Physical Sciences and Mathematics Commons^™

Nanofabrication Of Tetraphenyl Porphyrin Surface Assemblies Linked With Tin Tetrachloride: A Scanning Probe Microscopy Investigation, Quynh Do

LSU Doctoral Dissertations

Scanning probe microscopy (SPM) and colloidal lithography methods were used to study the covalent coupling of porphyrins to surfaces. In this dissertation, experimental methods for SPM operation, techniques, and applications are described. Measurement of tip-sample interactions between a sharp tip and surface is translated into digital image data maps with x-, y-, and z-data. Colloidal lithography can be used to fabricate test platforms for AFM studies. The periodicity and arrangement of the designed nanostructures is determined by the size of the colloidal particles used for surface masks. Data processing is required to obtain images and topography information from raw AFM …

Alphafold2-Based Characterization Of Apo And Holo Protein Structures And Conformational Ensembles Using Randomized Alanine Sequence Scanning Adaptation: Capturing Shared Signature Dynamics And Ligand-Induced Conformational Changes, Nishank Raisinghani, Vedant Parikh, Brandon Foley, Gennady M. Verkhivker

Mathematics, Physics, and Computer Science Faculty Articles and Research

Proteins often exist in multiple conformational states, influenced by the binding of ligands or substrates. The study of these states, particularly the apo (unbound) and holo (ligand-bound) forms, is crucial for understanding protein function, dynamics, and interactions. In the current study, we use AlphaFold2, which combines randomized alanine sequence masking with shallow multiple sequence alignment subsampling to expand the conformational diversity of the predicted structural ensembles and capture conformational changes between apo and holo protein forms. Using several well-established datasets of structurally diverse apo-holo protein pairs, the proposed approach enables robust predictions of apo and holo structures and conformational ensembles, …

Comparing Metabolism And Hypoxia Tolerance Of Native And Non-Native Florida Freshwater Fishes In Climate Change Scenarios, Benjamin A. Share

All HCAS Student Capstones, Theses, and Dissertations

As climate change brings rising water temperatures and lower dissolved oxygen (DO) concentrations to freshwater bodies, it has become increasingly important to understand how this will affect ecosystems with established non-native or invasive species. Fishes of the family Cichlidae are the most pervasive non-native fishes in the Everglades and may increase their range further north under a changing climate. To better understand potential invasibility and competition with native fishes, the metabolism and hypoxia tolerance of non-native Blue Tilapia Oreochromis aureus was compared to native Bluegill Lepomis macrochirus when acclimated across a range of seasonal and projected temperatures. Intermittent-flow respirometry was …

The Impact Of Student Engagement Activities On Future Climate Change Adaptation: The Case Of Student Simulation Models, Bassel Mostafa Elkalaf

Future Journal of Social Science

This paper explores the critical role of student engagement in addressing the growing challenges of climate change, with a focus on the Model United Nations (MUN) as a case study. As climate-related security threats increase globally, educational platforms that prepare youth for effective leadership in climate politics are more essential than ever. MUN, a widely practiced student activity simulating global policy-making, provides a valuable opportunity for students to deepen their understanding of the interconnectedness between climate change, peace, and security. By participating in MUN simulations, students engage in debates, develop innovative solutions, and practice diplomatic skills, all while exploring the …

Why Linear Faults Have Fewer Earthquakes: A Geometric Explanation, Julio C. Urenda, Aaron Velasco, Olga Kosheleva, Vladik Kreinovich

Departmental Technical Reports (CS)

Earthquakes usually occur in the vicinity of fault lines. Until recently, geophysical analysis implied that the fault shape should not strongly affect the frequency of its earthquakes. However, recent statistical analysis has shown that faults whose shape is close to linear experience much fewer earthquakes than faults of more complex shape. Based on this empirical fact, researchers have adjusted the corresponding geophysical models, so the updated models do explain this newly discovered phenomenon. The experience of geophysics shows that the updated model will probably need to be updated again when new data appears. It is therefore desirable to come up …

