Physical Sciences and Mathematics Commons^™

Ionic Liquid Enhanced Proton Transfer For Neutral Oxygen Evolution Reaction, Ming-Xing Chen, Nian Liu, Zi-He Dua, Jing Qi, Rui Cao

Journal of Electrochemistry

The development of highly active catalyst in pH-neutral media for oxygen evolution reaction (OER) is critical in the field of renewable energy storage and conversion. Nevertheless, the slow kinetics of proton-coupled electron transfer (PCET) hinders the overall OER efficiency. Herein, we report an ionic liquid (IL) modified CoSn(OH)₆ nanocubes (denoted as CoSn(OH)₆-IL), which could be prepared through a facile strategy. The modified IL would not change the structural characteristics of CoSn(OH)₆, but could effectively regulate the local proton activity near the active sites. The CoSn(OH)₆-IL exhibited higher intrinsic OER performances than the pristine …

High Spatial Resolution Crop Type And Land Use Land Cover Classification Without Labels: A Framework Using Multi-Temporal Planetscope Images And Variational Bayesian Gaussian Mixture Model, Minh Tri Le

Mathematics, Physics, and Computer Science Faculty Articles and Research

Previous studies often combined high spatial resolution data (e.g., PlanetScope) with wider spectral range data (e.g., Sentinel-2) and relied on supervised classification methods to produce land use and land cover (LULC) maps. This study proposed a new unsupervised framework to generate crop type and LULC maps at high spatial resolution (< 5 m) using available PlanetScope data solely without requiring ground truths. We used PlanetScope surface reflectance images and their derived spectral indices during growing seasons to create multi-temporal input features, which were fed into an unsupervised Variational Bayesian Gaussian Mixture Model (VBGMM). The VBGMM, unlike the traditional unsupervised classification methods, (1) first estimated optimal parameters that are most suitable based on the input features and then (2) assigned pixels to the cluster with maximum posteriori probability of a mixture of several Gaussian distributions. The crop type and LULC maps were then generated by labeling the derived clusters using the best possible assignment method, referring to the existing crop type or LULC products. We evaluated the produced PlanetScope-based crop type and LULC maps using true labels, corresponding reference maps, and other unsupervised classification methods. The results demonstrated the robustness and effectiveness of the proposed framework in mapping crop types and LULC at 3–5 m pixels across various ecosystems, climate zones, and human-managed landscapes. The spatial patterns of PlanetScope-based maps were (1) highly comparable with all the reference datasets at 10–30 m spatial resolution and (2) better than the traditional GMM and K-means clustering methods. The VBGMM produced classification maps with high confidence, yielding class probabilities above 0.9 for over 90 % of all study areas. The area percentage for all crop type and LULC classes agreed well with their reference maps, with R2 of 0.95 and RMSE of 1.04 %. The confusion matrices using true labels indicated that PlanetScope-based maps achieved a higher overall accuracy of 84 % than the supervised referenced maps of 81 %. Besides, the entropy comparison showed that our framework-based maps were better at capturing fine-scale features such as developed areas within cities that commonly mix with open space and vegetation, deforestation and cropland conversion in South America, smallholder croplands in Africa and Asia, and generating homogeneous crop fields in North America. This study further highlighted the potential for future research to implement our proposed framework to generate timely and extensive annotated datasets, which can be used for operationally training machine learning models to map crop types and LULC, track deforestation, detect wildfires, and delineate flooded areas at larger scales using medium/coarse Earth observations.

