting community resilience. By repurposing both natural and artificial materials in inclusive, accessible crafting activities, the Eco-Craft Cabal aims to empower participants to confront feelings of despair and hopelessness with tangible, meaningful actions.

The Performance Of Arima And Arfima In Modelling The Exchange Rate Of Nigeria Currency To Other Currencies, Adewole Ayoade I.

Al-Bahir

Economic performance of a nation depends majorly on the stability of foreign exchange rate; the economic viability hangs on the exchange rate of local currencies against other currencies across the globe. Box – Jenkins Approach was employed to model the Naira exchange rate to other major currencies using Autoregressive Integrated Moving Average (ARIMA) and The autoregressive fractional integral moving average (ARFIMA) models. This studies aimed on measuring forecast ability of Autoregressive Integrated Moving Average (ARIMA) (p,d,q) and autoregressive fractional integral moving average (ARFIMA) (p, fd, q) models for stationary type series that exhibit features of Long memory properties. Results indicate …

The Santa Clara, 2024-05-10, Santa Clara University

The Santa Clara

No abstract provided.

The Heavy Metal Survey: The Evolution Of Stellar Metallicities, Abundance Ratios, And Ages Of Massive Quiescent Galaxies Since Z ∼ 2, Aliza G. Beverage, Mariska Kriek, Katherine A. Suess, Charlie Conroy, Sedona H. Price, Guillermo Barro, Rachel Bezanson, Marijn Franx, Brian Lorenz, Yilun Ma, Lamiya A. Mowla, Imad Pasha, Pieter Van Dokkum, Daniel R. Weisz

Pacific Faculty Work

We present the elemental abundances and ages of 19 massive quiescent galaxies at z ∼ 1.4 and z ∼ 2.1 from the Keck Heavy Metal Survey. The ultradeep LRIS and MOSFIRE spectra were modeled using a full-spectrum stellar population fitting code with variable abundance patterns. The galaxies have iron abundances between [Fe/H] = −0.5 and −0.1 dex, with typical values of −0.2 [−0.3] at z ∼ 1.4 [z ∼ 2.1]. We also find a tentative log σ v -[Fe/H] relation at z ∼ 1.4. The magnesium-to-iron ratios span [Mg/Fe] = 0.1-0.6 dex, with typical values of 0.3 [0.5] dex at …

Anthropaean Storytelling, Community, And The Ripples Of The Climate Crisis, Jonathan Summers

Undergraduate University Honors Capstones

The climate crisis has grown into a dangerous global threat, pushing our planet to the point of ecological no return. We face the certainty of increasingly destructive climate disasters and social upheaval, threatening our societal and biological survival. The next few years will prove critical to the future welfare of our species and our planet. However, we are not without our defenses. Through the lens of fictional short stories, this capstone concentrates on community and storytelling, two deeply human behaviors that could be two of our greatest tools in the struggle against climate change. Human beings are social creatures at …

Cleaner, Green Oxidation Chemistry: Development Of New Oxoammonium- And Nitroxide- Mediated Transformations, Katrina Doherty

Honors Scholar Theses

This work investigates various key oxidation and oxidative functionalization reactions that occur using a bench-stable nitroxide and its oxoammonium nitrate salt congener. Such transformations include amidation of aldehydes to acyl azoles or hexafluoroisopropyl esters and oxidation of alcohols to ketones or aldehydes. These transformations are key, everyday reactions within organic chemistry, and the aim to make them cleaner and greener is essential to the future of chemistry. Novel compounds produced by these green methods will also be discussed, as well as the results of a scale-up protocol showing the efficacy of the reactions on a process chemistry level. As an …

Surface Water Quality Assessment Of Mingo Creek County Park: The Impacts Of Extractive Industries, Mikayla J. Bayto

Electronic Theses and Dissertations

Historical and current extraction operations and infrastructure, including natural gas pipelines, conventional and unconventional oil and natural gas drilling, longwall coal mining, and strip coal mining, occur throughout the Mingo Creek watershed of Washington County, Pennsylvania, including Mingo Creek County Park. Mingo Creek and several associated tributaries flow through Mingo Creek County Park, eventually discharging into the Monongahela River. An independent water quality study was conducted from June 2020 through July 2023 in Mingo Creek County Park to determine if historical and current extraction activities impact Mingo Creek and its associated tributaries. Weekly sampling of Mingo Creek and associated tributaries …

Audience Preferences For Extension Forestry Zoom Webinars, Kevin W. Zobrist, Brendan J. Whyte

Journal of Extension

The Washington State University Extension Forestry program switched to all online programming in 2020 in response to the COVID-19 pandemic. Over 2,000 people participated in our webinars, providing an opportunity to survey a large audience about their webinar preferences. We found that people prefer webinars that are approximately an hour long and offered in the evening or late morning. Participants placed high importance on having a recording available, but they had mixed views on including video of the instructor speaking. Participants found online delivery to be successful and had a strong preference for online programming in the future.