Fair Economic Division: How To Modify Shapley Value To Take Into Account That Different People Have Different Productivity, Christian Servin, Vladik Kreinovich

Departmental Technical Reports (CS)

Purpose: When several participants, working together, gained some amount of money, what is the fair way to distribute this amount between them? This is the problem that the future Nobelist Lloyd Shapley was working on when he proposed what is now called the Shapley value -- a division uniquely determined by natural fairness assumptions. However, this solutions is not universal: it assumes that all participants are equal -- in particular, that they have equal productivity. In practice, people have different productivity levels, and these productivity levels can differ a lot: e.g., some software engineers are several times more productive than …

How Shapley Value And Its Generalizations Can Help In The Analysis Of Complex Engineering Systems And What Next, Niklas Winnewisser, Michael Beer, Olga Kosheleva, Vladik Kreinovich

Departmental Technical Reports (CS)

For a complex engineering system -- such as a city's street network -- it is important to predict how its functionality is decreased when some of these components break down, and, if repairs are needed and repairs budget is limited, which subset of the set of components should be repaired first to maximize the resulting functionality. For systems with a large number of components, the number of possible subsets is astronomical, we cannot try to simulate all these subsets. So, the natural idea is to approximate the actual dependence of functionality on the subset by a simple expression -- linear …

What Is Optimal Granularity When Estimating Reliability Of A Complex Engineering Systems, Niklas Winnewisser, Michael Beer, Olga Kosheleva, Vladik Kreinovich

Departmental Technical Reports (CS)

For complex engineering systems, the usual way to estimate their reliability is to run simulations. If the resulting estimate does not satisfy the desired reliability level, we must replace some components with more reliable and again run simulations. This can take several iterations, so the required computation time often becomes unrealistically long. It is known that it is possible to speed up computations if components belong to a few types, and components of each type are identical. So, a natural idea to deal with the general case is to use the general granularity idea, i.e., to group components with similar …

Investigating Crystalline Rock Weathering In Distinct Climate And Ecological Settings: Insights From Shallow Seismic Refraction, Rachel Uecker

All Dissertations

Despite decades of research, understanding the subsurface of the critical zone (CZ) remains a challenge, constrained by limited access to information at depth. Traditionally, boreholes, outcrops, soil pits, and near-surface (<1 meter) geochemical measurements provided access to and quantified CZ structure. These methods, though valuable in their detail, are spatially limited, and many landscape-scale weathering hypotheses are based on these observations. In recent years, geophysical techniques have been applied to characterize large-scale CZ structure and test the validity of existing hypotheses. This dissertation harnesses nearly 10 kilometers of seismic refraction data from diverse ecoregions across the United States to challenge prevailing assumptions about weathering patterns and CZ evolution. The objective of this work is to characterize the interpreted range of weathered materials in each ecoregion and connect them to remotely-sensed information like canopy height, elevation, slope, and aspect. To do this, this work first investigates differences in weathering at depth in a north and south-facing slope system in the Laramie Range, Wyoming. The motivation for this work came from nearly a century of soil and geochemical studies from the western United States that show a greater degree and depth of weathering on north-facing slopes when compared to south-facing slopes. Our seismic refraction data were used to show that there is not a significant difference in weathering thickness at depth between north and south-facing aspects at the study site, thus conflicting with the hypothesis that there would be. Next, the hypothesis that the depth of weathering is affected by elevation was tested in the San Jacinto Mountains in southern California. The motivation for this work came from several geochemical studies in the Sierra Nevada Mountains that show ecologically prosperous mid-elevations possess an ideal combination of temperature and precipitation to produce a greater degree and depth of weathering. Again, the seismic results from the San Jacinto Mountains provided observations that conflict with the existing hypothesis that climate conditions dominate the thickness of weathering seen in rocks. Lastly, I used seismic refraction data and topographic curvature to build a groundwater model of a watershed in the Carolina Piedmont. The results of this model reveal that seismic refraction as an application for including more realistic geometry in groundwater models can improve model calibration fits. This model is the first of its kind, and, therefore, is an important step forward in merging geophysical data with the hydrogeologic and modeling field and, with further development, can be used to explore the role of topographic and regional groundwater flow as a driver of CZ evolution.