Thermally Tunable Mid-Infrared Nanocavity Resonance Of Coupled Surface Plasmon-Phonon Polaritons, Satya R. Kachiraju, Zachary M. Brown, Sundar Kunwar, Long Chang, Imtiaz Ahmad, Pinku Roy, Vladimir Kuryatkov, Yejin Kwon, Ayrton A. Bernussi, Chase T. Ellis

Physics & Astronomy Faculty Publications

Phase-change materials (PCMs) are essential for achieving tunability of metasurfaces. However, they frequently face limitations in the long-wave infrared range because of their lossy behavior. Here, we experimentally demonstrate a thermally tunable mid-infrared nanocavity resonance from coupled surface plasmon-phonon polaritons that are supported within a trilayer structure of metal-PCM layer-polar dielectric (Au-VO2-SiC). The top metal structures configure the Fabry-Perot cavity resonance near 840 cm−1 (11.9 µm), which is sensitively tunable and reversible with small changes in the VO2 refractive index ∆n near below its insulator-to-metal phase transition temperature where the loss is small. The maximum resonance shift of 7.7 cm−1 …

Evaluation Of Windninja Simulations In Canyons And Complex Terrain, Marc Buchs

Master's Theses

This study describes a validation of the surface wind model WindNinja conducted over different types of complex terrain. WindNinja is one of many software tools first responders use to better understand wind flow over such terrain. One approach to receive a higher resolution wind field to account for local terrain effects is to downscale numerical weather prediction model output with the help of WindNinja. 2 km resolution Weather Research and Forecasting model (WRF) output was used as input for our WindNinja simulations. We tested the surface wind model for two case sites in California characterized by canyons of different terrain …

Estimating Galactic Structure Using Galactic Binaries Resolved By Space-Based Gravitational Wave Observatories, Shao-Dong Zhao, Xue-Hao Zhang, Soumya Mohanty, Màrius Josep Fullana I Alfonso, Yu-Xiao Liu, Qung-Ying Xie

Physics & Astronomy Faculty Publications

Space-based gravitational wave detectors, such as the Laser Interferometer Space Antenna (LISA) and Taiji, will observe GWs from O(108) galactic binary systems, allowing a completely unobscured view of the Milky Way structure. While previous studies have established theoretical expectations based on idealized data-analysis methods that use the true catalog of sources, we present an end-to-end analysis pipeline for inferring galactic structure parameters based on the detector output alone. We employ the GBSIEVER algorithm to extract GB signals from LISA Data Challenge data and develop a maximum likelihood approach to estimate a bulge-disk galactic model using the resolved GBs. We introduce …

Combination Of Irreversible Electroporation And Clostridium Novyi-Nt Bacterial Therapy For Colorectal Liver Metastasis, Zigeng Zhang, Guangbo Yu, Qiaoming Hou, Farideh Amirrad, Sha Webster, Surya M. Nauli, Jianhua Yu, Vahid Yaghmai, Aydin Eresen, Zhuoli Zhang

Pharmacy Faculty Articles and Research

Colorectal liver metastasis (CRLM) poses a significant challenge in oncology due to its high incidence and poor prognosis in unresectable cases. Current treatments, including surgical resection, systemic chemotherapy, and liver-directed therapies, often fail to effectively target hypoxic tumor regions, which are inherently more resistant to these interventions. This review examines the potential of a novel therapeutic strategy combining irreversible electroporation (IRE) ablation and Clostridium novyi-nontoxic (C. novyi-NT) bacterial therapy. IRE is a non-thermal tumor ablation technique that uses high-voltage electric pulses to create permanent nanopores in cell membranes, leading to cell death while preserving surrounding structures, and …

Newtonian Fractional-Dimension Gravity And The Mass-Dimension Field Equation, Gabriele U. Varieschi

Physics Faculty Works

We resume our analysis of Newtonian Fractional-Dimension Gravity (NFDG), an alternative gravitational model which does not require the Dark Matter (DM) paradigm. We add three more galaxies (NGC 6946, NGC 3198, NGC 2841) to the catalog of those studied with NFDG methods. Once again, NFDG can successfully reproduce the observed rotation curves by using a variable fractional dimension D (R), as was done for nine other galaxies previously studied with these methods. In addition, we introduce a mass-dimension field equation for our model, which is capable of deriving the fractional mass-dimension Dm (R) from first principles, as opposed to the …

Transformation With Genes To Improve Lipid Production And Barcoding To Identify Unknown Algal Species, Michelle T. Rada

Theses and Dissertations

With the rising demand for alternative fuels, algal-based biofuels are a promising, sustainable source that meets commercial interest while producing lower greenhouse gas emissions compared to fossil fuels. This thesis explored two studies, evaluating microalgae for their future potential in lipid yield for biofuel production.

