Physical Sciences and Mathematics Commons^™

Llm-Driven Semantic Explanations For Soil Moisture Prediction Models, Bamory Ahmed Toru Koné, Khouloud Boukadi, Rima Grati, Emna Ben Abdallah, Massimo Mecella

All Works

Efficient soil moisture prediction is crucial for sustainable agricultural practices, especially in the face of climate change and increasing water scarcity. However, the adoption of machine learning (ML) models in this context is frequently limited by their lack of interpretability, particularly among non-expert users such as farmers. This study proposes a novel approach to soil moisture prediction that combines high predictive performance with enhanced explainability. We propose a framework that leverages large language models (LLMs) to generate textual explanations based on a proposed irrigation and soil moisture ontology, thus making the model's predictions more understandable to farmers. The ontology formalizes …

Artificial Intelligence In Waste Management Systems: Applications, Challenges, And Prospects, Imane Belyamani

All Works

Despite global recognition of the climate crisis, greenhouse gas emissions are projected to rise by 8.8 % by 2030, primarily due to inadequate planning, poor implementation, and insufficient financial support. While international initiatives such as the ’Waste to Zero’ coalition launched at the 28th Conference of the Parties to the UNFCCC (COP 28) highlight the urgency of advancing decarbonization and the circularity of waste systems, this review focuses on how artificial intelligence (AI) can accelerate that transformation. It systematically explores the role of AI in advancing waste management practices, with a focus on predictive analytics, route optimization, and machine learning-based …

Semi-Hyponormality Of Commuting Pairs Of Hilbert Space Operators, Raul E. Curto, Jasang Yoon

School of Mathematical & Statistical Sciences Faculty Publications

We first find an explicit formula for the square root of positive 2 ×2 operator matrices with commuting entries, and then use it to define and study semi-hyponormality for commuting pairs of Hilbert space operators. For the well-known 3–parameter family 𝑊(𝛼,𝛽)⁡(𝑎,𝑥,𝑦) of 2–variable weighted shifts, we completely identify the parametric regions in the open unit cube where 𝑊(𝛼,𝛽)⁡(𝑎,𝑥,𝑦) is subnormal, hyponormal, semi-hyponormal, and weakly hyponormal. As a result, we describe in detail concrete sub-regions where each property holds. For instance, we identify the specific sub-region where weak hyponormality holds but semi-hyponormality does not hold, and vice versa. To accomplish this, …

Adsorption-Photodegradation Performance Of Silver Titanate For Methylene Blue Removal: Kinetics, Thermodynamics And Isotherm Studies, Nawrin Rahman Shefa, Most. Afroza Khatun, Ahmed Hasnain Jalal, M. Jasim Uddin, Md. Wasikur Rahman

Physics & Astronomy Faculty Publications

Silver titanate (AgTO) was synthesized via an ion-exchange reaction between sodium titanate and silver nitrate. This study investigates the efficiency of AgTO in the combined adsorption-photodegradation process for removing Methylene Blue (MB). The synthesized material was characterized using FTIR, XRD, SEM, and EDX techniques. Batch adsorption experiments were conducted to assess the effects of AgTO dosage (0.1–1.0 g/L), initial MB concentration (5–20 mg/L), pH (3–11), and temperature (313–333 K). The highest MB removal efficiency (90 %) was achieved at 313 K, pH 3, and an initial MB concentration of 5 mg/L. The photocatalytic performance of AgTO was further evaluated under …

Early Conceptual Sketches Of Blended Reality And The Precursor To The Bbs Quad (2022), David Smith

Publications and Research

This document contains two original hand-drawn conceptual sketches created in early 2022, representing the earliest visual formulations of what would later evolve into the Balanced Blended Space (BBS) framework. The drawings predate my first conversations with ChatGPT and were produced as part of my independent sabbatical research into blended environments, mediated performance, and human–machine interaction.

