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Full-Text Articles in Physical Sciences and Mathematics

Biomimetic Design Of Mechanochromic Single-Chain Nanoparticle Polymer Networks, Samuel Robinson May 2025

Biomimetic Design Of Mechanochromic Single-Chain Nanoparticle Polymer Networks, Samuel Robinson

Honors Theses

Hydrogels are a class of polymer networks that show promise in many biomedical applications but are typically limited in use due to their brittle nature. Synthesizing hydrogel networks that are comparable to biological materials has long been an area of interest. In this study, we are working to create a polymer network inspired by the muscular protein, titin. Titin can unfold under mechanical tension, releasing stored length, making the muscle material extensible and durable. To mimic this behavior, we propose creating a polymer network with similar stored length using single chain nanoparticles (SCNPs) cross-linked with phenolphthalein (PP) and β-cyclodextrin (β-CD). …


Comparison Of Rt-Qpcr And Rt-Ddpcr On Assessing Model Virus In Wastewater, Wafa Youssfi May 2025

Comparison Of Rt-Qpcr And Rt-Ddpcr On Assessing Model Virus In Wastewater, Wafa Youssfi

Graduate Theses and Dissertations

There is an increasing demand for quantifying viral loads in diverse wastewater systems using polymerase chain reaction (PCR). This study evaluates the performance of two commonly used workflows: reverse transcription quantitative PCR (RT-qPCR) and reverse transcription droplet digital PCR (RT-ddPCR) in wastewater. We compared the two methods by measuring the viral ribonucleic acid (RNA) of a model virus Phi6 in samples collected from various treatment stages at the Westside Wastewater Treatment Facility in Fayetteville, AR. RNA was extracted from real and synthetic wastewater samples and analyzed in parallel using both RT-qPCR and RT-ddPCR. Findings reveal that both methods demonstrated similar …


An Integrative Approach To Einstein’S Field Equations Of General Relativity For High School Students, Christina M. Aintablian May 2025

An Integrative Approach To Einstein’S Field Equations Of General Relativity For High School Students, Christina M. Aintablian

Senior Honors Theses

Einstein’s Field Equations form the foundation of the theory of General Relativity, describing the interdependence of mass-energy and spacetime curvature, where curvature gives rise to gravity. However, the complexity of these equations makes them difficult for high school students to grasp. The mathematical framework of General Relativity is introduced step by step, beginning with relative motion and culminating in a discussion of complex phenomena that challenge modern physics. Each explanation intertwines core concepts of relativity with pre-established mental models to enhance learning. Through the use of figures, analogies, narratives, and thought experiments, a structured framework is developed to make relativity …


Nonlinear Power Function Model Changepoint Detection., Jacob Steven Townson May 2025

Nonlinear Power Function Model Changepoint Detection., Jacob Steven Townson

Electronic Theses and Dissertations

Most work surrounding changepoint analysis focuses on linear models. This dissertation explores changepoint detection in nonlinear power function models, specifically focusing on models where the constant multiplier and power are the parameters to be estimated in addition to the changepoint parameter. The study assumes an asymptotic framework as the number of observations approaches infinity. The study explores various model fitting algorithms, and decides to employ the Newton-Raphson method for parameter estimation, with a custom implementation developed to optimize the process. The research first establishes the strong consistency of estimators for the model without a changepoint. Building on this result, consistency …


Finer Resolution Paleoclimatological Network Analysis Of Hydrological Extremes And Tree-Growth Response For Kentucky, U.S.A., Jordan Sharp May 2025

Finer Resolution Paleoclimatological Network Analysis Of Hydrological Extremes And Tree-Growth Response For Kentucky, U.S.A., Jordan Sharp

Electronic Theses and Dissertations

As climate change accelerates, southeastern states like Kentucky face increasing environmental and economic challenges. To improve future climate predictions, this study enhances paleoclimate reconstructions with a high-resolution tree-ring network for Kentucky, combining data from both living trees and dendroarchaeological sources. I evaluated the climate sensitivity of tree growth using superposed epoch analysis, static correlations, and spatial field correlations in KNMI Climate Explorer, along with moving correlations against seasonal temperature and moisture variables. Findings reveal that white oak and tulip poplar exhibit significant drought sensitivity across both live and archeological sites. However, I observed a weakening relationship between tree-ring growth and …