The first study involved developing a cost-efficient electroporation protocol that allowed for the genetic transformation of Chlamydomonas reinhardtii using the pChlamy_4 vector, which supports future cloning of genes to enhance lipid production. Parameters affecting DNA uptake and integration into algal genomes were studied: the effect of cell density, the settings of the electroporation device, and …

Asymptotic Behavior Of Evolution Equations Via Spectral Theory Of Functions On The Half Line, Sums Of Commuting Operators And Evolution Semigroups, Minh Nguyen, Vu Trong Luong

Faculty Scholarship

In this paper we give a survey of recent developments in the spectral theory of bounded functions on the half line, and its applications to study the asymptotic behavior of solutions of evolution equations of the form , where A(t) is periodic in t. For the applications we consider spectra of the evolution semigroups associated with the evolution equations in various spectral invariant function spaces and their generators. The main results presented in the paper are concerned with the existence and uniqueness within decaying functions with specific spectral properties. These asymptotic behaviors are related to the Katznelson–Tzafriri Theorem and Massera …

Detection Of Oil Pollution On The Tigris River In Iraq Using Fluorescence And Reflecting Techniques, Ahmad K. Ahmad, Thamer M. Mohammed

Karbala International Journal of Modern Science

In this study, a broadband light source (visible and ultraviolet) was used to name minerals via fluorescence spectra and estimate slick oil thickness, ranging from sub-millimetres, using the reflecting spectrum technique. Using a fluorescent technique, we obtained fluorescence spectra of the samples, converting and processing the signals to produce high-resolution data, which enabled the identification of the types of dissolved elements and oil slicks in the Tigris River, highlighting pollution sources and potential control measures. This system aims to show the faint signal in fluorescence samples collected from the cooling system outlet water throughout the refining process from AL-Dora (Baghdad) …

Multilingual Cyber Threat Intelligence Feeds Preprocessing For Threat Intelligence Event Extraction: A Systematic Literature Review, Jamal H. Al-Yasiri, Mohamad Fadli Bin Zolkipli, Nik Fatinah N. Mohd Farid

Karbala International Journal of Modern Science

In cyber threat intelligence (CTI), information security specialists face overwhelming data flows from multiple sources, including hacker forums, dark web markets, and social media. These diverse and multilingual information streams require extensive analysis and processing. However, the current state of CTI faces several challenges, such as reliance on manual annotation and evaluation, as well as limited support for non-English languages, which hinders advanced threat detection and comprehensive analysis. This systematic literature review proposes a conceptual framework designed to overcome existing state-of-the-art limitations. It evaluates recent advancements in CTI methodologies by following PRISMA guidelines and analyzing selected studies from reputable sources, …

Key Technologies And Approaches For Water Resource Conservation And Utilization In Arid To Semi-Arid Open-Pit Coal Mining Areas In The Northern Sand Prevention Belt Of China, Fang Jie, Xu Zhimin, Cheng Wei, Lu Zihan, Zhao Yongqiang, Zhu Yuhao, Chen Tianci

Coal Geology & Exploration

Background The northern sand prevention belt (NSPB) of China is primarily distributed in arid and semi-arid regions such as Xinjiang, Inner Mongolia, Ningxia, and Gansu. This belt exhibits scarce rainfall and intense evaporation, which lead to a shortage of water resources and vulnerable ecosystems. In recent years, the large-scale development of open-pit coal mines has caused increasingly violent mining disturbance in this belt, as well as increasingly prominent issues such as a decline in regional groundwater levels and ecological contradictions. To address technical challenges in balancing coal exploitation and water resource conservation in this belt, there is an urgent need …