The first drawing examines human–computational mediation, perception, and internal mapping. The second sketch—later referred to informally as the “BBS Quad”—extends this idea by reconciling cognition–computation symmetry with physical–virtual spatial relationships. Published together, these images document the conceptual foundations of the BBS framework prior to its …

Greenhouse Gas Accounting For Western Australian Agriculture 2023, Johnny Machon, Christophe D'Abbadie

Climate Science Published Reports

This report presents new modelling of the greenhouse gas emissions attributable to Western Australia’s agricultural industries and provides an overview of sequestration at the state level. The report updates the estimates from previous technical reports by the Department of Primary Industries and Regional Development (DPIRD). It presents not only emissions from agricultural activities in Western Australia (WA) but also from the production of agricultural inputs and energy use. This broader picture of emissions aligns with frameworks for emissions reporting at the business and product level.

Total on-farm and pre-farm emissions are estimated to have been about 12.6–13.3 million tonnes of …

Instance-Adaptive Gated Fusion Of Multi-Transform Image Representations, Prince Appiah

Open Access Theses & Dissertations

This dissertation proposes the Instance-Adaptive Gated Fusion (IAGF) framework, a novel deep learning architecture for adaptive and interpretable fusion of multiple time–series image transformations. While existing methods rely on static concatenation or dataset-level optimization, IAGF introduces a learnable gating mechanism that dynamically assigns per-instance weights to Recurrence Plots (RP), Gramian Angular Summation Fields (GASF), and Gramian Angular Difference Fields (GADF). The gating layer performs a convex fusion of transformation-specific embeddings under a softmax constraint, ensuring mathematical stability and interpretability. An entropy-regularized objective prevents dominance collapse and promotes balanced exploration of transformations during training. Comprehensive experiments across eighteen benchmark datasets, spanning …

Hydrological Responses To Rainfall Pulses In Desert Vadose Zones: A Multi-Scale Approach Integrating Geophysical, Isotopic, And Eddy-Covariance Measurements, Alfredo Dagda-Torres

Open Access Theses & Dissertations

Drylands are shaped by natural episodic precipitation, where short, intense rainfall pulses interrupt prolonged drought and drive most hydrological and ecological activity. Yet the mechanisms that determine how pulse water infiltrates, is redistributed, stored, evaporated, and ultimately used by desert vegetation remain under quantified in landscapes underlain by shallow petrocalcic horizons. This dissertation integrates three complementary approaches 1) three-dimensional electrical resistivity tomography, 2) eddy-covariance evapotranspiration partitioning, and 3) stable-isotope tracing to improve a mechanistic understanding of pulse-driven water movement and plant water use in a caliche-rich piedmont at the Jornada Experimental Range. The first component characterizes how infiltration pulses interact …

Intelligent Predictive Frameworks Under Data Scarcity And Uncertainty, Solayman Hossain Emon

Open Access Theses & Dissertations

Modern predictive systems frequently operate under conditions of limited annotated data, high uncertainty, and the need for reliable decision-making. When the predictive models expand across heterogeneous data types (e.g., spatial, temporal streams), the challenge lies not only in accurate prediction but also in adapting in data distributions shifts or label scarcity. To address these issues, this thesis explores an Intelligent Predictive Framework that operates robustly under data scarcity and uncertainty across two distinct domains: medical imaging (spatial) and time-series forecasting (temporal). In the first part of this work, a semi-supervised mean teacher (MT) paradigm is tailored for medical image segmentation …

Development Of Oxide And Oxynitride Thin Films For Advanced Optical Applications, Nathan Christopher Episcopo

Open Access Theses & Dissertations

To develop Ga2O3 and TiOₓNᵧ thin films for optical applications, the process–structure–properties relationship was investigated using a comprehensive set of characterization techniques to establish the atomic structure and composition of the films in relation to the deposition conditions. The results provide critical insights into how deposition parameters influence the atomic structure and composition during magnetron sputtering. Furthermore, the correlation between atomic structure and composition with the optical and electrical properties of the films was examined to determine how variations in these factors affect functional performance. Collectively, these findings offer the necessary information to target desirable optical properties for Ga2O3 and …

