Dynamic Flaring Non-Potential Fields On Quiet Sun Networks Scales, David L. Chesney, Hakeem M. Oluseyi, Norton B. Orange

Aerospace, Physics, and Space Science Faculty Publications

We report on the identification of dynamic flaring non-potential structures on quiet Sun (QS) supergranular network scales. Data from the Atmospheric Imaging Assembly on board the Solar Dynamics Observatory allow for the high spatial and temporal resolution of this diverse class of compact structures. The rapidly evolving nonpotential events presented here, with lifetimes <10 minutes, are on the order of 10″ in length. Thus, they contrast significantly with well-known active region (AR) non-potential structures such as high-temperature X-ray and EUV sigmoids (>100″) and micro-sigmoids (>10″) with lifetimes on the order of hours to days. The photospheric magnetic field environment derived from the Helioseismic and Magnetic Imager shows a lack of evidence for these flaring non-potential fields being associated with significant concentrations of bipolar magnetic elements. Of much …

Isothermal Titration Calorimetry Uncovers Substrate Promiscuity Of Bicupin Oxalate Oxidase, Hassan Ali Rana

Master of Science in Chemical Sciences Theses

Oxalate oxidase from Ceriporiopsis subvermispora (CsOxOx) is a manganese-dependent enzyme that catalyzes the oxygen-dependent oxidation of oxalate to form two moles of carbon dioxide and one mole of hydrogen peroxide. CsOxOx is the first oxalate oxidase reported to have a two beta barrel architecture (bicupin). The CsOxOx catalyzed oxidation of oxalate reaction can be monitored by coupling the product H₂O₂ to the horseradish peroxidase-catalyzed oxidation of 2,2'-azinobis-(3- ethylbenzthiazoline-6-sulphonic acid) and by membrane inlet mass spectrometry. Coupled enzyme assays often confound data interpretation. Isothermal titration calorimetry (ITC) measures heat changes that occur during a reaction. Therefore, ITC can …

Lead-Free Gunshot Residues As Forensic Evidence, Lashaundra A. Fambro

Master of Science in Chemical Sciences Theses

The analysis of gunshot residue (GSR) has been forensically relevant for many years and several methods are well characterized in scientific literature. However, the manufacture and distribution of lead-free alternatives to small caliber firearms ammunition is increasing rapidly as these types of rounds are more environmentally friendly and safer for use in indoor shooting ranges. Removing lead-containing compounds (e.g., lead styphnate) from the primer mixture eliminates a significant chemical marker vital to the legal precedent governing GSR analysis. The American Society for Testing and Materials (ASTM) standard ASTM E1588-95 is no longer applicable to such residues. With this emerging market, …

Nonnative Forest Insects And Pathogens In The United States: Impacts And Policy Options, Gary M. Lovett, Marissa Weiss, Andrew M. Liebhold, Thomas P. Holmes, Brian Leung, Kathy F. Lambert, David A. Orwig, Faith T. Campbell, Jonathan Rosenthal, Deborah G. Mccullough, Radka Wildova, Matthew P. Ayres

Dartmouth Scholarship

We review and synthesize information on invasions of nonnative forest insects and diseases in the United States, including their ecological and economic impacts, pathways of arrival, distribution within the United States, and policy options for reducing future invasions. Nonnative insects have accumulated in United States forests at a rate of ~2.5 per yr over the last 150 yr. Currently the two major pathways of introduction are importation of live plants and wood packing material such as pallets and crates. Introduced insects and diseases occur in forests and cities throughout the United States, and the problem is particularly severe in the …

The Dawn–Dusk Asymmetry Of Ion Density In The Dayside Magnetosheath And Its Annual Variability Measured By Themis, Andrew P. Dimmock, Tuija I. Pulkkinen, Adnane Osmane, Katariina Nykyri

Publications

The local and global plasma properties in the magnetosheath play a fundamental role in regulating solar wind–magnetosphere coupling processes. However, the magnetosheath is a complex region to characterise as it has been shown theoretically, observationally and through simulations that plasma properties are inhomogeneous, non-isotropic and asymmetric about the Sun-Earth line. To complicate matters, dawn–dusk asymmetries are sensitive to various changes in the upstream conditions on an array of timescales. The present paper focuses exclusively on dawn–dusk asymmetries, in particularly that of ion density. We present a statistical study using THEMIS data of the dawn–dusk asymmetry of ion density in the …

