Physical Sciences and Mathematics Commons^™

Vascular Countercurrent Network For 3d Triple-Layered Skin Structure With Radiation Heating, Xiaoqi Zeng

Doctoral Dissertations

Heat transfer in living tissue has become more and more attention for researchers, because high thermal radiation produced by intense fire, such as wild fires, chemical fires, accidents, warfare, terrorism, etc, is often encountered in human's daily life. Living tissue is a heterogeneous organ consisting of cellular tissue and blood vessels, and heat transfer in cellular tissue and blood vessel is quite different, because the blood vessels provide channels for fast heat transfer. The metabolic heat generation, heat conduction and blood perfusion in soft tissue, convection and perfusion of the arterial-venous blood through the capillary, and interaction with the environment …

Zero Divisor Graphs And Poset Decomposition, Bette Catherine Putnam

Electronic Theses and Dissertations

A graph is associated to any commutative ring R where the vertices are the non-zero zero divisors of R with two vertices adjacent if x · y = 0. The zero-divisor graph has also been studied for various algebraic stuctures such as semigroups and partially ordered sets. In this paper, we will discuss some known results on zero-divisor graphs of posets as well as the concept of compactness as it relates to zero-divisor graphs. We will dicuss equivalence class graphs defined on the elements of various algebraic structures and also the reduced graph defined on the vertices of a compact …

Ion Transport, Viscoelastic, And Thermal Properties Of Several Poly(Ethylene Glycol) And Poly(Propylene Glycol) Based Polymer Electrolytes, Benjamin Jacob Yancey

Electronic Theses and Dissertations

This dissertation explores the relationship between ionic conductivity, viscosity, and thermal properties of several MePEG and MePPG based copolymer electrolytes. In particular two main copolymer modifications have been investigated namely copolymerization with "bulky groups" and cross polymerization of MePEG and MePPG monomers. The modifications were made to vary the fractional free volume of the MePEG polymers. All of the copolymers obeyed the Doolittle equation. For both the bulky copolymers and MePEG/MePPG copolymers, increases in the FFV corresponded to increases in the viscosity and decreases in FFV correspond to decreases in viscosity. The FFV and H+ conductivity for these copolymers were …

Multiple Differential Study Of Fragmentation Processes In 75 Kev Proton-Molecular Hydrogen Collisions, Kisra Nayomal Egodapitiya

Doctoral Dissertations

"Double Differential Cross Sections (DDCS) were measured for single ionization of H₂ by 75 keV proton (p) impact as a function of the projectile scattering angle (θp) for a fixed energy loss (ΔE) for two different target-collimating slit distances, which determined the width of the projectile wave packet (Δx). In one case Δx was larger than the inter-nuclear separation of the H₂ molecule (coherent projectile beam), while for the other case it was much smaller than the inter-nuclear separation (incoherent projectile beam). A Young type interference pattern was observed in the coherent data, but this was not present in the …

Ecological Design Of Marine Construction For Socio-Economic Benefits: Ecosystem Integration Of A Pipeline In Coral Reef Area, Sylvain Pioch, Philippe Saussola, Kirk Kilfoyle, Richard E. Spieler

Marine & Environmental Sciences Faculty Articles

It is critical to understand that an ecosystem integration of construction requires a close Engineering/Biology partnership to meet socio-economic benefits in management goals. Biologists are not typically trained or licensed for the requisite engineering involved in construction. Likewise, non-biologists designing habitat often can lead to egregious results. For example, unintentionally constructing the wrong habitat, i.e., refuge for predators in a nursery area, or habitat that facilitates the spread of non-desirable species can increase, rather than ameliorate, the impact of construction. In recent years, Pioch and co-workers (unpublished) developed an alternative to the “classic” engineering approach to marine construction. This new …

Dispersive Wave Equations For Solids With Microstructure, A. Berezovski, Juri Engelbrecht, Mihhail Berezovski

Publications

The dispersive wave motion in solids with microstructure is considered in the one-dimensional setting in order to understand better the mechanism of dispersion. It is shown that the variety of dispersive wave propagation models derived by homogenization, continualisation, and generalization of continuum mechanics can be unified in the framework of dual internal variables theory.