The Petm: A Window Into Earth's Future Climate, Jacalyn M. Wittmer Malinowski May 2025

The Petm: A Window Into Earth's Future Climate, Jacalyn M. Wittmer Malinowski

Climate Change and the Individual, 2025-26

The Paleocene-Eocene Thermal Maximum (PETM) is not just an event that occurred in Earth’s distant past (~55 million years ago) but is a crucial lesson for today’s meteoric climate change. The PETM offers a historical parallel of rapid flux of greenhouse gases into the atmosphere that caused global warming, ocean acidification, dramatic changes in weather, and extinctions. This global warming event was the result of 20,000 years of “rapid” warming (in geological terms) however, we are experiencing rates of warming that are 5-10x higher than PETM levels. We are not experiencing rapid warming today, in comparison to the past, we …


Bibliography Of Christianity And Mathematics Update, Calvin Jongsma May 2025

Bibliography Of Christianity And Mathematics Update, Calvin Jongsma

Faculty Work Comprehensive List

This was a banquet talk given at the Twenty-fourth Biennial Conference of the Association of Christians in the Mathematical Sciences held at Dordt University on May 28-June 1, 2024.

It provides an update on the progress being made in the author’s project of producing a second edition of Bibliography of Christianity and Mathematics. This work is now being developed as a Zotero database with a slightly broader focus on Religious Faith and the Mathematical Sciences and with a much expanded list of books, articles, and blog posts on the topic. The author hopes to make the database public sometime …


Setting Up Students For Success: Analysis Of Effectiveness For Mathematics Placement, Jeff Carvell, Jason N.E. Ho, Dave Klanderman, Sarah Klanderman May 2025

Setting Up Students For Success: Analysis Of Effectiveness For Mathematics Placement, Jeff Carvell, Jason N.E. Ho, Dave Klanderman, Sarah Klanderman

Faculty Work Comprehensive List

How do we effectively and equitably place students into math classes in a way that provides them the best chance of success? As many higher education institutions veer away from placement based on standardized testing, many departments are seeking placement alternatives that will properly support students. Additionally, math placement determines not only a student’s mathematics courses but also influences their progress in related fields, including physics, chemistry, engineering, and more. This paper will describe three different existing placement systems at each of our liberal arts institutions as well as the affordances and constraints of each approach. Further, we analyze data …


Iowa Waste Reduction Center Newsletter, May 2025, University Of Northern Iowa. Iowa Waste Reduction Center. May 2025

Iowa Waste Reduction Center Newsletter, May 2025, University Of Northern Iowa. Iowa Waste Reduction Center.

Iowa Waste Reduction Center Newsletter

Contents:

--- Meet the Environmental Assistance Program Staff
--- IWRC Director Joe Bolick joins ISOSWO Board of Directors
--- Keeping Tabs on PFAS
--- IGBC Brewery wins gold
--- Farewell to Paige
--- Compost Operator Renewal Training
--- Industry News


The Impact Of Corporate Profits On Gdi Estimates: Forecasting And Data Revisions, Peterson Haas May 2025

The Impact Of Corporate Profits On Gdi Estimates: Forecasting And Data Revisions, Peterson Haas

Honors Theses

The National Income and Product Accounts (NIPAs) produced by the U.S. Bureau of Economic Analysis (BEA) provide key measures of U.S. economic activity, including gross domestic product (GDP) and gross domestic income (GDI). Although conceptually equivalent, GDP and GDI often diverge due to differences in source data and revision timing. This study focuses on corporate profits—a small but volatile component of GDI that is frequently revised, especially during the BEA’s annual (A1) and benchmark (C1) revisions. I examine how revisions to corporate profits influence GDI revisions and whether they can improve real-time estimates of GDI. First, I document the size …


