Physical Sciences and Mathematics Commons^™

Assessment Of The Presence And Strength Of H-Bonds By Means Of Corrected Nmr, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The downfield shift of the NMR signal of the bridging proton in a H-bond (HB) is composed of two elements. The formation of the HB causes charge transfer and polarization that lead to a deshielding. A second factor is the mere presence of the proton-accepting group, whose electron density and response to an external magnetic field induce effects at the position of the bridging proton, exclusive of any H-bonding phenomenon. This second positional shielding must be subtracted from the full observed shift in order to assess the deshielding of the proton caused purely by HB formation. This concept is applied …

Infrared Spectroscopy Of The Nitrogenase Mofe Protein Under Electrochemical Control: Potential-Triggered Co Binding, P. Paengnakorn, Philip A. Ash, Sudipta K. Shaw, Karamatullah Danyal, T. Chen, Dennis R. Dean, Lance C. Seefeldt, Kylie A. Vincent

Chemistry and Biochemistry Faculty Publications

We demonstrate electrochemical control of the nitrogenase MoFe protein, in the absence of Fe protein or ATP, using europium(III/II) polyaminocarboxylate complexes as electron transfer mediators. This allows the potential dependence of proton reduction and inhibitor (CO) binding to the active site FeMo-cofactor to be established. Reduction of protons to H2 is catalyzed by the wild type MoFe protein and Β-98^Tyr→His and Β-^99Phe→His variants of the MoFe protein at potentials more negative than -800 mV (vs. SHE), with greater electrocatalytic proton reduction rates observed for the variants compared to the wild type protein. Electrocatalytic proton reduction is strongly …

Scalable Clustering Using The Dempster-Shafer Theory Of Evidence, Alireza Chakeri

USF Tampa Graduate Theses and Dissertations

Clustering large data sets has become very important as the amount of available unlabeled data increases. Single Pass Fuzzy C-Means (SPFCM) is useful when memory is too limited to load the whole data set. The main idea is to divide dataset into several chunks and to apply fuzzy c-means (FCM) to each chunk. SPFCM uses the weighted cluster centers of the previous chunk in the next data chunks. However, when the number of chunks is increased, the algorithm shows sensitivity to the order in which the data is processed. Hence, we improved SPFCM by recognizing boundary and noisy data in …

Cosm News, Georgia Southern University

College of Science & Mathematics: News & Publications (2012-2022)

• Physics Major Reed Hodges: Blue Waters Student Internship Update

Fundamentals Of Machine Learning For Neural Machine Translation, John D. Kelleher

Conference papers

This paper presents a short introduction to neural networks and how they are used for machine translation and concludes with some discussion on the current research challenges being addressed by neural machine translation (NMT) research. The primary goal of this paper is to give a no-tears introduction to NMT to readers that do not have a computer science or mathematical background. The secondary goal is to provide the reader with a deep enough understanding of NMT that they can appreciate the strengths of weaknesses of the technology. The paper starts with a brief introduction to standard feed-forward neural networks (what …

Geolocator Tracking Of Great Reed-Warblers (Acrocephalus Arundinaceus) Identifies Key Regions For Migratory Wetland Specialists In The Middle East And Sub-Saharan East Africa, Joshua J. Horns, Evam Buechley, Mark William Chynoweth, Lale Aktay, Emrah Çoban, Mehmet Sli Kırpık, Jordan M. Herman, Yakup Şaşmaz, Çağan H. Şekercioğlu

Wildland Resources Faculty Publications

Wetland-dependent migratory songbirds represent one of the most vulnerable groups of birds on the planet, with >67% of wetland-obligate species threatened with extinction. One of the major hurdles for conservation efforts is determining the migration routes, stopover sites, and wintering sites of these species. We describe an annual migration cycle revealed by geolocator tracking of Great Reed-Warblers (Acrocephalus arundinaceus) breeding in the Aras River wetlands of eastern Turkey. Because of its relatively large size and breeding ground fidelity, the Great ReedWarbler is an excellent candidate for geolocator studies and can serve as an indicator species for other wetland songbirds, many …

Long-Term Data Storage In Diamond, Siddharth Dhomkar, Jacob Henshaw, Harishankar Jayakumar, Carlos A. Meriles