Mechanisms Behind Grouting Pressure Jumping In Low-Permeability Limestones And Techniques For Grouting Pressure Control, Fan Zhenli, Cao Lutong, Cui Yong, Zhang Zhiwei, Zhang Fengda

Coal Geology & Exploration

Background The exploitation of the Carboniferous-Permian coalfields in China is gradually transitioning toward coal seams in lower formations. In this context, issues including the confined water hazards in the floor and karst water preservation become increasingly pronounced. During the advanced surface treatment of karst water hazards in coal seam floors, the unclear patterns of matching between grout selection and grouting pressure control lead to empirical parameter selection, thereby yielding poor performance of grouting reinforcement. Methods This study aims to deal with the phenomena of rapid pressure rise with a limited grout volume in the low-permeability argillaceous limestones within the top …

Suitability Evaluation For Deep Geological Storage Of Mine Water In The Ordos Basin, Gulbostan Tursun, Sui Wanghua, Aibibai Mamat, Yang Weifeng, Chen Ge, Gao Liang

Coal Geology & Exploration

Objective Given the issues of large mine water drainage in coal mines in China, as well as the corresponding high treatment cost and low utilization rate, thoroughly investigating efficient, environmentally friendly, economically feasible mine water treatment technologies is the key to the green transformation and the implementation of the sustainable development strategy in the coal industry. Deep geological storage of mine water represents an emerging technology for mine water treatment, enjoying the advantages of low cost and zero emissions. A key step in the application of this technology is to select suitable target reservoirs. Although relevant studies have proposed some …

Permeability Evolutionary Patterns Of Fractured Rock Masses In Fault Zones Under Seepage-Stress Coupling, Zhao Dekang, Han Bing, Zeng Yifan, Feng Guorui, Xi Yonghong, Chang Bofeng, Li Zhenghao, Wang Pengwei, Wang Lisan

Coal Geology & Exploration

Background In coal mines, fault structures serve as critical pathways for water inrushes from coal seam floors, posing serious threats to the production safety of mines. Delving into the permeability evolutionary patterns of fractured rock masses in fault zones under seepage-stress coupling holds great significance for the prevention and control of water inrushes along faults from coal seam floors.Methods Against the engineering background of the Gaohe Coal Mine under the Shanxi Lu’an Mining (Group) Co., Ltd. in Shanxi Province, this study analyzed the microscopic physical properties and the pore and fracture structures of a fractured rock mass in a …

Re: Comment Letter For The Butte Priority Soils Operable Unit (Bpsou) Draft Final 2022 Unreclaimed Sites Sampling: Ur-06 Site Evaluation Summary Report (Dated April 1, 2025), Molly Roby

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

More Everything Forever: Ai Overlords, Space Empires, And Silicon Valley’S Crusade To Control The Fate Of Humanity, Joseph Kirby

Consensus

Becker, A. (2025). More everything forever : AI overlords, space empires, and Silicon Valley’s crusade to control the fate of humanity. Basic Books. ISBN: 9781541619593

Fabrication, Calibration, And Deployment Of A Home-Made Radiometer, Callum Flowerday, Ryan Thalman, Jaron Hansen

ScholarsArchive Data

Subfolders and Contents:

Chamber Characterization: Contains emission spectrum measured from inside the chamber with converted spectra to power and photon flux.

LED Calibration: (Each calibration file contains folders of data from each LED used in calibration)

• Cone
• Cone 2
• Dome 2
• Flat Top
• Quartz Rod
• Uniform Dome

Outside:

• Cone 2 front porch
• Cone 2 roof
• Flat top

(Arise) Achievements In Research, Inquiry And Scholarship Exhibition 2025, Office Of Undergraduate Research

(ARISE) Achievements in Research, Inquiry and Scholarship Exhibition

Conference held at John A. Delaney Student Union on July 25, 2025

Theory And Engineering Practice Of Coal-Water Coordinated Mining Based On Constraints Of Formation Bearing Capacity, Pang Zhenzhong, Zeng Yifan, Han Keyao, Wu Qiang, Liu Shouqiang, Hua Zhaolai, Zhao Gangyi, Zhang Shuai, Yang Huxiong, Wang Xuejun, Li Feifan