Comparing Spatial Interfaces Of The Tower Of London Task, Paean Luby May 2025

Comparing Spatial Interfaces Of The Tower Of London Task, Paean Luby

Honors Theses

Executive functioning involves key mental skills like self-control and problem-solving, which are often impaired by brain injuries. The Tower of London (TOL) task is a problem set commonly used to assess planning, but both traditional and digital versions can lack consistency, and, in the case of digital versions, realism and physical engagement. Research shows that 3D tasks, such as a 3D version of the Tower of Hanoi, engage the brain in distinct and meaningful ways, likely due to increased spatial involvement. By merging immersive 3D environments with the consistency of digital tools, virtual reality (VR) has the potential to enhance …


Tracking The Evolution Of Crossings In Memristive Hysteresis Responses, Eric Neuhaus May 2025

Tracking The Evolution Of Crossings In Memristive Hysteresis Responses, Eric Neuhaus

Honors Theses

A memristive device has an internal resistance that depends on the history of the applied voltage signal. This dependence gives rise to a pinched hysteresis loop in its current-voltage (I-V) characteristic, a property of resistive switching.

Beyond the crossing at the origin, additional crossings can emerge throughout the loop.

Our computational model simulates the current-voltage response of a memristive device under a sinusoidal voltage. We apply techniques from catastrophe theory to perform parametric analysis, assessing how intrinsic parameters influence the emergence of additional crossings. From there, we introduce a voltage transformation parameter to continuously transition the signal to a symmetric …


Privacy-Aware Ai-Based Agricultural Monitoring Using Internet Of Drones, Md Benozir Hossain May 2025

Privacy-Aware Ai-Based Agricultural Monitoring Using Internet Of Drones, Md Benozir Hossain

Honors Theses

Artificial Intelligence (AI) has become a vital tool for agricultural farming. AI-based image processing models utilizing different machine learning (ML) algorithms and deep learning (DL) offer advanced functionalities in disease detection, yield estimation, land use, etc. This thesis examines AI-driven techniques utilizing Convolutional Neural Networks (CNN) with the addition of Federated Learning (FL) to analyze satellite and drone images for agricultural insights, especially in detecting Cotton diseases. The AI models improve agricultural farming in many ways, such as using data to make critical decisions, reducing labor costs, pest infestations, etc. Moreover, these models allow farmers to minimize yield losses by …


Tailoring The Morphology Of Block Copolymers Via Solvent-Vapor Annealing, Bayleigh Madelin Loving May 2025

Tailoring The Morphology Of Block Copolymers Via Solvent-Vapor Annealing, Bayleigh Madelin Loving

Honors Theses

Triblock polystyrene-polyisobutylene-polystyrene (PS-PIB-PS) copolymers have widespread applications from thermoplastic elastomers to protective coatings for ballistic applications. The incompatibility between the soft PIB and hard PS phases leads to phase separation and subsequent formation of morphological domains like lamellae and cylinders. The structures are stabilized by physical crosslinks, which can greatly improve the toughness of the triblock systems by preventing chain pullout during tensile deformation. We tailored the morphologies (achieving different morphologies with the same block copolymer) by changing the annealing conditions of the block copolymers. Solvent vapor annealing was used to selectively activate the mobility of a particular block, causing …


A Spectroscopic Survey Of Atmospheres Of Super-Earths, Luke Brust May 2025

A Spectroscopic Survey Of Atmospheres Of Super-Earths, Luke Brust

Honors Theses

Recent research has made it possible to use spectroscopy to analyze the composition of the atmospheres of exoplanets, planets that orbit other stars. Most projects thus far have focused on the atmospheres of gas giants, as it is less challenging to observe them with available equipment. This project studies the atmospheres of four Super- Earths, planets that have a mass greater than the Earth but smaller than Neptune. This is accomplished by processing the raw spectroscopic data from the Hubble Space Telescope and modeling the atmosphere using the program 𝝉-Rex3. This survey found clear results from two of the selected …


Globally Adaptive Exponential Integrators For Stiff Systems Of Odes, Anzhelika Vasilyeva May 2025

