Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons™

Open Access. Powered by Scholars. Published by Universities.®

Discipline
Institution
Keyword
Publication Year
Publication
Publication Type
File Type

Articles 18001 - 18030 of 294581

Full-Text Articles in Physical Sciences and Mathematics

Lethality And Survivability Of Autonomous Self-Sensing Uavs, Jeffrey T. Wilson Mar 2025

Lethality And Survivability Of Autonomous Self-Sensing Uavs, Jeffrey T. Wilson

Theses and Dissertations

Unmanned Aerial Vehicles (UAVs) have seen increased usage over the past two decades during the Global War on Terrorism (GWOT), operating in low-risk environments against dispersed enemies with minimal counter-drone capabilities. However, as the U.S. military shifts focus to Multi-Domain Operations (MDO) and Large Scale Combat Operations (LSCO), UAVs face significantly higher risks, including frequent and successful attacks, as well as the exploitation of their technology. Battle damage assessment (BDA) is not new; however, autonomous self-assessment by UAVs represents a novel advancement. Currently, UAV BDA relies on manual inspection, requiring approximately eight hours per drone. By adopting self-sensing technology, UAVs …


Evaluating Dry Air Personnel Decontamination Of Methyl Salicylate As A Chemical Agent Surrogate In Extreme Cold Environments To Reduce Airborne Risks Using A Manikin, Lance E. Campbell Mar 2025

Evaluating Dry Air Personnel Decontamination Of Methyl Salicylate As A Chemical Agent Surrogate In Extreme Cold Environments To Reduce Airborne Risks Using A Manikin, Lance E. Campbell

Theses and Dissertations

This research investigated a mobile air shower as an alternative to water washing for personnel chemical decontamination in Arctic environments, where traditional methods like disrobing and rinsing are impractical. Interest in Arctic operations has grown with recent U.S. military focus on strategic advancements by Russia and China, yet research on air shower effectiveness for chemical decontamination remains limited. This study examined whether a commercial off-the-shelf air shower could effectively decontaminate methyl salicylate (MES), a surrogate for chemical warfare blister agents, from a manikin outfitted in military cold-weather gear. Researchers used a ppbRAE 3000 photo-ionization detector to measure MES concentrations following …


Molecular Scale Investigations Of Interactions Between Pfas And Concrete, Eric E. Keeler Mar 2025

Molecular Scale Investigations Of Interactions Between Pfas And Concrete, Eric E. Keeler

Theses and Dissertations

Per- and polyfluoroalkyl substances (PFAS), widely referred to as “forever chemicals,” exhibit high environmental persistence and potential health risks due to their robust carbon-fluorine bonds. These substances are prevalent in aqueous film-forming foams (AFFF), used in industrial and military applications, and are known to contaminate environmental surfaces, including concrete. This study aims to characterize the molecular-level interaction energies of six PFAS species—PFOA, PFOS, PFHxS, PFHxA, 6:2 FTS, and PFBS—with calcium silicate, a key component of concrete, using density functional theory (DFT) calculations. Change in Gibbs free energy (ΔG) was determined for each of the interactions, revealing negative ΔG values for …


Atmospheric Characterization For Optical Paths In Lunar Proximity, Patrick D. Carattini Mar 2025

Atmospheric Characterization For Optical Paths In Lunar Proximity, Patrick D. Carattini

Theses and Dissertations

This paper presents a novel technique for estimating the Fried seeing parameter (r0) for optical paths around the Moon, where traditional methods fail due to the Moon's intensity. Using image processing, it derives the atmospheric optical transfer function (OTF) by using the Moon's edge as a step-input. A simulation chain validates the approach, achieving r0 estimation within 0.0012 m. Real-world tests confirm accuracy through visual and statistical analysis, offering an effective alternative for atmospheric characterization of optical paths close to the moon.


