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2014

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Articles 1 - 30 of 7238

Full-Text Articles in Engineering

A Kinect-Based System For Automatic Recording Of Some Pigeon Behaviors, Damian Lyons, James Macdonall, Kelly Cunningham Dec 2014

A Kinect-Based System For Automatic Recording Of Some Pigeon Behaviors, Damian Lyons, James Macdonall, Kelly Cunningham

Faculty Publications

Contact switches and touch screens are the state of the art for recording pigeons’ pecking behavior. Recording other behavior, however, requires a different sensor for each behavior, and some behaviors cannot easily be recorded. We present a flexible and inexpensive image-based approach to detecting and counting pigeon behaviors that is based on the Kinect sensor from Microsoft. Although the system is as easy to set up and use as the standard approaches, it is more flexible because it can record behaviors in addition to key pecking. In this article, we show how both the fast, fine motion of key pecking …

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Design And Development Of The Portable Build Platform And Heated Travel Envelope For The Multi3d Manufacturing System, Steven Daniel Ambriz Dec 2014

Design And Development Of The Portable Build Platform And Heated Travel Envelope For The Multi3d Manufacturing System, Steven Daniel Ambriz

Open Access Theses & Dissertations

The final product functionality of parts produced by Additive Manufacturing (AM) can, in part, be improved by the inclusion of multi-material capabilities. The “Multi3D system” that is under development at The University of Texas at El Paso uses material extrusion printing (or fused deposition modeling), solid conductor wire embedding, direct-write, component placement, and micromaching to enable multi-material fabrication. The Multi3D was designed to transport a workpiece between manufacturing stations via a six-axis robot, portable build platform (PBP), and a controlled temperature environment or chamber that travels to each manufacturing station. The heated travel envelope (HTE) was included to mitigate thermal …

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Dynamics Of Suspended Sediment Flux On The Rivers Bandon And Owenabue, Ireland, S. T. Harrington, Joseph R. Harrington Dec 2014

Dynamics Of Suspended Sediment Flux On The Rivers Bandon And Owenabue, Ireland, S. T. Harrington, Joseph R. Harrington

Publications

Monitoring, analysis and modelling of suspended sediment transport in riverine systems has received much attention in recent decades. Quantitive analysis techniques have been applied to allow river basin managers to assess suspended sediment transport and its importance in transporting a range of pollutants including excess metals and nutrients, which negatively impact on aquatic systems. In this paper, an analysis of the suspended sediment fl ux (SSF) dynamics is presented for the small and medium sized catchments of the River Owenabue and the River Bandon, respectively. The results contribute to the fi lling of a research gap in an Irish context …

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Congenital Epidermoid Cyst Results In Muscle Fusion Defect In The Upper Lip, Fatih Dogan, Ibrahim Hakan Bucak Dec 2014

Congenital Epidermoid Cyst Results In Muscle Fusion Defect In The Upper Lip, Fatih Dogan, Ibrahim Hakan Bucak

Materials Science and Engineering Faculty Research & Creative Works

Epidermoid cysts are rarely detected malformations in the oral cavity. Their development sites are the sublingual, submaxillary, and submandibular spaces. In this paper, we report a three-month-old infant who was admitted to our hospital due upper lip swelling. Magnetic resonance imaging showed that she had a two-centimeter cystic lesion and fusion defects of orbicularis oris muscle. The cyst was surgically removed, and histopathological diagnosis was “epidermoid cyst.” In recent literature, we could not find reports related to orbicularis oris muscle fusion defects because of epidermoid cyst.

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Seeing Red: Characterizing Historic Bricks At Sylvester Manor, Long Island, Ny 1652-1735, Martin John Schmidheiny Dec 2014

Seeing Red: Characterizing Historic Bricks At Sylvester Manor, Long Island, Ny 1652-1735, Martin John Schmidheiny

Graduate Masters Theses

The goal of this project is to develop a basic material characterization of the bricks excavated at the site of Sylvester Manor on Shelter Island, New York. In the early Manor period of 1650-1690, this early Northern provisioning plantation supplied Barbadian sugar operations and pursued mercantile interests independent of state control. Accounting for the range of production defects and material characteristics of the bricks suggests on-site or local manufacture as a regional ceramic industry developed. Qualitative visual analysis and petrographic thin-sections were used to characterize the internal composition, variation and production evidence in the bricks. Interpreting the results of this …

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Loss Modeling Of A Permanent Magnet Dc Motor Drive Water Pumping System, Nelson Lujara Dec 2014

Loss Modeling Of A Permanent Magnet Dc Motor Drive Water Pumping System, Nelson Lujara

Tanzania Journal of Engineering and Technology (TJET)

The paper presents an analytical approach to the determination of losses in each of the sub-systems of the Photovoltaic (PV) Permanent Magnet DC Motor (PMDC) drive water pumping system with and without maximum power tracking. The losses of the system at varying heads are firstly, determined using parameters from the data sheets and then validated by experimental results. The results are used to establish the head and the flow rate optimal operating point of the system.

