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Articles 2491 - 2520 of 36209

Full-Text Articles in Physics

Critical Dynamics In Biological Boolean Networks Follows From Symmetric Response To Input Genes, Hamza Çoban, Alkan Kabakçioğlu Jan 2022

Critical Dynamics In Biological Boolean Networks Follows From Symmetric Response To Input Genes, Hamza Çoban, Alkan Kabakçioğlu

Turkish Journal of Physics

A recent observation on an extensive collection of biological gene regulatory networks suggests that the regulatory dynamics is tuned to remain close to the order-chaos boundary in the Lyapunov sense [1]. We here investigate, from a mathematical perspective, the structural/functional constraints which give rise to such accumulation around criticality in these systems. While the role of canalizing functions in this respect is well established, we find that critical sensitivity to small input variations also follows from an over-abundance of symmetrical inputs, i.e. regulatory genes invoking identical or complementary responses on their common target. A random network ensemble constructed to have …


3d Self-Assemble Formation Of Molybdenum Disulfide (Mos2)-Doped Polyacrylamide (Paam) Composite Hydrogels, Sümeyye Durmaz, Ekrem Yildiz, Bengü Özuğur Uysal, Mehmet Önder Pekcan Jan 2022

3d Self-Assemble Formation Of Molybdenum Disulfide (Mos2)-Doped Polyacrylamide (Paam) Composite Hydrogels, Sümeyye Durmaz, Ekrem Yildiz, Bengü Özuğur Uysal, Mehmet Önder Pekcan

Turkish Journal of Physics

Polyacrylamide (PAAm), a renowned member of the hydrogel class, has many uses throughout a wide range of industrial processes, including water absorbed diapers, contact lenses, wastewater treatment, biomedical applications such as drug delivery vehicles and tissue engineering because of its physical stability, durability, flexibility easier shaping, and so on. PAAm also provides new functionalities after the incorporation of inorganic structures such as molybdenum disulfide (MoS2). During the copolymerization process, the transmittance of all samples reduced significantly after a particular time, referred to as the gel point. Microgels form a tree above the gel point as projected by Flory-Stockmayer …


Dynamic Multicritical Phase Diagrams Of The Mixed Spin (2, 5/2) Blume-Emery-Griffiths Model With Repulsive Biquadratic Coupling, Mustafa Gençaslan, Mustafa Keski̇n Jan 2022

Dynamic Multicritical Phase Diagrams Of The Mixed Spin (2, 5/2) Blume-Emery-Griffiths Model With Repulsive Biquadratic Coupling, Mustafa Gençaslan, Mustafa Keski̇n

Turkish Journal of Physics

We investigated the dynamic phase transitions (DPTs) in the mixed spin (2, 5/2) Blume-Emery Griffiths model with repulsive biquadratic interaction in the presence of a time-varying magnetic field. We used the path probability method to obtain the set of the dynamic equations. We numerically solved these dynamic equations to characterize the nature of first- and second-order phase transitions and to find the DPT temperatures as well as obtain the phases in the system. We constructed the dynamic phase diagrams (DPDs) in reduced temperature and amplitude of oscillating magnetic field plane. We observed that the DPDs display richer, complex and more …


การศึกษาปัจจัยที่ส่งผลต่อสมบัติของยางแผ่นรมควันเกรดพรีเมียม, สายสุณี จิตกล้า Jan 2022

การศึกษาปัจจัยที่ส่งผลต่อสมบัติของยางแผ่นรมควันเกรดพรีเมียม, สายสุณี จิตกล้า

Chulalongkorn University Theses and Dissertations (Chula ETD)