Autonomous Vehicle Path Planning Under Uncertainty, Madison C. Gillan Mar 2025

Autonomous Vehicle Path Planning Under Uncertainty, Madison C. Gillan

Theses and Dissertations

Autonomous vehicles are increasingly being deployed for use in high-stakes and uncertain environments where safe and efficient navigation is critical. In these scenarios, traditional path planning approaches, which rely primarily on deterministic models and fixed assumptions, fall short due to the inherent uncertainty of dynamic threats, sensor inaccuracies, and incomplete information. This research addresses these challenges by developing a novel path-planning methodology that combines the Chance-Constrained Rapidly Exploring Random Tree* (CC-RRT*) algorithm with a probabilistic risk assessment heuristic. This method models uncertainty in sensor detection zones, obstacles in the environment, and the Autonomous Vehicle itself, which allows for uncertainty during …


On The Exploration Of Crystallographic Anisotropy And Defects In Shock Loading Using Molecular Dynamics, Benjamin P. Helman Mar 2025

On The Exploration Of Crystallographic Anisotropy And Defects In Shock Loading Using Molecular Dynamics, Benjamin P. Helman

Theses and Dissertations

The impact of crystallographic orientation, grain boundaries, and vacancies on the shock behavior of aluminum was investigated using molecular dynamics simulations. Shock loading in the [001], [011], and [111] directions was explored, revealing anisotropic behavior in shock speed, melting, dislocation density, and unique phase changes. The Hugoniot elastic limit in the [100], [110], and [111] directions was calculated as 23.2 GPa, 24 GPa, and 18.4 GPa respectively. These results were found to be an order of magnitude larger than the compressive yield strength computed at equilibrium. Additionally, metastable melting in the [011] and [111] directions occurred roughly 1000 K below …


Evaluating Weather Effects On Sortie Generation Using Discrete Event Simulation, Markus Case Mar 2025

Evaluating Weather Effects On Sortie Generation Using Discrete Event Simulation, Markus Case

Theses and Dissertations

United States Air Force (USAF) operations rely on sortie generation, a complex system involving aircraft maintenance, operational planning, munitions, security forces, and aircrew. Failures in any of these areas can jeopardize a mission, and extreme weather events such as lightning, high winds, and snow further complicate operations. This thesis examines the impact of extreme weather on sortie generation, focusing on developing a data-driven discrete-event simulation (DES) to predict generation timelines and identify high-risk areas. The model allows users to adjust key inputs, including the month, number of aircraft, processing times, and personnel/equipment availability. By simulating real-world conditions, the model helps …


Class Imbalance: A Landscape Of Classification Models, Joshua L. Edmonds Mar 2025

Class Imbalance: A Landscape Of Classification Models, Joshua L. Edmonds

Theses and Dissertations

Class imbalance poses significant challenges in machine learning classification. This study evaluates the performance of seven models (ANN, k-Means, kNN, LDA, LR, SVM, XGBoost) across multiple imbalance levels (10\%, 5\%, 1 \%, 0.5\%) and investigates the effectiveness of sampling techniques (Undersampling, SMOTE, SMOTE-ENN). ANOVA results confirm that model choice is the most critical factor, with XGBoost and SVM demonstrating superior robustness. SMOTE improves recall but reduces precision, while undersampling generally degrades overall performance. While significant, imbalance levels do not play a critical role in model effectiveness.


Data Lakehouse And Machine Learning Pipeline For Aircraft Fuel Efficiency Experimentation, Skyler G. Kepley Mar 2025

Data Lakehouse And Machine Learning Pipeline For Aircraft Fuel Efficiency Experimentation, Skyler G. Kepley

Theses and Dissertations

Fuel efficiency is crucial for the U.S. Air Force, impacting mission success, aircraft performance, and cost savings. This study presents an information system that integrates flight and maintenance data using a data lakehouse. It automates ingestion, enrichment, and predictive modeling, leveraging AutoML for optimization and SHAP for transparency. A case study on C-130J aircraft shows that optimizing D Check cycles can save 11.52 pounds of fuel per flight hour. These findings highlight the effectiveness of data-driven decision-making in aviation, offering a scalable, automated solution for improving fuel efficiency and reducing costs.


Machine Learning With Flight Data Recorder Data For Flight Fuel Consumption Predictions, Adam C. Levandowski Mar 2025

Machine Learning With Flight Data Recorder Data For Flight Fuel Consumption Predictions, Adam C. Levandowski

Theses and Dissertations

This study applies advanced Machine Learning (ML) to Flight Data Recorder (FDR) data for fuel consumption predictions. It explores feature engineering, model selection, and Hyper-Parameter Optimization (HPO) across all flight phases. Baseline models like Ordinary Least Squares (OLS) regression, Multi- Layer Perceptrons (MLPs), and decision trees are compared to Deep Neural Networks (DNNs), Recurrent Neural Networks (RNNs) with Gated Recurrent Unit (GRU) layers, and XGBoost. Results analyze segmentation strategies, tailored features, and model performance. A counterfactual analysis compares ML models to operational fuel predictions, demonstrating their deployment potential. Findings establish a foundation for future ML-driven advancements in aviation fuel optimization.