A Picture Is Worth 972 Words: The Old, Red Barn, Chris Laingen

Faculty Research and Creative Activity

No abstract provided.

Historic And Contemporary Trends Of The Conservation Reserve Program And Ring-Necked Pheasants In South Dakota, Chris Laingen

Faculty Research and Creative Activity

Over the past century, the interactions between agricultural land use and government cropland retirement programs have affected pheasant population change. Two government land retirement programs that returned croplands to grasslands, Soil Bank in the 1960s and the current Conservation Reserve Program (CRP), help to illustrate these connections. From 2007 to 2010, South Dakota lost 41% of its CRP lands and experienced an 18% decline in pheasants per mile. However, because of where CRP expirations have occurred and where pheasant populations are found , some regional variability is seen. Western South Dakota (Region 1) had an 80% increase in pheasants per …

Aligned And Exchange-Coupled Fept-Based Films, Yi Liu, Thomas A. George, Ralph Skomski, David J. Sellmyer

David Sellmyer Publications

Two-phase nanostructures of hard L1₀-ordered FePt and soft iron-rich fcc Fe-Pt are investigated experimentally and by model calculations. The Fe-Pt thin films were produced by epitaxial co-sputtering onto MgO and have a thickness of about 10 nm. They form two-phase dots that cover a large fraction of the surface but are separated from each other. X-ray diffraction and TEM show that the c-axis of the phase FePt is aligned in the direction normal to the film plane. The experimental and theoretical hysteresis loops indicate archetypical exchange coupling, and excellent magnetic properties are obtained. The largest values of …

Dissociative Electron Attachment And Vibrational Excitation Of Cf3cl: Effect Of Two Vibrational Modes Revisited, Michal Tarana, Karel Houfek, Jiri Horacek, Ilya I. Fabrikant

Ilya Fabrikant Publications

We present a study of dissociative electron attachment and vibrational excitation processes in electron collisions with the CF₃Cl molecule. The calculations are based on the two-dimensional nuclear dynamics including the C-Cl symmetric stretch coordinate and the CF₃ symmetric deformation (umbrella) coordinate. The complex potential energy surfaces are calculated using the ab initio R-matrix method. The results for dissociative attachment and vibrational excitation of the umbrella mode agree quite well with experiment whereas the cross section for excitation of the C-Cl symmetric stretch vibrations is about a factor-of-three too low in comparison with experimental data.

Influence Of Karst Landscape On Planetary Boundary Layer Atmosphere: A Weather Research And Forecasting (Wrf) Model–Based Investigation, Ronnie Leeper, Rezaul Mamood, Arturo I. Quintanar

HPRCC Personnel Publications

Karst hydrology provides a unique set of surface and subsurface hydrological components that affect soil moisture variability. Over karst topography, surface moisture moves rapidly below ground via sink holes, vertical shafts, and sinking streams, reducing surface runoff and moisture infiltration into the soil. In addition, subsurface cave blockage or rapid snowmelt over karst can lead to surface flooding. Moreover, regions dominated by karst may exhibit either drier or wetter soils when compared to nonkarst landscape. However, because of the lack of both observational soil moisture datasets to initialize simulations and regional land surface models (LSMs) that include explicit karst hydrological …

Length Scales Of Interactions In Magnetic, Dielectric, And Mechanical Nanocomposites, Ralph Skomski, Balamurugan Balamurugan, Eva Schubert, Axel Enders, David J. Sellmyer

Axel Enders Publications

It is investigated how figures of merits of nanocomposites are affected by structural and interaction length scales, Aside from macroscopic effects without characteristic lengths scales and atomic-scale quantum-mechanical interactions there are nanoscale interactions that reflect a competition between different energy contributions. We consider three systems, namely dielectric media, carbon-black reinforced rubbers and magnetic composites. In all cases, it is relatively easy to determine effective materials constants, which do not involve specific length scales. Nucleation and breakdown phenomena tend to occur on a nanoscale and yield a logarithmic dependence of figures of merit on the macroscopic system size. Essential system-specific differences …

Detecting An Extended Light Source Through A Lens, E. T. Litaker, J. R. Machacek, Timothy J. Gay

Timothy J. Gay Publications

We present a Monte Carlo simulation of a cylindrical luminescent volume and a typical lens–detector system. The results of this simulation yield a graphically simple picture of the regions within the cylindrical volume from which this system detects light. Because the cylindrical volume permits large angles of incidence, we use a modification of the thin-lens approximation for ray tracing. We compare simulation results with concepts from imaging optics, and comment on implications for experimental design.