ถึงแม้ว่าสมบัติเชิงกลของยางแผ่นรมควันจะเหนือกว่ายางแห้งชนิดอื่นก็ตาม แต่ความไม่สม่ำเสมอในคุณภาพของยางส่งผลให้ปริมาณการใช้งานยางแผ่นรมควันในอุตสาหกรรมล้อยางลดลงอย่างต่อเนื่อง ปัจจุบันการยางแห่งประเทศไทยได้กำหนดมาตรฐานการผลิตยางแผ่นรมควันขึ้นเพื่อควบคุมและให้ได้ยางแผ่นรมควันที่มีสมบัติต่าง ๆ คงที่ ซึ่งยางที่ได้จะเรียกว่า “ยางแผ่นรมควันเกรดพรีเมียม” หรือ “ยางแผ่นรมควันเกรด P” เพื่อให้เข้าใจถึงสาเหตุที่ส่งผลให้สมบัติต่าง ๆ ของยางแผ่นรมควันแปรปรวนดียิ่งขึ้น งานวิจัยนี้ได้ศึกษาถึงอิทธิพลด้านภาวะการผลิต ช่วงฤดูกาลกรีดยาง รวมไปถึงพิ้นที่ปลูกยางต่อสมบัติทั้งทางกายภาพและเชิงกลของยางแผ่นรมควัน ผลการทดลองที่ได้พบว่า เมื่อใช้น้ำยางที่มีปริมาณเนื้อยางแห้งแตกต่างกันและใช้ความเข้มข้นกรดฟอร์มิกในการจับตัวเนื้อยางแตกต่างกัน สมบัติของยางแผ่นรมควันจะแตกต่างกันไป โดยพบว่าเมื่อปริมาณเนื้อยางแห้งและความเข้มข้นกรดฟอร์มิกเพิ่มขึ้นส่งผลให้ค่าสิ่งระเหยในยางแผ่นรมควันเพิ่มขึ้น เนื่องจากก้อนยางที่ได้จากการจับตัวของเนื้อยางด้วยกรดค่อนข้างแข็ง ทำให้เมื่อนำไปรีดเป็นแผ่นบางทำได้ยาก น้ำในเนื้อยางจึงระเหยออกมาได้ไม่ดี เมื่อเพิ่มปริมาณเนื้อยางแห้งจะทำให้ค่า PO, PRI และความหนืดมูนีเพิ่มขึ้น การแปรปริมาณเนื้อยางแห้งในน้ำยางจาก 20% (ภาวะใช้ในการผลิตยางแผ่นรมควันพรีเมียม) เป็น 18, 20 และ 25% โดยน้ำหนัก ส่งผลให้ความทนต่อแรงดึงของยางแตกต่างกันมากที่สุดอยู่ที่ 2.1 MPa การเพิ่มความเข้มข้นกรดฟอร์มิกจะส่งผลทำให้ค่า PO, PRI และความหนืดมูนีลดลง การแปรความเข้มข้นกรดฟอร์มิกจาก 4% (ภาวะที่ใช้ในการผลิตยางแผ่นรมควันเกรดพรีเมียม) เป็น 2, 3, 5, 8 และ 10% โดยปริมาตร ส่งผลให้ความทนต่อแรงดึงของยางแตกต่างกันมากที่สุดอยู่ที่ 3.2 MPa เมื่อพิจารณาฤดูกาลกรีดยางแตกต่างกัน น้ำยางที่ได้จากช่วงการผลัดใบของต้นยางจะมีปริมาณเนื้อยางแห้งในน้ำยางลดลง และปริมาณธาตุต่างๆ ในยางเพิ่มขึ้น ซึ่งจะส่งผลต่อค่าเถ้าและไนโตรเจนในยางแผ่นรมควันแตกต่างกัน ค่าความหนืดมูนีของยางแผ่นรมควันขึ้นอยู่กับช่วงฤดูกาลกรีดยางค่อนข้างชัดเจน โดยยางแผ่นรมควันที่เตรียมจากน้ำยางที่ได้จากการกรีดในช่วงกรีดปกติจะมีความหนืดมูนีที่สูงกว่ายางแผ่นรมควันที่เตรียมจากน้ำยางที่ได้จากการกรีดในช่วงก่อนปิดกรีด ยางแผ่นรมควันที่ได้จากภาคตะวันออกเฉียงเหนือมีปริมาณเถ้ามากกว่าที่ได้จากภาคใต้ ซึ่งปริมาณเถ้าเกิดจากปริมาณสารและแร่ธาตุต่าง ๆ ในดินที่ไม่เหมือนกัน อย่างไรก็ตาม ยางที่ได้จากทั้งสองบริเวณที่มีค่า PO , PRI และ ความหนืดมูนี ไม่ได้แตกต่างกันอย่างเห็นได้ชัด