Globally Adaptive Exponential Integrators For Stiff Systems Of Odes, Anzhelika Vasilyeva

Honors Theses

This thesis introduces a novel method for solving systems of Ordinary Differential Equations (ODEs) resulting from the spatial discretization of Partial Differential Equations (PDEs). The proposed approach builds upon an existing technique that employs Krylov projection, which requires evaluating a matrix function at each timestep. The innovation of the new method lies in its reuse strategy, which shifts the perspective from direct matrix function evaluation to polynomial interpolation. Numerical experiments conducted on constant and variable coefficient heat equations, with both smooth and discontinuous initial data, demonstrate the computational time advantage of the new approach. The results indicate that this method …


Knighted Pawn's Tour, Morgan Wilson May 2025

Knighted Pawn's Tour, Morgan Wilson

Honors Theses

The Knighted Pawn’s Tour is a variant of the traditional Knight’s Tour problem, whichitself is an instance of the Hamiltonian cycle problem. The deviation from the Knight’s Tour problem is that a pawn begins on any field on the second rank (row), and advances with legal moves that can include captures to the opposite end of the board to become a knight. These fields, used by the pawn on the path to knighthood, are subsequently forbidden for the knight’s return to the starting field. The knight must traverse the rest of the chessboard, visiting each remaining field exactly once …


Synthetic Efforts Towards An Analog Of Ly426965, Macy Sproles May 2025

Synthetic Efforts Towards An Analog Of Ly426965, Macy Sproles

Honors Theses

The 5-hydroxytryptamine1A (5-HT1A) receptor is a key target in the treatment of various neuropsychiatric conditions, and the development of selective antagonists offers promising therapeutic potential.24 This study aimed to develop a synthetic analog of LY426965, a selective 5-HT1A receptor antagonist. The synthetic route was initiated from dimethyl-2-phenylmalonate, employing pig liver esterase (PLE) as an enantioselective biocatalyst to achieve regioselective hydrolysis of one ester moiety in the malonic diester intermediate.17 Through a series of stereochemically controlled transformations, a new intermediate was successfully synthesized. Although the target molecule was not obtained, a new compound was synthesized …


Joint Modelling Of Longitudinal Egfr Trajectory And Time To Acute Kidney Injury In Lung Transplant Patients, Samiha Zakir May 2025

Joint Modelling Of Longitudinal Egfr Trajectory And Time To Acute Kidney Injury In Lung Transplant Patients, Samiha Zakir

Theses and Dissertations

Progressive declines in estimated glomerular filtration rate (eGFR) often precede acute kidney injury (AKI), yet the relationship between eGFR trends and AKI risk remains unclear. This study investigates longitudinal eGFR changes and their association with AKI in 459 lung transplant patients followed for up to 7 years (n = 6419). We applied a piecewise linear mixed-effects model to evaluate eGFR trajectories and a Cox proportional hazards model to assess time to AKI. A joint model was used to explore the interplay between longitudinal and survival processes. Key covariates included gender, age at transplantation, antibody-mediated rejection (AMR), and pre-transplant eGFR. Males …


Effects Of Reflective Journaling And Nudges On Academic Motivation And Engagement, Lakshmi Satya Sai Veda Mahita Uppuluri May 2025

Effects Of Reflective Journaling And Nudges On Academic Motivation And Engagement, Lakshmi Satya Sai Veda Mahita Uppuluri

Theses and Dissertations

This study investigates the effects of reflective journaling and motivational nudges on academic motivation and engagement among college students. Grounded in Self- Determination Theory (SDT), the research examines how different interventions influence intrinsic motivation, and academic behaviors such as class attendance, participation, and preparation. The study employed a between-group experimental design with three conditions: a control group, a journaling group, and a journaling group that also received daily motivational nudges. Results showed that students in the journaling groups—particularly those who received nudges—experienced a significant increase in academic motivation. While changes in academic engagement were not significant, the effect size suggested …


Stochastic Analysis With Operational Calculus In Reliability, Hend Hamdan Al-Jahani May 2025

