Engineering Commons^™

Development Of A Multivariate Qsar Model To Predict Desorption Of Halogenated Aliphatic Hydrocarbons From Activated Sludge Solids, Sudhi Ranjan Mukherjee

Dissertations

Data collected from different wastewater treatment processes have provided statistically significant evidence that many toxic organic contaminants on EPA's list of priority pollutants concentrate several orders of magnitude greater than influent concentrations in industrial and municipal wastewater sludges. Because of the reversibility of sorption processes, it is possible for sorbed organic compounds to desorb at a later time, hence making disposal of these sludges a potential problem. Although a number of models have been developed to predict sorption parameters, they have all been based on empirically derived descriptors whose validity is seriously compromised by the variation in available data for …

A Full Wave Method For Rough Surface Scattering Using Fictitious Current Distributions, Anthony A. Triolo

Dissertations

Rough surface scattering is a current topic of interest in many diverse fields. But, despite its importance, the two most widely used solution methods, the Kirchhoff and first order perturbation methods, are valid only for a restricted range of surface types. There is a large range of surface statistics for which neither of these theories is valid. There are purely numerical solutions to the problem, i.e., the integral equation technique and FDTD method, but these methods require a prohibitively large amount of computer time and storage space for use in practical applications. A full wave method has been introduced by …

Reduction Of Inertia-Induced Forces In A General Spatial Mechanism, Sahidur Rahman

Dissertations

A computer-aided design procedure has been developed for minimizing the adverse effects of the inertia-induced forces by optimum mass redistribution amongst the links of high speed general spatial linkages. The evaluation of an optimality criterion for the mass redistribution of the mechanism will be carried out with the aid of a quadratic programming technique. This has been found to be successful in minimizing inertia induced forces and torques. The validity of the optimization procedure will be demonstrated by application to one kind of spatial linkage.

No literature has been found on the balancing of a general spatial mechanism, since its …

Discrete Element Modeling Of Dry Granular Material Using A Massively Parallel Supercomputer, David W. Washington

Dissertations

It is the state-of -the-art within Geotechnical Engineering to model soils as systems of particles rather than using the traditional continuum approach. Simulating these systems of particles for geotechnical boundary value problems results in systems which are of necessity large, motivating the application of massively parallel supercomputers. This thesis pursues such an approach.

The following work describes numerical experiments using a Discrete Element Method (DEM) paradigm for soils (Trubal) together with massively parallel computers with Single Instruction Multiple Data (SIMD) architecture. The discrete element method describes the behavior of granular assemblies using the classical mechanics of discrete bodies. The computational …

A Digital Signal Processor Based Optical Position Sensor And Its Application To Flexible Beam Control, Thomas J. Spirock

Theses

A Digital Signal Processor (DSP) based optical position sensor was developed. The sensor system consists of the following components: 1) analog electronics, 2) the DSP based synchronous demodulation software, 3) PC based interface software which samples and saves the data, and 4) PC based control codes for a flexible beam. experiment.

The ability of the system to determine the distance from the optical sensor to the power modulated light source was assessed by the following tests: 1) a stationary drift test to evaluate the system's noise, 2) a short-range test to determine the resolution of the optical sensor over a …

Plasma Enhanced Chemical Vapor Deposition Of Stress Free Tungsten Films, David Perese

Theses

This study focuses on PECVD to make tungsten film for X-ray absorber for use in X-ray lithography applications. The previous LPCVD study was used for comparison of film properties. A cold wall, single wafer, Spectrum 211 CVD reactor was used for the deposition of tungsten from H2 and WF6. The growth kinetics were determined as a function of temperature, pressure and flow rate ratio. The deposition rate was found to follow an Arrehnius behavior between 300-500°C with an activation energy of 55.7 kJ/mol. The growth rate increased linearly with total pressure and H2 partial pressure. In the H2/WF6 ratio studies …

Advanced Characterization And Leaching Behavior Of Hexavalent And Trivalent Chromium From Waste Material, Erik Moerman

Theses

In this thesis we employed advanced characterization techniques such as XRF, XRD, XPS, SEM, and EDS to provide detailed information about the chromium waste _ specifically chromium valence states (Cr(VI) and Cr(III)), and their chemical association with other phases in the waste matrix.