Companionship, Romance, And Self-Perception With Conversational Chatbots, Jonathan Windsor

Departmental Honors & Graduate Capstone Projects

Serving as a metaphorical gateway transcending the communicative barriers of physical relationships in interpersonal dialogues, artificial imators of human behavior and speech, also known as conversational chatbots; a simulation of human knowledge and existence in a bi-directional conversation, functions as a rhetor of expression. Spanning from contexts of professional to romantic, I serve to dissect and critically analyze the nuances of human-machine relationships based on pre-established literature, inviting ethical considerations and biases in their design and marketing. Corporate influences spark pre-established servitude-esque relationships with conversational agents. Professional applications, both task-oriented and emotionally based alike, paint a mixed picture of …

Chemical Extraction Of Non-Exchangeable Radiocesium From Fukushima Soils Using Ion-Exchange And Selective Precipitation, Ian Danquah

Master's Theses

The Fukushima Daiichi Nuclear Power Plant meltdown in Japan resulted in the release of radionuclides into the environment. Soil in neighboring prefectures has been reported to be among the most contaminated. Since the event in 2011, a large volume of soil has been collected and stored in temporary storage facilities, awaiting decontamination. Numerous methods have been used and employed to remediate these soils, but most methods do not achieve the 90% removal target set by the Japanese government for safe disposal. Among all reported methods, the ion-exchange technique has been reported to be cost-efficient and effective. A study by Tamura …

Program Analysis Of C For Conversion To Memory-Safe Rust, Dylan Cassidy

Honors Scholar Theses

C is a memory-unsafe language, which can cause software security issues. Rust is a more recent high-performance language that has memory-safe features, which motivates developers to move software to Rust. However, given the large existing C codebase, this is a tedious task, and current approaches result in memory-unsafe blocks of code remaining unsafe after conversion. We seek to use program analysis techniques to create software that identifies blocks of C code that could be safely converted to memory-safe Rust, despite using seemingly memory- unsafe access patterns. We performed manual translation of functions within the libGeoIP C library to Rust, ensuring …

Evaluation Of Changes In Evaporative Losses From Lake Powell Reservoir Contributions In The Colorado River Basin, Maria Mlinarcik

Electronic Theses and Dissertations

The Colorado River Basin (CRB) is one of the most critical water sources for the western United States (U.S.) and Mexico. For over a century, numerous policies and regulations have been implemented in attempts to manage the Colorado River Basin to address the concern of overuse, collectively referred to as the “Law of the River.” The USGS hydrologist E.C. LaRue warned that the optimistic estimates used in negotiating the Colorado River Compact did not align with the actual water availability in the river. His analysis in 1925 revealed a potential deficit if all allocated water was utilized, exacerbated by overallocation …

Draft Final 2024 Residential Metals Abatement Program (Rmap) Mandan Park Soil Remedial Action Work Plan (Rawp), Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Hemp-Seed Oil-Based Polyurethane Composite Foam: Effect Of Fillers On The Properties Of Polyurethanes, Mansi Ahir

Electronic Theses & Dissertations

Over the past few decades, polymer composites have been receiving significant interest and become a protagonist due to their enhanced properties and wide range of applications. Herein, the study has been done on the effect of filler and flame-retardant in hemp seed oil-based rigid polyurethane foams (RPUFs) composite performance. First of all, hemp seed oil (HSO) was gone through an epoxidation process using hydrogen peroxide and acetic acid. After that, epoxidized hemp-seed oil (EHSO) was converted into hemp polyol (HSOP) by a ring-opening reaction with methanol. The synthesized HSOP was then reacted with diisocyanate monomer in the presence of commercial …

Bio-Based Rigid Polyurethane Foams Using Modified Hemp Seed Oil Combined With Flame Retardants, Sagar Jariwala

Electronic Theses & Dissertations

In today's world, the idea is to synthesize bio-based polyurethane (PU) goods, which reduces reliance on petroleum-based products. As a result, we produced polyol from hemp seed oil (HSO) and evaluated it using FTIR, GPC, hydroxyl value, and acid value. Hemp seed oil polyol (HSOP) was successfully synthesized and combined with additional ingredients such as catalysts, blowing agents, hardeners, and flame-retardant chemicals to produce stiff polyurethane foams. The focus of this research was to synthesize high-quality flame-retardant rigid polyurethane foams (RPUFs) through the addition of flame retardants. The test results revealed that the HSO-based PU without flame retardants has 47.04 …

Wyoming Conservation Exchange: A Case Study In Grassroots Conservation Program Design, Kristiana Hansen, Sara Brodnax, Roger Coupal, Jennifer Lamb, Anne Mackinnon, Ginger Paige, Eric Peterson, Melanie Purcell

Journal of Extension

This article describes the conception and development of a market-based conservation program in Wyoming whose purpose was threefold: to compensate landowners for good stewardship of their land and water resources; facilitate meaningful conservation; and encourage environmentally responsible energy development. The program was developed with strong stakeholder support against a backdrop of significant regulatory change. The project, called the Wyoming Conservation Exchange (WCE), represents a project-based alternative to more traditional program-based Extension efforts. This article evaluates ways in which the WCE can act as a road map—but also a cautionary tale—for similar Extension efforts in the future.