Production Of Excited Atomic Hydrogen And Deuterium From H2, Hd And D2 Photodissociation, J R. Machacek, V M. Andrianarijaona, J. E. Furst, A L D Kilcoyne, A L Landers, E T Litaker, K W Mclaughlin, Timothy J. Gay

Timothy J. Gay Publications

We have measured the production of Lyman α and Balmer α fluorescence from atomic H and D for the photodissociation of H₂, HD and D₂ by linearly-polarized photons with energies between 22 and 64 eV. We discuss systematic uncertainties associated with our data, and compare our results with previous experimental results and ab initio calculations of the dissociation process. We comment on the discrepancies.

Measurement Of Electron Beam Polarization From Unstrained Bulk Gaas Via Two Photon Photoemission, J L Mccarter, Timothy J. Gay, J Hansknecht, M Poelker, M L Stutzman

Timothy J. Gay Publications

This paper describes measurements of the beam polarization and quantum efficiency for photo-emission using two-photon excitation from unstrained bulk GaAs illuminated with pulsed, high intensity 1560nm laser light. Quantum efficiency is linearly proportional to 1560nm peak laser intensity, which was varied in three independent ways, indicating that the emitted electrons are promoted from the valence to the conduction band via two-photon absorption. Beam polarization was measured using a microMott polarimeter, with a value of 16.8(4)% polarization at 1560nm, which is roughly half the measured value of 33.4(8)% using 778 nm light.

A Gis Investigation Of Regional Geologic Controls On Mercury Deposits In The Southwest Region Of Arkansas, Lindsey Carol Langsdon

Electronic Theses and Dissertations

The mercury district of southwest Arkansas, located within Clark, Pike, and Howard counties, contains 77 mapped mercury deposits, primarily in the form of cinnabar, found within the sandstones and shales of the Stanley and Jackfork Formations. The geographic locations of the majority of the deposits tend to form an east-northeast alignment in map view. Utilization of Geographic Information Systems (GIS) tools provided insight to the regional controls on the spatial distribution of the mercury deposits by examining the proposed relationships between mercury deposits and regional faults or changes in lithology, both of which have been suggested (Clardy and Bush, 1976) …

Sequence Stratigraphy And Source Rock Characterization Of Organic-Rich Shales Within The Jurassic Smackover Formation, Conecuh Embayment, Alabama, U.S.A., Patrick W. Niemeyer

Electronic Theses and Dissertations

The Upper Jurassic Smackover Formation is a prolific producer of hydrocarbons known throughout the U.S. Gulf Coast region, and typically consists of carbonate lime mudstones, ooid grainstones, microbial boundstones, and dolostones. Recent exploration efforts in the Conecuh Embayment of southwest Alabama revealed the presence of two black, siliciclastic shale layers containing abundant terrestrially derived organic matter within the Smackover Formation. The shale layers provide interesting insight into the sequence stratigraphy and paleoclimate of the Conecuh Embayment, and the source of the hydrocarbons accumulated there. The two shale layers reach a maximum thickness of 50 feet along the longitudinal axis of …

Sol-Gel Resorcinarene Sorbent For Capillary Microextraction Coupled To Gas Chromatography, Abdullah Awadh Alhendal

USF Tampa Graduate Theses and Dissertations

For the first time, octahydroxyl methylresorcinarene with four hexyl groups on the lower rim was utilized in the in-situ preparation of a silica-based sol-gel organicinorganic hybrid coating for sample preconcentration by capillary microextraction (CME). Tetraethoxysilane (TEOS) was chosen as a sol-gel precursor to create a crosslinked sol-gel network via acid-catalyzed hydrolytic polycondensation reactions. Sol-gel chemistry helped in the in situ preparation of resorcinarene-containing extraction phase in the form of a surface coating. It also provided an effective means to chemically bind the coating to the inner surface of fused silica capillary via condensation of the hydroxyl groups in the sol-gel …

Synthesis And Characterization Of Self-Healing Poly (Carbonate Urethane) Carbon-Nanotube Composites, Roger Wesley Bass

USF Tampa Graduate Theses and Dissertations

Synthesis of high molar mass polycarbonate polyurethanes using a novel polyol is described. The resulting elastomers demonstrate excellent mechanical properties as well as the capability to re-heal after rupture without the addition of additives or imbedded healing agents. The self-healing functionality is shown to greatly improve with the addition of up to 1% single and multi-walled carbon nanotubes. The interface of the carbon nanotubes and self-healing polymer are probed using Raman techniques and provide an insight into how the self-healing actions are improved with the addition of carbon nanotubes.