The removal of Cr(VI) was accomplished by leaching with aqueous solutions containing inorganic anions such as Cl^-, SO₄^2-, PO₄^3- and others. Cr(VI) can be released from the waste by a combination of desorption and ion exchange processes. The efficiency and kinetics of displacing CrO₄^2- from the waste by …

The Study Of Sige-Channel Heterojunction Mos Device, Yunchen Qiu

Theses

The advances in the growth of pseudomorphic silicon-germanium epitaxial layer combined with the strong need for high-speed CMOS VLSI circuit have led to increased interest in silicon-based heterojunction MOSFET's transistors. The high-performance heterostructure SiGe MOSFET exhibits higher channel mobility than its bulk Si counterpart. The most critical and challenging process for fabricating a SiGe MOSFET device is that for making a gate oxide with sufficient quality for useful conductivity modulation. PECVD methods was employed to deposit the gate oxide and C-V method was used to investigate the electrical characteristics of the film. For PECVD gate oxide, a film refractive index …

Development Of A Fiber Optic Polarimetric Sensor For Concrete, Insang Lee

Theses

Development of a fiber optic sensor for embedment in cementitious composites and measurement of displacements associated with the opening of microcracks is described. The sensor can be employed as a transducer for measurement of crack tip opening displacements during fracture tests. A polarization maintaining fiber is used as the sensing element, and transduction mechanism is similar to those of other polarimetric type based sensors. However, the deformation resolving power of the sensor is increased by way of increasing the effective length of the optical fiber. This is done by winding the optical fiber into a coil. A direct relationship between …

Remote Measurement Calibration In Power System, Xiaofeng Li

Theses

Power system reliability and economy of operation require accurate measurements of current, voltage, real and reactive powers. These measurements are transmitted to a control center of a power system for monitoring, display, and use in power system real-time analysis. The number of measurements is in thousands. Routinely field technicians must calibrate transducers and/or determine other sources of metering errors. Due to the large number of measurements and the time required to check each individual measurement, field calibration procedures are impractical, expensive, and not timely.

There has been a need for a more efficient approach to measurement calibration and identification of …

Removal Of Vocs From Waste Gas Streams By Cyclic Membrane Separation Techniques, Gordana Obuskovic

Theses

In this study, new separation techniques called Flow Swing Membrane Absorption Permeation (FSMABP) and Flow Swing Membrane Permeation (FSMP) were used for the removal of the volatile organic compounds (VOCs). In both cases, processes are cyclic in terms of feed flow while desorption of the VOCs is constantly taking place. The transport mechanism in the FSMABP process is selective permeation followed by absorption of the VOCs into the stagnant nonvolatile absorbent liquid on the shell side of the membrane module and then desorption through a similar polymeric membrane. In the FSMP process, VOCs selectively permeate through the membrane into the …

Granular Dynamics Study Of Sieving, Heng Yung

Theses

The objective of this thesis is to study the behaviors of granular particles under sieving. A three-dimensional dynamic simulation code was transferred and modified for this purpose, The major concern is the mass flow rate of the particles. Lots of case studies were run. The influences of the friction coefficient, the sieve aperture, and the energy of vibration are studied.

Measurement Of The Electroencephalogram (Eeg) Coherence, Atmospheric Noise, And Schumann Resonances In Group Meditation, Douglas A. Newandee

Theses

Electrical activity in the human body was investigated using EEG and ECG measurements while subjects remained with eyes open, eyes closed and in a meditation state. During these measurements, additional antennas were attached to the equipment to record atmospheric noise and signal activity simultaneously. The obtained data was analyzed and various observations were made. Processed data based on antenna signals clearly showed the presence of man-made signals, having narrow spectral widths that could be treated as atmospheric noise in the frequency range up to 50 Hz. In addition, signals clustered around 7.8, 14.1, 20.3, 26.4, and 32.5 Hz were observed …

Comparison Of Different Signal Processing Algorithms To Extract The Respiration Waveform From The Ecg, David J. Caggiano

Theses

Power spectral analysis of heart rate variability is a powerful tool to measure the activity of the parasympathetic division of the autonomic nervous system noninvasively. To determine the parasympathetic activity, the frequency of respiration must be known. However, during ambulatory studies, the frequency of respiration is not acquired. To alleviate this problem, methods have been proposed in the past to derive the respiration from the ECG. Unfortunately, these previous methods are unreliable if the subject's breathing rate is uncontrolled. In this study, four methods to derive the respiration waveform from the electrocardiogram (ECG) were developed. Two leads of ECG and …

A Mathematical Model Of Cardiovascular System With Feedback Control, Jiayu Gu

Theses

A mathematical model of human cardiovascular system is presented in this study. The closed-loop model is composed of twenty compartments which includes the left and right ventricles, and the systemic and pulmonary circulations. Two physiologic feedback control mechanisms, autoregulation of blood flow and baroreceptor reflex regulation of arterial pressure, are incorporated in the model. Autoregulation acts by changing local resistance to blood flow through metabolic and myogenic mechanisms, thereby insuring a match between oxygen supply and demand for any tissue or organ. Baroreceptors act through neural pathways to alter heart rate, contractility and peripheral resistance in order to return sudden …

Relay Ladder Logic And Petri Nets For Discrete Event Control Design : A Comparative Study, Edward Twiss