Impact Of Introductory Physics For The Life Sciences In A Senior Biology Capstone Course, Benjamin D. Geller , '01, Jack Rubien , '20, Sara Hiebert Burch, Catherine Hirshfeld Crouch Jan 2022

Impact Of Introductory Physics For The Life Sciences In A Senior Biology Capstone Course, Benjamin D. Geller , '01, Jack Rubien , '20, Sara Hiebert Burch, Catherine Hirshfeld Crouch

Physics & Astronomy Faculty Works

A goal of introductory physics for life sciences (IPLS) curricula is to prepare students to effectively use physical models and quantitative reasoning in biological and medical settings. To assess whether this goal is being met, we conducted a longitudinal study of the impact of IPLS on student work in later biology and chemistry courses. We report here on one part of that study, a comparison of written responses by students with different physics backgrounds on a diffusion task administered in a senior biology capstone course. We observed differences in student reasoning that were found to be associated with prior or …


3-D Printed Arduino Powered Drone, Michael Floccare Jan 2022

3-D Printed Arduino Powered Drone, Michael Floccare

Senior Honors Projects

With the 3D technology available today creating something in a lab has never been easier. Using 3D printers, the body of a drone is created and printed using a combination of programs. With a body created using PLA filament the drone is durable and light weight. The drone’s flight system and controller are programmed with the built-in software from Arduino. Adding the Arduino nano to the drone body then gives the drone capabilities to fly.


Editorial For The Special Issue On Micromachines For Non-Newtonian Microfluidics, Lanju Mei, Shizhi Qian Jan 2022

Editorial For The Special Issue On Micromachines For Non-Newtonian Microfluidics, Lanju Mei, Shizhi Qian

Mechanical & Aerospace Engineering Faculty Publications

In lieu of an abstract, this is an excerpt from the first page.

Microfluidics has seen a remarkable growth over the past few decades, with its extensive applications in engineering, medicine, biology, chemistry, etc [...]


Comparing Twins Ion Temperature Maps With Mms, Ampere, And Themis Observations During July 26, 2017 Reconnection Event, Isabella M. Householder Jan 2022

Comparing Twins Ion Temperature Maps With Mms, Ampere, And Themis Observations During July 26, 2017 Reconnection Event, Isabella M. Householder

Honors Theses and Capstones

The solar wind releases a constant stream of ionized particles into space which causes complex behaviors to occur within Earth’s magnetosphere. These disruptions can initiate magnetic reconnection and cause flow reversal of ions in the magnetotail. Two flow reversal events were locally detected by the Magnetospheric Multiscale Mission (MMS) on July 26, 2017 at 0700 UT and 0730 UT. The Two Wide-Angle Imaging Neutral-Atom Spectrometers (TWINS) provide a global measurement of heated signatures of the magnetic field and detected an increase in ion temperature during these reconnection events without the presence of a geomagnetic storm. Active Magnetosphere and Planetary Electrodynamics …