Publications and Research

The negatively charged nitrogen vacancy (NV−) center in diamond is the focus of widespread attention for applications ranging from quantum information processing to nanoscale metrology. Althoughmostwork so far has focused on the NV− optical and spin properties, control of the charge state promises complementary opportunities. One intriguing possibility is the long-term storage of information, a notion we hereby introduce using NV-rich, type 1b diamond. As a proof of principle, we use multicolor optical microscopy to read, write, and reset arbitrary data sets with twodimensional (2D) binary bit density comparable to present digital-video-disk (DVD) technology. Leveraging on the singular dynamics of …

2016 Program, Office Of Academic Affairs

Programs

Eastern Illinois University is a community enthusiastically engaged in intellectual exploration. This includes faculty testing the boundaries of knowledge within their disciplines and the boundaries of how to convey that knowledge to their students. It also includes students, both graduate students joining with their faculty mentors in pressing the disciplinary boundaries, and undergraduate students discovering the front edges of the disciplines under the guidance of their instructors. Today we celebrate the full range of such faculty contributions: journal articles, book chapters, monographs, art works, music compositions, performances in all forms, and a host of others. Funded research contributions also are …

The Tribology And Chemistry Of Phosphorus Containing Lubricant Additives, David W. Johnson

Chemistry Faculty Publications

Phosphate esters, thiophosphate esters and metal thiophosphates have been used as lubricant additives for over 50 years. Recently, phosphorus‐containing ionic liquids have emerged as a new class of lubricant additives. While the use of phosphorus compounds has been extensive, a detailed knowledge of how they work has been a much more recent development. In this chapter, the use of phosphate esters, thiophosphate esters, metal thiophosphates and phosphorus‐containing ionic liquids as antiwear or extreme pressure additives is discussed. The primary emphasis will be on how they form a protective film, which is both durable and reduces friction. The first part of …

Asymmetric Transformations Catalyzed By Chiral Binol Alkaline Earth Metal Phosphate Complexes, Sri Krishna Nimmagadda

USF Tampa Graduate Theses and Dissertations

Small molecule hydrogen bond donors have emerged as versatile catalysts in asymmetric synthesis. Within this class, chiral BINOL phosphoric acid is regarded as one of the pioneer catalysts used in several asymmetric transformations. The ability of the catalyst to activate the substrates could be controlled in two different ways. (1) Dual activation/bifunctional activation of substrate by hydrogen bond interactions or ion pairing with phosphoric acid or (2) By forming chiral BINOL phosphate metal complex that could significantly alter the interactions in chiral space. In particular, chiral alkaline earth metal phosphate complexes have unique advantages as catalysts owing to the ubiquitous …

Art As A Tool In Quantum Mechanics, Zachary Vealey

Oglethorpe Journal of Undergraduate Research

Revolutions in scientific thought often have substantial societal consequences, however, cultural assimilation of the new idea is contingent on a widespread understanding. Historically recent developments in modern physics, such as quantum mechanics and general relativity, suffer from their notoriously perceived difficulty, thus hindering cultural assimilation. To address this issue, art can serve as a useful complement to a student studying quantum mechanics - especially through its interpretation of delocalized electron density. A cross-disciplinary approach affords a greater diversity in participation and consequently results in a broader scientific outreach.

Open Access Geospatial Data, Hannah Hamalainen

Open Access Events

The landscape of open-access geospatial data is vastly growing with an abundance of open source software, websites, and datasets available to the public. How do we find and access these resources? Find out from the Geospatial Services Center.

U.S. Drought Monitor, October 25, 2016, David Simeral

United States Agricultural Commodities in Drought Archive

Drought map of U.S. for October 25, 2016 (10/25/16) plus: U.S. crop areas experiencing drought (map), Approximate percentage of crop located in drought, by state (bar graph), Percent of crop area located in drought, past 52 weeks (line graph) for: Corn, Soybeans, Hay, Cattle, Winter wheat.

