Physical Sciences and Mathematics Commons^™

Biomechanics Of The Atherosclerotic Lipidome: (Un)Expected Statin Interactions And Membrane Remodelling, Ethan M. Fong

Pomona Senior Theses

Statins interact with lipid membranes in ways that shape their pharmacokinetics, off-target effects, and pleiotropic actions, yet these interactions' mechanical and biophysical consequences remain poorly understood. This thesis employs a combination of surface plasmon resonance (SPR), quartz crystal microbalance with dissipation monitoring (QCM-D), and rheological modelling to characterize how representative statins intercalate within biomimetic supported lipid bilayers (SLBs) of healthy and diseased composition. SPR reveals that lipophilic statins exhibit higher apparent affinities and slower dissociation kinetics, especially in cholesterol- and anionic lipid-rich membranes. QCM-D analyses demonstrate that statins alter membrane mass, dissipation, and interfacial stiffness in a statin- and membrane-dependent …

Analysis Of Early Interventions To Retain Underrepresented Students In Computer Science, Michael Conti

Open Access Dissertations

Computer science, like many STEM disciplines, faces persistent challenges in recruiting and retaining women and individuals from racially and ethnically minoritized backgrounds. This study examines whether targeted interventions can produce sustained improvements in academic performance and sense of belonging among these underrepresented groups. By analyzing longitudinal data, this research aims to evaluate the effectiveness of these interventions in promoting equity and persistence in computer science education.

The Tyrant King Of The Auction House: The Disastrous “Fine Artification” Of The Dinosaur, Amelia C. Kolstad

Anthós

This article examines how fine art auctioneers market dinosaur fossils as art pieces to wealthy collectors, depriving the paleontological field of specimens for scientific research. Drawing from recent examples of fossils sold at fine art auctions, this article notes how rising auction prices for specimens as ‘art’ prevent museums and research institutions from acquiring specimens for research and restoration. Kolstad concludes that the art auction houses’ marketing of fossils as art is detrimental to paleontological research. To protect fossils and their scientific value, Kolstad proposes alternatives, such as selling replicas to collectors and highlighting the importance of original specimens for …

Sealing The Deal: A Case Study Of A Private, Southeastern, Regional College’S Student Onboarding Practices, Alicia R. Gaston, Kristen Meyer, Tyler Ogden, Jennifer Perkinson, Casey Yocum Michaels

Doctor of Education Capstones

Each year, higher education institutions offer support to new, incoming students through an onboarding process that requires dedication and collaboration across multiple departments. Offering streamlined guidance and clear communication throughout the onboarding process is essential to ensure incoming students understand action steps without becoming overwhelmed with new terminology, processes, and environments. This explanatory case study is set to understand the current communication practices and technology use across onboarding departments at Brightside College – also referred to as Brightside or BC (pseudonym). The research team aimed to understand Brightside's onboarding staff's perspective of current processes and practices. With emphasis on the …

Integrated Pest Management: State Infrastructure Status After 50 Yr Of Federal Support (1973 To 2023), Daren S. Mueller, Laura C. Iles, Carol L. Pilcher, Adam J. Sisson, Roger Magarey, Ryan Adams, Wanda I. Almodovar, Diane Alston, Patrick Beauzay, Ricardo Bessin, Mandy Bish, Mary Burrows, Alejandro Calixto, Rakesh Chandran, Jed B. Colquhoun, Mary Concklin, Amy J. Dreves, Peter C. Ellsworth, Paul D. Esker, James J. Farrar, Alfred Fournier, Daniel Frank, Kelly Hamby, George Hamilton, Anthony Hanson, Ann Hazelrigg, Natalie Hein-Ferris, David Held, James Jasinski, Heather M. Kelly, David Kerns, Miranda Kersten, Lauren Kerzicnik, Janet Knodel, Glen Koehler, Heidi Kratsch, Christian H. Krupke, Norman C. Leppla, Erin Lizotte, Casey Matney, Rebecca A. Melanson, Frannie Miller, Marion Murray, David Owens, Diane Plewa, Francis P. F. Reay-Jones, Silvia I. Rondon, Tom A. Royer, Philip A. Rozeboom, Hilary A. Sandler, Scott P. Schell, Marissa Schuh, Timothy Seipel, Danesha Seth Carley, Ashfaq Sial, Raghuwinder Singh, Damon L. Smith, Tim Stock, Glenn Studebaker, Adrianna Szczepaniec, Lisa Tewksbury, John Tooker, Adam J. Varenhorst, Amber Vinchesi-Vahl, Doug Walsh, Desiree Wickwar, Robert J, Wright, Simon Zebelo