Development Of A Fluxgate Magnetometer Model, Eleonora Olsmats Jan 2022

Development Of A Fluxgate Magnetometer Model, Eleonora Olsmats

Honors Theses and Capstones

As a part of the UNH SWFO-L1 mission to monitor space weather and the sun’s behavior, the fluxgate magnetometer is an important component to measure external magnetic fields. The basic principle of a fluxgate magnetometer is to detect changes in the ambient magnetic field by inducing a magnetic field in a ferromagnetic material via a drive winding. Each magnetometer is unique due to the ferromagnetic properties of the core material which can be seen in the hysteresis loop which is a relationship between the magnetic field strength (H) and the induced magnetic field (B). Measuring the hysteresis of a fluxgate …


Location And Calibration Of Lightning Pulses From Lofar Radiation Measurements, Nicholas R. Demers Jan 2022

Location And Calibration Of Lightning Pulses From Lofar Radiation Measurements, Nicholas R. Demers

Honors Theses and Capstones

Lightning has the power to shock and awe as an incredible force of nature, yet so many phenomena surrounding lightning are still not well-understood. In fact, the very physics regarding what actually sparks a lightning strike remain poorly defined. In an effort to understand how lightning initiation is achieved, data collected from the Low Frequency Array in the Netherlands were calibrated and interferometry performed to map the flash in 4D space. The calibration process itself is explored, from choosing lightning sources to calibrate, to the various stages of calibration leading to a fully calibrated flash ready for interferometric analysis. Using …


Attempts To Measure Nanosecond Resolved Electronic Dynamics Of Charge Density Wave Phase Transition In 1t-Tas2, Ben Campbell Jan 2022

Attempts To Measure Nanosecond Resolved Electronic Dynamics Of Charge Density Wave Phase Transition In 1t-Tas2, Ben Campbell

Honors Theses and Capstones

Scanning tunneling microscopes allow for atomic spatial resolution but the resulting images are necessarily time-averaged and fast dynamics are lost. Pump-probe spectroscopy is a common optical technique used to measure ultrafast electronic dynamics but the integration of optical pump-probe spectroscopy into an STM requires specialized knowledge and equipment. Alternatively, an all-electronic pump-probe spectroscopy technique has recently been developed for use with an STM that replaces the laser pulses of optical pump-probe with voltage pulses. In this paper, I implemented an all-electronic pump-probe scheme into an existing scanning tunneling microscope using an arbitrary waveform generator and a lock-in amplifier. I developed …


Strain-Enhanced Coherent Exciton-Polaron States In 1d Phthalocyanine Crystalline Thin Films, Libin Liang Jan 2022

Strain-Enhanced Coherent Exciton-Polaron States In 1d Phthalocyanine Crystalline Thin Films, Libin Liang

Graduate College Dissertations and Theses

Organic semiconductors are at the forefront of materials research, due to their desired electric and mechanical properties. They offer the unique opportunity to modify material properties during synthesis process, opening an avenue to the development of novel flexible and wearable electronic and photonic devices.Molecular excitons are of importance in organic semiconductor properties. While majority of research studies are centered on achieving good control of amorphous or polycrystalline thin film properties, the static disorder effect leads to poor device performance when compared to inorganic semiconductors with superior crystalline ordering. On the other hand, the macroscopic molecular long-range ordering can enhance device …


Tuning Electroluminescence From Resonators Based On Fabry-Pérot Microcavity Oleds, Ekraj Dahal Jan 2022

Tuning Electroluminescence From Resonators Based On Fabry-Pérot Microcavity Oleds, Ekraj Dahal

Graduate College Dissertations and Theses

This thesis comprises a series of methods for controlling the electroluminescence from Fabry-Pérot microcavity OLEDs by varying the resonator geometry and the location of the organic emitter within the resonator. In pursuit of this thesis, I conducted three experimental projects backed by theoretical modeling. First the thickness of the microcavity was varied to observe changes in resonant state wavelength, linewidth of the states, angular dispersion, and polarization splitting. The resulting electroluminescence can be tuned to span the entire color gamut using a single green chromophore. Electroluminescence of this green chromophore was used to pump the optical states of nominally identical …