Case Study On Seney National Wildlife Refuge: How The Upper Peninsula Led Wildlife Conservation In The Beginning Of The Twentieth Century, Holly A. Galligan

HS 390 Primary Research Papers

The research presented in this paper will weave together the story of how the Upper Peninsula became a crucial hub for wildlife conservation in the first half of the twentieth century. Seeking to answer the question of how and why this occurred, as well as why it is distinct from the social movement of the 1960s, the research is based on public awareness, photographic research developments, and the concept of the national system for conservation. Hunting played the main role in the motivations for this movement therefore, it is also heavily discussed throughout. The previous research on this subject emerged …

Grosafe: In-Classroom Technology-Enabled Solution To Build Societal Resilience Against Child Grooming, Christina Thorpe, Fiona Jennings

Conference Papers

GroSafe is an innovative initiative developed by TU Dublin in partnership with the ISPCC to address the critical issue of child grooming. By leveraging cutting-edge digital technologies, GroSafe focuses on educating children, caregivers, and educators to recognise, report, and prevent grooming behaviours. It integrates a 3D educational gaming environment with adaptive learning tools, enabling safe and effective engagement for children, including those with diverse learning needs. Designed to align with Ireland’s SPHE curriculum, GroSafe empowers schools and communities to tackle grooming through early intervention and resilience building.

Multiple And Nonexistence Of Positive Solutions For A Class Of Fractional Differential Equations With P-Laplacian Operator, Haoran Zhang, Zhaocai Hao, Martin Bohner

Mathematics and Statistics Faculty Research & Creative Works

Research about multiple positive solutions for fractional differential equations is very important. Based on some outstanding results reported in this field, this paper continues the focus on this topic. By using the properties of the Green function and generalized Avery–Henderson fixed point theorem, we derive three positive solutions of a class of fractional differential equations with a p-Laplacian operator. We also study the nonexistence of positive solutions to the eigenvalue problem of the equation. Three examples are given to illustrate our main result.

Reaction Of A Chiral Platinum Triamine Compound With Key Amino Acid And Guanine Analog, Onu Emmanuel Chukwu

Masters Theses & Specialist Projects

Platinum compounds can exhibit cytotoxic activity through reaction with DNA; however, interaction with proteins and DNA bases, especially with methionine residues and Guanine analogs, is another common biological reaction. Our lab has synthesized Chloro[2-(4-Methyl-1,4- diazepan-1-yl) ethanamine]platinum(II) chloride ([Pt(L)Cl]Cl), which has a tridentate binding mode for the amine ligand. This study focused on the reaction of the chiral platinum triamine with key amino acids (methionine and 2-hydroxybutyric acid) and guanine analogs under different pH and temperature conditions. The mass spectrometry of N-AcMet Interaction with [Pt(L)Cl]+ showed a m/z of 542 and 579 for reactions at pH 4. The m/z of 542 …

Western Australian Soil Groups - A Diagnostic Key To Identify Soils In Western Australia (5th Edition), Paul Galloway, Dennis Van Gool, Angela Stuart-Street, Edward A. Griffin, Shahab Pathan, Noel R. Schoknecht

Resource management technical reports

The aim of the Western Australian soil groups (WA soil groups) is to classify soils of Western Australia into a limited set using criteria that are easy to recognise in the field. It is a general-purpose classification with a focus on agronomic and rangeland grazing potential. The WA soil groups are designed for WA needs. It complements the Australian Soil Classification (ASC) by grouping the continuum of soils into a limited set of soil types, which simplifies soil variability for generalists, allows soil surveyors to create standardised soil-type legends for mapping products and permits further analyses of spatial data for …