Department of Entomology: Faculty Publications

Integrated pest management uses a variety of tools coupled with historical, current, and projected information for economical pest protection of crops and other resources while accounting for risk to humans and the environment. Following the 1972 US Federal IPM Policy, funding for integrated pest management programming has continued for 50+ years. However, multifaceted changes during this time have significantly affected state-level integrated pest management infrastructure, prompting a comprehensive survey to assess conditions, limitations, and growth potential of US integrated pest management programs. A survey was sent to 50 US states and 3 territories with integrated pest management programs in November …

Cover Crops Can Reduce Greenhouse Gas Emissions From No-Till Maize In Southern Brazil: Insights From A Long-Term Field Experiment, Guilherme Rosa Da Silva, Adam J. Liska, Cimélio Bayer

Adam Liska Papers

Brazil is one of the countries that has the most agricultural area under no-till (NT) management. This research study aims to evaluate life-cycle greenhouse gas (GHG) emissions from maize (M) grain production in agroecosystems that used different cover crops under NT management in southern Brazil. The data for this study were from a long-term 41-year field experiment in southern Brazil. The long-term experiment evaluated the effects of fallow (F) and cover crops (oat (O), vetch (V), cowpea (B), pigeon pea (P), and lablab (L)) on nitrous oxide and methane emissions and soil carbon (C) sequestration in maize agroecosystems. Five cropping …

Oer Ancient Egyptian Numerals Activity, Cynthia Huffman Ph.D.

Open Educational Resources - Math

Ancient Egypt captures our imagination not just because of its pyramids, but because of its incredible staying power. This civilization thrived for over 3,000 years, influencing cultures across the globe—including the very roots of mathematics. As Egyptologist Bob Brier puts it, “No civilization lasted so long, contributed so much, or repeatedly amazed as did ancient Egypt.”

Ready to crack the code of Ancient Egypt and the pharoahs? In this activity, you will learn to decipher Egyptian numerals by examining real photos from temples and museums. Master this skill, and next time you visit a museum exhibit on ancient Egypt, you …

Heterotrophy Of Particulate Organic Matter Subsidies Contributes To Divergent Bleaching Responses In Tropical Sclaractinian Corals, Connor R. Love, Kelly E. Speare, Michael D. Fox, Veronica Z. Radice, Kelton W. Mcmahon, Gretchen E. Hofmann,, David L. Valentine, Marie E. Strader

Biological Sciences Faculty Publications

Heterotrophic feeding on plankton and particulate organic matter (POM) by tropical Scleractinian corals is known to aid in the resistance and recovery from thermally induced bleaching. However, the relative importance of heterotrophy in promoting bleaching resistance and recovery is likely to vary based on ecological context and the severity of heat stress. In 2019, the Pacific Island of Mo'orea experienced mass coral mortality during a widespread marine heatwave. Many Acropora hyacinthus colonies on the shallow reef slope (5 m) were resistant to bleaching, while colonies on the deeper fore reef (14 m) often bleached and subsequently recovered, despite similar thermal …

Analyzing Microbial Communities In Porites Astreoides, Sanaa Caldwell, Katie Parker, Daniel Barshis

Biological Sciences Faculty Publications

Coral reefs are vital marine ecosystems that support many different species and ecosystem services through protecting coastlines from storms and erosion, providing raw materials for medication, and facilitating diversity amongst marine species. Anthropogenic climate change is causing ocean temperatures to exceed the range of coral thermal tolerance resulting in more coral bleaching events globally. However, some corals have the capacity to withstand high temperatures through different thermal tolerance strategies. A balanced microbial community plays a critical role in coral health and recent studies have indicated that a balanced microbiome is associated with temperature-stress tolerant corals. Yet, there is a severe …

A Blueprint To Greener Shorelines: Advancing The Effectiveness, Sustainability, And Widespread Adoption Of Coastal Nature-Based Solutions Through Transdisciplinary Research, Taylor M. Sloey, Sierra Hildebrandt, Rebecca L. Morris, Matthew V. Bilskie, Aaron Bland, David Bushek, Gabriella Dipetto, Daniel Elefant, Vincent Encomio, Ramin Familkhalili, Christine Hladik, Danielle Kreeger, Avery B. Paxton, Cindy M. Palinkas, Latina Steele, Andrew Scheld, Daisuke Taira, Jason D. Toft, Armando J. Ubeda, Christine Whitcraft, Donna Marie Bilkovic