Edge Fueling And Neutral Density Studies Of The Alcator C-Mod Tokamak Using The Solps-Iter Code, Richard M. Reksoatmodjo Jan 2022

Edge Fueling And Neutral Density Studies Of The Alcator C-Mod Tokamak Using The Solps-Iter Code, Richard M. Reksoatmodjo

Dissertations, Theses, and Masters Projects

Understanding edge neutral dynamics in high-field tokamaks has strong consequencesfor both fueling and plasma profile predictions. We validate the ability of SOLPS-ITER, a 2D fluid plasma/kinetic Monte Carlo neutral code, to accurately model the upstream neutral density profiles of L-mode, I-mode, and H-mode discharges in the Alcator CMod tokamak, for which Lyman-alpha emission measurements were available. We achieve simulated Lyman-alpha emission and neutral density profiles that are within one standard deviation of empirically inferred profiles for all three discharges, via iterative tuning of the perpendicular transport coefficient profiles alone, providing confidence in the conclusion that while further physics (drifts, impurities, …


Inclusive And Inelastic Scattering In Neutrino-Nucleus Interactions, Amy Filkins Jan 2022

Inclusive And Inelastic Scattering In Neutrino-Nucleus Interactions, Amy Filkins

Dissertations, Theses, and Masters Projects

Neutrino-nucleus cross section measurements can provide both insights into nuclear physics and important data that can be used to improve model predictions used for neutrino oscillation physics. Two measurements of neutrino-nucleus cross sections were performed using data from the MINERvA experiment, each probing different classes of neutrino interactions. Double and single-differential flux-integrated measurements of inclusive charged current neutrino-nucleus cross sections at a peak neutrino energy of 3.5 GeV are presented as a function of the longitudinal and transverse momentum of the muon produced in the interaction. Additionally, an analysis of charged-current deep inelastic scattering (DIS) of muon neutrinos was performed …


Partial Wave Analysis Of Strange Mesons Decaying To K + Π − Π + In The Reaction Γp → K + Π + Π − Λ(1520) And The Commissioning Of The Gluex Dirc Detector, Andrew Hurley Jan 2022

Partial Wave Analysis Of Strange Mesons Decaying To K + Π − Π + In The Reaction Γp → K + Π + Π − Λ(1520) And The Commissioning Of The Gluex Dirc Detector, Andrew Hurley

Dissertations, Theses, and Masters Projects

Hadron spectroscopy is a cornerstone of our understanding of the strong nuclear interac-tions. Studying the hadron spectrum led to the postulation of quarks and gluons, and the development of Quantum Chromodynamics (QCD), the theory of the strong nuclear force. Today hadron spectroscopy provides an important test of QCD, particularly in the non-perturbative energy regime. One such test is the existence of hybrid hadrons that have gluonic degrees of freedom, e.g. qq̄g states, that are allowed by QCD but have remained elusive in experimental searches. The GlueX experiment located at Thomas Jefferson National Accelerator Facility, is designed to map the light …


Exploring The Photophysics Of Brown Carbon Chromophores Using Laser-Based Spectroscopy And Computational Methods, Megan Elizabeth Alfieri Jan 2022

Exploring The Photophysics Of Brown Carbon Chromophores Using Laser-Based Spectroscopy And Computational Methods, Megan Elizabeth Alfieri

Dissertations, Theses, and Masters Projects

Atmospheric aerosols are made up of suspended liquids and solids in the atmosphere. These aerosols play a very important role in the solar energy exchange in Earth’s atmosphere as well have dramatic impact on human health. Different aerosols have different effects on the atmosphere depending on the physical properties of the aerosols.