From Morphology To Machine Learning And Genomics: Understanding Phenotypic Variation In Wild Ducks, Sara Gonzalez

Open Access Theses & Dissertations

Understanding the genetic underpinning and distribution of phenotypic variation within and between divergent groups is core towards shedding light into how populations diverge and adapt, as well as how hybridization breaks or builds on these scenarios; and thus, central to evolutionary biology. In wild organisms, however, quantifying and linking phenotypic traits to underlying genetic processes, like mutation, gene expression, epigenetics and allele interactions, remains challenging. This difficulty arises from the complex interplay between morphology, environment, and gene regulation, as well as the logistical barriers of collecting and standardizing large-scale data across individuals and populations. As a result, researchers are increasingly …

Facilitating Deep Learning Performance Analysis Through Automated Roofline Model Generation, Irvin Lopez-Audetat

Open Access Theses & Dissertations

This thesis presents a tool to profile deep learning (DL) and machine learning (ML) models by collecting FLOPs, memory movement, and timing data through cyPAPI to generate roofline performance models. The tool is containerized for portability and reproducibility, integrates directly with PyTorch workflows, and provides fine grained insights into computational bottlenecks across model components. Unlike prior system-level or benchmarking-centric tools, this project empowers developers and researchers with an accessible, modular framework for performance analysis and optimization.

A Half Century Of Biophysical Change In Polygonized Tundra On The Coastal Plain Of Northern Alaska, Mariana Mora

Open Access Theses & Dissertations

Climate change is amplified in the Arctic. As a result, Arctic tundra landscapes are undergoing physical changes through accelerated thaw and ice-wedge degradation. Understanding the magnitude and direction of these changes in the Arctic is a necessary step toward understanding the response of the Arctic to climate change and feedbacks to the Climate System. Through repeat measurements collected from 1973 through 2018, we were able to assess decadal time scale changes in polygon geomorphology, thaw depth, land surface compression and expansion, and vertical elevation within a highly polygonized tundra system, and their implications when scaled to a regional level. This …

What Limits Dryland Ecosystems? Patterns Of Soil Fertility And Resource Limitation In The Chihuahuan Desert, Dylan Stover

Open Access Theses & Dissertations

Human activities are substantially altering global resource cycles with widespread implications for biogeochemistry and ecosystem functioning globally. Drylands, regions where precipitation is outweighed by water losses, are especially sensitive to these large shifts in resource cycles due to their inherently low and variable resource availability. In these regions, resource availability and biological activity are often concentrated around plants – or fertile islands – and predominantly driven by pulses of water. However, our knowledge of the processes influencing biological productivity in drylands – patterns of soil fertility and resource limitation – remains lacking, and their unique biogeochemical and biological processes create …

A Unified Framework For Embedding-Based Synthetic Data Generation With High Cardinality Categorical Features, Cesar Iram Vazquez

Open Access Theses & Dissertations

High-cardinality categorical variables remain difficult to model in tabular data, where classical encoders encounter sparsity, susceptibility to leakage, and the loss of meaningful relational structure. This dissertation develops a unified framework for learning, evaluating, and synthesizing representations of such variables using both traditional encoders and modern embedding methods, including Word2Vec, FastText, Node2Vec, TF–IDF/SVD, and supervised entity embeddings. The framework is applied across three benchmark datasets (Adult, PetFinder, Breast Cancer) and a hierarchical educational case study (IPEDS/CIP). Embedding quality is examined through both downstream predictive performance and structure-focused diagnostics that quantify neighborhood behavior and geometric coherence. To assess whether synthetic data …

Hubert-Based Models And Evaluation Strategies For Pragmatically-Faithful Speech To Speech Translation, Javier Vazquez

