Physical Sciences and Mathematics Commons^™

Charge And Strain Engineering Of Ferroic And Correlated Oxides, Yifei Hao

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

This dissertation presents a comprehensive study of the charge and strain effects on the electronic and magnetic properties of epitaxial ferroic and correlated oxide thin films and heterostructures. We perform the planar Hall effect to quantify the magnetocrystalline anisotropy (MCA) in epitaxial La_1-xSr_xMnO₃ films (x = 0.2 and 0.33) deposited on SrTiO₃ substrates. The biaxial magnetic anisotropy energy of L_0.67Sr_0.33MnO₃ is about 17% larger than La_0.8Sr_0.2MnO₃. By comparing with the theoretically predicted values, we have decoupled the doping and strain effects on …

Effect Of Biomass Water Dynamics In Cosmic-Ray Neutron Sensor Observations: A Long-Term Analysis Of Maize–Soybean Rotation In Nebraska, Tanessa Morris

School of Natural Resources: Dissertations, Theses, and Student Research

The precise measurement of soil water content (SWC) is crucial for effective water resource management. This study utilizes the Cosmic Ray Neutron Sensor (CRNS) for area-averaged SWC measurements, emphasizing the need to consider all hydrogen sources, including the time-variable ones like plant biomass and water content. Chapter 1 presents a background on soil moisture estimation, CRNS technology, and an overview of the study. It discusses various soil moisture measurement techniques, highlights the gap in knowledge addressed by CRNS technology, explains CRNS functionality and advancements, and outlines the study's motivations and methods.

Chapter 2 reports a study conducted near Mead, Nebraska, …

A Compilation, Analysis, And Categorization Of 403 Atmospheric And Climate Science Misconceptions, Haeli Leighty

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The National Association of Geoscience Teachers (NAGT) has listed the inaccessibility of research related to misconceptions in atmospheric and climate science as a Geoscience Education Research Grand Challenge (Cervato et al. 2018). This project was a direct response to this call for research and consisted of three distinct steps: 1) data gathering, which included reviewing the literature for relevant misconception data, 2) a qualitative analysis, which included compiling, organizing, and categorizing the data collected, and 3) a quantitative analysis, which included determining the prevalence of each misconception across topic categories, demographic categories, and over time. A total of 403 misconceptions …

The Analysis Of Mechanical Exfoliation Of Graphene For Various Fabrication And Automation Techniques, Lance Yarbrough

Mechanical Engineering Undergraduate Honors Theses

Mechanical Exfoliation of Graphene is an often-overlooked portion of the fabrication of quantum devices, and to create more devices quickly, optimizing this process to generate better flakes is critical. In addition, it would be valuable to simulate test pulls quickly, to gain insight on flake quality of various materials and exfoliation conditions. Physical pulls of graphene at various temperatures, pull forces, and pull repetitions were analyzed and compared to the results of ANSYS simulations, solved for similar results. Using ANSYS’ ability to predict trends in exfoliations, flake thickness and coverage using stress and deflection analyses were investigated. Generally, both strongly …

Investigate The Importance Of Local Magnetic Moment And Magnetic Interaction In Superconducting Fese Monolayer Using Density Functional Calculations, Sudip Pokharel

Graduate Theses and Dissertations

In this dissertation, we present two projects to study superconducting FeSe monolayer using first-principles density functional calculations. Monolayer FeSe/SrTiO₃ system has very different properties as compared to its bulk counterpart in terms of critical superconducting temperature, Fermi surface topology and antiferromagnetic (AFM) stability. For FeSe monolayer, local magnetic moment (LMM) and AFM fluctuation are closely linked to superconductivity. However, LMM is not studied enough for FeSe monolayer. For FeSe/SrTiO₃ system, the substrate SrTiO₃ constrains the in-plane lattice constant for FeSe and also plays a crucial role in the onset and enhancement of superconductivity by providing charge transfer. …

Year-Round Co2 Emissions From The Drawdown Area Of A Tropical Reservoir: Strong Seasonal And Spatial Variation, Ícaro Barbosa, José R. Paranaíba, Sebastian Sobek, Sarian Kosten, Rafael M. Almeida, Vitor Duque, Natália Mendonça, Nathan Barros, Raquel Mendonça

School of Earth, Environmental, & Marine Sciences Faculty Publications

Highlights

• Drawdown areas emitted 80% of reservoir CO2 with just 1/5 area.

