Physical Sciences and Mathematics Commons^™

Uc-184 Onaccount A Web-Based Accounting Software, Manuel A Jackson, Russell E Steele, Grzegorz Loj, Zachary B Powell

C-Day Computing Showcase

This project streamline and improve the efficiency of the whole accounting process, by using current best practices for user interaction engineering and current design practices. Our software should be able to provide secure, user-friendly, and accessible financial management solutions anywhere and everywhere through various devices including desktop and mobile. Allowing users to manage their accounts whenever it seems necessary while still maintaining a high level of security. The project is inspired by the various complexity and problems regarding the accounting process in the real world such as financial reporting, miscalculations, and data security; by streamlining this process and making it …

Tubarr: A Self-Hosted Video Archiver, Joshua Sheputa

Honors Program Theses and Projects

Over the past few years, I’ve been slowly expanding my homelab, a personal setup for me to experiment with software, hardware, and deployment configurations. One driving force behind this is my desire to digitize and save anything that is important to me or that I want easy access to. I started with my family’s old CD collection, then moved on to any Blu-rays movie discs we had. Eventually, I started thinking about what else I care about and don’t want to lose track of. This brought me to the thought that any YouTube video that I may want to revisit …

Two Decades Of Climate Measurements Reveal El Niño's Role In Andean Elevation-Dependent Warming, Luke Davies

Honors Program Theses and Projects

Driven by climate change, elevation-dependent warming (EDW) has become a critical issue in the Cordillera Blanca of Peru. This study focuses on gathering evidence of EDW and determining the relationship between El Niño Southern Oscillation (ENSO) events and micrometeorological forcing in two proglacial valleys. A climate monitoring network was maintained through a 20-year collaboration between Bridgewater State University (BSU), Universidad Nacional Santiago Antúnez de Mayolo (UNASAM), and the Autoridad Nacional de Agua (ANA). Fieldwork in June 2023 and June 2024 included repairing weather stations, installing new Lascar sensors, and downloading data loggers to sustain and improve the climate record. Data …

Probing The Interactions Of Anticancer Drug Doxorubicin To Dna Using Optical Tweezers, Jason Martin

Honors Program Theses and Projects

Doxorubicin (Doxo) is a historically significant anti-cancer drug that has been used to treat multiple types of cancers for half a century. The drug targets DNA of cancer cells through a binding mode called intercalation, acting as roadblock during DNA replication to stop tumor formation. While Doxo has been extensively studied through traditional methods, only a handful of research has utilized single molecule methods, which can provide new insights at the molecular level. In this study, we used dual beam optical tweezers to isolate single DNA molecules and mechanically manipulate the DNA in the presence of Doxo. We conducted two …

Synthesis, Characterization, And Investigation Of Photochemical And In Vitro Properties Of Novel Zn(Ii) Phthalocyanine, Yasemi̇n Bayğu Yildiz, Ni̇lgün Kabay, Burak Yildiz, İpek Ömeroğlu, Mahmut Durmuş, E. Riza Karagür, Hakan Akça, Çağri Ergi̇n, Yaşar Gök

Turkish Journal of Chemistry

In our work, a new non-peripheral zinc(II) phthalocyanine bearing octa carboxylic acid ethyl ester derivative substituted triazole attached propylmercaptothiobenzylmercapto derivative was synthesized by the tetramerization reaction of phthalonitrile. The photochemical in vitro photodynamic activity of zinc(II) phthalocyanine (ZnPc-I), such as human non-small cell lung carcinoma cell lines, was investigated in this study. The singlet oxygen generation property of novel zinc(II) phthalocyanine (ZnPc-I) was also examined due to the significantly high singlet oxygen quantum yield of ZnPc-I (ΦΔ = 0.66). The antiproliferative effects of ZnPc-I were also investigated on A549 and H1299 cell lines, our results demonstrate that the ZnPc-I has …

Synthesis, Structure, Hirshfeld Surface Analysis, And Molecular Docking Studies Of The Cocrystal Between The Cu(Ii) Complex Of Salicylic Acid And Uncoordinated Piracetam, Nazokat N. Yuldasheva, Ikram I. Abdullaev, Oybek I. Khudoyberganov, Lola A. Gandjaeva, Pirnazar K. Kodamboev, Elyor Sh. Samandarov, Adkhamjon S. Normamatov, Abror Kh. Ruzmetov, Yuldosh Y. Yakubov, C. Balakrishnan, Bakhtiyar T. Ibragimov, Aziz Bakhti̇yarovich Ibragimov