Age Re-Assessment Of The Cave Bear Assemblage From Urşilor Cave, North-Western Romania, Marius V. Robu

International Journal of Speleology

The most common methods used for assessing the relative age of a cave bear bone assemblage are the P⁴/₄ index (morphodynamic index of the cave bear fourth premolar), the K-index and the Index of Plumpness (both used for cave bear’s 2^nd metatarsal). Preliminary work on this (Robu et al., 2011), for Urşilor Cave (NW Romania), has indicated one of the youngest European cave bear populations. As the number of extracted fossil bones from the palaeontological excavation increased recently, a re-assessment of the of the age of the cave bear assemblage is necessary. 206 cave bear fourth …

Tools For Gravitational Wave Astronomy, Maria Babiuc-Hamilton

Physics Faculty Research

Gravitational waves have been confirmed. Tools are available for their study, including the Einstein Toolkit, SimulationTools and the SXS Gravitational Waveform Database.

Instrumentation Enhancements For Electron Yield Measurements Of Extremely Low-Conductivity High-Yield Dielectrics, Justin Christensen, Gregory Wilson, Jr Dennison

Presentations

Electron yield, a material dependent property which describes how it will charge under incident electron irradiation of a given energy, is defined as the number of electrons emitted from a material per incident electron. While very important for spacecraft charging modelling, the measurement of electron yield for insulating materials is very challenging because insulators quickly charge up under electron irradiation, thereby modifying the yield measurements.

Improved techniques have been implemented to reduce charging with each yield measurement, as well as to neutralize acquired charge between measurements. The goal is to determine the “intrinsic yield” (yield of uncharged insulator). New analysis …

Applications Of Nanoporous Gold Monoliths As Substrates For The Capture And Release Of Lectins And Glycoproteins, Allan Jonson Alla

Dissertations

Nanoporous gold (np-Au) monoliths are a free-standing nanostructured material with typical pore dimensions in the tens of nanometers range. The microstructure of np-Au resembles those of macroporous monolithic materials being used in chromatographic separations. The surfaces of np-Au monoliths were modified via flow methods with different ligands to develop affinity substrates for separations. A carbohydrate-modified np-Au monolith was prepared by immobilizing thiolated saccharides and further used to separate lectins. The np-Au monolith surface was also functionalized with self-assembled monolayers (SAMs) of α-lipoic acid (LA) followed by activation of carboxyl terminal groups to create amine reactive esters. Concanavalin A (Con A) …

Instrumentation Enhancements For Electron Yield Measurements Of Extremely Low-Conductivity High-Yield Dielectrics, Justin Christensen, Gregory Wilson, Jr Dennison

Conference Proceedings

Electron yield, a material dependent property which describes how it will charge under incident electron irradiation of a given energy, is defined as the number of electrons emitted from a material per incident electron. While very important for spacecraft charging modelling, the measurement of electron yield for insulating materials is very challenging because insulators quickly charge up under electron irradiation, thereby modifying the yield measurements.

Improved techniques have been implemented to reduce charging with each yield measurement, as well as to neutralize acquired charge between measurements. The goal is to determine the “intrinsic yield” (yield of uncharged insulator). New analysis …

Speleogenesis Of Critchfield Bat Caves And Associated Hydrogeology Of The Northern Edwards Aquifer, Williamson County, Texas, Ashley N. Landers

Electronic Theses and Dissertations

Karst development in the Edwards Aquifer has been significantly studied in the San Antonio and Barton Spring Segments; however, karst development remains poorly studied in the Northern Segment. Detailed characterization of the Northern Segment is vital for future water conservation because of increasing urban sprawl along the Interstate 35 corridor. The Northern Segment of the Edwards Aquifer consists of Lower Cretaceous strata of the Comanche Peak, Edwards, and Georgetown formations. The stratigraphy is dominated by Edwards Limestone as it is the only formation that crops out in the study area.