Stochastic Analysis With Operational Calculus In Reliability, Hend Hamdan Al-Jahani

Theses and Dissertations

Our dissertation models several reliability systems subject to occasional random shocks of random magnitudes W1,W2,..occurring at times tau0, tau2,..In Model 1, the underlying system becomes inoperational if it wears out due to aging specified by a monotone increasing continuous function Delta identifying system's wear at any time t>=0 . The system is deemed inoperational if delta crosses a sustainability threshold at some moment T=(delta )^-1(D). The precise time T is difficult to identify making the realistic failure time randomly delayed and thus identified at some opportune observation epoch. The system can also fail due to damages by external shocks, …


An Analysis Of Face Morphing Presentation Attacks Against Facial Recognition Systems, Joshua Breininger May 2025

An Analysis Of Face Morphing Presentation Attacks Against Facial Recognition Systems, Joshua Breininger

Theses and Dissertations

Security has been a problem for human society for as long as history has been recorded. The identification of people is an ongoing, ancient battle, with a variety of methods that only become more complex with time. The Romans performed censuses, ciphers have been used for thousands of years in the pursuit of security, and in modern day we own identifications and governments keep track of who lives in their country with citizenship and licenses. The question of ”Who are you?” is vital for society to function, which opens up a massive field of potential for how to ask that …


Expressive And Interpretable User Engagement Prediction Using Multivariate Survival Processes, Akshay Aravamudan May 2025

Expressive And Interpretable User Engagement Prediction Using Multivariate Survival Processes, Akshay Aravamudan

Theses and Dissertations

The ability to characterize how information diffuses online is of paramount importance to stakeholders that are interested in tasks such as proposing solutions for mitigating and countering dis/misinformation, predicting user engagement of content in social media, planning marketing campaigns to roll-out products and planning dissemination of political campaign messaging among others. One such facet of learning the dynamics of information diffusion is the ability to predict user engagement or the popularity of a single piece of information as it spreads through an online medium. Existing works in this regard mainly either obfuscate user level information or utilize frameworks that are …


Hello Again! Llm-Powered Personalized Agent For Long-Term Dialogue, Hao Li, Chenghao Yang, An Zhang, Yang Deng, Xiang Wang, Tat-Seng Chua May 2025

Hello Again! Llm-Powered Personalized Agent For Long-Term Dialogue, Hao Li, Chenghao Yang, An Zhang, Yang Deng, Xiang Wang, Tat-Seng Chua

Research Collection School Of Computing and Information Systems

Open-domain dialogue systems have seen remarkable advancements with the development of large language models (LLMs). Nonetheless, most existing dialogue systems predominantly focus on brief single-session interactions, neglecting the real-world demands for long-term companionship and personalized interactions with chatbots. Crucial to addressing this real-world need are event summary and persona management, which enable reasoning for appropriate long-term dialogue responses. Recent progress in the human-like cognitive and reasoning capabilities of LLMs suggests that LLM-based agents could significantly enhance automated perception, decision-making, and problem-solving. In response to this potential, we introduce a model-agnostic framework, the Long-term Dialogue Agent (LD-Agent), which incorporates three independently …


Decoding The Algorithm: The Mathematics Behind Tiktok’S Short-Form Content Success, Ashley N. Lynch May 2025

Decoding The Algorithm: The Mathematics Behind Tiktok’S Short-Form Content Success, Ashley N. Lynch

Honors Scholar Theses

Within the realm of social networks, TikTok has become the central hub for short-form video content. The network’s unique ability to capture individual preferences using predictive analytics has greatly contributed to its massive success, allowing the company to optimize its performance and content personalization. In an age where digital media have such a significant influence on society, it is essential that users develop an understanding of how social network algorithms function to make more informed online decisions. Although TikTok’s technological system is primarily undisclosed, the platform certifiably leverages several key mathematical principles within its algorithm to achieve its core goals …