Open Access Theses & Dissertations

Pragmatic fidelity in speech-to-speech translation (S2ST) has largely been understudied, leading to communication tools inadequate to support non-superficial dialog. We aim to improve pragmatic faithfulness in English-Spanish translation through the development of machine learning models that are able to predict a corresponding pragmatic representation in the other language. To evaluate performance, we developed a pipeline that utilizes a recently-developed pragmatic similarity evaluation metric to compare models. Further, we developed models that exploit HuBERT features as these have been found suitable for various prosody and pragmatics related tasks. Our models outperformed human and state-of-the-art predictions, albeit the methodology being limited to …

Metal Zonation And Evolution Of The Bronson Slope Porphyry Cu-Au-Mo Deposit In The Iskut Region Of British Columbia, Canada, Luis Jacobo Yagual

Open Access Theses & Dissertations

Bronson Slope is a Cu-Au-Mo porphyry deposit located within the Stikine Terrane in the Golden Triangle District of northwestern British Columbia, Canada. This deposit represents a complex, multistage magmatic-hydrothermal system emplaced into sedimentary and volcanoclastic rocks of the Triassic Stuhini Group. Bronson has an inferred resource of 517.3 Mt at 0.33 g/t Au, and 0.09% Cu. This study integrates detailed and quick logging from 20 drill holes, totaling 20,296m, SWIR spectral analysis, ICP-MS geochemistry, XRF analysis, magnetic susceptibility measurements, geochronology, and 3D models developed in Leapfrog Geo which define the stratigraphy, intrusive geometry, extension, alteration footprint assemblage, metal zonation, and …

Physics-Guided Strategies For Enhancing Neural Networks Trained With Limited Data, Jose Guadalupe Perez Zamora

Open Access Theses & Dissertations

Deep neural networks excel at a wide range of processing tasks across various disciplines. However, the quantity and quality of data significantly impact network performance. In specialized domains, high-quality datasets are often difficult to gather, interpret, and curate for effective learning. Few-shot learning techniques, including transfer learning, data augmentation, and meta-learning, have emerged to address these constraints.

We propose three physics-guided strategies for enhancing neural networks trained with limited data: (1) combining existing models like LSTMs with Physics-Informed Neural Networks through two-branch architectures that merge their outputs, (2) deriving custom physics-informed data augmentation algorithms to expand limited datasets, and (3) …

Real-Time Estimated Sequential Organ Failure Assessment (Sofa) Score With Intervals: Improved Risk Monitoring With Estimated Uncertainty In Health Condition For Patients In Intensive Care Units, Yan He, Qian Luo, Hai Wang, Zhichao Zheng, Haidong Luo, Oon Cheong Ooi

Research Collection Lee Kong Chian School Of Business

Purpose: Real-time risk monitoring is critical but challenging in intensive care units (ICUs) due to the lack of real-time updates for most clinical variables. Although real-time predictions have been integrated into various risk-scoring systems to aid monitoring, existing systems do not address uncertainties in risk assessments. We developed an enhanced risk monitoring framework based on commonly used systems like the Sequential Organ Failure Assessment (SOFA) score by incorporating uncertainties to improve the effectiveness of real-time risk monitoring in ICUs.Methods: This study included 5,351 patients admitted to the Cardiothoracic ICU in the National University Hospital in Singapore. We developed machine learning …

Synthesis Of Phenyl-Substituted Zinc Dipyrrin Photosensitizer For Carbon Dioxide Reduction, Stephen Ankomah

Electronic Theses and Dissertations

The release of CO₂ from fossil fuel combustion drives the need for its conversion into more sustainable options like CO and CH₄ via photocatalytic reduction. This process requires a catalyst, sensitizer, and electron donor. Zinc dipyrrin-based complexes are promising photosensitizers, offering an alternative to expensive, rare-metal-based systems. Most first-row transition metal dipyrrin compounds have short excited-state lifetimes due to rapid nonradiative decay, but Zn(II) dipyrrin complexes stand out. With a d¹⁰ configuration, they lack deactivating ligand field states and can access long-lived triplet states through a charge-separated intermediate. A phenyl-substituted Zn(II) dipyrrin complex was synthesized and studied using NMR to …