Turkish Journal of Chemistry

The cocrystal or supramolecular complex between Cu(II) complex of salicylic acid and uncoordinated piracetam has been synthesized. Its structure is characterized by element analysis, FT-IR, UV-Visible spectroscopy and X-ray crystallography. Spectroscopic methods confirm the formation of the metal complex while X-ray crystallography establishes molecular and crystal structure of the obtained compound. Binuclear Cu(II) complex of salicylic acid (complex molecule) is in the form of “Chinese lantern” and it interacts with uncoordinated piracetam by complicated system of H-bonds. However, according to the Hirshfeld surface analysis a contribution of the O•••H/H•••O contacts is only 24.9% while H•••H and H•••C/C•••H contacts account for …

Preparation Of Manganese-Doped Carbon Quantum Dots@Halloysite Nanotubes Composites Films For Advanced Uv Shielding Properties, Xiao Zhang, Bin Wang

Turkish Journal of Chemistry

The development of Ultraviolet (UV) shielding materials are of great importance to protect human's health concerns and prevent the degradation of organic matters. However, the synthesis of highly efficient UV shielding polymer nanocomposites is currently limited by the agglomeration of inorganic anti-UV nanoparticles (NPs) within the polymer matrix and limited absorption spectrum of UV shielding agents. In this study, highly effective manganese doped carbon quantum dots@halloysite nanotubes composites (Mn-CDs@HNTs/PAS) were successfully synthesized by loading manganese doped carbon quantum dot (Mn-CDs) into UV shielding effective halloysite nanotubes (HNTs) via solvothermal method, followed by polymerization modification. The results show that inorganic NPs …

A Fast And Responsive Turn-On Fluorescent Probe Based On A Quinone Conjugated Alkoxy Derivative For Biothiols And A Cellular Imaging Study, Ulviyye Nemetova, Ayşe Nur Önem, Alev Er, Sefa Çeli̇k, Ayşen E. Özel, Sevi̇m Akyüz, Mustafa Özyürek, Si̇bel Şahi̇nler Ayla

Turkish Journal of Chemistry

Detection of intracellular biothiols (cysteine (CYS), N-acetyl cysteine (NAC) and glutathione (GSH)) with high-selectivity and sensitivity is important to reveal biological functions. In this study, 2-(2-methoxy-4-methylphenoxy)-3-chloro-5,8-dihydroxynaphthalene-1,4-dione (3) (DDN-O) compound was newly synthesized and used as a fluorogenic probe (detector molecule) in the fluorometric method for the rapid, highly selective and sensitive determination of biothiols. The intensity values (λex = 260 nm, λem = 620 nm) of the product were measured by adding biotihols to the reaction medium at varying concentrations and the glutathione equivalent thiol content (GETC) values of each biotiol were calculated. Using the compoud (3), the reference biotiol …

Understanding Ammonia's Role In Mitigating Concentration Polarization In Anion-Exchange Membrane Electrodialysis, Abdallah Timmaoui, Mahmoud Ferhat, Nesri̇ne Souad Ferhat, Ahmed Hamdi

Turkish Journal of Chemistry

In processes such as electrodialysis, the applied electrical potential is constrained by concentration polarization at the membrane/solution interface. This polarization, which intensifies at higher current densities, impedes ion transport efficiency and may lead to problems such as salt precipitation, membrane degradation, and increased energy consumption. Therefore, understanding concentration polarization is essential for enhancing membrane performance, improving efficiency, and reducing operational costs. This study investigates the impact of ammonia buffer (NH₄⁺/NH₃) on sulfate ion transport through anion-exchange membranes, with a particular focus on limiting current density and concentration polarization under constant current conditions. Our findings demonstrate that ammonia effectively eliminates concentration …

New Naphthalene-Linked Pyrazoline-Thiazole Hybrids As Prominent Antilung And Antibreast Cancer Inhibitors, Hali̇li̇brahi̇m Çi̇ftçi̇, Masami Otsuka, Mikako Fujita, Belgi̇n Sever

Turkish Journal of Chemistry

Epidermal growth factor receptor (EGFR) and HER2, pioneer members of the receptor tyrosine kinase subfamily, are frequently mutated and/or overexpressed in several types of human cancers, including non-small cell lung cancer (NSCLC) and breast cancer, which are leading causes of cancer-related deaths worldwide. EGFR and HER2-focused anti-NSCLC and anti-breast cancer studies encouraged us to search for new potential agents. For this purpose, in the current work, naphthalene-linked pyrazoline-thiazole hybrids (BTT1-10 and BTP1-10) were synthesized and examined for their antiproliferative effects on A549 NSCLC and MCF-7 breast cancer cell lines. According to the results, MTT assay showed that BTT-5 induced strong …

