Physics Commons^™

Effect Of Fabrication Parameters On The Ferroelectricity Of Hafnium Zirconium Oxide Films: A Statistical Study, Guillermo A. Salcedo, Ahmad E. Islam, Elizabeth Reichley, Michael Dietz, Christine M. Schubert Kabban, Kevin D. Leedy, Tyson C. Back, Weison Wang, Andrew Green, Timothy S. Wolfe, James M. Sattler

Faculty Publications

Ferroelectricity in hafnium zirconium oxide (Hf_1−xZr_xO₂) and the factors that impact it have been a popular research topic since its discovery in 2011. Although the general trends are known, the interactions between fabrication parameters and their effect on the ferroelectricity of Hf_1−xZr_xO₂ require further investigation. In this paper, we present a statistical study and a model that relates Zr concentration (x), film thickness (t_f), and annealing temperature (T_a) with the remanent polarization (P_r) in tungsten (W)-capped Hf_1−xZr_xO₂. …

Measurements Of Magnetic Field Penetration Of Materials For Superconducting Radiofrequency Cavities, Iresha Harshani Senevirathne

Physics Theses & Dissertations

Superconducting Radio Frequency (SRF) cavities used in particle accelerators are typically formed from or coated with superconducting materials. Currently high purity niobium is the material of choice for SRF cavities which have been optimized to operate near their theoretical field limits. This brings about the need for significant R&D efforts to develop next generation superconducting materials which could outperform Nb and keep up with the demands of new accelerator facilities. To achieve high quality factors and accelerating gradients, the cavity material should be able to remain in the superconducting Meissner state under high RF magnetic field without penetration of quantized …

The Influence Of The Substrate On The Functionality Of Spin Crossover Molecular Materials, Saeed Yazdani, Jared Phillips, Thilini K. Ekanayaka, Ruihua Cheng, Peter A. Dowben

Department of Physics and Astronomy: Faculty Publications

Spin crossover complexes are a route toward designing molecular devices with a facile readout due to the change in conductance that accompanies the change in spin state. Because substrate effects are important for any molecular device, there are increased efforts to characterize the influence of the substrate on the spin state transition. Several classes of spin crossover molecules deposited on different types of surface, including metallic and non-metallic substrates, are comprehensively reviewed here. While some non-metallic substrates like graphite seem to be promising from experimental measurements, theoretical and experimental studies indicate that 2D semiconductor surfaces will have minimum interaction with …

Novel As-S-Se Compositions Of Solution-Processed Chalcogenide Thin Films For Infrared Optics, Annabella Orsini

Physics and Astronomy Honors Papers

Chalcogenide glasses (ChGs) have a wide range of interdisciplinary applications. In industry, ChGs are used to vastly improve infrared sight abilities. There are, however, improvements that can be made to the films’ stability, cost, and flexibility. Our project seeks to produce thin films that have these improvements, with capabilities comparable or better than what is widely used in the field. Thin films created through solution-based processes have proven to be much more flexible in comparison to bulk glass versions. Other elements in Group 16, such as Sulfur and Selenium have shown across literature to be a cost-effective alternative to Tellurium …

Design And Fabrication Of A Low-Cost Dip Coating System For Depositing Homogeneous And Transparent Zno Thin Films, Asaad S. Yasir, Basheer M. Hussein, Ammar S. Hameed, Noor J. Ridha, Firas K. Mohamad Alosfur, Khawla J. Tahir, Rajaa A. Madlol

Al-Bahir Journal for Engineering and Pure Sciences

ZnO has a resistivity of up to 104 Ω cm-1 in most cases. Nevertheless, by increasing the layer thickness, the resistivity decreases as well, resulting in greater current transport. The dip coating system was developed to prepare the ultra-thin film, it relied on a controller, stepper motor and some low-cost recycled materials. Thin films of ZnO were successfully deposited on indium tin oxide substrates. The effects of the dipping cycles were investigated. Dipping processes were applied several times (1, 2, and 3) for the same concentrations (0.1) M to obtain homogeneous thin films. X-ray diffraction showed that the structure of …

Direct Current Magnetic Hall Probe Technique For Measurement Of Field Penetration In Thin Film Superconductors For Superconducting Radio Frequency Resonators, Iresha Harshani Senevirathne, Alex Gurevich, Jean Delayen

Physics Faculty Publications

Superconducting Radio Frequency (SRF) cavities used in particle accelerators are typically formed from or coated with superconducting materials. Currently, high purity niobium is the material of choice for SRF cavities that have been optimized to operate near their theoretical field limits. This brings about the need for significant R & D efforts to develop next generation superconducting materials that could outperform Nb and keep up with the demands of new accelerator facilities. To achieve high quality factors and accelerating gradients, the cavity material should be able to remain in the superconducting Meissner state under a high RF magnetic field without …