Divergent Responses Of Branched-Chain And Straight-Chain Lipid Membranes To Butanol Stress Revealed By All-Atom Molecular Dynamics Simulations, Joshua Olaf Aggrey

Electronic Theses and Dissertations

Membrane integrity under chemical stress is critical to cellular survival and industrial microbial bioproduction, yet the molecular basis of bilayer resilience remains poorly understood. Using all-atom molecular dynamics simulation, we compare the effect of increasing concentrations of 1‑butanol on membranes composed of straight-chain (1,2-dipalmitoyl-sn-glycero-3-phosphocholine, DPPC) and branched-chain (1-anteiso-palmitoyl-2-palmitoyl-sn-glycero-3-phosphocholine, APPC) lipids, which differ in the point of attachment of a single methyl group. In the absence of butanol, both membranes exhibit well-ordered architectures consistent with experimental benchmarks; however, under increasing solvent stress, their behaviors diverge markedly. DPPC membranes display gradual thinning, modest area per lipid …

Stochastic Functional Data-Driven Models For Real-Time Battery Health Forecasting Under Dynamic Operating Conditions, Joshua Owusu

Electronic Theses and Dissertations

This thesis provides an effective statistical model to predict the real-time state of lithium-ion batteries for reliable Battery Management Systems (BMS). It highlights battery data (voltage, current, temperature) as smooth functional curves. The principal method demonstrates diminishing trends to health outcomes like State of Health (SoH) and Remaining Useful Life (RUL) by employing Functional Principal Component Analysis (FPCA) and Bayesian Functional Linear Models (FLMs). The primary objective is to figure out how uncertain forecasts are. Simulations demonstrate that the highest accuracy (lowest MSE) is achieved through low noise levels along with large sample sizes. The final system provides a highly …

The Food Truck: A Multi-Product Newsvendor With Expectile Risk, Sekyiwaah Nuamah

Electronic Theses and Dissertations

The Newsvendor Problem is a fundamental model in Operation Research and Supply Chain Management used to determine the optimal order quantity under uncertain demand to minimize expected costs.
This research extends the classical Newsvendor problem to a multi--product setting, addressing the risk of asymmetric cost structures faced by a food truck. This thesis introduces expectile risk measures to quantify and manage uncertainty in demand, moving beyond traditional risk metrics. To evaluate the impact of expectile-based decision-making, we analyze three types of demand distributions--simple, symmetric, and skewed. For skewed distributions, we apply linear spline inverse interpolation to derive expectile values from …

Deep Learning With Kalman Filter, Rexford Julius Quaye

Electronic Theses and Dissertations

This thesis presents an extension of the Kalman filter to handle nonlinear and non-Gaussian systems. The standard Kalman filter is optimal under Gaussian assumptions but struggles with more complex noise models. This work introduces a novel loss function based on the Mahalanobis distance, which incorporates the covariance structure of measurement errors, enabling the filter to adapt to non-Gaussian scenarios. The neural network framework is applied to predict the system’s process model, while retaining the classical Kalman measurement update. The proposed methodology is demonstrated through examples of car position and rocket altitude tracking. The results show that the new approach performs …

An Income Subsystem As A Discrete Stochastic Leslie System: A Simulation-Based Approach, Fahd Nii Okantah Cobblah