Exploring The Potential Linkages Between Oil-Field Brine Reinjection, Crystalline Basement Permeability, And Triggered Seismicity For The Dagger Draw Oil Field, Southeastern New Mexico, Usa, Using Hydrologic Modeling, Y. Zhang, Stanislav S. Edel, Jeff D. Pepin, Mark A. Person, Ronald F. Broadhead, J. P. Ortiz, Susan L. Bilek, Peter S. Mozley, James P. Evans

Geosciences Faculty Publications

We used hydrologic models to explore the potential linkages between oil-field brine reinjection and increases in earthquake frequency (up to M_d 3.26) in southeastern New Mexico and to assess different injection management scenarios aimed at reducing the risk of triggered seismicity. Our analysis focuses on saline water reinjection into the basal Ellenburger Group beneath the Dagger Draw Oil field, Permian Basin. Increased seismic frequency (>M_d 2) began in 2001, 5 years after peak injection, at an average depth of 11 km within the basement 15 km to the west of the reinjection wells. We considered several scenarios …

Pedestrian Detection In Low Quality Moving Camera Videos, Saurabh Hinduja

USF Tampa Graduate Theses and Dissertations

Pedestrian detection is one of the most researched areas in computer vision and is rapidly gaining importance with the emergence of autonomous vehicles and steering assistance technology. Much work has been done in this field, ranging from the collection of extensive datasets to benchmarking of new technologies, but all the research depends on high-quality hardware such as high-resolution cameras, Light Detection and Ranging (LIDAR) and radar.

For detection in low-quality moving camera videos, we use image deblurring techniques to reconstruct image frames and use existing pedestrian detection algorithms and compare our results with the leading research done in this area.

Women On The Board Of Directors And Their Impact On The Financial Performance Of A Firm: An Empirical Investigation Of Female Directors In The United States Technology Sector, Obinna Mogbogu

Theses and Dissertations

This study uses a sample of S&P 500 firms in the United States technology sector to investigate the likely relationship between female directors and financial performance of firms measured by return on average assets and return on average equity as the two accounting based measures of performance. Reasonable theoretical arguments drawn from resource dependency, human capital, agency, and social psychology theory, suggests that the gender diversity of the board of directors may have either a positive, negative, or neutral effect on the financial performance of the firm. Using nonparametric statistics approach, we find a small negative relationship between female directors …

The Purdue Agro-Climatic (Pac) Dataset For The U.S. Corn Belt: Development And Initial Results, Xing Liu, Elin Jacobs, Anil Kumar, Larry Biehl, Jeff Andersen, Dev Niyogi

Department of Earth, Atmospheric, and Planetary Sciences Faculty Publications

This study is a result of a project titled ‘‘Useful to Usable (U2U): Transforming Climate Variability and Change Information for Cereal Crop Producers”. This paper responds to the project goal to improve farm resiliency and proftability in the U.S. Corn Belt region by transforming existing meteorological dataset into usable knowledge and tools for the agricultural community.

A high-resolution agro-climatic dataset that covers the U.S. Corn Belt was built for the U2U project based on a Land Data Assimilation System (LDAS) framework. This data referred to as the Purdue Agro-climatic (PAC) dataset is a gridded, continuous dataset suitable for agrocli- matic …

Designing Laboratories For Small Scale Digital Device Forensics, Richard P. Mislan, Tim Wedge

Annual ADFSL Conference on Digital Forensics, Security and Law

The ubiquity of small scale digital devices (SSDD), the public’s ever increasing societal dependence on SSDD, and the continual presence of SSDD at all types of crime scenes, including non-technical and violent crimes, demand a formalized curriculum for the education and training of future cyber forensic examiners. This paper presents the various SSDD forensics labs currently in use and under development for future use at the Purdue University Cyber Forensics Laboratory. The primary objective of each module is to provide specific real-world cases for the learning, comprehension, and understanding of hands-on investigative techniques and methodologies. The purpose of this paper …

Network Forensic Investigation Of Internal Misuse/Crime In Saudi Arabia: A Hacking Case, Abdulrazaq Al-Murjan, Konstantinos Xynos

Annual ADFSL Conference on Digital Forensics, Security and Law

There are ad-hoc guidelines and a limited policy on computer incident response that does not include computer forensic preparation procedures (e.g. logging incidents). In addition, these guidelines do not consider the requirement of Islamic law for admissible evidence at an organisational level in Saudi Arabia. Network forensic investigation might breach the Saudi law if they follow ad-hoc or international digital forensic standards such as Association of Chief Police Officers (ACPO) guidelines. This might put the organisation in a costly situation when a malicious employee sues an Islamic court. This is because the law of Saudi Arabia is complying with Islamic …