Analysis And Optimization Of The Adsorption Of Lead Ions On A New Material Based On Silica Synthesized From Blast Furnace Slag, Toufik Chouchane, Ouahida Khireddine, Sabiha Chouchane, Mohamed Tayeb Abedghars, Hazem Meradi

Turkish Journal of Chemistry

A novel silica-based material (SBM), synthesized from chemically, thermally, and mechanically treated blast furnace slag (TBFS), was examined for its batch-mode lead adsorption capacity, based on various parameters. Physico-chemical examinations revealed that the formulation of the new material (SBM) consists mainly of silica, which represents 81.79% of its total composition. After modification, the measured specific surface area changed significantly, from 275.8 to 480.13 m2/g, with a point of zero charge (PZC) of approximately 3.4 on the pH scale. The experiment revealed that the driving factors (contact time, stirring speed, solution pH, temperature, and initial concentration) greatly influenced the improvement of …

2024 December 19 - Tennessee Weekly Drought Summary, Tennessee Climate Office, East Tennessee State University

Tennessee Climate Office Weekly Drought Summaries

No abstract provided.

Geochemical Characterization And Predictive Soil Mapping Of Ice-Free Regions In Antarctica, Rachel Willmore

Theses and Dissertations

Antarctic soils are formed by extreme climate, minimal biological activity, and diverse geological settings. This study analyzes 201 soil samples across four ice-free Antarctic Conservation Biogeographic Regions - North-west Antarctic Peninsula, Transantarctic Mountains, South Victoria Land, and North Victoria Land - to create a geochemical database (pH, EC, CEC, C and N, and ion concentrations) as well as to determine if there are consistent trends between geochemical properties and soil forming factors (SCORPAN). Despite variation in geochemical properties and SCORPAN covariates, some consistent trends emerged across all regions and individual Antarctic Conservation Biogeographic Regions. Using SCORPAN covariates and multiple linear …

Butte Priority Soils Operable Unit (Bpsou) Unreclaimed Sites And Insufficiently Reclaimed Areas – Racetrack Borrow Material Usage, Mike Mcanulty

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Contributions Of Glacier Meltwater To Water Resources And Water Quality Below The Ablating Coropuna Ice Cap In The Arid Peruvian Andes, Alexis Rowley

Theses and Dissertations

Rapidly retreating glaciers in the arid tropics are an invaluable resource for communities that depend on meltwater to support drinking water, agriculture, hydropower production, and mining. There is limited understanding of how glacier loss will impact regional water resources, groundwater flow paths, and water quality, especially during the dry season. The Nevado Coropuna volcano in Southern Peru has one of the largest remaining ice caps in the tropics, but has experienced rapid ice loss in the past few decades and is projected to disappear in the next century due to climate change. Located in the northern Atacama Desert, the arid …

Using Two-Dimensional Terahertz Spectroscopy To Explore Vibrations, Magnetism, And Their Coupling, Megan Faux Biggs

Theses and Dissertations

Terahertz (THz) light is at the resonant frequency of important fundamental excitations within crystalline materials such as carrier dynamics, phonons, and spin-wave excitations called magnons. THz light can be produced at high field strengths using optical rectification in nonlinear optical (NLO) crystals. N-benzyl-2-methyl-4-nitroaniline (BNA) is one such crystal commonly used to produce THz when pumping with 800 nm light. Here, we improve upon the design of the molecular building blocks of BNA by replacing a hydrogen atom with a fluorine atom, leading to improved THz generation and a higher crystal damage threshold. Later, we focus on using THz light to …

Racial And Ethnic Differences In Outcomes Of Neonates Born At Less Than 30 Weeks' Gestation, 2018-2022, Nansi S. Boghossian, Marco Geraci, Erika M. Edwards, Jeffrey D. Horbar

Faculty Publications

Importance: Previous research has examined outcomes among very preterm newborns by the birthing parent's race and ethnicity, but knowledge about these trends during the COVID-19 pandemic is limited. Objective: To examine trends in outcomes among Black, Hispanic, and Asian preterm newborns compared with White preterm newborns. Design, Setting, and Participants: This cohort study (2018-2022) took place at 774 neonatal intensive care units in the Vermont Oxford Network. Participants were newborns born at 22 to 29 weeks' gestation. Exposure: Race and ethnicity. Main Outcomes and Measures: The primary outcomes were mortality and complications, including respiratory distress syndrome, necrotizing enterocolitis (NEC), early-onset …

Navigating Transdisciplinary Communication: A Graduate Student's Perspective, Sirimuvva Pathikonda, James Lipuma, Cristo Leon