Electronic Theses and Dissertations

This thesis formulates the household-income engine of an integrated population sim- ulator as a Discrete Stochastic Leslie System (DSLS). The nonnegative state vector nt ∈ Rk + aggregates income, savings, debt, employment, and transfers. (Here, the subscript + denotes the positive cone, i.e., vectors with nonnegative components). Annual evolution is linear in state, stochastic in coefficients: nt+1 = Ttnt + εt, with Tt : Rk + → Rk + cone-preserving. Exogenous macro drivers (inflation, employment, tax, salary inflation, mortgage) are forecast via ARIMA; forecasts multiply entries of Tt, preserving linearity in expectation while introducing realistic temporal correlation. The discrete-event implemented …

Postprocessing Gan-Generated Synthetic Time Series Using Dynamic Time Warping, Md Raisul Islam Roni

Electronic Theses and Dissertations

Generative Adversarial Networks (GANs) are a class of deep learning models capable of producing realistic synthetic data that preserve the statistical and temporal characteristics of real datasets. The DoppelGANger (DGAN) framework extends this approach to time series data by jointly modeling temporal dependencies and contextual metadata. However, synthetic sequences generated by GAN may show temporal misalignment, resulting in inconsistencies when compared with real data. This study presents a postprocessing framework based on Dynamic Time Warping (DTW) and its differentiable extension Soft-DTW to improve the temporal alignment of synthetic time series. The framework is evaluated using quantitative measures of alignment and …

Mountain Communities During A Time Of War: A Case Study Of The Hutsul Region In The Carpathian Mountains Of Ukraine, Pavlo Rybaruk

Electronic Theses and Dissertations

This thesis investigates the ethno-ecological technologies employed by the Hutsul people within the highland agrarian economy of the Carpathian Mountains. Over centuries, the Hutsuls have developed ethno-ecological technologies that maintain ecological integrity while supporting community livelihoods.

The study addresses three primary research questions: What are the most important ethno-ecological technologies of the Hutsul highland economy? How might these traditional ethno-ecological practices be applied to economic, agricultural, and tourism development in the Hutsul region? How might these traditional ethno-ecological practices be combined with contemporary approaches to encourage sustainable development in the region?

The research explores the devastating impact of the Russian …

A Leslie System For A Demographic Simulation: From An Actuarial Point Of View, David Kings

Electronic Theses and Dissertations

This thesis develops a discrete stochastic linear systems interpretation of age–stage demographic evolution grounded in Leslie operators and realized in a discrete-event simulation implemented with salabim. The central claim is that one annual cycle of the simulation constitutes a cone-preserving, stochastic affine transformation on a high- dimensional population state vector indexed by age, sex, marital status, household type, employment, and education, and that the composition of yearly operators yields a random matrix product whose top Lyapunov exponent is the stochastic counterpart of the Perron–Frobenius growth rate (Caswell, 2001; Tuljapurkar, 1997)[1, 2]. The actuarial bridge is constructed by mapping simulated survival …

Isolation, Chemical Characterization, And In-Vitro Cytotoxic Evaluation Of Novel Polar Flavonoids From Chromolaena Leivensis, Matthew Tohatsu Tetteh

Electronic Theses and Dissertations

This study focuses on isolation, chemical characterization, and in-vitro cytotoxic evaluation of novel polar flavonoids from chromolaena leivensis. A 95% ethanolic extract of c. leivensis shipped by Prof. Ruben Torrenegra from University of Applied and Environmental Sciences, Bogota, Colombia, was dissolved in 1:1 methanol/chloroform mixture and its purity analyzed by TLC. The sample was eluted with toluene/methanol in an increasing order of polarity on silica gel, resulting in 49 fractions labelled CLA1 to CLA49. Among these fractions, CLA10 (1) and CLA19 (2) obtained yellow and white crystals. They were analyzed by GCMS, IR, and …

By The Numbers: Numeracy, Religion, And The Quantitative Transformation Of Early Modern England (Book Review), Calvin Jongsma

Faculty Work Comprehensive List

Reviewed Title: By the Numbers: Numeracy, Religion, and the Quantitative Transformation of Early Modern England by Jessica Marie Otis. New York, NY: Oxford University Press, 2024. 264 pp. ISBN: 9780197608777.