Biological Sciences Faculty Publications

Coastal nature-based solutions (NbS) have emerged as powerful tools to enhance sustainable development and ecological restoration goals. As a rapidly growing field spanning across social, political, ecological, economic, and engineering disciplines, it is critical that researchers working in coastal NbS regularly attempt to identify emerging focal areas for scientific inquiry. Following the 27th Biennial meeting of the Coastal and Estuarine Research Federation, we provide a transdisciplinary perspective (including biologists, engineers, oceanographers, geoscientists, economists, and facilitators of workforce training programs) of pertinent research questions that, if answered, will advance the effectiveness, sustainability, and widespread adoption of coastal NbS. These suggestions for …

High Temporal Resolution Gene Expression Analysis Of Acute Heat Stress Response In Acropora Cervicornis And Porites Astreoides, Katherine Parker, Nicolas Evensen, Iliana Baums, Daniel Barshis

Biological Sciences Faculty Publications

Widespread coral bleaching and mortality events are becoming increasingly frequent due to rising ocean temperatures, though certain coral species and populations have displayed higher tolerance to elevated emperatures than others. As such, it is of high research priority to identify thermally tolerant coral populations for research and conservation and assess the biological mechanisms allowing these populations to survive exposure to higher temperatures. This research utilized the Coral Bleaching Automated Stress System (CBASS), a portable experimental aquaria system with precise temperature manipulation, to assess the thermal thresholds and heat stress response of two coral species from Summerland Key, FL, USA. Seven …

The Pluralistic Natural Capital Values Of A Tropical City, Adrienne Grêt-Regamey, Justine Saunders, Peter Edwards, Daniel Richards, Jahson I. Alemu, Natasha Bhatia, Roman Carrasco, Zuzana Drillet, Tze Kwan Fung, Yan Feng Leon Gaw, Wanggi Jaung, Andrea Law, Rachel Ai Ting Leong, Aikeen Youu Ming Lim, Mahyar Masoudi, Yudhishthra Nathan, Rachel Rui Ying Oh, Wen Ting Ooi, Fairul Edros Ahmad Shaikh Shaikh, Xiao Ping Song, Claudia L.Y. Tan, Puay Yok Tan, Sergio Wicki, Lynn-Wei Wong, Yanyun Yan, Erik Yando, Alex Thiam Koon Yee, Jingyuan Zhang, Daniel A. Friess

Biological Sciences Faculty Publications

Nature in cities is essential for human well-being. Quantifying and valuing the goods and services provided by nature to city dwellers is missing in tropical contexts. Yet, as cities worldwide face similar challenges, understanding the services provided by tropical urban ecosystems becomes imperative for effective management. Here, we present the first Natural Capital Assessment of a tropical city, unveiling three critical insights. Firstly, we demonstrate the vital reliance of a developed tropical city on nature, particularly for climate change mitigation through regulating services. Secondly, we identify intact natural areas as Singapore’s most valuable assets, stressing the significance of the quality …

Low Salinities Impair Heat Tolerance And Alter Reproductive Traits With No Implications For Survival In A Marine Annelid From Coastal Habitats, Gabrielle Newton, Gloria Massamba-N'Siala

Biological Sciences Faculty Publications

Climate change is expected to intensify salinity and temperature fluctuations in estuarine and coastal habitats. However, the impact of salinity variation on ectotherms’ thermal tolerance remains underexplored, limiting our understanding of the interplay between these stressors. This study investigated salinity-dependent changes in life history traits (survival, growth rate, fecundity, and egg size) over a 33-day exposure to a salinity gradient (12, 17, 22, 27, 32, 35, 40, 45, 50) in the marine annelid Ophryotrocha labronica. Individuals that survived the salinity treatments were assessed for their upper and lower thermal tolerance limits. Female individuals, the target of the study, exhibited …

Gasb Nanowires Grown On A Si Substrate And Nanolaminatate Tio2/Ag/Tio2 Structure, Malina Milanova, Petko Vitanov, Nikolay Petkov, Kiril Kirilov, Hristosko Dikov, Pavlina Ralova