Using Climate Information For Drought Planning, Taryn Finnessey, Michael Hayes, Jeff Lukas, Mark D. Svoboda

National Drought Mitigation Center: Faculty Publications

Historically, drought has been responded to rather than prepared for, yet studies have illustrated that proactive investment in drought risk management reduces impacts and overall response costs. One key element of preparedness is the use of sufficient climate information for monitoring, forecasting, and tracking long-term trends. In the face of a changing climate and increasing variability, these types of data are even more critical for planning and overall resiliency. The systematic use of these data to inform the drought planning component of drought risk management is a relatively recent development. Actionable science has direct applicability for planning and decision-making, and …

Lava Flow Hazard Assessment For The Idaho National Laboratory, Idaho Falls, And Pocatello, Idaho, U.S.A., Elisabeth Gallant

USF Tampa Graduate Theses and Dissertations

This study presents a probabilistic lava flow hazard assessment for the Idaho National Laboratory (INL) and the cities of Idaho Falls and Pocatello, Idaho. The impetus of this work is to estimate the conditional probability that a lava flow on the eastern Snake River Plain (ESRP) will impact the areas of interest given the formation of a new volcanic vent in the region. A list of 288 eruptive events, derived from a previously published inventory of 506 surface and 32 buried vents, was created to reduce the biasing of spatial density maps towards eruptions with multiple dependent vents. Conditional probabilities …

Mapping Robinia Pseudoacacia Forest Health Conditions By Using Combined Spectral, Spatial And Textureal Information Extracted From Ikonos Imagery, H. Wang, Ruiliang Pu, Z. Zhang

School of Geosciences Faculty and Staff Publications

n this study grey-level co-occurrence matrix (GLCM) textures and a local statistical analysis Getis statistic (Gi), computed from IKONOS multispectral (MS) imagery acquired from the Yellow River Delta in China, along with a random forest (RF) classifier, were used to discriminate Robina pseudoacacia tree health levels. The different RF classification results of the three forest health conditions were created: (1) an overall accuracy (OA) of 79.5% produced using the four MS band reflectances only; (2) an OA of 97.1% created with the eight GLCM features calculated from IKONOS Band 4 with the optimal window size of 13 × 13 and …

Evolution From The Plasmon To Exciton State In Ligand-Protected Atomically Precise Gold Nanoparticles, Meng Zhou, Chenjie Zeng, Yuxiang Chen, Shuo Zhao, Matthew Y. Sfeir, Manzhou Zhu, Rongchao Jin

Publications and Research

The evolution from the metallic (or plasmonic) to molecular state in metal nanoparticles constitutes a central question in nanoscience research because of its importance in revealing the origin of metallic bonding and offering fundamental insights into the birth of surface plasmon resonance. Previous research has not been able to probe the transition due to the unavailability of atomically precise nanoparticles in the 1-3 nm size regime. Herein, we investigate the transition by performing ultrafast spectroscopic studies on atomically precise thiolate-protected Au₂₅, Au₃₈, Au₁₄₄, Au₃₃₃, Au_∼520 and Au_∼940 nanoparticles. Our results …

Phenomenological Mssm Interpretation Of Cms Searches In Pp Collisions At √S=7 And 8 Tev, M M. Baarmand, Vallary Bhopatkar, Stefano Colafranceschi, Marcus Hohlmann, H Kalakhety, D Noonan, Tuhin S. Roy, Francisco X. Yumiceva, Cms Collaboration

Aerospace, Physics, and Space Science Faculty Publications

Searches for new physics by the CMS collaboration are interpreted in the framework of the phenomenological minimal supersymmetric standard model (pMSSM). The data samples used in this study were collected at s=7 and 8 TeV and have integrated luminosities of 5.0 fb−1and 19.5 fb−1, respectively. A global Bayesian analysis is performed, incorporating results from a broad range of CMS supersymmetry searches, as well as constraints from other experiments. Because the pMSSM incorporates several well-motivated assumptions that reduce the 120 parameters of the MSSM to just 19 parameters defined at the electroweak scale, it is possible to assess the results of …

Drop By Drop

SIGNED: The Magazine of The Hong Kong Design Institute

In October 2013 Yale University professor Sheila Levrant de Bretteville began exploring the water's edge at four Hong Kong harbours with an interdisciplinary group of students from HKDI. The issues that captured their attention formed the basis of some vivid and emotionally compelling work.