• Emissions from reservoir shorelines near forests were greater than from areas near grassland.

• CO2 emissions increase with the distance from the water.

• Estimates of reservoir drawdown CO2 flux vary by ∼ 300 % across the seasons examined here.

• There was no discernible difference in CO2 emissions between day and night-time.

• A significant increase in CO2 fluxes was observed 30 min after a rewetting event.

Abstract

A growing body of literature points to drawdown areas as important sources of atmospheric CO2 within reservoirs. Yet seasonal and temporal patterns of …

Best Practices For Offline Evaluation For Top-N Recommendation: Candidate Set Sampling And Statistical Inference, Ngozi Ihemelandu

Boise State University Theses and Dissertations

Evaluation of recommender systems is key to ensuring that we are making progress by only promoting proposed algorithms that actually outperform the state-of-the-art. Evaluation can be performed offline using logged historic data, or online such as A/B tests. Offline evaluation is the most popular evaluation paradigm used in recent research publications because of its accessibility. It has been an area of study since its earliest days, and is still currently an active area of research. Even though significant work has been done to improve the process and metrics of offline evaluation, it still faces fundamental difficulties. Given the significant role …

Chm116 Principles Of Chemistry Ii Lecture Slides, Leah S. Cohen, Probal Banerjee

Open Educational Resources

This file contains the lecture slides that are used in CHM116, Principles of Chemistry II.

Resource Scarcity Caused By Environmental Changes: Driving Factor In Terrorism Attacks In Afghanistan, Pakistan, Syria, Amaris Bustamante

Open Access Theses & Dissertations

Climate change, resource scarcity, and terrorist attacks are ever-growing crises that disproportionately impact different states. They are crises that can impact the stability and resilience of humanity in the following decades if they are not addressed and mitigated. This study addresses the impact of resource scarcity caused by climate change that can then serve as a driving force in terrorist attacks in climate-sensitive and conflict-prone states. The objective of this mixed-methods study is to identify the correlation between climate changes that lead to resource scarcity such as rainfall and surface temperatures with terrorist attacks when taking into consideration other demographic, …

Water Sufficiency For Organismal Function In Dryland Critical Zones, Lindsey Dacey

Open Access Theses & Dissertations

Water availability is crucial for organismal survival and growth in dryland environments, affecting both ecological interactions and carbon dynamics. The goal of this thesis is to develop soil water release curves (SWRCs) that link soil water potentials (Ψ) to soil water content (θ). Using the SWRCs, temporal soil water sufficiency curves are developed, which quantify the amount of time that dryland critical zones have enough water to sustain the physiology of organisms. These curves allow for effectively indicating water availability across different species, coverage types, and soil conditions, enhancing our understanding of water dynamics in drylands and contributing important parameters …

Relations Between Printability And Rheology In A Ceramic Paste Extrusion Process, Nicholas Durand

Open Access Theses & Dissertations

Ceramic additive manufacturing (AM) uses the same fundamentals as material extrusion (MEX) that utilizes polymers or resins for printing applications. Ceramic AM uses the same process of slicing an STL file to determine a toolpath for the printer that will facilitate material deposition to manufacture full parts; ceramic AM also provides a low-cost advantage when compared to processes that require high powered lasers for melting metal powders or heated nozzles used for dispensing thermoplastics. Despite having the similar design freedom and ability for rapid prototyping that other printing methods benefit from with the addition of low cost, ceramic AM has …

Assessing Urban Tree Coverage Along The U.S.-Mexico Border: A Gis Analysis Of Paso Del Norte, Melanie Escobar

Open Access Theses & Dissertations

In recent years, researchers have extensively studied the spatial distribution of social demographics and urban tree canopy (UTC) in urban cities, but very few, to this date, address U.S.-Mexico border cities. To date, there is no research that assesses the distribution of urban tree canopy (UTC) in the city of El Paso, Texas, and Ciudad Juarez, Chihuahua, along the U.S.- Mexico border. Leveraging advanced mapping techniques and GIS tools, the study performs comparisons between countries (Juárez vs. El Paso urbanized areas and intra-country (within each country). It compares land cover classifications, assesses variations in UTC distribution across census tracts and …

Assessing Nordihydroguaiaretic Acid Properties And Its Potential Therapeutic Effect For Glioblastoma, Jose Arturo Guerrero