(R2100) Optimality Conditions Of A Topsis Optimization Model And Its Application On Interval-Valued Data, Sudipta Roy, Sandip Chatterjee

Applications and Applied Mathematics: An International Journal (AAM)

The Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS) is widely used in the field of multi-criteria decision analysis. Despite its popularity and widespread application, little attention has been given to the mathematical foundation that underlies the TOPSIS algorithm. The existing literature on this subject is far from comprehensive, leaving many aspects of the algorithm unexplored. This paper aims to address this gap in the literature by delving into the optimization problem associated with TOPSIS. Unlike traditional interval analysis theory, which only covers a limited scope, our approach extends to a broader range of scenarios and offers …

(R2111) Effect Of Stenotic-Aneurysmal Arterial Regime On Unsteady Magnetohydrodynamic Non-Newtonian Blood Flow With Heat Radiation, Babatunde A. Joseph, Dada M. Sunday, Bello A.J. Funsho, Akeem B. Disu, Alamu-Awoniran F., Danas James Y.

Applications and Applied Mathematics: An International Journal (AAM)

The study aims to investigate the effect of magneto-hydrodynamic on a non-Newtonian unsteady blood flow with internal heat energy in the presence of blood ironic properties characterized by stenosis. The formulated mathematical equations resulted in differential forms and were solved analytically by Differential Transform Method. The obtained solutions were displayed by graphs showing different flow physiognomies like blood velocity, temperature profile, Nusselt number, wall shear stress and stream function.

The results indicated that velocity profile increases as magnetic field, Darcy number and aneurysmal artery rise, while it decreases as heat radiation, Reynold number, and Casson parameter speedup. The temperature profile …

Using Llms To Establish Implicit User Sentiment Of Software Desirability, Sherri Weitl-Harms, John D. Hastings, Jonah Lum

Research & Publications

This study explores the use of LLMs for providing quantitative zero-shot sentiment analysis of implicit software desirability, addressing a critical challenge in product evaluation where traditional review scores, though convenient, fail to capture the richness of qualitative user feedback. Innovations include establishing a method that 1) works with qualitative user experience data without the need for explicit review scores, 2) focuses on implicit user satisfaction, and 3) provides scaled numerical sentiment analysis, offering a more nuanced understanding of user sentiment, instead of simply classifying sentiment as positive, neutral, or negative.

Data is collected using the Microsoft Product Desirability Toolkit (PDT), …

Northern Great Plains Native Seed Strategy, Lora Perkins, Amy Symstad, Jennifer Zavaleta-Cheek, Emily Rohrer, Krista Ehlert

Native Plant Initiative Newsletters and Reports

Developed by the Northern Great Plains Native Seed Partnership

A New Reduced Basis Method For Parabolic Equations Based On Single-Eigenvalue Acceleration, Qijia Zhai, Qingguo Hong, Xiaoping Xie

Mathematics and Statistics Faculty Research & Creative Works

In this paper, we develop a new reduced basis (RB) method, named as Single Eigenvalue Acceleration Method (SEAM), for second order parabolic equations with homogeneous Dirichlet boundary conditions. The high-fidelity numerical method adopts the backward Euler scheme and conforming simplicial finite elements for the temporal and spatial discretizations, respectively. Under the assumption that the time step size is sufficiently small, and time steps are not very large, we show that the singular value distribution of the high-fidelity solution matrix U is close to that of a rank one matrix. We select the eigenfunction associated to the principal eigenvalue of the …

Photogeneration, Characterization, And Kinetic Study Of A New Phthalocyanine Species, Sobenna Onyeso

Masters Theses & Specialist Projects

In the search for green chemistry, the development of synthetic metal complexes that model enzyme function has been extensively studied. Phthalocyanine metal complexes, closely related to these heme-containing macrocycles, have gained continued interest due to their ease of direct synthesis, efficient redox, and optical properties. Despite the significant progress in phthalocyanine metal complexes, much more work needs to be done in the characterization and identification of their metal-oxo species, as well as mechanistic insights into their catalytic oxidations. To date, the reactivity of metal-oxo species on phthalocyanine platforms has not been probed.