Karst, stratigraphic, GIS, and geochemical studies were conducted to evaluate …

The Stratigraphic Position Of Fossil Vertebrates From The Pojoaque Member Of The Tesuque Formation (Middle Miocene, Late Barstovian) Near Española, New Mexico, Garrett R. Williamson

Electronic Theses and Dissertations

The stratigraphy of the Pojoaque Member of the Tesuque Formation near Española, NM is not well understood. This region, during the Middle Miocene, represented a dynamic alluvial fan-fluvial-lacustrine environment within the Española Basin while the Rio Grande Rift was active. Cavazza (1986) identified two paleodrainage systems (lithosome A, basin-margin facies and B, basin-floor facies) by means of sandstone and conglomerate petrology, paleocurrent, and sedimentary facies analyses. After x-ray diffraction analyses of claystones within lithosome B, mordenite was discovered, which is a zeolite mineral commonly found within volcanic rocks. This is significant because the presence of mordenite confirms Cavazza’s (1986) conclusion …

Governor Signs Bill Establishing Commonwealth Center For Recurrent Flooding Resiliency, Brendan O'Hallarn

News Items

No abstract provided.

Quantum And Classical Optics–Emerging Links, Joseph H. Eberly, Xiao-Feng Qian, Asma Al Qasimi, Hazrat Ali, M. A. Alonso, R Gutiérrez-Cuevas, Bethany Little, John C. Howell, Tanya Malhotra, A. N. Vamivakas

Mathematics, Physics, and Computer Science Faculty Articles and Research

Quantum optics and classical optics are linked in ways that are becoming apparent as a result of numerous recent detailed examinations of the relationships that elementary notions of optics have with each other. These elementary notions include interference, polarization, coherence, complementarity and entanglement. All of them are present in both quantum and classical optics. They have historic origins, and at least partly for this reason not all of them have quantitative definitions that are universally accepted. This makes further investigation into their engagement in optics very desirable. We pay particular attention to effects that arise from the mere co-existence of …

On The Dimension Of Algebraic-Geometric Trace Codes, Phong Le, Sunil Chetty

Mathematics Faculty Publications

We study trace codes induced from codes defined by an algebraic curve X. We determine conditions on X which admit a formula for the dimension of such a trace code. Central to our work are several dimension reducing methods for the underlying functions spaces associated to X.

Information Seeking Practices Of Parents: Exploring Skills, Face Threats And Social Networks, Betsy Disalvo, Parisa Khanipour Roshan, Briana B. Morrison

Computer Science Faculty Proceedings & Presentations

Parents are often responsible for finding, selecting, and facilitating their children's out-of-school learning experiences. One might expect that the recent surge in online educational tools and the vast online network of information about informal learning would make this easier for all parents. Instead, the increase in these free, accessible resources is contributing to an inequality of use between children from lower and higher socio-economic status (SES). Through over 60 interviews with a diverse group of parents, we explored parents' ability to find learning opportunities and their role in facilitating educational experiences for their children. We identified differences in the use …

Complexity And Art, Jeffrey Jenkins

Physics Capstone Projects

A python application was written with the purpose of facilitating the representation of data in both an audio and visual manner. The representations are in the artistic forms of color field paintings and music. This allows for the quick recognition of similarities and differences in the complexities of the data and art. Data was created from musical pieces to give a reference of how closely the program could recreate art. They were chosen from nursery rhymes and Mozart. Also data was generated from random white noise, 1/f, and Brownian data sets. Comparing these data sets showed the greatest similarity between …

Effects Of Agricultural Restoration Practices On Stream Health In The Shenandoah Valley, Virginia, Erin L. Thady

Senior Honors Projects, 2010-2019

The Shenandoah Valley encompasses some of the highest agricultural producing regions in Virginia, many of which are large contributors of nutrients and sediment. The Conservation Reserve Enhancement Program (CREP) assists landowners in the installation of riparian restoration projects in which cattle are fenced out or a riparian buffer is planted. We examined the temporal effects of riparian restoration and the impact of upstream landuse on water quality for eleven farms participating in the CREP program for various times (from 1 to 14 years). We hypothesized that the length of time that the CREP program has been established would have a …