Improving Zero Shot Learning By Linking Multi-Label Cnns With Llms, Michael A. Wegner Mar 2025

Improving Zero Shot Learning By Linking Multi-Label Cnns With Llms, Michael A. Wegner

Theses and Dissertations

Classifying previously unseen objects poses a significant challenge for traditional computer vision algorithms, which rely on extensive labeled training data. Zero-shot reasoning offers a way to overcome this limitation. This research explores a novel method for image recognition using the Animals with Attributes 2 (AWA2) dataset as a proof of concept. A multi-label ResNet50 model predicts core attributes like color, ear shape, or number of limbs. Those attributes then feed into ChatGPT which leverages its extensive knowledge base to classify the animal based on the provided attributes. This novel approach skips the need to train on every possible class. Instead, …


Analyzing And Comparing Refinement Indicators For Rbf-Fd Adaptive Algorithms, Anders R. Johnson Mar 2025

Analyzing And Comparing Refinement Indicators For Rbf-Fd Adaptive Algorithms, Anders R. Johnson

Theses and Dissertations

Recent progress has been made in the development of collocation-based iterative algorithms that approximate solutions to PDEs. These algorithms rely on the ability to identify regions within a domain where a finer discretization is required. Such iterative algorithms are beneficial particularly when solution functions have highly localized behavior. This thesis proposes an indicator for node refinement that is constructed by approximating the forward error. This proposed indicator also helps to establish confidence in the accuracy of a given solution estimate. The proposed error estimator is theoretically examined and compared with contemporary refinement indicators. It is shown that an iterative algorithm, …


Uranium Particle Classification Using Statistical Machine Learning And Deep Neural Networks For Nuclear Forensics, Lee C. Lambert Mar 2025

Uranium Particle Classification Using Statistical Machine Learning And Deep Neural Networks For Nuclear Forensics, Lee C. Lambert

Theses and Dissertations

The classification of uranium particles from scanning electron microscopy (SEM) imagery is critical to nuclear forensics, but has traditionally relied solely on skilled analysts whose classification accuracy and procedures may vary widely. Existing morphology lexicology [1] provides standardization guidelines to aid analysts but cannot fully address analyst variability. Using a dataset of 1,906 SEM images across 13 unevenly distributed particle classes and 73 magnification levels, final accuracy between statistical and deep learning methods were compared to find the best classification techniques. Ultimately, the deep learning model achieved an impressive 82% accuracy (80% balanced accuracy) on a withheld test set. This …


A Machine Learning/Deep Learning Investigation On Remote Manufacturing Machine State Classification, Ajeet S. Parmar Mar 2025

A Machine Learning/Deep Learning Investigation On Remote Manufacturing Machine State Classification, Ajeet S. Parmar

Theses and Dissertations

Determining the extent of manufacturing capabilities with respect to adversarial or hostile nations is a topic of significant importance to the Department of Defense. Manufacturing capabilities can serve as indications of a nation's industrial power and its economy of force in warfare. Remotely detecting machine operations via electromagnetic sensors may be possible via Deep Learning (DL) and Machine Learning (ML) algorithms. To predict machine states, sensor data is collected externally from a machine shop on a college campus to monitor the operating states of lathes and mills in individual and concurrent operation. Furthermore, several sensors are placed in various positions, …


Hypergame Models For Cyber Defense In A Purple Team Setting, Thomas N. Whitney Mar 2025

Hypergame Models For Cyber Defense In A Purple Team Setting, Thomas N. Whitney

Theses and Dissertations

Hypergame theory and purple teaming are two fields that can support an increased cybersecurity posture. This research investigates a hypergame theory framework that incorporates fittingly into the purple team feedback loop. Additionally, this research integrates empirical data into the hypergames. The data and the hypergames are supported by the MITRE ATT&CK framework. This research also includes a review of available game theory and hypergame theory software, five different hypergame models, a comparison of the two hypergame formats, and an innovative analysis technique using a multi-stage hypergame to represent the cyber kill chain. One finding of this research is that a …


Evaluating Atmospheric Water Generation For The Indo-Pacific: Predictive Modeling, Energy Considerations, And Regional Viability, Jose I. De La Serna Mar 2025