In this study, metal phthalocyanine complexes have been …

Classroom To Console, Ashton Headley

ART 108: Introduction to Games Studies

In an era where technology is continuously growing and intertwined into daily life, the field of education has seen drastic changes and innovation. Including changes we see today, with the ability to connect to class online, procter tests, submit assignments etc. And amongst these innovations, educational games have surfaced as a resource for helping learners across various age groups. By merging entertainment/gamification with educational content, these games offer an interactive and entertaining approach to acquiring knowledge and learning essential or non-essential skills. Whether it is implemented in classrooms, workplaces, or home settings, educational games are transforming the educational environment effectively …

The Impacts Of Seasonality And Nutrient Loading On Microcystis Bloom Development In Wall Pond, Alyssa Antolak

Bridges: A Journal of Student Research

The harmful cyanobacteria Microcystis dominates eutrophic freshwater systems globally. Eutrophication leading to nitrogen and phosphorus loading into aquatic systems is increasing bloom propagation and shifting diatom/dinoflagellate dominated systems to cyanobacteria dominated systems. Understanding seasonal variability and environmental parameters combined with nutrient loading will allow for better understanding of what factors are influencing Microcystis blooms. Biweekly plankton samples and environmental parameters were collected from Wall Pond on campus from spring 2022-spring 2023. Results show that yearly plankton samples shifted from Microcystis dominated in the early summer to diatom dominated in the late summer-early fall, then back to Microcystis dominated in late …

Are Rising Seas Pushing Ghost Crabs Out Of Their Comfort Zone?, Finn Gillette

Bridges: A Journal of Student Research

Ghost crabs (Ocypode quadrata) can be found on sandy beaches bordering the western Atlantic Ocean. These semiterrestrial crustaceans are often found between the swash zone and the dunes on beaches. Dunes are critical refuges for ghost crabs during storms and extreme tide events. This makes them a useful indicator species for monitoring the effects of global warming-induced sea level rise on beach biota, as their distribution patterns among beach zones may correlate with shifts found in other species. Beach surveys conducted from 2015 onward assessed the population density of ghost crabs on beaches of Horry and Georgetown counties in South …

Draft Management Plan For The South Coast Scallop Managed Fishery, Department Of Primary Industries And Regional Development, Western Australia

Fisheries Management Papers

The Minister for Fisheries (Minister) intends to transition the South Coast Trawl Fishery (SCTF) to formal management by determining a management plan for the fishery in accordance with section 54(1) of the Fish Resources Management Act 1994 (FRMA).

Section 54(1) of FRMA provides for the Minister to determine by instrument in writing published in the Government Gazette, a management plan for a fishery. Not less than two months prior to determining a management plan, the Minister must, in accordance with section 64(2) of FRMA, prepare a draft of the plan and by notice in the Gazette, state their intent to …

Curbing Environmental Degradation To Balance Sustainable Development: Evidence From China, Muneza Kagzi, Vishal Dagar, Nadia Doytch, Deepika Krishnan, Manisha Raj

Ateneo School of Government Publications

To achieve the goals of sustainable development, it is crucial to check the balance of increased level of international trade along with financial development, foreign direct investment (FDI), energy consumption, and institutional advancement with the quality of the environment. This study focuses on how these variables have caused environmental degradation in China. To achieve Goal 13 of the Sustainable Development Goals (SDGs), i.e. to increase the nation's resilience to natural disasters and hazards related to climate change, to promote climate action and safeguard life as part of sustainable development, this involves the analysis of time-series data sets from 1975 to …