Some Optical Properties Of (Znte) Thin Films Prepared By Thermal Evaporation Technique On A Glass Substrate, Abdulla Saeed Ba-Sabiah, Mohamed Ali Seyam

Hadhramout University Journal of Natural & Applied Sciences

Thin films of Zinc telluride (ZnTe)were deposited by thermal evaporation technique on a glass substrate. The optical obtained data were analyzed using a numerical analysis program which showed that the transition mechanism involved indirectly allows transition since the best line dependence is obtained from a plot of 0.5 ( )  h versus photon energy ( ) h . The bandgap decreased from 1.15 to 0.96 eV as the substrate temperature varied from 410 to 510 K. Such behaviour is attributed to unsaturated defects, which are confirmed by XRD examinations. PACS:78.20.Ci, 71.30.+h, 72.90. +y

The Magnetic Field Penetration Measurement Of Thin Film And Multilayered Superconductors For Srf Cavities, Iresha Harshani Senevirathne, Jean Delayen

College of Sciences Posters

Radio Frequency (RF) Cavities are used in particle accelerators and they are typically formed from or coated with superconducting materials. High purity niobium is the material of choice for SRF cavities and niobium cavities operate at their theoretical field limits. SRF researchers have begun a significant R&D effort to develop alternative materials to continue to keep up with the demands of new accelerator facilities. To achieve high performance with high accelerating gradient, cavity material should have an ability to persist in superconducting state under high magnetic field without magnetic flux penetration through the cavity wall. Therefore, the magnetic field at …

Magnetic Properties Of Lsmo/Sto Thin Films: Magnetocaloric, Spin Dynamics And Magnetic Viscosity Investigations, Navid Mottaghi

Graduate Theses, Dissertations, and Problem Reports

While other films are discussed, this dissertation will focus on detailed studies of the dc and ac bulk magnetometry in a characteristic 7.6 nm thin film of La_0.7Sr_0.3MnO₃ grown on SrTiO₃ (001). The dc bulk magnetometry measurements show that the sample is magnetically inhomogeneous. Temperature variation of magnetization (M vs. T) was measured in zero-field-cooled and field-cooled protocols to determine the blocking temperature T_B in different applied magnetic fields. The field variation of T_B is interpreted as the presence of embedded spin clusters of 1.4 nm. Moreover, the M vs. …

Heterostructure Of 2d Materials: Hfs2/Hfo2/Si, Christopher J. Robledo

MSU Graduate Theses

Heterostructures have been utilized in electronic devices for over 50 years with the proposal for the first heterostructure transistor in 1957. With the scaling of devices, it is necessary to create new heterostructures that will comply with Moore’s Law, as well as make devices faster and consume less power. Novel 2D materials, such as hafnium disulfide, have shown promise as an active channel layer, while hafnium dioxide is already proven to be a replacement of silicon dioxide for the gate insulating layer. However, fabrication techniques for wide-scale integration of these heterostructures have not yet been achieved. Also, the dielectric properties …

High-Temperature Optical Properties Of Indium Tin Oxide Thin-Films, Jiwoong Kim, Sujan Shrestha, Maryam Souri, John G. Connell, Sungkyun Park, Ambrose Seo

Physics and Astronomy Faculty Publications

Indium tin oxide (ITO) is one of the most widely used transparent conductors in optoelectronic device applications. We investigated the optical properties of ITO thin films at high temperatures up to 800 °C using spectroscopic ellipsometry. As temperature increases, amorphous ITO thin films undergo a phase transition at ~ 200 °C and develop polycrystalline phases with increased optical gap energies. The optical gap energies of both polycrystalline and epitaxial ITO thin films decrease with increasing temperature due to electron-phonon interactions. Depending on the background oxygen partial pressure, however, we observed that the optical gap energies exhibit reversible changes, implying that …

Fabrication Of Magnetocaloric La(Fe,Si)13 Thick Films, N H. Dung, N B. Doan, P De Rango, L Ranno, Karl G. Sandeman, N M. Dempsey

Publications and Research

La(Fe,Si)₁₃–based compounds are considered to be very promising magnetocaloric materials for magnetic refrigeration applications. Many studies have focused on this material family but only in bulk form. In this paper we report on the fabrication of thick films of La(Fe,Si)₁₃, both with and without post-hydriding. These films exhibit magnetic and structural properties comparable to bulk materials. We also observe that the ferromagnetic phase transition has a negative thermal hysteresis, a phenomenon not previously found in this material but which may have its origins in the availability of a strain energy reservoir, as in the cases of …