Evaluating Atmospheric Water Generation For The Indo-Pacific: Predictive Modeling, Energy Considerations, And Regional Viability, Jose I. De La Serna

Theses and Dissertations

Atmospheric Water Generator (AWG) technology presents a promising solution for extracting and harvesting water from ambient air through condensation methods. This innovative approach offers a viable alternative for water production in regions with limited or unreliable water sources. AWGs operate most effectively in hot and humid environments, typically at temperatures of 80°F and relative humidity levels of 80%. As of 2020, the Department of Defense (DoD) has identified the Indo-Pacific region as a strategic focus for addressing future greatpower competition. Within the framework of Agile Combat Employment, this study evaluates the feasibility and performance of AWG technology at pre-determined locations …


Atmospheric Water Generation: Bacterial And Inorganic Chemical Quality, Garrett E. Stanley Mar 2025

Atmospheric Water Generation: Bacterial And Inorganic Chemical Quality, Garrett E. Stanley

Theses and Dissertations

This study investigated the quality of untreated water collected from a vapor compression-based atmospheric water generator (AWG) operated outdoors in Dayton, Ohio. The concentrations of bacterial and chemical constituents were determined. The concentration of culturable bacteria was between 200 and 2300 CFU/mL, significantly higher than the reference levels described in recreational and drinking water quality guidance. Three discrete bacteria phenotypes were visually identified; two were yellow in color, rod-shaped and gram-negative while the third was milky white, circular, and gram-positive. Chemical analysis on 15 randomly selected samples revealed the presence of Barium (average = 0.16 mg/L), Magnesium (0.08 = mg/L), …


Jamming-Tolerant Low-Rate Wireless Personal Area Network For Detection Sensor Networks, Michael A. Eddy Mar 2025

Jamming-Tolerant Low-Rate Wireless Personal Area Network For Detection Sensor Networks, Michael A. Eddy

Theses and Dissertations

This research evaluates the impact of electronic warfare, particularly jamming, on an audio-based drone detection wireless sensor network (WSN) using Monte Carlo simulations. A six-node IEEE 802.15.4 network, with five edge nodes and a central sink, is tested against jamming probabilities ranging from 0-100% in 5% increments across 30 iterations per configuration. Results show that packet delivery ratio (PDR) degrades linearly at approximately 20% per jammed node, while detection performance often exceeds PDR. Even at 80% jamming, detection success rates remain above 57%, highlighting resilience despite network degradation. The study reveals that jamming effectiveness depends on node placement relative to …


Emergency Response Digital Twin: Integrating Augmented Reality And Live Position Data With Simulation-Aided Decision-Making In Real-Time, Joseph Fuentes Mar 2025

Emergency Response Digital Twin: Integrating Augmented Reality And Live Position Data With Simulation-Aided Decision-Making In Real-Time, Joseph Fuentes

Theses and Dissertations

With the growing use of simulation across industries, the digital twin remains an underexplored research area, particularly in emergency management and response. Its real-time updating capability is often overlooked due to the misconception that "digital twin" is merely a complex term for simulation. This paper highlights its distinctiveness through an evasion exercise involving two independent entities in a collocated environment. Using a highly integrated virtual environment (HIVE) and internet of things (IoT) devices, we link the physical system with an analytical simulation, demonstrating the impact of lag times in high-pressure scenarios. The computational model leverages agent-based modeling (ABM) and discrete-event …


Performing Requirements Specification And Analysis Through Open Generative Pre-Trained Transformers, Harvey J. Hurst Mar 2025

Performing Requirements Specification And Analysis Through Open Generative Pre-Trained Transformers, Harvey J. Hurst

Theses and Dissertations

Every acquisition program begins with a requirement, and for those programs to succeed, robust requirements engineering (RE) must be implemented. RE encompasses eliciting, analyzing, specifying, and validating requirements—a critical process throughout a program's lifecycle. Despite its importance, RE faces challenges such as scope creep, ambiguity, redundancy, and inadequate automation support, often exacerbated by reliance on historical data. To address these issues, this thesis leverages advancements in Generative Technology, particularly large language models (LLMs) such as Generative Pre-Trained Transformers (GPTs). This research developed two GPT-based tools: the Single Requirement Analysis Tool and the Set of Requirements Analysis Tool. These tools were …


Air-Based Chemical Patient Decontamination Methodologies For Arctic Regions Using Methly Salicylate As A Chemical Agent Surrogate On A Litter-Bound Manikin, Marcus D. Shadd Mar 2025