Ethics And Environmental Impact Of Video Games, Anushka Chokshi

ART 108: Introduction to Games Studies

As video games grow in popularity, concerns regarding their ethical and environmental implications are brought up. While once, topics like their impact on child development or harm to Earth might have been considered minor or irrelevant, these concerns are now voiced in numerous articles across the internet, amplifying the urgency to develop games in an ethical context before matters are blown out of proportion. For the purposes of exploring both past and present views, this work draws from older and newer sources surrounding many topics on the idea of game development in the video game industry. Essentially, video game development …

Multi-Criteria Decision-Making Approach Based On Correlation Coefficient For Multi-Polar Interval-Valued Neutrosophic Soft Set, Hamza Naveed, Saalam Ali

Neutrosophic Systems with Applications

The correlation coefficient between two factors is crucial in statistical computation, indicating the extent and evolution of the appropriate link. The precision of applicability evaluations frequently relies on the thoroughness and caliber of data obtained from a certain dataset. Statistical research sometimes entails data marked by intrinsic trade-offs and uncertainty. This study seeks to present m-polar interval-valued neutrosophic soft sets (mPIVNSSs) through the integration of m-polar fuzzy sets with interval-valued neutrosophic soft sets. The suggested mPIVNSS structure is a significantly generalized version of m-polar neutrosophic soft sets and serves as a substantial extension of interval-valued neutrosophic soft sets. In this …

Neutrosophic Cox Proportional Hazards Model For Robust Variable Selection In Survival Analysis, Ibrahim Yasser, Aya A. Abd El-Khalek, A. A. Salama, Doaa A. Abdo

Neutrosophic Systems with Applications

This paper introduces a novel approach for variable selection in survival analysis by integrating neutrosophic logic into the Cox Proportional Hazards (Cox PH) model to address the limitations of recent studies related to high dimensionality. Neutrosophic logic, is a mathematical framework that allows for uncertainty, indeterminacy, and inconsistency, and particularly well suited for handling the complexity and often-ambiguous nature of biological data. By incorporating neutrosophic sets into the Cox PH model, we aim to enhance model robustness, improve variable selection, and address the curse of dimensionality. We compare the performance of the neutrosophic-enhanced Cox PH model with traditional variable selection …

On Neutrosophic Pδs-Irresolute Functions In Neutrosophic Topological Spaces, Bishnupada Debnath, Anjan Mukherjee

Neutrosophic Systems with Applications

In general topology the notion of pds-irresolute and aδs-irresolute functions were introduced by Beceren and Noiri. In the present paper, these concepts of pδs-irresolute (briefly, Npδs-irresolute) and aδs-irresolute (briefly, Naδs-irresolute) functions are explored for the first time in neutrosophic topological spaces (NTS) as generalized version. We proved that every Naδs-irresolute function is Npδs-irresolute function but not conversely. Some characterizations, counter examples, and fundamental features are also presented. By neutrosophic pre-open, neutrosophic δ-open, and neutrosophic δ-semi-open sets, some new fundamental properties of such functions are provided. Furthermore, under Npδs-irresolute functions, the behavior of neutrosophic semi-connected, neutrosophic pre-connected, neutrosophic pre-T2, neutrosophic δ-semi-T2, …

Analysis Of Bck/Bci-Algebras Based On Bipolar Complex Intuitionistic Fuzzy Soft Ideals, Zeeshan Ali

Neutrosophic Systems with Applications

In this article, we design an informative and reliable technique of bipolar complex intuitionistic fuzzy soft sets with numerous operational laws by merging the model of soft sets, complex fuzzy sets, and bipolar intuitionistic fuzzy sets to handle imprecise data. In addition, an ideal in a BCK-algebra is derived based on bipolar complex intuitionistic fuzzy soft set theory are proposed which can capture the information of hesitancy, vagueness, and non-membership information within the circumstance of BCK-algebra. Moreover, we design union, intersection, AND, and OR based on bipolar complex intuitionistic fuzzy soft ideal and simplify it with the help of numerous …