Open Access Theses & Dissertations

This study employs a combination of theoretical and experimental analysis to spectroscopically investigate the biomechanistic structure relationship and therapeutic effects of the Nordihydroguaiaretic Acid (NDGA) chemical derived from the Larrea Tridentata plant. These relationships are crucial for understanding NDGA's efficacy in disease prevention, treatment, and potential toxicological effects. While the medicinal and antiviral properties of the NDGA have been studied extensively, there remains a gap in optically identifying and reporting its structural changes. The current research successfully reveals evident trends in NDGA's vibrational signatures, particularly highlighting the absence of the Raman feature at 780 〖cm〗^(-1) as indicative of a fully …

Study Of Morphology, Structure, And Magnetic Properties Of High Entropy Alloy Systems, Matthew G. Guerrero

Open Access Theses & Dissertations

Abstract:This thesis presents an investigation into the magnetic properties of high entropy alloy (HEA) samples, focusing primarily on compositions within the FeNiCoMn system and their gallium/chemically doped derivatives. High entropy alloys represent a promising class of materials with unique properties resulting from their complex composition and structural arrangements. The behavior of these alloys, particularly in their magnetic properties, remains an area of significant interest due to their potential applications in magnetic storage, sensing, and other technological domains. The study encompasses an examination of seven distinct HEA samples: FeNiCo, FeNiCoMn0.2, FeNiCoMn0.4, FeNiCoMn0.6, FeNiCoMn0.2Ga0.1, FeNiCoGa0.2, FeNiCoMn0.2Ga0.3. Furthermore, three samples of FeNiCoMn0.2 and …

Local Map Of The Interstellar Fuv Field, David Lomeli

Open Access Theses & Dissertations

The strength of the far-ultraviolet field is an important parameter in determining the chemistry that takes place in star-forming regions. FUV radiation is produced by bright stars in the galaxy and absorbed by interstellar dust. By using newly available maps of the dust distribution, in conjunction with catalogs of stellar positions and spectra, we created a local map of the FUV field ranging from 6-13.6 eV. We find a value of 6.57*10^-14 erg/cm^3 at the location of the Sun. This value, alongside its spectra, follow previous measurements and estimates of the FUV field at the Sun. We further study the …

Manipulation Of The Magnetic Properties Of Van Der Waals Materials Through External Stimuli, Luis Martinez

Open Access Theses & Dissertations

A new revolutionary application dependent on the electron spin to carry information with greater efficiency in data storage, transfer, and processing, will rely heavily on 2D magnets and the ability to effectively control their electron spins and engineer their properties. Previously, magnetic thin films were heavily studied to achieve this goal, however, these materials came with pitfalls and lacked naturally occurring 2D magnetism. The recent discovery of intrinsic magnetism in few-layered van der Waals (vdW) magnets has inspired researchers to extensively study them because of the feasibility to exfoliate them down to a monolayer. Due to this dimensionality factor, vdW …

Modeling The Spatiotemporal Variations Of The Magnetic Field In Active Regions On The Sun Using Deep Neural Networks, Godwill Asare Mensah Mensah

Open Access Theses & Dissertations

Solar active regions are areas on the Sun's surface that have especially strong magnetic fields. Active regions are usually linked to a number of phenomena that can have serious detrimental consequences on technology and, in turn, human life. Examples of these phenomena include solar flares and coronal mass ejections, or CMEs. The precise predictionof solar flares and coronal mass ejections is still an open problem since the fundamental processes underpinning the formation and development of active regions are still not well understood. One key area of research at the intersection of solar physics and artificial intelligence is deriving insights from …

Microwave Emission Model Parameter Tuning For Surface Soil Moisture Retrieval Using Uav-Mounted Dual Polarization L-Band Radiometer, Santiago Hoyos Echeverri

Open Access Theses & Dissertations

Surface soil moisture retrieval from L-band brightness temperature has been developed for the past decades due to multiple beneficial characteristics of 1-2 GHz frequency bands for remote sensing of the environment. Numerous microwave emission models have been proposed for tower and satellite-based operations with successful retrieval of surface soil moisture and vegetation water content. As a result of the development of cost-effective and low-mass microwave L-band radiometers such as the Portable L-band Radiometer (PoLRa), surface soil moisture surveying traditionally developed by satellite missions SMOS and SMAP can now be developed at local scales, bringing these operations to commercial small unmanned …

Combining Green Analytical Methods And Machine Learning To Develop Urinary Fatty Acid Models For Cancer Detection, Elizabeth Noriega Landa