Air-Based Chemical Patient Decontamination Methodologies For Arctic Regions Using Methly Salicylate As A Chemical Agent Surrogate On A Litter-Bound Manikin, Marcus D. Shadd

Theses and Dissertations

This study evaluated a mobile air shower for patient decontamination without disrobing or rinsing, an alternative for Arctic conditions where water is scarce. A manikin in extreme cold weather gear was exposed to 10 µL of methyl salicylate (MeS), a sulfur mustard surrogate, and placed in a horizontal chamber on a military litter. Airborne MeS was measured using a ppbRAE 3000 detector to assess inhalation risk for the patient and decontamination team. Three methods were tested: an air-knife system, paper towels, and no decontamination, with 10 trials each (30 total). ANOVA analysis showed significant reductions in airborne MeS with air-knife …


Early-Phase Cost Estimation For Department Of Defense Construction Projects Via Artificial Neural Networks: Implications And Policy Recommendations For Artificial Intelligence Integration, Kobe T. Thompson Mar 2025

Early-Phase Cost Estimation For Department Of Defense Construction Projects Via Artificial Neural Networks: Implications And Policy Recommendations For Artificial Intelligence Integration, Kobe T. Thompson

Theses and Dissertations

The Department of Defense lost over 500 million dollars between 2016 and 2024, partially due to poor early cost estimates resulting in cost overruns. practice for cost estimation relied on parametric techniques that incorporate historical data, subject matter experts in cost estimating, and predictive software applications. The main motivation for this study was to assess the viability of artificial neural networks as a means of providing a more accurate cost estimate in the early design phases of a construction project. The dataset initially contained approximately 48,000 data points from a database of various Air Force projects, including maintenance, repair, minor …


Material Classification With Spectropolarimetric Lidar, Alexander J. Watson Mar 2025

Material Classification With Spectropolarimetric Lidar, Alexander J. Watson

Theses and Dissertations

A method for characterizing unknown targets using a hyperspectral polarimetric light detection and ranging (LiDAR) system is presented. Light reflected from manmade objects tends to be more polarized than light reflected from objects in the natural world. As such, polarization measurements can be used in remote sensing applications to differentiate artificial and natural objects. Previous works have attempted to characterize objects through passive polarimetric imagery. Methods developed by Cain and Lemaster and Cunningham facilitate reconstruction of the Stokes Vector from returning light. Martin used multispectral polarimetry to classify targets when the angle of incidence (AOI) is close to 0º. Here, …


A Reinforcement Learning Approach For Maneuvering And Firing Decisions In Sead Operations, Nathaniel Garcia Mar 2025

A Reinforcement Learning Approach For Maneuvering And Firing Decisions In Sead Operations, Nathaniel Garcia

Theses and Dissertations

The integration of automated processes in defense continues to expand, enhancing the lethality of military forces. Artificial intelligence accelerates decision-making cycles, removes the constraints of human-operated hardware, and improves coordination by enabling seamless integration across multiple systems. Suppression of Enemy Air Defenses (SEAD) missions are critical to the United States (U.S.) military, as they neutralize hostile air defense systems, ensuring air superiority and enabling safe and effective operations for aircraft in contested environments. Therefore, it is necessary to pair emerging autonomous capabilities with an important mission set in defense. This research investigates the Autonomous Unmanned Air-to-Ground Strike (AUAGS) problem, modeling …


Symbology Detection And Numerical Recognition For T-38 Heads-Up Display Recordings, Ben T. Hepner Mar 2025

Symbology Detection And Numerical Recognition For T-38 Heads-Up Display Recordings, Ben T. Hepner

Theses and Dissertations

The extraction of symbology and numerical data from the T-38 Heads-Up Display (HUD) enhances post-flight analysis and supports real-time decision-making. This research develops a deep learning pipeline using YOLO-based object detection and Optical Character Recognition (OCR) to analyze HUD video data. Model evaluations showed mAP0.5:0.95 ranging from 0.422 (YOLOv11m, hard test set) to 0.696 (YOLOv8m, medium test set), demonstrating robust symbology detection. Numeric detection performed well (mAP0.5:0.95 = 0.764), but OCR struggled with glare and resolution limitations, achieving a recognition accuracy of 17.35%. These results validate deep learning for HUD data extraction but highlight the need for improved robustness …


Proximal Policy Optimization Applied To The Beyond Visual Range Air Combat Maneuvering Problem, Daniel B. Joseph Mar 2025