Synthesis of polycarbonate polyurethanes and carbon nanotube composites using a novel …

Cataloguing Diseases And Pests In Captive Corals, Adrienne George

USF Tampa Graduate Theses and Dissertations

Stony corals (Order Scleractinia) are susceptible to a variety of diseases, which can occur from abiotic or biotic factors, or a combination of both. Public aquaria provide opportunities to study coral disease. Because coral mucus is the first line of defense against disease, the Biolog EcoplateTM is a useful tool to detect differences in microbial assemblages in the surface mucopolysaccharide (mucus) layer when comparing healthy and diseased corals. Histological examination is essential to document structural changes in coral tissue in response to diseases. This study identifies and characterizes diseases in captive corals through visual recognition, characterization of carbon utilization by …

Heterogeneous Modeling Of Medical Image Data Using B-Spline Functions, Olya Grove

USF Tampa Graduate Theses and Dissertations

Ongoing developments in the field of medical imaging modalities have pushed the frontiers of modern medicine and biomedical engineering, prompting the need for new applications to improve diagnosis, treatment and prevention of diseases.

Biomedical data visualization and modeling rely predominately on manual processing and utilization of voxel and facet based homogeneous models. Biological structures are naturally heterogeneous and in order to accurately design and biomimic biological structures, properties such as chemical composition, size and shape of biological constituents need to be incorporated in the computational biological models.

Our proposed approach involves generating a density point cloud based on the intensity …

Growth And Characterization Of Thermoelectric Ba8Ga16Ge30 Type-I Clathrate Thin-Films Deposited By Pulsed Dual-Laser Ablation, Robert Harry Hyde

USF Tampa Graduate Theses and Dissertations

The on-going interest in thermoelectric (TE) materials, in the form of bulk and films, motivates investigation of materials that exhibit low thermal conductivity and good electrical conductivity. Such materials are phonon-glass electron-crystals (PGEC), and the multi-component type-I clathrate Ba₈Ga₁₆Ge₃₀ is in this category. This work reports the first investigation of Ba₈Ga₁₆Ge₃₀ films grown by pulsed laser deposition (PLD).

This dissertation details the in-situ growth of polycrystalline type-I clathrate Ba₈Ga₁₆Ge₃₀ thin-films by pulsed laser ablation. Films deposited using conventional laser ablation produced films that contained a …

Combining Natural Language Processing And Statistical Text Mining: A Study Of Specialized Versus Common Languages, Jay Jarman

USF Tampa Graduate Theses and Dissertations

This dissertation focuses on developing and evaluating hybrid approaches for analyzing free-form text in the medical domain. This research draws on natural language processing (NLP) techniques that are used to parse and extract concepts based on a controlled vocabulary. Once important concepts are extracted, additional machine learning algorithms, such as association rule mining and decision tree induction, are used to discover classification rules for specific targets. This multi-stage pipeline approach is contrasted with traditional statistical text mining (STM) methods based on term counts and term-by-document frequencies. The aim is to create effective text analytic processes by adapting and combining individual …

Modeling Endogenous Treatment Eects With Heterogeneity: A Bayesian Nonparametric Approach, Xuequn Hu

USF Tampa Graduate Theses and Dissertations

This dissertation explores the estimation of endogenous treatment effects in the presence of heterogeneous responses. A Bayesian Nonparametric approach is taken to model the heterogeneity in treatment effects. Specifically, I adopt the Dirichlet Process Mixture (DPM) model to capture the heterogeneity and show that DPM often outperforms Finite Mixture Model (FMM) in providing more flexible function forms and thus better model fit. Rather than fixing the number of components in a mixture model, DPM allows the data and prior knowledge to determine the number of components in the data, thus providing an automatic mechanism for model selection.