Theses

In the 1960's and earlier discrete event systems (DES) were controlled by hardwired electromechanical relay systems. In 1969 an electronic programmable logic controller (PLC) was introduced. PLC's have been programmed utilizing relay ladder logic (RLL). RLL is a graphical programming language with software "devices" used to emulate electromechanical devices. RLL programs, however, often become large and difficult to understand because its graphical representation of physical switching devices obscures the discrete event dynamics inherent in the process to be controlled. Petri nets are a methodology for modeling discrete event systems (DES). Using a Petri net based controller, a control strategy could …

Validation Of A Mathematical Model Of The Human Walking Cycle Using Parameter Identification Methods, Robert Mccann

Theses

A mathematical model of the swing phase, toe-off and heel strike is presented in this paper and is mathematically represented as a two dimensional, simple coupled pendulum system with three degrees of freedom. Lagange equations of motion are used to solve this highly idealized system. The model consists of three segments which represent the stance leg, thigh and shank. During the swing phase it is assumed that the only external forces acting on the system are gravity and viscous dissipative terms proportional to joint angular velocities. It is assumed that muscle forces act only to establish the initial limb segment …

Dynamic Mechanical Analysis Of Particulate Dental Composites, Minu Parekh

Theses

Typically, dental composites are used in different configurations and situations. When a cavity forms at the occlusal surface of a posterior tooth, a class I and class II filling is used, depending on the extent and nature of the cavity formed. These fillings have to be designed to resist mechanical abrasion and occlusal stress during chewing, bruxing and other tooth functions. Class IV fillings are also designed to resist biting stress. In these applications composites with high filler loading with filler particles of size >0.6μm are used. These composites are typically known as minifill or midifill composites. When more than …

Mass Transfer Of Pryene Between A Solid Phase And Oil/Water Suspensions, Sachin Ashok Purekar

Theses

This study dealt with understanding the partitioning of pyrene between water and mineral oil, and the mass transfer of pyrene from solid particles to oil/water suspensions.

It was found that when pyrene is dissolved in mineral oil, the amount transferred to water is negligible even after 10 days of phase contact.

Glass beads and sand were used as model solid phases to simulate soil and PAH (pyrene)-contaminated industrial sludges.

The transfer of pyrene from glass beads to mineral oil when no water phase is present was quantified. Mass transfer coefficients, and their dependence on the rate of environment shaking were …

Separation Of Polycyclic Aromatic Hydrocarbons By Using Micellar Electrokinetic Chromatography, Patricia Simmons

Theses

In this work, the use of micellar electrokinetic chromatography (MEKC) for the separation of five polycyclic aromatic hydrocarbon (PAH) compounds is investigated. All of the compounds studied are listed by the United States Environmental Protection Agency as priority pollutants.

In micellar electrokinetic chromatography, solutes partition between the aqueous phase and the micellar phase. This partition is based on the hydrophobicity of each compound. In some cases, organic modifiers are added to the electrophoretic solution to enhance the separation efficiency. The organic modifier used in this study is y-cyclodextrin (y-CD), and sodium dodecyl sulfate (SDS) is used as the micellar phase. …

A New Concept In Artificial Ligament And Tendons Modeling : Finite Element Analysis, Miroslaw Sokol

Theses

Reconstruction of the Anterior Cruciate Ligament (ACL) has been a major focus in sports medicine for over twenty years. Severe or unrepairable damage of the ACL due to sport injury is a major problem faced by orthopedic surgeons and engineers. To successfully replace or reconstruct an injured ACL, the mechanical properties as well as the dimensional limitation of the material used must be similar to the biological ligaments. Although excessive literature describes experimental investigation on the mechanical property and clinical application of the ligament material, there is no analytical study that describes strains, stresses, and endurance in the bone/ligament/bone complex. …

Simple Fast Vector Quantization Of The Line Spectral Frequencies, Jin Zhou

Theses

Speech coding has been of interest to communication specialists for years. A number of technologies for describing and transmitting the speech spectral envelope have been studied. Among them, the Vector Quantization (VQ) of Line Spectral Frequencies (LSF) is receiving more attention because of its good rate-distortion performance. Typically, about 30 bits are assigned to code 10-dimensional LSF vectors with a resulting spectral distortion of less than ldB. However, 30-bit full-search VQ is totally impractical in terms of both computational complexity and memory space. Various standard suboptimal, low-complexity VQ techniques have been used for coding the LSF's in the literature. The …

Measured Impacts Of Air Conditioner Condenser Shading, Florida Solar Energy Center, Danny Parker

FSEC Energy Research Center®

A study has been conducted by the Florida Solar Energy Center (FSEC) to examine if space cooling energy savings can be achieved from shading of residential air conditioning (AC) condenser units. The investigation consisted of before-and-after experiments conducted on three homes over a two year period. A recent EPA study recommends shading of exterior AC condensers, using landscaping or other means, as a method to reduce space cooling energy use (Akbari et al., 1992).