Fabrication Of Nanoscale Columnar Diodes By Glancing Angle Deposition, Jacob D. Weightman

Macalester Journal of Physics and Astronomy

Glancing angle deposition (GLAD) is a process in which thin films are deposited onto a substrate with obliquely incident vapor together with precisely controlled azimuthal substrate rotation. Ballistic shadowing effects due to the oblique incidence produce nanoscale structures, and a variety of feature shapes, including tilted columns, helices, and vertical columns can be achieved by varying the azimuthal rotation during the deposition process. Due to this control of morphology and the compatibility of the process with a wide variety of materials, GLAD films have found applications in a variety of fields including sensing, photonics, photovoltaics, and catalysis, where they are …

Investigation Of Mnxni1-Xo Thin Films Using Pulsed Laser Deposition, Md Ashif Anwar

MSU Graduate Theses

The exchange bias (EB) effect, especially in nanomaterials, is highly promising for use in antiferromagnet-based spintronics applications. NiO is a well known antiferromagnetic material with a high Néel temperature (525K) and can exhibit ferromagnetism/ ferrimagnetism by adding other magnetic transition elements. Our previous work has shown that the antiferromagnetic characteristics of conventional NiO insulating nanostructured material can be altered to have substantial ferrimagnetic characteristics by doping NiO with Mn or Co. Pulsed laser deposition (PLD) was used to grow heterostructures comprised of a nanostructured thin NiO film deposited on the surface of a MgO (100) and Al₂O_{3 …}

Structural Behavior Of Rf Magnetron Sputtered Cupric Oxide (Cuo) Films, Ali Nadhim Khilkhal, Abdalhussain A. Khadayeir

Al-Qadisiyah Journal of Pure Science

In this paper a CuO thin film, has been deposited using RF sputtering technique, then the thin film has been characterized by XRD, result obtained showed that strongest peak was 48.6503 degree, and FWHM was 0.145 degree, while lattice constant was 4.65 Aº, and the average grain size was 62.78 nm. While AFM analysis showed that the increasing of another four samples temperature led to increase of roughness average from (3.77 to 15.7) nm, root mean square from (4.66 to 18.8) nm and ten points height from (22.6 to 52.6) at 250,300,350 and 400 C respectively. On the other hand …

Gamma-Ray Radiation Effects In Graphene-Based Transistors With H-Bn Nanometer Film Substrates, E. J. Cazalas, Michael R. Hogsed, S. R. Vangala, Michael R. Snure, John W. Mcclory

Faculty Publications

Radiation effects on graphene field effect transistors (GFETs) with hexagonal boron nitride (h-BN) thin film substrates are investigated using 60Co gamma-ray radiation. This study examines the radiation response using many samples with varying h-BN film thicknesses (1.6 and 20 nm thickness) and graphene channel lengths (5 and 10 μm). These samples were exposed to a total ionizing dose of approximately 1 Mrad(Si). I-V measurements were taken at fixed time intervals between irradiations and postirradiation. Dirac point voltage and current are extracted from the I-V measurements, as well as mobility, Dirac voltage hysteresis, and the total number of GFETs that remain …

Erratum: "Imaging The Three‐Dimensional Orientation And Rotational Mobility Of Fluorescent Emitters Using The Tri‐Spot Point Spread Function", Oumeng Zhang, Jin Lu, Tianben Ding, Matthew D. Lew

Electrical & Systems Engineering Publications and Presentations

In the original paper, a calibration error exists in the image-formation model used to analyze experimental images taken by our microscope, causing a bias in the orientation measurements in Figs. 2 and 3. The updated measurements are shown in Fig. E1. We have also updated the supplementary material for the original article to discuss the revised PSF model and estimation algorithms (supplementary material 2) and show the revised model and measurements (Figs. S1, S3, S7, S8, and S10–S13).

Optical Transmission Measurements Of Explosive Boiling And Liftoff Of A Layer Of Micron-Scale Water Droplets From A Krf Laser-Heated Si Substrate, Sergey I. Kudryashov, Susan D. Allen

Susan D. Allen

Water plume velocities were measured in air by optical transmission as a function of laser fluence using a KrF laser for explosive boiling and liftoff of a layer of micron-scale waterdroplets from a laser-heated Si substrate of interest for laser particle removal. The thickness of the superheated water layer near the water/Si interface determines acceleration and removal of the waterdroplets from the Si substrate.