Nonlinear Dynamics Of Filaments In Free Space And Fluids, Victoria Kelley

Senior Honors Projects, 2010-2019

The purpose of this paper is to study a straight rod, held at both ends, with a known twist and tension or compression. We study the stability of this steady state when the system is dominated either by inertia or drag. In order to do this, we first replicate the work of Goriely and Tabor to look at the case with inertia, without drag. After conducting the analysis for that case, we then apply their framework to perform a linear stability analysis of a model that is without inertia, but with hydrodynamic drag. Our motivation is the study of locomotion …

Compost Land Management And Soil Carbon Sequestration, Kylene A. Hohman

Senior Honors Projects, 2010-2019

Extensive fossil fuel burning has released carbon dioxide into the atmosphere. Under proper ecological conditions plants convert atmospheric carbon dioxide into stable soil organic matter, a natural and efficient means of mitigating climate change. In the symbiotic relationship between mycorrhizae and plants, mycorrhizae provide plants with essential nutrients in exchange for carbon sugars leaked from the plants. Mycorrhizae convert carbon sugars to an exudate called glomalin, a protein that assists in developing soil aggregates composed of sand, silt, and clay. These aggregates, called humus, store carbon for hundreds of years under healthy ecological conditions. Compost prompts soil microbes to aerobically …

Pilot Project To Advance Distributed Wind In Virginia, Sydney Sumner, Kayla Cook

Senior Honors Projects, 2010-2019

The Virginia Energy Plan of 2014 created a demand for alternative energy sources to meet the goal of producing 25% of Virginia's energy from alternative sources by 2025. One of the most promising sources of alternative energy in Virginia is wind. As a result, the Virginia Department of Mines, Minerals, and Energy (DMME) took action to incentivize distributed wind (DW) power by enabling loan assistance with highly favorable terms toward the purchase and installation of distributed wind systems. Our team identified the nine sectors considered most likely to present the strongest potential for development of DW, and landowners within these …

Homogeneous And Isotropic Cosmology, The Schwarzschild Solution, And Applications, Pengcheng Zhang

Departmental Honors & Graduate Capstone Projects

Classically, the physics of the universe is described by Newton's Laws of Motion and Newton's Law of Universal Gravitation. In most cases, the results predicted by Newton's theories accurately agree with experimental observations. However, under certain limitations, classical theories may yield slight deviation from observations, such as when the speed of an object approaches the speed of light. At the extreme, classical theory completely fails to explain the motion of photons, which are massless particles of light. In 1915, Albert Einstein published the General Theory of Relativity. Einstein's theory provides a new perspective to a better understanding of the physics …

The Synthesis Of 1,3-Difluoro-2-Methyl-4-Phenylbenzene From A One-Pot Reaction Of Difluorocarbene And 1-Phenyl-2-Methylcyclobutene, Ruth Felicitas Menger

Senior Honors Projects, 2010-2019

Previous studies show that 1,2-disubstituted cyclobutenes can be used in reaction with difluorocarbene to produce 1,3-difluorobenzenes. A pathway to the synthesis of these types of compounds is of interest due to their presence in fluoroquinolone antibacterials, resins, and insecticides. The synthesis is unique because the fluorine atoms from the difluorocarbene are not adjacent to each other when the ring expands to a benzene ring. This study focuses on the reaction of difluorocarbene with 1-phenyl-2-methylcyclobutene, which was synthesized in one-pot in 4 steps starting from 1-phenyl-1-propyne and zirconocene dichloride.

The Synthesis And Colloidal Characterization Of Several Triscationic Amphiphilic Antibacterial Agents, Kristin R. Mckenna

Senior Honors Projects, 2010-2019

M-P,12,12, a triscationic amphiphile, was characterized for its antibacterial and colloidal properties as well as its ability to associate with sodium dodecyl sulfate (SDS). This amphiphile has a mesitylene core, one pyridinium headgroup, and two dimethyldodecylammonium tails. The critical aggregation concentration (CAC) for M-P,12,12 was determined by three different methods. According to isothermal titration calorimetry (ITC), the CAC is 2.54 mM, conductivity studies determined the CAC to be 2.07 and the degree of ionization to be 0.188, and nuclear magnetic resonance (NMR) spectroscopy yielded a CAC value of 1.73 mM. The NMR study of the water-insoluble solid formed by M-P,12,12 …