Small Scale Magnetohydrodynamic Thruster, Samuel Rabaey May 2025

Small Scale Magnetohydrodynamic Thruster, Samuel Rabaey

Celebrating Scholarship and Creativity Day (2018-)

This paper explores the performance of a self-constructed, small-scale magnetohydrodynamic (MHD) thruster using saltwater as the conductive fluid. The MHD drive generates propulsion through Lorentz force by applying an electric current across electrodes in the presence of an orthogonal magnetic field. Two experiments were conducted: one measuring static water displacement to determine force output, and another using fluid velocity in a closed loop to evaluate both force and efficiency at varying magnetic field strengths. Theoretical predictions based on MHD and fluid dynamics principles were compared with experimental results. While the measured outputs were consistently lower than theoretical approximations, likely due …


Fluorescence Lifetime Of Bulk Cadmium Sulfide Excited By Two-Photon Absorption, Grady Schierts May 2025

Fluorescence Lifetime Of Bulk Cadmium Sulfide Excited By Two-Photon Absorption, Grady Schierts

Celebrating Scholarship and Creativity Day (2018-)

An attempt was made to measure the fluorescence lifetime of bulk cadmium sulfide excited by two-photon absorption. The excitation source was an 800-nm unamplified Ti:sapphire laser that produced 50-fs pulses at a repetition rate of 82 MHz. An acousto-optic modulator (AOM) driven by a waveform generator was used as a pulse-picking device. A sufficiently fast AOM could pick a single pulse from the pulse train to excite the cadmium sulfide. Due to limitations on the speed of the available AOM, it was not possible to pick a single pulse. Instead, packets with a minimum of three pulses could be picked …


Synthesis, Characterization, And Redox Properties Of Select 1,4-Diazocine-6,11-Diones Towards An Electrochromic Dye-Set, Jeffrey Scott Richards May 2025

Synthesis, Characterization, And Redox Properties Of Select 1,4-Diazocine-6,11-Diones Towards An Electrochromic Dye-Set, Jeffrey Scott Richards

Open Access Theses & Dissertations

The daily consumption of personalized digital visual information depends on the current purview of electronic-based displays. Present manufacturers utilize modern technologies, such as LCD, OLED, QLED, and electronic ink, or "E Ink," in their devices to display text, pictures, and other forms of media to individual users. However, as modern society continues to rely on the use of digital displays, the demand for low-power alternatives will continue to rise as their application in varying scenarios is realized. Currently, "E Ink" technology continues to grow as the dominant solution in the e-readers and digital signage marketplace, and can even be seen …


From Basel (1989) To Busan (2024): Developments And Contradictions In The Global Plastic Waste Trade, Megan E. Hughes May 2025

From Basel (1989) To Busan (2024): Developments And Contradictions In The Global Plastic Waste Trade, Megan E. Hughes

Honors Theses

In 1989, the international community convened in Basel to adopt groundbreaking, legally binding legislation on the transboundary movement of hazardous waste. Plastic waste was notably absent from the initial Basel Convention due to the perceived economic value in plastic recycling despite social, economic, and environmental harms. Consequently, the transboundary sale of plastic waste for recycling– known as the Global Plastic Waste Trade (GPWT)– has proceeded largely unregulated, enabling unsustainable plastic consumption while exacerbating environmental justice divides between developed and developing nations. Recent commitments in the GPWT, such as the European Commission Circular Economy Action Plan (2015), China’s National Sword policy …


Exploring Educational Affordances Of Interactive Murals, Alyshia Bustos May 2025

Exploring Educational Affordances Of Interactive Murals, Alyshia Bustos

Computer Science ETDs

Interactive murals are a new technology that blend traditional mural painting and embedded electronics. My work contrasts traditional STEAM projects by introducing youth to programming, building electronics, and interaction design principles within the context of designing and constructing interactive murals. Accordingly my dissertation addresses the following: 1) How can we integrate traditional mural practices and ubiquitous computing in an interactive mural, 2) How do interactive murals support youth in learning how to program and build electronics, and 3) How can we design learning activities that support youth as interaction designers?

To address my research questions, I first conducted technical tests …