The purpose of this research project is to understand how the structure of molecular chromophores impacts the solar absorption properties of aerosols. We propose a series of laboratory studies to investigate the outcomes from solar absorption of brown carbon chromophores: 1-phenylpyrrole, 2-phenyl-1-H-pyrrole, 2-phenylimadazole, as well as water complexes. …


Broadband Infrared Microspectroscopy And Nanospectroscopy Of Local Material Properties: Experiment And Modeling, Patrick Mcardle Jan 2022

Broadband Infrared Microspectroscopy And Nanospectroscopy Of Local Material Properties: Experiment And Modeling, Patrick Mcardle

Dissertations, Theses, and Masters Projects

Infrared phenomena at the micro and nanoscales can elucidate fundamental physics of highly correlated and complex systems. However, accessing these length scales require high resolution microscopic instrumentation and novel analysis methods to extract meaningful information. Initially this work describes the implementation of a far-field microscope and subsequent study of single strands of spider silk and temperature dependent behavior of Li2RuO3.

Little is known about the internal structure of protein fibrils, the basic building blocks of spider silk. Polarized Fourier-transform infrared micro transmittance on single strands of native spider silk was performed to determine the concentrations and orientations of seven protein …


Radiative Width Of K*(892) From Lattice Quantum Chromodynamics, Archana Radhakrishnan Jan 2022

Radiative Width Of K*(892) From Lattice Quantum Chromodynamics, Archana Radhakrishnan

Dissertations, Theses, and Masters Projects

In this dissertation, we use lattice quantum chromodynamics to explore the radiative transitions of πK to K, to calculate the radiative width of the resonant K*(892) which appears in the P-wave πK → γK transition amplitude. The matrix elements are extracted from three-point functions calculated in a finite-volume discretized lattice with a pion mass of 284 MeV. The finite-volume amplitudes, which are constrained over a large number of πK energy points and four-momentum transfers, are mapped to the infinite volume transition amplitude by using the Lellouch-Lüscher formalism. The radiative width is determined to be …


Pymoocfd - A Multi-Objective Optimization Framework For Cfd, George Martin Cunningham Love Jan 2022

Pymoocfd - A Multi-Objective Optimization Framework For Cfd, George Martin Cunningham Love

Graduate College Dissertations and Theses

Modern computational resource have solidified the use of computer modeling as an integral part of the engineering design process. This is particularly impressive when it comes to high-dimensional models such as computational fluid dynamics (CFD) models. CFD models are now capable of producing results with a level of confidence that would previously have required physical experimentation. Simultaneously, the development of machine learning techniques and algorithms has increased exponentially in recent years. This acceleration is also due to the widespread availability of modern computational resources. Thus far, the cross-over between these fields has been mostly focused on computer models with low …


What Happens When Transition Metal Trichalcogenides Are Interfaced With Gold?, Archit Dhingra, Dmitri E. Nikonov, Alexey Lipatov, Alexander Sinitskii, Peter Dowben Jan 2022

What Happens When Transition Metal Trichalcogenides Are Interfaced With Gold?, Archit Dhingra, Dmitri E. Nikonov, Alexey Lipatov, Alexander Sinitskii, Peter Dowben

Peter Dowben Publications

Transition metal trichalcogenides (TMTs) are two-dimensional (2D) systems with quasi-one-dimensional (quasi-1D) chains. These 2D materials are less susceptible to undesirable edge defects, which enhances their promise for low-dimensional optical and electronic device applications. However, so far, the performance of 2D devices based on TMTs has been hampered by contact-related issues. Therefore, in this review, a diligent effort has been made to both elucidate and summarize the interfacial interactions between gold and various TMTs, namely, In4Se3, TiS3, ZrS3, HfS3, and HfSe3. X-ray photoemission spectroscopy data, supported by the results …