The Effect Of Hofmeister Series Counterions On The Colloidal And Antimicrobial Properties Of Triple-Headed Cationic Amphiphiles, Kirstie A. Thompson

Senior Honors Projects, 2010-2019

Antibacterial resistance is becoming increasingly prominent, causing a great need for novel antibacterial products. This work focuses on developing an understanding of the relationship between counterion identity on colloidal and antibacterial activity for cationic amphiphiles. In an amphiphile series with three hydrophilic quaternary ammonium bromide head groups and one hydrophobic tail, the amphiphile with a linear hydrocarbon chain with 18 carbons is more antibacterial than those with longer or shorter tails. Counterion exchange of the bromide counterions with various Hofmeister series anions significantly affects both antibacterial and colloidal activity. The logarithm of critical aggregation concentration [log(CAC)] was found to have …

Testing Of The Late-Ordovician Pre-Gice Warm Water Carbonate Hypothesis In Alabama, Brandon Euker, Stacey Law

Senior Honors Projects, 2010-2019

The Guttenberg Carbon Isotope Excursion (GICE) (uppermost Sandbian-lower Katian, Late Ordovician) has been suggested to represent the transition from a Cambrian-Ordovician greenhouse world to Late Ordovician icehouse world. This transition is thought to coincide with a proposed shift from deposition of warm water carbonate rocks to cool water carbonate rocks in the North American midcontinent. We used oxygen isotopes (d¹⁸O) of conodonts to test the idea that the rocks below the GICE interval represent a consistently warm environment. Conodonts were isolated from samples of the Chickamauga Group collected at the Tidwell Hollow section in Blount County, AL, from …

Sequences Of Spiral Knot Determinants, Ryan Stees

Senior Honors Projects, 2010-2019

Spiral knots are a generalization of the well-known class of torus knots indexed by strand number and base word repetition. By fixing the strand number and varying the repetition index we obtain integer sequences of spiral knot determinants. In this paper we examine such sequences for spiral knots of up to four strands using a new periodic crossing matrix method. Surprisingly, the resulting sequences vary widely in character and, even more surprisingly, nearly every one of them is a known integer sequence in the Online Encyclopedia of Integer Sequences. We also develop a general form for these sequences in terms …

A Computational Investigation Of Large Gaps In Contingency Tables, Noah J. Watson

Senior Honors Projects, 2010-2019

Integer programming can be used to find upper and lower bounds on the cells of a multi-dimensional contingency table using the information from the released margins. The linear relaxation of these programs also provides bounds and the discrepancy between these bounds, the integer programming gap, can be large. While the more notable examples of large gaps have been shown to be rare, here we provide some results on the rarity of large gaps on small tables.

Quantifying The Use Of Chloroform Vapor Exposure To Improve The Adhesion Of Au Thin Films Onto Pmma, Kathleen T. Krist

Senior Honors Projects, 2010-2019

The metallization of Au onto plastics is an important processing step in applications such as the aerospace and automotive industries, the field of microelectronics, and the fabrication of microfluidic devices. While its corrosion resistance and excellent electrical and thermal conductivity make Au a useful choice, its inertness results in poor adhesion to polymer surfaces. Previous studies have indicated that exposing commercially available poly(methyl methacrylate) (PMMA) sheets to chloroform vapor following Au deposition significantly improves adhesion. In this study, we utilized electron-beam evaporation and magnetron sputtering to deposit Au thin films onto 1.50 mm thick PMMA and exposed the samples to …

Population Projection And Habitat Preference Modeling Of The Endangered James Spinymussel (Pleurobema Collina), Marisa Draper

Senior Honors Projects, 2010-2019

The James Spinymussel (Pleurobema collina) is an endangered mussel species at the top of Virginia’s conservation list. The James Spinymussel plays a critical role in the environment by filtering and cleaning stream water while providing shelter and food for macroinvertebrates; however, conservation efforts are complicated by the mussels’ burrowing behavior, camouflage, and complex life cycle. The goals of the research conducted were to estimate detection probabilities that could be used to predict species presence and facilitate field work, and to track individually marked mussels to test for habitat preferences. Using existing literature and mark-recapture field data, these goals were accomplished …