Open Access Theses & Dissertations

This study aimed to explore fatty acids (FAs) as non-invasive biomarkers for prostate cancer (PCa) detection and prognosis, and their potential applications in other cancers. The objectives of this study were: 1) Develop a non-invasive urinary FAs-based model for diagnosing PCa; 2) Develop a FAs-based liquid biopsy model for non-invasive monitoring of PCa progression; 3) Investigate FAs composition in periprostatic adipose tissue (PPAT) collected from PCa positive patients; 4) Investigate the potential of urinary FAs biomarkers for diagnosing clear cell renal cell carcinoma (ccRCC) and ovarian cancer (OC).For the PCa diagnostic model, urine samples from 334 biopsy-confirmed PCa-positive and 232 …

Computational Study Of Fluorescent Molecular Probes For The Early Detection Of Alzheimer's Disease, Gabriela Elizabeth Molina Aguirre

Open Access Theses & Dissertations

Alzheimer's disease is a debilitating brain disorder that affects memory, thinking, and behavior. It is the most prevalent form of dementia and the seventh leading cause of death in the United States. As, researchers have identified biomarkers that can indicate the presence of the disease many years before the first symptoms appear, so there is an opportunity for early detection and treatment follow-ups, which could significantly improve the quality of life for those affected by this disease.This dissertation investigates the relationship between molecular structure and optical properties of donor-bridge-acceptor (DBA) fluorescent molecular probes designed for detecting Amyloid-β and p-Tau protein …

Produced Water: Characterization And Treatment, Ramon Antonio Sanchez Rosario

Open Access Theses & Dissertations

In recent years, environmental concerns have urged companies in the energy sector to modify their industrial activities to facilitate greater environmental stewardship. For example, the practice of unconventional oil and gas extraction has drawn the ire of regulators and various environmental groups due to its reliance on millions of barrels of fresh water for hydraulic fracturing well stimulation, which is generally withdrawn from natural sources and public water supplies. Additionally, this process generates two substantial waste streams, which are collectively characterized as flowback and produced water. Whereas flowback water is comprised of various chemical additives that are used during hydraulic …

Computational Investigation Of Transition Metal Photoredox Catalysis: Redox Property Tuning Via Ligand Modification, Christian Fernando Sandoval Pauker

Open Access Theses & Dissertations

In the last decade, photoredox catalysis has become a powerful tool in synthetic chemistry. It relies on the ability of catalytic systems that facilitate energy-demanding redox reactions thanks to photoinduced electron transfer processes. This dissertation focuses on the computational investigation of the redox properties of transition metal photoredox catalysts using density functional theory (DFT) calculations. The research systematically explores the effects of altering redox-active ligands on the thermodynamics of electron transfer events in the photoredox cycle. The electronic structure changes throughout oxidative and reductive quenching cycles are analyzed, with a particular focus on Cu(I) complexes. Through computational techniques, insights into …

Automated Composition Of Multivariable Scientific Workflows Considering Scientific Assumptions, Raul Alejandro Vargas Acosta

Open Access Theses & Dissertations

Many ground-breaking scientific experiments require the execution of multiple complex scientific computations. Thus, scientific workflows (i.e., a sequence of scientific computations) have received significant attention, more specifically, the automated composition of scientific workflows. Scientific workflows that repurpose data may have unique scientific assumptions that need to be considered when composing a workflow. Workflow composition tools have enabled a wider range of stakeholders (e.g., policymakers, the general public, and researchers) to create and execute workflows; however, domain expertise is still required for these tasks. The overarching goal of this work is to further improve the automatic composition of scientific workflows by …

Selective Transfection Of A Transferrin Receptor-Expressing Cell Line With Dna-Lipid Nanoparticles And Synthesis Of Parasite-Derived Glycans As Biomarkers For Leishmaniasis, Irodiel Vinales Lozano

Open Access Theses & Dissertations

Despite notable progress in lipid nanoparticle (LNP)-mediated gene delivery, achieving selective transfection of specific cell types, such as cancer cells, remains a significant hurdle, hindering the advancement of innovative gene therapies. In this study, we engineered an LNP formulation encapsulating plasmid DNA (pDNA) encoding the monomeric Green Lantern (mGL) fluorescent reporter protein. The DT7 peptide ligand targeting human transferrin receptor 1 (hTfR1) was also conjugated to the LNP surface for targeted delivery to hTfR1-expressing cells. Optimization of LNP composition yielded favorable particle diameter, ζ-potential, yield, and pDNA encapsulation efficiency. Evaluation of transfection selectivity using a panel of two engineered cell …