Data-Driven Methods For Low-Energy Nuclear Theory, Jordan M.R. Fox Jan 2022

Data-Driven Methods For Low-Energy Nuclear Theory, Jordan M.R. Fox

CGU Theses & Dissertations

The term data-driven describes computational methods for numerical problem solvingwhich have been developed by the field of data science; these are at the intersection of computer science,mathematics, and statistics. When applied to a domain science like nuclear physics, especially with the goalof deepening scientific insight, data-driven methods form a core pillar of the computational science endeavor.In this dissertation I explore two problems related to theoretical nuclear physics: one in the framework of numerical statistics, and the other in the framework of machine learning. I) Historically our understanding of the structure of the atomic nucleus, the quantum many-body problem, has been …


Optical And Single Particle Properties Of North Atlantic Free Tropospheric Aerosols And Implications For Aerosol Direct Radiative Forcing, Megan Morgenstern Jan 2022

Optical And Single Particle Properties Of North Atlantic Free Tropospheric Aerosols And Implications For Aerosol Direct Radiative Forcing, Megan Morgenstern

Dissertations, Master's Theses and Master's Reports

Human-induced climate change has steadily become a reality rather than a possibility. One factor that plays into climate change is radiative forcing due to aerosol-radiation interactions (ARI). As such, it is important to understand how aerosols (atmospheric particles) interact with solar radiation. This work looks at seven samples of well-aged aerosols (aerosols traveling in the atmosphere for at least a few days) collected at Pico Mountain Observatory in the summer of 2015. Pico Mountain Observatory is located in a remote, high elevation site in the Azores, in the Eastern-North Atlantic Ocean. The goals of the study were to analyze the …


Measuring The Diphoton Production From Higgs Boson Decays And In Association With Heavy Flavor Jets, Brianna Lynn Dwyer Jan 2022

Measuring The Diphoton Production From Higgs Boson Decays And In Association With Heavy Flavor Jets, Brianna Lynn Dwyer

Graduate Research Theses & Dissertations

In this dissertation, two important measurements are presented related to diphoton production, the differential cross-section measurement of the Higgs boson in the diphoton decay channel as well as a measurement on inclusive diphoton production with associated heavy-flavor jets. Selections between the two analyses are complimentary, making them a natural pairing in the context of this dissertation. The cross-section measurement is performed in a fiducial region of phase space to closely matches experimental selections. This allows for a largely model-independent measurement, providing a meticulous test of the Standard Model as well as other theoretical predictions. The production of diphoton + heavy-flavor …


Charge Transfer Mediated Triplet Excited State Formation In Donor-Acceptor-Donor Bodipy: Application For Recording Of Holographic Structures In Photopolymerizable Glass, Tatsiana Mikulchyk, Safakath Karuthedath, Catherine S.P. De Castro, Andrey A. Buglak, Aimee Sheehan, Aaron Wieder, FréDéRic Laquai, Izabela Naydenova, Mikhail Filatov Jan 2022

Charge Transfer Mediated Triplet Excited State Formation In Donor-Acceptor-Donor Bodipy: Application For Recording Of Holographic Structures In Photopolymerizable Glass, Tatsiana Mikulchyk, Safakath Karuthedath, Catherine S.P. De Castro, Andrey A. Buglak, Aimee Sheehan, Aaron Wieder, FréDéRic Laquai, Izabela Naydenova, Mikhail Filatov

Articles

Donor–acceptor–donor BODIPY triads bearing anthracene or pyrene as electron donating subunits were prepared through a stepwise synthesis. Photoinduced electron transfer and formation of long-lived triplet excited states via spin–orbit charge transfer intersystem crossing (SOCT-ISC) was studied by steady-state and ultrafast pump-probe spectroscopy and further supported by DFT computations. New BODIPYs were found to form triplet states and sensitize singlet oxygen in both polar and non-polar solvents which is unusual for photosensitizers operating via SOCT-ISC. BODIPY-anthracene triad (ABA) was used as a photosensitizer component in a photopolymerizable glass that was prepared by a four-step sol–gel process. ABA in combination with N …


Design And Analysis Of Marangoni-Driven Robotic Surfers, Mitchel L. Timm Jan 2022