STEM for Success Resources

Discover "Navigating Transdisciplinary Communication: A Graduate Student’s Perspective," a comprehensive exploration of how diverse disciplines converge to tackle complex challenges. This study, presented at WMSCI 2024, employs a Constructivist lens to highlight the co-construction of knowledge, innovative teamwork tools, and practical strategies for research in STEM and beyond. Co-authored by Sirimuvva Pathikonda, MEM, and James Lipuma, Ph.D., the paper underscores the value of Transdisciplinary Communication (TDC) in fostering collaboration, innovation, and holistic problem-solving across fields. Read the full article here: https://doi.org/10.54808/JSCI.22.06.151.

New Chapters In An Old Book: New Discoveries In Transferrin's Blood Stream Modulators And Analytical Methods, Shelby Thomas Harris

Theses and Dissertations

Human serum transferrin is a 79 kDa glycoprotein responsible for the safe transport of iron throughout the blood stream. Transferrin binds up to two ferric ions in two domains known as the N-lobe and C-lobe respectively. Thus, there are four transferrin metalloforms: apo-Tf (with no iron bound), FeN-Tf (with one iron bound in the N-lobe), FeC-Tf (with one iron bound in the C-lobe) and holo-Tf(with two iron ions bound, one in each of the lobes). The two domains are homologous but feature differences in the kinetics and thermodynamics of iron binding and release. The two lobes are also different in …

Integrating Criminological Theories In Cybersecurity Risk Assessment: A Study Of The Traci Framework's Application To Critical Infrastructure, Connor S. Martin

Doctoral Dissertations and Projects

This dissertation explores the application of the Taxonomy for Risk Assessment of Cyberattacks on Critical Infrastructure (TRACI) framework, a tool designed to systematically evaluate cybersecurity threats against critical infrastructure. TRACI integrates principles from Routine Activity and Rational Choice Theories to provide a detailed and comprehensive understanding of cybersecurity risks. This integration facilitates an in-depth analysis not only of how cyberattacks occur but also of the underlying reasons they are initiated, by categorizing and assessing risks based on factors such as attacker motivations and systemic vulnerabilities. By employing ANOVA to assess variations in risk assessment scores across TRACI's designated categories—Assets, Risk …

Unquantifiable: The Impacts Of Len Vacher, Victor J. Ricchezza, Nathan D. Grawe

Numeracy

This article celebrates H.L. (Len) Vacher, the founding editor of Numeracy. While many readers of this journal are no doubt familiar with Len’s contributions here and to quantitative literacy as a practice and habit of mind, fewer are intimately familiar with Len’s history and impacts as a professor and colleague. This paper analyzes Len's contributions to the advancement of quantitative literacy through his scholarship in the journal and through the careers of former students and colleagues at the University of South Florida. The former observations originate in interview data originally collected as part of research on Len’s computational geology course …

Time Reversal Delivery Of Long Duration Noise To A Targeted Location: Achieving Higher Amplitude While Maintaining A Desired Spectral Shape And Maximizing The Spatial Extent, Rylee Scott Russell

Theses and Dissertations

Time Reversal (TR) is a signal processing technique that can be used to focus acoustic waves to a specific location in space, with most applications aiming to create an impulsive focus. This study instead aims to focus long-duration noise signals using TR. This thesis seeks to generate higher amplitude noise at a desired location over an existing method of broadcasting equalized noise. Additionally, this thesis explores various characteristics associated with focusing long duration noise using TR. The dependence of the focal amplitude on the duration of the focused signal is explored as well as the implications of using multiple sources …

Capacity-Weighted Figures-Of-Merit For Battery Transport Metrics, Cj Sturgill, Christopher Sutton, Julian Schwenzel, Morgan Stefik

Faculty Publications

New battery materials with improved transport are needed. Typical measurements yield widely varying voltage-dependent diffusivities and reporting practices are diverse. Some materials (e.g. first-order phase change) have most redox occur at a specific voltage and may be sufficiently represented by singular transport metrics. Many rapid intercalation materials, however, exhibit second-order phase transitions with redox over a broad voltage range. How should such cases be compared? The use of capacity-weighted average values is suggested where voltage-dependent metrics are consolidated into representative descriptors as figures-of-merit. Examples are elaborated where differential capacity (dQ/dV) is used to derive a …

Re: Approval Letter For The Butte Priority Soils Operable Unit (Bpsou) Butte Reduction Works (Brw) Phase Ii Interim Demolition Plan Construction Drawings And Floodplain Encroachment Analysis (Dated November 27, 2024), Emma Rott