© 2003 American Institute of Physics

Voltage Controlled Magnetism In Cr2o3 Based All-Thin-Film Systems, Junlei Wang, Will Echtenkamp, Ather Mahmood, Christian Binek

Christian Binek Publications

Voltage-control of exchange biases through active selection of distinct domain states of the magnetoelectric and antiferromagnetic pinning layer is demonstrated for Cr2O3/CoPd heterostructures. Progress and obstacles towards an isothermal switching of exchange bias are discussed. An alternative approach avoiding exchange bias for voltage-controlled memory exploits boundary magnetization at the surface of Cr2O3 as voltage-controlled state variable. We demonstrate readout and switching of boundary magnetization in ultra-thin Cr2O3/Pt Hall bar devices where reversal of boundary magnetization is achieved via magnetoelectric annealing with simultaneously applied ±0.5 V and 400 mT electric and magnetic fields.

Space-Charge Limited Conduction In Epitaxial Chromia Films Grown On Elemental And Oxide-Based Metallic Substrates, C.-P. Kwan, Mike Street, Ather Mahmood, Will Echtenkamp, M. Randle, K. He, J. Nathawat, N. Arabchigavkani, B. Barut, S. Yin, R. Dixit, Uttam Singisetti, Christian Binek, J. P. Bird

Christian Binek Publications

We study temperature dependent (200 – 400 K) dielectric current leakage in high-quality, epitaxial chromia films, synthesized on various conductive substrates (Pd, Pt and V2O3). We find that trap-assisted space-charge limited conduction is the dominant source of electrical leakage in the films, and that the density and distribution of charge traps within them is strongly dependent upon the choice of the underlying substrate. Pd-based chromia is found to exhibit leakage consistent with the presence of deep, discrete traps, a characteristic that is related to the known properties of twinning defects in the material. The Pt- and V2O3-based films, in contrast, …

Studying The Interface Between Croconic Acid Thin Films And Substrates Using A Slow Positron Beam, Dean Peterson, Jiandang Liu, Jonas Etzweiler, Gabriel Sontoyo, Sara J. Callori, Kimberley R. Cousins, Timothy Usher, Renwu Zhang

Physics Faculty Publications

Croconic acid (CA) is the first organic ferroelectric with a spontaneous polarity in bulk samples comparable to its inorganic counterparts. As a natural extension of study, ultrathin CA films (∼nm scale) were investigated to reveal ferroelectric effects in films on different substrates for their fundamental and industrial significance. However, the void defect at the interface between the film and substrate is presumed to interfere with surface effects. In this work, a non-invasive technique, a slow positron beam, coupled with Doppler broadening energy spectroscopy (DBES), is applied to study the void defects within the interfacial layer between CA films and Si …

Imaging The Three-Dimensional Orientation And Rotational Mobility Of Fluorescent Emitters Using The Tri-Spot Point Spread Function, Oumeng Zhang, Jin Lu, Tianben Ding, Matthew D. Lew

Electrical & Systems Engineering Publications and Presentations

Fluorescence photons emitted by single molecules contain rich information regarding their rotational motions, but adapting single-molecule localization microscopy (SMLM) to measure their orientations and rotational mobilities with high precision remains a challenge. Inspired by dipole radiation patterns, we design and implement a Tri-spot point spread function (PSF) that simultaneously measures the three-dimensional orientation and the rotational mobility of dipole-like emitters across a large field of view. We show that the orientation measurements done using the Tri-spot PSF are sufficiently accurate to correct the anisotropy-based localization bias, from 30 nm to 7 nm, in SMLM. We further characterize the emission anisotropy …

Characterization And Analysis Of Ultrathin Cigs Films And Solar Cells Deposited By 3-Stage Process, Grace Rajan, Krishna Aryal, Shankar Karki, Puruswottam Aryal, Robert W. Collins, Sylvain Marsillac

Electrical & Computer Engineering Faculty Publications

In view of the large-scale utilization of Cu(In,Ga)Se₂ (CIGS) solar cells for photovoltaic application, it is of interest not only to enhance the conversion efficiency but also to reduce the thickness of the CIGS absorber layer in order to reduce the cost and improve the solar cell manufacturing throughput. In situ and real-time spectroscopic ellipsometry (RTSE) has been used conjointly with ex situ characterizations to understand the properties of ultrathin CIGS films. This enables monitoring the growth process, analyzing the optical properties of the CIGS films during deposition, and extracting composition, film thickness, grain size, and surface roughness which …

Dielectric Properties Of Thin Cr2o3 Films Grown On Elemental And Oxide Metallic Substrates, Ather Mahmood, Mike Street, Will Echtenkamp, Chun Pui Kwan, Jonathan P. Bird, Christian Binek