Coal Geology & Exploration

Background The high-intensity mining of coal resources in the Yushen mining area has caused negative environmental effects and water disasters on coal seam roofs, seriously restricting the sustainable development of the area.Methods and Results Based on a summary of previous research results on the mitigation of the impacts of coal mining on groundwater resources and surface ecosystem, this study analyzed the contradiction between coal mining and the protection of the fragile ecosystem in the Yushen mining area in Shaanxi Province through theoretical analysis, field investigation, and data statistics. Then, it systematically illustrated the concept of the formation bearing capacity …

Impacts Of Boundary Conditions And Parameter Heterogeneity On The Simulation And Prediction Of Water Inflow In Coal Mines, Ji Qiang, Wu Zhenjiang, Yao Yingying

Coal Geology & Exploration

Background Accurate prediction of water inflow in coal mines is essential for ensuring safe mining operations. Three-dimensional (3D) groundwater numerical models can be used to characterize hydrogeological conditions in mining areas and simulate the dynamic processes of water inflow, providing a theoretical basis for scientifically predicting mining-induced water inflow. However, there is a lack of a clear understanding of the impacts of the boundary conditions with surface water-groundwater interactions and the heterogeneity of aquifer permeability coefficients (K) on the simulation and prediction of water inflow during coal mining. Methods This study developed a 3D transient groundwater numerical model …

An Experimental Study On The Seepage Characteristics Of Sandstones With Different Numbers Of Fractures Before And After Grouting, Chen Juntao, Zhou Haoyu, Yu Junjian, Li Guo, Fan Mingjin, Li Lu, Wang Yunhao

Coal Geology & Exploration

Background Grouting in surrounding rocks serves as a conventional approach to controlling disasters in coal mine roadways. The developmental degree of fractures significantly influences the reinforcement and sealing effects of grouting. Methods To determine the changes in the impermeability of fractured surrounding rocks before and after grouting, this study investigated sandstones—the most common sedimentary rocks in coal mines. Using laboratory experiments and numerical simulations, this study explored the permeability variations of sandstone specimens with varying fracture numbers under different confining pressures and assessed the impact of grouting on their seepage performance. Through triaxial compression-seepage experiments using a Rock Top multi-field …

Re: Comment Letter For The Butte Priority Soils Operable Unit (Bpsou) Draft Final 2022 Unreclaimed Sites Sampling: Ur-12 Site Evaluation Summary Report (Dated April 8, 2025), Molly Roby

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

An Experimental Investigation Of Federal Messaging On Public Support For Enforcement- And Treatment-Based Approaches For Opioid Overdose Prevention In South Carolina, Lídia Gual-Gonzalez, Hunter M. Boehme, Peter Baker, Melissa Nolan Ph.D., Mph

Faculty Publications

Background

As the opioid overdose crisis continues to produce excessive morbidity and mortality in the United States, government agencies have applied various approaches to prevent overdoses, including law-enforcement efforts (e.g., arresting people who use drugs, interrupting drug traffickers, etc.) and treatment-based approaches (e.g., naloxone, medications for opioid use disorder, etc.). Public perception and support of these approaches are relevant for informing policy, allocating resources, and effectively implementing community interventions to prevent drug-related harms.

Methods

Using an embedded informational survey design, we experimentally assessed whether public support for strategies to prevent overdose in South Carolina is influenced by language from federal …

Table Of Contents, The Editors

Coal Geology & Exploration

No abstract provided.