Quaternary Diamond-Like Sulfides For Nonlinear Optical Applications: Investigation Into Composition-Structure-Property Relationships Of The I2-Ii-Iv-Vi4 And I4-Ii-Iv2-Vi7 Formulae, Jordan Kelly

Electronic Theses and Dissertations

The research work presented in this dissertation focuses on the synthesis, characterization, and property assessment of new and existing quaternary diamond-like semiconductor (DLS) materials for the potential application in infrared (IR) nonlinear optics (NLO). Chapter 2 discusses the previously discovered temperature-dependent polymorphs of Cu₂ZnGeS₄ (CZGS); however, the IR NLO properties, neutron powder diffraction data, and single crystal X-ray diffraction structures were previously undetermined. The high-temperature α-CZGS polymorph was superior to the low-temperature β-CZGS analog in both second harmonic generation (SHG) and laser-induced damage threshold (LIDT). Chapter 3 presents the discovery of Li₂MgGeS₄ and comparison …

Chandra Hetg X-Ray Spectra And Variability Of Π Aqr, A Γ Cas-Type Be Star, David P. Huenemoerder, Pragati Pradhan, Claude R. Canizares, Sean Gunderson, Richard Ignace, Joy S. Nichols, A.M.T. Pollock, Norbert S. Schulz, Dustin K. Swarm, José M. Torrejón

Publications

High-resolution X-ray spectra of π Aqr, a γ Cas-type star, obtained with the Chandra/HETG spectrometer, revealed emission lines of H-like ions of Mg, Si, S, and Fe; a strong, hard continuum; and a lack of He-like ions, indicating the presence of very hot thermal plasma. The X-ray light curve showed significant fluctuations, with coherent variability at a period of about 3400 s in one observation. The hardness ratio was relatively constant except for one observation in which the spectrum was much harder and more absorbed. We interpret the X-ray emission as arising from accretion onto the secondary, which is likely …

Cadmium Oxide Nanoparticles From New Organometallic Cd(Ii)-Schiff Base Complex And In Vitro Biological Potentials: Dual S. Aureus And E. Coli Dna Gyrase Inhibition By The Precursors Via In Silico Binding Modes’ Study, Ikechukwu P. Ejidike, Amani Direm, Cemal Parlak, Mercy O. Bamigboye, Olajumoke Oluade, Juliana B. Adetunji, Athar Ata, Michael O. Eze, Joshua W. Hollett, Hadley S. Clayton

Michigan Tech Publications

At the nanoscale level, several biological processes take place, owing to the potential that engineered nanomaterials might interrelate with bio-molecules and cellular procedures. This study aimed to synthesize cadmium oxide nanoparticles via a one-step calcination process of tetradentate Schiff base-Cd(II) complex at different temperature ranges. The as-synthesized compounds were carried out via a viz UV–visible, elemental analysis, 1H NMR, molar conductivity, transmission electron microscopy (TEM), FT-IR spectroscopy, and X-ray diffraction (PXRD). The band gap energy and average particle sizes of the CdO particles are respectively (2.69 eV, 3.54 eV), 26.88 nm for CdO@250, and (3.20 eV, 3.57 eV), 25.67 nm …

Towards Carbon Dioxide Reduction: Synthesis And Characterization Of Ccc-Nhc Pincer Iron Complexes., Joshua Mensah

Theses and Dissertations

The industrial revolution came with its downside of emission of greenhouse gases into the atmosphere. The NOAA reported in 2019 that, of the greenhouse gases emitted into the atmosphere, CO2 contributed to about 80% of the increased greenhouse gases hence the need for CO2 Sequestering and Storage (CSS) and ultimately leading to Carbon Capture and Recycling (CCR) as a viable option to convert CO2 into useful forms. The race to find the best catalyst for CCR has led to the synthesis of many organometallic compounds. Pincer complexes catalyzed CO2 reduction has gained notoriety recently because of the tunability and robustness …

Analysis Of Modeled 3d Solar Magnetic Field During 30 X/M-Class Solar Flares, Seth H. Garland, Vasyl B. Yurchyshyn, Robert D. Loper, Benjamin F. Akers, Daniel J. Emmons Ii