Proximal Policy Optimization Applied To The Beyond Visual Range Air Combat Maneuvering Problem, Daniel B. Joseph

Theses and Dissertations

Artificial intelligence (AI) grows ever-more important in warfighting. Emerging technologies allow for the use of AI to control aircraft and weapons systems. This research investigates the application of reinforcement learning (RL) through the Proximal Policy Optimization (PPO) algorithm to a two-versus-two (2v2) beyond-visual-range (BVR) air combat maneuvering problem (ACMP). Implemented in the Advanced Framework for Simulation, Integration, and Modeling (AFSIM), the methodology frames the engagement as a Markov decision process, wherein an autonomous RL agent learns continuous control decisions—throttle, pitch, roll, and yaw—under a cooperative communication scheme. A multi-phase curriculum-learning approach facilitates the progressive acquisition of flight stability, weapon deployment, …


Machine Learning Techniques To Predict Solar Particle Events And Radiation Of Aircrew, Haley Traub Mar 2025

Machine Learning Techniques To Predict Solar Particle Events And Radiation Of Aircrew, Haley Traub

Theses and Dissertations

Solar Particle Events (SPEs) are high-energy phenomena from the Sun that pose risks to technology, human health, and Air Force operations. Accurate prediction of SPEs exceeding 100 MeV is crucial for mitigating these risks. This thesis explores using Bayesian statistical models to predict such events, integrating prior knowledge from solar physics with the ability to update predictions based on new data. The research uses a dataset spanning three solar cycles (21–23) and incorporates attributes like flare fluence, peak flux, latitude, longitude, and class. Four Bayesian models (PyMC, Bnlearn, and two Dredge models) were compared to machine learning models. The Bayesian …


Cloud One Migration Duration And Its Drivers, Grayson T. Hall Mar 2025

Cloud One Migration Duration And Its Drivers, Grayson T. Hall

Theses and Dissertations

As modern warfare evolves with rapid technological advancements, cloud computing plays a critical role in managing the vast amounts of data required for real-time decision making, as well as enabling seamless organizational access to mission-critical programs and information from around the globe. Recognizing its importance, the Department of Defense (DoD) identified cloud computing as essential for maintaining the military’s technological edge. However, despite cloud computing’s strategic significance, the DoD faces challenges in successfully implementing department-wide cloud computing. In contrast, the Air Force’s cloud computing environment, Cloud One, is fully operational and has already integrated over 145 systems into its platform. …


Numerical Studies Of Semiclassical Light Storage Using The Coherent Atomic Transfer Function, Zachary T. Johnson Mar 2025

Numerical Studies Of Semiclassical Light Storage Using The Coherent Atomic Transfer Function, Zachary T. Johnson

Theses and Dissertations

Quantum communication through photons relies on photonic storage to preserve quantum states. However, when photons interact with matter, quantum information becomes distorted. A recently developed semi-classical analytical model predicts output light pulses from an electromagnetically induced transparency (EIT) system. Using the predictions, the model known as the Coherent Atomic Transfer (CAT) Function, is capable of predicting the stored pulse or reconstructing the original pulse. Using numerical convolution and deconvolution with the CAT function as an analog of the point spread function of Fourier optics can provide insights on the effects of EIT storage on the retrieved pulse. Blind deconvolution is …


Isotopic Analysis Of Lithium Hydroxide Monohydrate Using Laser-Induced Breakdown Self-Reversal Isotopic Spectrometry (Libris) And Machine Learning, Madison R. Moran Mar 2025

Isotopic Analysis Of Lithium Hydroxide Monohydrate Using Laser-Induced Breakdown Self-Reversal Isotopic Spectrometry (Libris) And Machine Learning, Madison R. Moran

Theses and Dissertations

High-resolution Laser-Induced Breakdown Self-Reversal Isotopic Spectrometry (LIBRIS) is implemented to record the 15.8 pm Li I 670.8 nm isotopic shift in LiOH · H2O samples of varying 6, 7Li abundance. A simple univariate linear regression demonstrates an acquired isotopic shift of 13.813 ± 1.21 pm in samples varying from 3 to 95 6Li at%. Supervised machine learning regressions are trained on self-reversal wavelength locations in order to quantify 6Li abundance. A stacked ensemble using two base learners yields the superlative characterization of 6Li abundance with RMSE of 5.66 at% and detection limit of 18.8 at%. Using …