Status Of The Research And Development For Fuel Cell Technology Abroad, Naichao Li, Baolian Yi

Journal of Electrochemistry

Status of the research and development for fuel cell technology abroad was overviewed, and at the aim of accelerating the research and development for fuel cell technology in China, the corresponding stategy for our country was recommended.

In Situ Studies Of Copper Electrodepostion On Hopg By Using Ecstm, Zhaoxiong Xie, Bingwei Mao, Xiangdong Zhuo, Jiqian Mu, Zhaowu Tian

Journal of Electrochemistry

In this paper, copper electrodepostion on HOPG had been in situ studied by using a homebuilt electrochemical scanning tunneling microscopy (ECSTM). Three dimensional nucleation and subsequent growth of copper crystals were found as the initial stage of copper deposition on HOPG. In the case of lower overpotential or lower concentration of Cu²⁺ , the bulk deposited copper layer tended to form smooth terraces, and grow at the edge of steps. The terraces were stable to some extent, which made it possible to be observed with atomic resolution. At a higher overpotential, the crystal size of copper were somehow smaller. …

United States Patent: System And Method For Compensating Polarization-Dependent Sensitivity Of Dispersive Optics In A Rotating Analyzer Ellipsometer System, Steven E. Green, Shakil A. Pittal, Blaine D. Johs, John A. Woollam, David W. Doerr, Reed A. Christenson

Department of Electrical and Computer Engineering: Faculty Publications

An ellipsometer system which includes a pivotal dispersive optics positioned to receive polychromatic light from an analyzer thereof, without further focusing after reflection from a substrate system, is presented. In addition, a rotating compensator, positioned between the analyzer and the dispersive optics, which serves to reduce detector element polarization dependent sensitivity to light entering thereto after it interacts with the dispersive optics, is disclosed. The method of the present invention can include application of mathematical correction factors to, for instance, substrate system characterizing PSI and DELTA values, or Fourier ALPHA and BETA coefficients.

Problems On The Study Of Anodic Films On Pb In Sulfuric Acid Solution (Ⅱ), Houtian Liu, Qunzhou Wang, Yongqin Wan, Weifang Zhou

Journal of Electrochemistry

The conditions for the growth of the different phases in the anodic Pb(Ⅱ) film on Pb in sulfuric acid solution were discussed.

A Study Of The Electroplated Fe-Cr-Ni Alloy Microstructure, Donglin Li, Jianping Liu, Fangzhou Guo, Jianrong Hua

Journal of Electrochemistry

The microstructure of the electroplated Fe-Cr-Ni alloys from the mixed carboxylic acid solution containing Cr(Ⅲ) and additives were determined with XRD and SEM. Experimental results showed that, under the experimental condition, the phase component, structure of Cu base electroplated Fe-Cr-Ni alloys had a critical thickness, which was 11 μm and a critical Ni content, which was 32%. Organic additives, formic acid or polyethylene Glycol, mainly affected the surface, cross section morphology of the electroplated Fe-Cr-Ni alloys. Adding Mo to the electroplated Fe-Cr-Ni alloys led to remarkable corrosion resistance in concentrated HCl.

The Applications Of Poap Ni2+ Films Modified Electrode As Sensor For Alcohol, Bingzeng Hua, Wenyun Hu, Yanzhen Chen

Journal of Electrochemistry

POAP Ni²⁺ films modified electrode can electrocatalyzes significantly the oxidation of alcohol. The modified electrode can be used as the electrochemical sensor for the detection of alcohol. But the oxidation of alcohol is effected by the thickness of films、the concentration of nickel ion in films, pH of electrolyte, as well as temperative. All of those conditions have been studied in order to achieve stable response current during the oxidation of alcohol, and the relation between concentration and current has been made. At last the major characteristic parameters, such as the low limitation of concentration, the response time, the ability …

Electrocatalytic Oxidation Of Some C2 Compounds (Alcohols, Aldehydes, And Carboxylic Acids) On A Pt/SbAd Electrod, Hong Li, Lincai Jiang, Xiong Jiang

Journal of Electrochemistry

The electrocatalytic oxidation behavior of some C₂ compounds(alcohols, aldehydes and carboxylic acids) on a Pt/Sb_ad electrode prepared in-situ or ex-situ UPD was investigated using pontential sweep and rotating disc electrode methods. It is confirmed that Pt/Sb_ad electrode show the most electrocatalytical active to the oxidation of aldehyde functional group and only a little activity to the oxidation of hydroxyl group, but no activity for the oxidation of carboxyl group.

The experimental results show that the activity of the Pt/Sb_ad electrode prepared by ex-situ UPD is higher than that prepared by in-situ UPD.

The limitations of the …