Synthesis And Characterization Of Indole-Based Zinc Dipyrrin Photosensitizers, Jean-Pierre Sanza

Electronic Theses and Dissertations

Metal complexes of dipyrromethene (dipyrrins) used as sensitizers in photocatalysis offer a way to harness solar energy in chemical bonds to create new fuels. This offers the dual role of reducing fossil fuel dependence and atmospheric CO₂ levels. Traditionally, metal dipyrrin complexes are synthesized using substituted pyrroles, aldehydes, and transition metals. Indoles have a more expanded pi-electron system and their dipyrrin-type complex may exhibit visible light absorption, suggesting that they can act as photosensitizers for CO₂ reduction processes. A novel indoledipyrromethene was synthesized using unsubstituted indole and mesitaldehyde. The complex exhibits visible light absorption at 422 nm. Its …

Conversion Of Microcrystalline Cellulose To Hexane Using Hydrogenated Metal Oxides At Low Temperature And Pressure, Mubarak Osman

Electronic Theses and Dissertations

Increasing global energy demand and environmental concerns have fueled the exploration of sustainable and efficient methods for renewable fuel production. The conversion of cellulosic waste to hydrocarbon fuels using hydrogenated metal oxides presents a novel and eco-friendly approach to sustainably address energy demand. In this study, hydrogenated metal oxides were used as catalysts in a relatively low-temperature and atmospheric-pressure environment to facilitate the conversion of cellulosic waste into hydrocarbon fuels. Hydrogenated metal oxides have been introduced as potential hydrogen transfer catalysts. The expected result is the selective conversion of cellulose to hexane at relatively low temperatures, which significantly reduces energy …

Landslide Susceptibility And Tree Ring Eccentricity Analysis Along Unstable Slopes Of The New River Watershed, Anderson And Morgan Counties, Tn, Megan Palmer

Electronic Theses and Dissertations

Landslides are mass movements that affect infrastructure across East Tennessee, causing problems for the Tennessee Department of Transportation (TDOT). An assessment of conditions and locations of unstable slopes can aid TDOT in infrastructure management. Landslide susceptibility was evaluated for Anderson and Morgan counties, TN, off State Route 116 in the New River watershed. Susceptibility maps used a landslide inventory and six factors: elevation, slope, geology, distance from stream, rainfall, and curvature, input in forest-based classification and logistic regression models. Additionally, affected trees along these unstable slopes in Anderson and Morgan counties were cored to analyze mass movement impacts on tree …

Regret-Based Defense In Adversarial Reinforcement Learning, Roman Belaire, Pradeep Varakantham, Thanh Hong Nguyen, David Lo

Research Collection School Of Computing and Information Systems

Deep Reinforcement Learning (DRL) policies are vulnerable to adversarial noise in observations, which can have disastrous consequences in safety-critical environments. For instance, a self-driving car receiving adversarially perturbed sensory observations about traffic signs (e.g., a stop sign physically altered to be perceived as a speed limit sign) can be fatal. Leading existing approaches for making RL algorithms robust to an observation-perturbing adversary have focused on (a) regularization approaches that make expected value objectives robust by adding adversarial loss terms; or (b) employing "maximin'' (i.e., maximizing the minimum value) notions of robustness. While regularization approaches are adept at reducing the probability …

Intriguing Properties Of Data Attribution On Diffusion Models, Xiaosen Zheng, Tianyu Pang, Chao Du, Jing Jiang, Min Lin

Research Collection School Of Computing and Information Systems

Data attribution seeks to trace model outputs back to training data. With the recent development of diffusion models, data attribution has become a desired module to properly assign valuations for high-quality or copyrighted training samples, ensuring that data contributors are fairly compensated or credited. Several theoretically motivated methods have been proposed to implement data attribution, in an effort to improve the trade-off between computational scalability and effectiveness. In this work, we conduct extensive experiments and ablation studies on attributing diffusion models, specifically focusing on DDPMs trained on CIFAR-10 and CelebA, as well as a Stable Diffusion model LoRA-finetuned on ArtBench. …

Multiple Continuous Top-K Queries Over Data Stream, Rui Zhu, Yujin Jia, Xiaochun Yang, Baihua Zheng, Bin Wang, Chuanyu Zong

Research Collection School Of Computing and Information Systems

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