Structure And Physical Conditions In The Huygens Region Of The Orion Nebula, C. R. O'Dell, Gary J. Ferland, M. Peimbert

Physics and Astronomy Faculty Publications

Hubble Space Telescope images, MUSE maps of emission lines, and an atlas of high velocity resolution emission-line spectra have been used to establish for the first time correlations of the electron temperature, electron density, radial velocity, turbulence, and orientation within the main ionization front of the nebula. From the study of the combined properties of multiple features, it is established that variations in the radial velocity are primarily caused by the photoevaporating ionization front being viewed at different angles. There is a progressive increase of the electron temperature and density with decreasing distance from the dominant ionizing star θ^{1 …}

Sdss-Iv Manga: Stellar Population Gradients As A Function Of Galaxy Environment, D. Goddard, D. Thomas, C. Maraston, K. Westfall, J. Etherington, R. Riffel, M. D. Mallmann, Z. Zheng, M. Argudo-Fernández, M. A. Bershady, K. Bundy, N. Drory, D. Law, Renbin Yan, D. Wake, A. Weijmans, D. Bizyaev, J. Brownstein, R. R. Lane, R. Maiolino, K. Masters, M. Merrifield, C. Nitschelm, K. Pan, A. Roman-Lopes, T. Storchi-Bergmann

Physics and Astronomy Faculty Publications

We study the internal radial gradients of stellar population properties within 1.5 R_e and analyse the impact of galaxy environment. We use a representative sample of 721 galaxies with masses ranging between 10⁹ M_⊙ and 10^11.5 M_⊙ from the SDSS-IV survey MaNGA. We split this sample by morphology into early-type and late-type galaxies. Using the full spectral fitting code firefly, we derive the light and mass-weighted stellar population properties, age and metallicity, and calculate the gradients of these properties. We use three independent methods to quantify galaxy environment, namely the Nth nearest neighbour, the …

Making Scholarly Activity Available To The Masses: The Scaffolding Of Scholarship Throughout The Undergraduate Curriculum, Michael Savarese, Trent R. Brown, Carolyn Culbertson, Anna Carlin

Florida Statewide Symposium: Best Practices in Undergraduate Research

Florida Gulf Coast University’s Quality Enhancement Plan (QEP) focuses on improving student critical thinking, information literacy, and written communication. Rather than developing these skills through traditional methods (e.g., through senior-level, independent research), these learning outcomes are practiced through scholarly experiences. Traditional undergraduate scholarship manifests itself through terminal, senior capstone or research experiences. These, because of the economy of scale, typically reach a minority of students, often just honors students or those approached by faculty mentors. At FGCU, however, scholarly experiences are a part of the curriculum throughout the program of study, and scaffolded to build greater depth and sophistication. Presented …

Space Environment Effects Of Ionizing Radiation On Seed Germination And Growth, Alex Souvall, Takuyuki Sakai, Takahiro Shimizu, Yuta Takahashi, Midori Morikawa, Shusuke Okita, Akihiro Nagata, Toshihiro Kameda, Shaunda Wenger, Jr Dennison

Presentations

An initial limited set of tests of germination rate and seed growth in a controlled environment have identified statistically significant differences between control samples and seed flown in a Russian LEO research flight. Most significantly, average seed germination of space borne seeds was 2 days less than the 6 days for the control seeds. Modification of the seed coat leading to enhanced rate of water uptake, as a result of radiation from the space environment or abrasion due to launch vibrations, is hypothesized to cause early germination. High school students will conduct growth tests on seeds exposed to simulated space …

Plasma Deflection Test Setup For E-Sail Propulsion Concept, Allen Andersen, Jason Vaughn, Todd Schneider, Ken Wright

Presentations

The Electronic Sail or E-Sail is a novel propulsion concept based on momentum exchange between fast solar wind protons and the plasma sheath of long positively charged conductors comprising the E-Sail. The effective sail area increases with decreasing plasma density allowing an E-Sail craft to continue to accelerate at predicted ranges well beyond the capabilities of existing electronic or chemical propulsion spacecraft. While negatively charged conductors in plasmas have been extensively studied and flown, the interaction between plasma and a positively charged conductor is not well studied. We present a plasma deflection test method using a differential ion flux probe …