Christian Binek Publications

In an attempt to optimize leakage characteristics of α-Cr₂O₃ thin films, its dielectric properties were investigated at local and macroscopic scale. The films were grown on Pd(111), Pt(111), and V₂O₃ (0001), supported on Al₂O₃ substrate. The local conductivity was measured by conductive atomic force microscopy mapping of Cr₂O₃ surfaces, which revealed the nature of defects that formed conducting paths with the bottom Pd or Pt layer. A strong correlation was found between these electrical defects and the grain boundaries revealed in the corresponding topographic scans. In comparison, …

Electronic And Optical Properties Of La-Doped Sr3Ir2O7 Epitaxial Thin Films, Maryam Souri, Jsaminka Terzic, J. M. Johnson, John G. Connell, John H. Gruenewald, J. Thompson, Joseph W. Brill, J. Hwang, Gang Cao, Sung S. Ambrose Seo

Physics and Astronomy Faculty Publications

We have investigated structural, transport, and optical properties of tensile strained (Sr_1−xLa_x)₃Ir₂O₇ (x = 0, 0.025, 0.05) epitaxial thin films. While high-T_c superconductivity is predicted theoretically in the system, we have observed that all of the samples remain insulating with finite optical gap energies and Mott variable-range hopping characteristics in transport. Cross-sectional scanning transmission electron microscopy indicates that structural defects such as stacking faults appear in this system. The insulating behavior of the La-doped Sr₃Ir₂O₇ thin films is presumably due to disorder-induced …

Heat, Charge And Spin Transport Of Thin Film Nanostructures, Devin John Wesenberg

Electronic Theses and Dissertations

Understanding of fundamental physics of transport properties in thin film nanostructures is crucial for application in spintronic, spin caloritronics and thermoelectric applications. Much of the difficulty in the understanding stems from the measurement itself. In this dissertation I present our thermal isolation platform that is primarily used for detection of thermally induced effects in a wide variety of materials. We can accurately and precisely produce in-plane thermal gradients in these membranes, allowing for thin film measurements on 2-D structures. First, we look at thermoelectric enhancements of doped semiconducting single-walled carbon nanotube thin films. We use the Wiedemann-Franz law to calculate …

Numerical Simulation For A Rising Bubble Interacting With A Solid Wall: Impact, Bounce, And Thin Film Dynamics, Changjuan Zhang, Jie Li, Li-Shi Luo, Tiezheng Qian

Mathematics & Statistics Faculty Publications

Using an arbitrary Lagrangian-Eulerian method on an adaptive moving unstructured mesh, we carry out numerical simulations for a rising bubble interacting with a solid wall. Driven by the buoyancy force, the axisymmetric bubble rises in a viscous liquid toward a horizontal wall, with impact on and possible bounce from the wall. First, our simulation is quantitatively validated through a detailed comparison between numerical results and experimental data. We then investigate the bubble dynamics which exhibits four different behaviors depending on the competition among the inertial, viscous, gravitational, and capillary forces. A phase diagram for bubble dynamics has been produced using …

Effects Of Interface Scattering And Carrier Localization On Conductance Of Cu-Based Superlattices, Jiyoon Jessica Kim

Legacy Theses & Dissertations (2009 - 2024)

Ultra-thin films and multilayer structures are widely used in modern technologies such as semiconductor logic and memory devices. As film thickness decreases to a few nanometers or smaller, classical transport theories are no longer valid. In this study, we investigate transport properties of superlattices with layer thickness reduced to ~1 nm. The superlattices are made of alternating layers of Cu and a transition metal (Ru, Mo, and Co). The layers are deposited by physical vapor deposition and resistance changes during superlattice growth are measured. The observed resistance evolution reveals the effects of carrier scattering and localization at the interfaces.

Carrier Scattering And Localization In Nm-Thick Al/Ru, Al/Co And Al/Mo Superlattices, Yanli Zhang

Legacy Theses & Dissertations (2009 - 2024)

Thin films and superlattices are widely used in modern technologies. Certain metal superlattices with layer thickness between 1 to 10 nm have interesting magneto transport properties and unique applications in spintronics and data storage. We have studied electrical conductance of Al/Ru, Al/Co, and Al/Mo superlattices with layer thickness between 1 to 2 nm. By monitoring the resistance change during the growth of the superlattice, we are able to observe directly the effects of carrier localization and scattering when a highly disordered interface is being deposited.

Magnetic Domain Morphology In [Co(4a)/Pt(7a] Thin Film, Jeremy Metzner

Student Works

A collection of results for multi-layered thin films and their magnetic domains.