Trace Element Migration In Groundwater In Sandstone Aquifers In The Jurassic Coalfields: A Case Study Of The Guojiahe Coal Mine, Shi Longqing, Qu Xingyue, Cheng Hao

Coal Geology & Exploration

Background The Ordos Basin, a vital energy hub in China, contains considerable coal reserves. However, the environmental issues arising from coal mining warrant attention, especially given the fragile ecosystems of the Jurassic coalfields. Methods This study investigated the Guojiahe Coal Mine in Shaanxi Province. Based on measured concentrations of 31 trace elements dissolved in sandstone aquifers across varying geological ages, this study conducted a comparative analysis of the evolutionary characteristics of these trace elements between unmined reducing and post-mining oxidizing conditions using numerical simulations. Accordingly, it revealed the impacts of coal seam mining on trace element migration in groundwater in …

Seismic Anisotropy Of Sandstone Aquifers In Coal Seam Roofs, Yu Hang, Chen Tongjun

Coal Geology & Exploration

Objective The identification and assessment of sandstone aquifers in coal seam roofs play a vital role in the safe mining of mines. Investigating the rock physics and amplitude variation with incidence and azimuth (AVAz) responses of these sandstone aquifers is critical to the prevention and control of water hazards in mines. Methods By integrating rock physical models Voigt-Reuss-Hill (VRH), differential equivalent medium (DEM), Hudson, and Wood, as well as Gassmann’s anisotropic fluid substitution theory, this study proposed a rock physics modeling method for fractured sandstones of the horizontal transversely isotropic (HTI) media type (hereafter referred to as HTI sandstones). Using …

Research On Monitoring And Early Warning Systems For Mine Water: Progress And Prospects, Yin Shangxian, Ding Yingying, Lian Huiqing, Dong Donglin, Du Tong, Yin Huichao, Zhao Peng, Zhang Yi’An, Wang Xiong

Coal Geology & Exploration

Background Water disasters in mines are occasional accidents occurring due to the influence or triggered by mining-induced intense changes in geological bodies. The complexity, heterogeneity, and dynamics of geological bodies, coupled with the random and instantaneous nature of mining influence, lead to the uncertainty, instability, occasionality, and transience of water disasters in mines. Given that mine water monitoring and early warning serve as a prerequisite for advanced disaster prevention and control, their research and system construction hold great theoretical significance and practical value. Progress and Prospects Fighting against water disasters in mines is conducted throughout the development and utilization of …

Experiments On The Diffusion Patterns Of Coal Gangue-Based Grout In Goaves Under Varying Rock Particle Sizes And Grout Mass Fractions, Zeng Yifan, Yuan Zilong, Li Hao, Wu Qiang, Zhao Gangyi, Zhou Anqi, Gao Xiang, Zhang Shuai, Bai Yanfei, Liang Jin, Yang Huxiong, Sheng Xinli, Yang Donghui, Zhao Yixia

Coal Geology & Exploration

Objective Investigating grout diffusion patterns and predicting the grouting range hold great significance for coal gangue grouting and filling engineering in goaves. Specifically, they are significant for designing grouting hole and row spacing, guiding grouting construction, determining the grouting filling degree, and further ensuring grouting effects. Methods Using crushed rocks as the medium to be grouted and coal gangue-based grout as the grouting materials, this study conducted grouting experiments under different particle sizes of crushed rocks and varying mass fractions of grout. Accordingly, it investigated the flow patterns of gangue-based grout in goaves. Results and Discussion Under a mass fraction …

Differential Roof Water Hazards And Comprehensive Utilization Of Mine Water In The Dongsheng Coalfield, Huang Haiyu, Ding Xiang, Liu Xi, Fan Jiangwei, Ji Zhuochen, Li Zhaoyang

Coal Geology & Exploration

Objective The Dongsheng coalfield exhibits various types of mine water hazards, complex water filling mechanisms, and high water inflow with high total dissolved solids (TDS) content in mining areas. These characteristics pose challenges to the comprehensive utilization of mine water, severely restricting the safe, green, and efficient coal mining in the coalfield. Methods This study aims to reveal the roof water filling characteristics of the Dongsheng coalfield and enhance the comprehensive utilization of mine water. Using methods including statistical analysis of drilling data, analytic hierarchy process, and hydrochemical tests, this study analyzed the strata, spatial distribution of aquifers, and the …