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Synthesis Of Higher-Order Catenanes And Catenane-Based Materials, Gray Harlan

Arts & Sciences Graduate Student Theses and Dissertations

Catenanes are a subset of mechanically interlocked molecules (MIMs) and are composed of interlocked rings that can be oriented linearly, radially, or branched. A defining feature of all MIMs is that they are bound through their architectures consisting of mechanical bonds, leading to unique topologies. Catenanes have attracted interest due to their stimuli-responsive behavior and the degrees of freedom afforded by the mechanical bond, a feature which is absent with standard covalent bonds. The stimuli responsiveness of catenanes arises from their templated syntheses, where two or more pre-macrocycles are brought together by a driving force. Various templation strategies rely on …

Using Bivalves As An Indicator For Fecal Bacteria, Kamala Chuss

Honors Scholar Theses

This project focuses on the integration of fecal bacteria from warm-blooded animals into bivalve tissue, and the utilization of bivalves as an indicator for fecal bacteria in waterways. Bivalves may give a more representative long-term average of fecal bacteria in water as compared to direct water testing. The primary objective is to create a standard operating procedure to use bacterial testing of bivalves as a proxy for bacteria concentration in the water. This method can be used in places where bivalves do not already exist by adding them to a body of water, or by collecting bivalves that already exist …

Grain Boundary Solute Segregation Across The 5d Space Of Crystallographic Character, Lydia Harris Serafin

Theses and Dissertations

Solute segregation in materials with grain boundaries (GBs) has emerged as a popular method to thermodynamically stabilize nanocrystalline structures. However, the impact of varied GB crystallographic character on solute segregation has never been thoroughly examined. This work examines Co solute segregation in a dataset of 7272 Al bicrystal GBs that span the 5D space of GB crystallographic character. Considerable attention is paid to verification of the calculations in the diverse and large set of GBs. In addition, the results of this work are favorably validated against similar bicrystal and polycrystal simulations. As with other work, we show that Co atoms …

Feasibility Of Large Language Models For Ceus Li-Rads Categorization Of Small Liver Nodules In Patients At Risk For Hepatocellular Carcinoma, Jiayan Huang, Rui Yang, Xiaotong Huang, Keyu Zeng, Yan Liu, Jun Luo, Andrej Lyshchik, Qiang Lu

Department of Radiology Faculty Papers

BACKGROUND: Large language models (LLMs) offer opportunities to enhance radiological applications, but their performance in handling complex tasks remains insufficiently investigated.

PURPOSE: To evaluate the performance of LLMs integrated with Contrast-enhanced Ultrasound Liver Imaging Reporting and Data System (CEUS LI-RADS) in diagnosing small (≤20mm) hepatocellular carcinoma (sHCC) in high-risk patients.

MATERIALS AND METHODS: From November 2014 to December 2023, high-risk HCC patients with untreated small (≤20mm) focal liver lesions (sFLLs), were included in this retrospective study. ChatGPT-4.0, ChatGPT-4o, ChatGPT-4o mini, and Google Gemini were integrated with imaging features from structured CEUS LI-RADS reports to assess their diagnostic performance for sHCC. …

A Topological Route To Engineering Robust And Bright Supersymmetric Laser Arrays, Soujanya Datta, Mohammad Alizadeh Fard, Ramy El-Ganainy, Krishanu Roychowdhury

Michigan Tech Publications

In recent years, several proposals that leverage principles from condensed matter and high-energy physics for engineering laser arrays have been put forward. The most important among these concepts are topology, which enables the construction of robust zero-mode laser devices, and supersymmetry (SUSY), which holds the potential for achieving phase locking in laser arrays. In this work, we show that the relation between supersymmetric coupled bosonic and fermionic oscillators on one side, and bipartite networks (and hence chiral symmetry) on another side can be exploited together with non-Hermitian engineering for building one- and two-dimensional laser arrays with in-phase synchronization. To demonstrate …

Schedulability Analysis Of Multi-Phase Limited-Preemption Tasks, Benjamin Standaert

McKelvey School of Engineering Graduate Student Theses & Dissertations

This work addresses hard real-time systems, in which tasks must be scheduled so that they are guaranteed to meet deadlines. In particular, when tasks execute across multiple domains with high preemption costs, the combined cost of these preemptions can cause the system to become unschedulable. The number of preemptions must therefore be bounded to limit the overall task execution time, while ensuring that task blocking times are small enough to allow the system to be schedulable. Prior work introduces the Multi-Phase Secure model, which describes a more exact version of this scenario, and an algorithm to determine schedulability of sporadic …