Physical Sciences Publications

This paper presents a comparative study of GaSb nanowire (NWs) growth on a Si substrate using Ag nanoparticles as catalyst and on a Si substrate coated with a transparent conductive TiO2/Ag/TiO2 laminate structure. Silver nanoparticles with different sizes between 30 and 70 nm were formed directly on Si surface or embedded between two TiO2 layers by RF magnetron sputtering. A thermal evaporation method was used to grow GaSb NWs via vapor–liquid-solid (VLS) mechanism. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) were used to study the surface morphology of the grown structures. Two kinds of nanostructures were observed on …

High-Fidelity Tin Processing Modes For Multigate Ge-Based Quantum Devices, Sinan Bugu, Sheshank Biradar, Alan Blake, Cheewee Liu, Maksym Myronov, Ray Duffy, Giorgos Fagas, Nikolay Petkov

Physical Sciences Publications

Charge or spin-qubits can be realized by using gate-defined quantum dots (QDs) in semiconductors in a similar fashion to the processes used in CMOS for conventional field-effect transistors or more recent fin FET technology. However, to realize a larger number of gate-defined qubits, multiples of gates with ultimately high resolution and fidelity are required. Electron beam lithography (EBL) offers flexible and tunable patterning of gate-defined spin-qubit devices for studying important quantum phenomena. While such devices are commonly realized by a positive resist process using metal lift-off, there are several clear limitations related to the resolution and the fidelity of patterning. …

Theoretical Proof Of And Proposed Experimental Search For The Ground Triplet State Of A Wigner-Regime Two-Electron ‘Artificial Atom’ In A Magnetic Field, Marlina Slamet, Viraht Sahni

Physics Faculty Publications

It is experimentally established that there is no ground triplet state of the natural 𝐻𝑒He atom. There is also no exact analytical solution to the Schrödinger equation corresponding to this state. For a two-dimensional two-electron ‘artificial atom’ or a semiconductor quantum dot in a magnetic field, as described by the Schrödinger–Pauli equation, we provide theoretical proof of the existence of a ground triplet state by deriving an exact analytical correlated wave function solution to the equation. The state exists in the Wigner high-electron-correlation regime. We further explain that the solution satisfies all requisite symmetry and electron coalescence constraints of a …

Predicting Biomechanical Risk Factors For Division - I Women’S Basketball Athletes, Aayushi Shah, Vanaja Agarwal, Dhairya Shah, Harman Jani, Sristi Sharma, Kaya Tolga, Christopher Taber, Mehul Raval

School of Computer Science & Engineering Faculty Publications

Collegiate basketball is characterized by high-impact movements such as jump landings, making athletes more susceptible to injuries. Critical biomechanical factors like knee flexion, lateral trunk flexion, and foot landing asymmetry are strongly associated with injury risk. This study aims to predict six biomechanical risk factors in the landing error scoring system (LESS). The dataset comprises 8600 video frames of counter-movement jumps (CMJs) from 17 NCAA Division I female basketball athletes, recorded from frontal and lateral perspectives and annotated using a customized error annotation algorithm. The study uses the You Only Look Once (YOLOv5nu) model to analyze the basketball athletes’ CMJ …

Navigating Together: The Conav Testbed And Framework For Benchmarking Cooperative Localization, Rohith Boyinine, Jayanth Ammapalli, Anusna Chakraborty, Rajnikant Sharma, Kevin Brink, Clark N. Taylor

Faculty Publications

This paper presents CoNaV, a comprehensive framework for creating a multi-vehicle cooperative localization (CL) testbed designed to support the benchmarking, development, and deployment of cooperative navigation algorithms. Given the essential role of CL in improving localization accuracy for both defense and civilian applications, CoNaV provides a robust environment for rigorously validating algorithms under real-world conditions. By establishing a benchmark for CL algorithms, CoNaV lays a foundation for advancing research into more sophisticated and distributed CL solutions. This framework highlights the potential of cooperative navigation to enhance multi-vehicle operations and offers a scalable, practical approach for future developments in CL technology.