Design And Analysis Of Marangoni-Driven Robotic Surfers, Mitchel L. Timm

Dissertations, Master's Theses and Master's Reports

We designed and experimentally studied the dynamics of two robotic systems that surf along the water-air interface. The robots were self-propelled by means of creating and maintaining a surface tension gradient resulting from an asymmetric release of isopropyl alcohol (IPA). The imbalance in the distribution of surface tension surrounding the robots generates a propulsive force commonly referred to as Marangoni propulsion. First, we considered a single surfer, which was custom-made with novel control mechanisms that allow for both forward motion and steering to be remotely adjusted solely through the manipulation of local surface stresses. We analyzed the performance of this …


Collective Hydrodynamics Of Robotic Fish, Rohit S. Pandhare Jan 2022

Collective Hydrodynamics Of Robotic Fish, Rohit S. Pandhare

Dissertations, Master's Theses and Master's Reports

Many animals in nature travel in groups either for protection, survival, or endurance. Among these, fish do so under the burden of hydrodynamic loads, which incites questions as to the significance of the multi-body fluid-mediated interactions that facilitate collective swimming. We study such interactions in the idealized setting of a rotational array of robotic fish whose tails undergo a prescribed flapping motion, but whose swimming speed is determined as a natural result of the hydrodynamic effects. Specifically, we examine how the measured collective speed of the swimmers varies with the imposed frequency and amplitude of their tail flapping, and with …


A Surrogate Model Of Molecular Dynamics Simulations For Polar Fluids: Supervised Learning Methods For Molecular Polarization And Unsupervised Methods For Phase Classification, Zackerie W. Hjorth Jan 2022

A Surrogate Model Of Molecular Dynamics Simulations For Polar Fluids: Supervised Learning Methods For Molecular Polarization And Unsupervised Methods For Phase Classification, Zackerie W. Hjorth

Dissertations, Master's Theses and Master's Reports

Molecular Dynamic (MD) simulation is a standard computational tool in soft matter physics. While very powerful, it is computationally expensive, leading to some simulations taking days or even weeks to complete depending on the size of your computer cluster. Finding computationally cheap surrogate models which can learn the output features of MD simulation is therefore highly motivated. In this report I explore the use of deep neural network ensembles as well as support vector machine regressors as surrogate models for MD simulation. From the output of the surrogate models, we can then employ unsupervised learning methods to get insight into …


Methods And Characterization Of Topological And Disordered-Induced Protection Of Coherence In Quantum Systems, Sayandip Dhara Jan 2022

Methods And Characterization Of Topological And Disordered-Induced Protection Of Coherence In Quantum Systems, Sayandip Dhara

Electronic Theses and Dissertations, 2020-

Quantum computers can efficiently simulate natural processes and solve certain types of mathematical problems. Two of the key issues preventing the development of platforms to realize a scalable quantum machine are the decoherence of the qubits due to the interaction with the environment and the existence of a large overhead to correct errors. Although there already exist noisy intermediate-scale quantum machines, we still need to improve much to be able to solve problems faster than the already existing classical computers. In this dissertation, we explore two approaches to tackle both issues. We propose a scheme where, using quasi-Majorana zero modes …


Development Of Holographic Phase Masks For Wavefront Shaping, Nafiseh Mohammadian Jan 2022

Development Of Holographic Phase Masks For Wavefront Shaping, Nafiseh Mohammadian

Electronic Theses and Dissertations, 2020-

This dissertation explores a new method for creating holographic phase masks (HPMs), which are phase transforming optical elements holographically recorded in photosensitive glass. This novel hologram recording method allows for the fast production of HPMs of any complexity, as opposed to the traditional multistep process, which includes the design and fabrication of a master phase mask operating in the UV region before the holographic recording step. We holographically recorded transmissive HPMs that are physically robust (they are recorded in a silicate glass volume), can handle tens of kilowatts of continuous wave (CW) laser power, are un-erasable, user defined, require no …