Faculty Publications

Using non-linear force free field (NLFFF) extrapolation, 3D magnetic fields were modeled from the 12-min cadence Solar Dynamics Observatory Helioseismic and Magnetic Imager (HMI) photospheric vector magnetograms, spanning a time period of 1 hour before through 1 hour after the start of 18 X-class and 12 M-class solar flares. Several magnetic field parameters were calculated from the modeled fields directly, as well as from the power spectrum of surface maps generated by summing the fields along the vertical axis, for two different regions: areas with photospheric |B_z|≥ 300 G (active region—AR) and areas above the photosphere with the …

Draft Final 2024 Residential Metals Abatement Program (Rmap) Park Soil Sampling Field Sampling Plan (Fsp) Submittal #13 [Copper Mountain Park], Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Quantum Measurement: Theory And Practice, Andrew N. Jordan, Irfan A. Siddiqi

Mathematics, Physics, and Computer Science Faculty Books and Book Chapters

This book adopts a novel, physics-first approach to quantum measurement, using physical experiments as the basis to describe the underlying mathematical formalism. Topics covered include weak measurements, quantum measurement reversal, quantum trajectories and the stochastic path integral formalism. The theory of quantum measurement is also covered in detail, including discussion of how it can be tested and demonstrated in a laboratory: how to build quantum-limited amplifiers, fundamental noise limits imposed on measurement by quantum mechanics, and the design of superconducting circuits. This text is an excellent introduction for students with a basic understanding of quantum mechanics wanting to learn more …

Examining The Authenticity Of The 'Ether Model' In Certain O-Glycosylation Reactions, Varad Vinayak Agarkar

LSU Doctoral Dissertations

Acinetobacter baumannii is a gram-negative bacterium species that is responsible for nosocomial infections. It has shown antibiotic resistance and has been designated an urgent threat by the CDC. In Chapter 1, I highlight my efforts in the synthesis of a Kdo building block in the journey towards the construction of an A. baumannii lipooligosaccharide (LOS) core pentasaccharide- a potential candidate for glycoconjugate vaccine against A. baumannii infection. I talk about various optimizations and improvements in the Kdo monosaccharide synthesis and the mechanistic insights I provided about a critical transformation in the synthetic sequence.

Chemical O-glycosylation is a significant research …

A Novel Method For Multiple Phenotype Association Studies Based On Genotype And Phenotype Network, Xuewei Cao, Shuanglin Zhang, Qiuying Sha

Michigan Tech Publications

Joint analysis of multiple correlated phenotypes for genome-wide association studies (GWAS) can identify and interpret pleiotropic loci which are essential to understand pleiotropy in diseases and complex traits. Meanwhile, constructing a network based on associations between phenotypes and genotypes provides a new insight to analyze multiple phenotypes, which can explore whether phenotypes and genotypes might be related to each other at a higher level of cellular and organismal organization. In this paper, we first develop a bipartite signed network by linking phenotypes and genotypes into a Genotype and Phenotype Network (GPN). The GPN can be constructed by a mixture of …

Removal Of Phenol From Oilfield Produced Water Using Non-Conventional Adsorbent Medium By An Eco-Friendly Approach, Salem Jawad Alhamd, Mohammed Nsaif Abbas, Hassan Jameel Jawad Al-Fatlawy, Thekra Atta Ibrahim, Zaid Nsaif Abbas

Karbala International Journal of Modern Science

Petroleum extraction generates substantial quantities of produced water, a challenge compounded by water scarcity in oil-producing regions, notably the Middle East. Leveraging produced water effectively, adhering to environmental standards, can offer a viable solution to the issue of water scarcity. This study explores the potential of mandarin peels as an available, cost-effective adsorbent for treating synthetic aqueous solution simulated to oil-field produced water, specifically targeting phenol, a dangerous pollutant. Employing a batch-mode adsorption unit, six operational factors—phenol concentration, acidity, agitation speed, contact time, adsorbent dose, and temperature—were investigated. Results revealed an inverse relationship between phenol removal and pH, concentration, and …

Study Of The Solar Coronal Plasma Properties, Shubhashri S. Shenoy

University Departments

No abstract provided.

Sunyaev-Zeldovich Effect In The Intra-Cluster Medium, Nathan Fronk

Senior Seminars and Capstones

This paper covers the Sunyaev-Zeldovich effect, it’s derivation, and it’s applications in astronomy. The effect is a result of inverse Compton scattering in a cloud of hot charged particles, causing an increase in the temperature of the the cosmic microwave background radiation passing through the cloud. This change in temperature can be measured, and used to calculate the physical properties of the structure in question. This paper focuses on the a method used by Adam et al. (2017) to find a temperature map of the intra-cluster medium.

Draft Final 2024 Butte Priority Soils Operable Unit (Bpsou) Borrow Amendment Submittal #1, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.