Revised Final Multi-Pathway Residential Metals Abatement Program Plan, Atlantic Richfield Company, Butte Silver Bow

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Fault Box Modeling Of Dip Slip Faults: A Framework For Fault Box Design And Future Studies, Hailey Pressnell

Master's Theses

The behavior of soils during surface fault rupture is a serious concern in the planning and design of infrastructure that may be located within or near a fault zone. Challenges associated with developing mitigation measures for surface fault rupture include the uncertainty of fault rupture and the variability of fault behavior. Current analytical procedures define surface fault rupture according to the type of fault movement (strike slip, normal or reverse), the amount of displacement on the fault, and the mechanics of the material overlying the fault. The purpose of this thesis is to reconfirm analytical solutions and gain a better …

Knowledge And Ontology Enhanced Approach To Natural Language Understanding (Koe-Nlu) In Computational Social Media And Healthcare, Naga Usha Gayathri Lokala

Theses and Dissertations

Natural Language Understanding (NLU) faces both opportunities and challenges as the amount of social media and healthcare data grows. This is particularly evident in context-sensitive applications such as evaluating cognitive health, identifying mental health symptoms, and monitoring drug abuse. Even though traditional NLU models work well for processing language in a wide range of areas, they often lack the ability to understand language in a specific domain, reason in context, and incorporate structured external knowledge. This dissertation talks about the Knowledge and Ontology Enhanced Approach to Natural Language Understanding (KOE-NLU), a new framework that is meant to make NLU systems …

Dataset On Indoor And Outdoor Pm2.5 Concentrations At Two Residences Using Low-Cost Sensors In The Rio Grande Valley Region Of South Texas, Kabir Bahadur Shah, Sai Deepak Pinakana, Mkhitar A. Hobosyan, Armando Montes, Amit U. Raysoni

School of Earth, Environmental, & Marine Sciences Faculty Publications

Fine particulate matter (PM2.5) is one of the criteria air pollutants associated with adverse respiratory and cardiovascular health effects. This dataset contains hourly and daily averaged measurements of PM2.5 concentrations (µg/m3) collected from two residential homes in the Rio Grande Valley (RGV) Region of South Texas, using PurpleAir-II-SD low-cost sensor. In addition, the dataset also includes temperature (ºC) and relative humidity (%) measured by the sensors. The data was collected for one month during the summer season from indoor (kitchen) and outdoor (front yard) environments at two locations: Home-1 in Weslaco City from June 16, 2024, to July 16, 2024, …

Examining The Presence And Effects Of Coherence And Fragmentation In The Gulf Of Maine Fishery Management Network, Derek A. Katznelson, Antonia Sohns, Dongkyu Kim, Evelyn Roozee, William Donner, Andrew M. Song, Jasper R. De Vries, Owen Temby, Gordon M. Hickey

School of Earth, Environmental, & Marine Sciences Faculty Publications

Natural resource management networks cohere due to mutual dependencies and fragment, in part, due to the perceived risks of interaction. However, research on these networks has tended to accept coherence a priori rather than problematizing dependence, and few studies exist on interorganizational risk perception. This article presents the results of a study operationalizing these concepts and measuring the distribution of three types of dependence (capital, legitimacy, and regulatory) and two types of perceived risk (performance and sanction) among nearly fifty stakeholder groups and organizations participating in the management of fisheries in the binational Gulf of Maine. The analysis reveals an …

Modification Of Nanoparticles For Designed Interfaces, Tony Lee Neely, Jr.

Theses and Dissertations

The work contained herein, is focused on the design, synthesis, and characterization of polymer nanocomposite interfaces and the property enhancement afforded from said interface design. Through the use of reversible addition fragmentation chain transfer (RAFT) polymerization for the grafting of polymer chains to silica nanoparticles, the surface of silica nanoparticles can be manipulated to tune the properties of the nanocomposite as a whole.

In the first part of this work, heterogeneity is introduced onto the surface of silica nanoparticles via a sequential RAFT polymerization to afford a bimodal brush system. A densely grafted, short brush population is polymerized from the …

Oriented Surface Immobilization Of Antibodies Using Enzyme-Mediated Site-Specific Biotinylation For Enhanced Antigen-Binding Capacity, Emily Beitello, Kwame Osei, Trent Kobulnicky, Faith Breausche, Jon A. Friesen, Jeremy D. Driskell

Faculty Publications – Chemistry

The effectiveness of surface-immobilized antibodies is often diminished by improper antibody orientation and limited stability, impeding the analytical performance of biosensors. Here, we report a novel enzyme-mediated strategy to biotinylate the Fc region of an anti-horseradish peroxidase (anti-HRP) antibody with site-specificity that enables oriented immobilization on a streptavidin-functionalized surface. Microbial transglutaminase (mTG) catalyzes the covalent coupling between the amine functional group on a biotin analogue (NH₂-PEG₄-biotin) and the side chain of a privileged glutamine residue (Q295) located on the heavy chain Fc region of IgG antibodies. For comparison, an anti-HRP antibody was biotinylated using an amine-reactive …