Two DPM models …

Usf's Coverage Of Women's Athletics: A Census Of The Usf Athletics Home Web Page, Laura Ann Lebeau

USF Tampa Graduate Theses and Dissertations

This study examines the coverage of women’s athletics at USF provided through photographic representations on the university’s Athletics Internet home web page during the 2009–2010 academic year. Findings from this census of five areas that comprise the USF Athletics Internet home web page revealed that, consistent with recent research on coverage of female athletes and women’s athletics on university web pages, women, compared to men, were underrepresented in the majority of the five areas of the home page analyzed. The difference in the number of overall total photographs of women and men was not that large—48% and 52%, respectively, not …

Device Physics Of Solution Processable Solar Cells, Jason Erik Lewis

USF Tampa Graduate Theses and Dissertations

This Ph.D work reports the studies of photovoltaic devices produced by solution processable methods. Two material systems are of interest: one is based on organic semiconductors, and another on organic/inorganic hybrid composites. Specifically, organic photovoltaic (OPV) devices are made using photoactive materials consisted of a p-conjugated polymer [Poly(3-hexylthiophene), or P3HT] and fullerene derivative [phenyl-C60-butric acid methyl ester, or PCBM] in a bulk heterojunction (BHJ) structure of donor/acceptor network. On the other hand, hybrid photovoltaic (HPV) devices are made from blend of quantum dots and p-conjugated polymers. The QD material presented here are of the lead sulfide (PbS), and lead selenide …

A Study Of Complex Systems: From Magnetic To Biological, Douglas Carroll Lovelady

USF Tampa Graduate Theses and Dissertations

This work is a study of complex many-body systems with non-trivial interactions. Many such systems can be described with models that are much simpler than the real thing but which can still give good insight into the behavior of realistic systems. We take a look at two such systems. The first part looks at a model that elucidates the variety of magnetic phases observed in rare-earth heterostructures at low temperatures: the six-state clock model. We use an ANNNI-like model Hamiltonian that has a three dimensional parameter space and yields two-dimensional multiphase regions in this space. A low-temperature expansion of the …

Problems In Classical Potential Theory With Applications To Mathematical Physics, Erik Lundberg

USF Tampa Graduate Theses and Dissertations

In this thesis we are interested in some problems regarding harmonic functions. The topics are divided into three chapters.

Chapter 2 concerns singularities developed by solutions of the Cauchy problem for a holomorphic elliptic equation, especially Laplace's equation. The principal motivation is to locate the singularities of the Schwarz potential. The results have direct applications to Laplacian growth (or the Hele-Shaw problem).

Chapter 3 concerns the Dirichlet problem when the boundary is an algebraic set and the data is a polynomial or a real-analytic function. We pursue some questions related to the Khavinson-Shapiro conjecture. A main topic of interest is …

Natural Product Drug Discovery Against Tropical Diseases, Wai Sheung Ma

USF Tampa Graduate Theses and Dissertations

This dissertation describes the isolation of secondary metabolites from natural origins through a series of chromatographic techniques and spectrometric characterization in the effort of drug discovery. The isolated compounds obtained were used as drug leads against tropical diseases, namely malaria and leishmaniasis. While first chapter offers an introduction on the use of a natural product by itself as an effective therapeutic and its role on inspiring the discovery of new drugs, the later chapters will concentrate on isolation and characterization of bioactive natural products from an Antarctic sponge and mangrove endophytic fungi during the dissertation work.

The second chapter describes …

Impacts Of Artificial Reefs On Surrounding Ecosystems, Sarine Manoukian

USF Tampa Graduate Theses and Dissertations

Artificial reefs are becoming a popular biological and management component in shallow water environments characterized by soft seabed, representing both important marine habitats and tools to manage coastal fisheries and resources. An artificial reef in the marine environment acts as an open system with exchange of material and energy, altering the physical and biological characteristics of the surrounding area. Reef stability will depend on the balance of scour, settlement, and burial resulting from ocean conditions over time. Because of the unstable nature of sediments, they require a detailed and systematic investigation.

Acoustic systems like high-frequency multibeam sonar are efficient tools …