Rhenium Chalcogenide Clusters Containing Para-Substituted Phenylacetylide Ligands: Synthesis, Characterization, And Investigation Of Substituent Effects On Spectroscopic And Electrochemical Properties, Katherine L. Helmink, Cory A. Hicks, B. Sage Lauper-Cook, Steven J. Peters, Christopher J. A. Daley, Yann Molard, Lisa F. Szczepura

Faculty Publications – Chemistry

Four new organometallic [Re₆Se₈]²⁺-based cluster complexes containing para-substituted phenylacetylide ligands, [Re₆Se₈(PEt₃)₅(C≡C–C₆H₄–X)](SbF₆) where X = NO₂, CO₂Me, CH₃, and OMe, have been synthesized and fully characterized using ¹H, ¹³C{¹H} and ³¹P{¹H} NMR, IR, and UV–vis spectroscopy, HRMS, and elemental analysis. Three of these cluster complexes, [Re₆Se₈(PEt₃)₅(C≡C–C₆H₄–NO₂)]⁺, [Re₆Se₈(PEt …

Automatic Identification And Visualization Of Reaction Mechanisms Contained Within Direct Dynamics Simulations, Trent Kobulnicky, Emmanuel Boafo, George L. Barnes

Faculty Publications – Chemistry

Direct dynamics simulations are employed in many areas of chemistry and biochemistry. When paired with an appropriate underlying ab initio, semiempirical, or DFT-based potential energy surface and proper sampling of initial conditions, direct dynamics simulations provide an atomic-level view of the reaction dynamics within the system of interest, yielding considerable fundamental insights. Moreover, when a sufficient number of simulations are conducted, they provide a wealth of information regarding the overall trends in reactivity. However, they also generate large data sets that often require significant manual interpretation through inspection or developing case-specific analysis techniques. Here, we present an analysis method …

Synthesis Of Alkyl Substituted Carbatripyrrins And Their Application To The Preparation Of Carbaporphyrins And Oxacarbaporphyrins, Ian A. Mclauchlan, Bethany K.X. Overbey, Tyler J. Smolczyk, John J. Woods, Timothy D. Lash

Faculty Publications – Chemistry

Unsubstituted carbatripyrrins have previously been shown to be useful intermediates in the synthesis of benzocarbaporphyrins and related core-modified analogues. However, the absence of substituents often resulted in the formation of poorly soluble products. In this study, four examples alkyl substituted carbatripyrrins were constructed by base-catalyzed condensation of dihydrofulvenes with pyrrole aldehydes. Further reaction with a pyrrole dialdehyde in the presence of trifluoroacetic acid afforded a series of carbaporphyrins, while reactions with 2,5-furandicarboxaldehyde generated oxacarbaporphyrins. These results demonstrate that alkyl substituted carbatripyrrins are promising precursors to new carbaporphyrinoid structures.

Synthesis Of Phenaliporphyrin, A Pah-Porphyrin Hybrid, From An Acenaphthene-Fused Cyclopropane Dialdehyde, Sunday Oladapo Jacob, Emily D. Harris, Melissa A. Mathius, Deyaa I. Abusalim, Gregory M. Ferrence, Timothy D. Lash

Faculty Publications – Chemistry

Phenaliporphyrin, a new aromatic benziporphyrin derivative, has been synthesized from an annulated cyclopropane dialdehyde intermediate. Corey-Chaykovsky cyclopropanation of dimethyl acenaphthylene-1,2-dicarboxylate gave a cyclopropane diester, and this was converted to the corresponding bis-Weinreb amide. Reduction with lithium aluminum hydride afforded an unstable dialdehyde and subsequent acid-catalyzed condensation with a tripyrrane dicarboxylic acid, followed by oxidation with aqueous ferric chloride, gave the targeted porphyrinoid system. This involves ring expansion of the acenaphthylene precursor to generate the phenalene unit. Phenaliporphyrin exhibits a porphyrin-like UV–vis spectrum with a Soret band at 443 nm and a relatively intense Q-band at 601 nm. The proton NMR …

Hyper B-Ary Representations Of A Number, Mingway Wang

Masters Theses

In this work, we summarize combinatorial, analytical, and computational properties of Stern's diatomic sequence, and do the same for a generalization of a combinatorial property of this sequence to higher bases. We then construct special ``bit conversion'' functions $g_{b}$ that allows us to find a semi-explicit formula for the generalized sequences. Lastly, we analyze some of the properties of these $g_{b}$ functions.