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Assessment Of Quality Stability Of Composite Flours Produced By Dar Es Salaam Smes, Leonard Rweyemamu Dec 2014

Assessment Of Quality Stability Of Composite Flours Produced By Dar Es Salaam Smes, Leonard Rweyemamu

Tanzania Journal of Engineering and Technology (TJET)

A study was conducted to assess quality stability of cereal flours processed by food processing SMEs in Dar es Salaam. This product is obtained by mixing various cereal grains and is considered as of higher nutritional values in Tanzania. The shelf-life was predicted by determining water activity (aw) and moisture content (MC) levels and plotting the water sorption isotherms (MSI). Ninety per cent of investigated samples (N=78) were found packaged in the materials of various quality conditions. It was found that the packaging materials mostly used is plastic films (63%), paper packets/bags (26%), hard papers (3%), plastic jars (1%) and …

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Application Of Trip Generation Models For Urban Transport Planning In A Data Scarce Developing Country City: The Case Of Dar Es Salaam, Hannibal Bwire Dec 2014

Application Of Trip Generation Models For Urban Transport Planning In A Data Scarce Developing Country City: The Case Of Dar Es Salaam, Hannibal Bwire

Tanzania Journal of Engineering and Technology (TJET)

With the increase in travel demand and traffic management problems in many developing countries cities, travel demand forecasting models are being employed increasingly to make informed decisions about the operational improvements to the existing transportation system and the design and performance of future transportation systems. The main advantage of using travel demand forecasting models for such purposes is that they are capable of capturing the interactive effects of different components of the system under study. However, for some time now there have been concerns about the application of transport planning models in developing countries. The concerns have been mainly in …

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A Critical Analysis Of Integrated Coastal And Ocean Management In Bangladesh With Lessons From Global Practices, Syed Mamtajul Islam Dec 2014

A Critical Analysis Of Integrated Coastal And Ocean Management In Bangladesh With Lessons From Global Practices, Syed Mamtajul Islam

World Maritime University Dissertations

The coast of Bangladesh is highly dynamic, unique and diverse, the south-western part of which hosts the world’s largest single mangrove forest; the south-central part receives the world’s second largest river system (Ganges-Brahmaputra-Meghna system), contributing to form the world’s largest delta in Bangladesh; and the south-eastern part provides room for major industrial and economic activities such as ports and shipping, ship recycling (2nd in global ranking), ship building, fisheries and tourism (Beaches in Cox’s Bazar – the world’s longest). The earlier land-side coastal management initiatives, which totally ignore ocean issues, have failed to bring a remarkable outcome mainly due to …

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Vessel Traffic Service As A Maritime Security Tool : Vessel Traffic Management Information Systems (Vtmis) In Ghana, Joseph Akwasi Kuma Dec 2014

Vessel Traffic Service As A Maritime Security Tool : Vessel Traffic Management Information Systems (Vtmis) In Ghana, Joseph Akwasi Kuma

World Maritime University Dissertations

The dissertation is an assessment of the role of the VTMIS in enhancing efforts to bring down maritime security in the threats in the Gulf of Guinea in West Africa focusing on Ghana. According to the International Maritime Organisation (IMO), Vessel Traffic Service (VTS) is implemented by a Competent Authority to improve the safety and efficiency of vessel traffic and to protect the environment. Technological development today has led to significant improvements in vessel traffic service. Vessel Traffic Management Information Service is the integration of Management information systems to improve the quality of vessel traffic services. Vessel traffic services essentially …

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A Study On The Effects Of E-Navigation On Reducing Vessel Accidents, Sun-Bae Hong Dec 2014

A Study On The Effects Of E-Navigation On Reducing Vessel Accidents, Sun-Bae Hong

World Maritime University Dissertations

The dissertation aims to evaluate how and to what extent e-navigation contributes to reducing accidents for SOLAS ships as well as non-SOLAS ships, hoping that the results are referred to IMO Member States when they are implementing enavigation along with the maritime sectors such as shipping companies, crews on board ships and manufactures developing e-navigation related systems. The study focuses on the potential effects of e-navigation based on tool kits of the IMO e-navigation for SOLAS ships and services of SMART-navigation, which is the Korean approach to implementing the e-navigation concept for both SOLAS ships and non-SOLAS ships. The processes …

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Properties Of Boards Made From Rice Husk And Portland Cement As Binders And Reinforced With Sisal Fibres, Alex Mrema Dec 2014

Properties Of Boards Made From Rice Husk And Portland Cement As Binders And Reinforced With Sisal Fibres, Alex Mrema

Tanzania Journal of Engineering and Technology (TJET)

A research study demonstrated that rice husks can be used to manufacture boards which can be used in low cost housing if bound by Portland limestone cement (CEM II/A-L/ 32.5R) and reinforced with sisal fibers to cater for their brittle behavior and that such boards can provide a substitute for wood panels. Boards made of rice husks and cement in the ratios of 1/3.3, 1/ 3.6 and 1/4 and with sisal fiber reinforcement contents of 0%, 0.4%, 0.5% and 0.8% were prepared and tested for their physical and mechanical properties. The results were compared with standard requirements for boards made …

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New Challenges For The Archiving Of Digital Writing, Heiko Zimmermann Dec 2014

New Challenges For The Archiving Of Digital Writing, Heiko Zimmermann

CLCWeb: Comparative Literature and Culture

In his article "New Challenges for the Archiving of Digital Writing" Heiko Zimmermann discusses the challenges of the preservation of digital texts. In addition to the problems already at the focus of attention of digital archivists, there are elements in digital literature which need to be taken into consideration when trying to archive them. Zimmermann analyses two works of digital literature, the collaborative writing project A Million Penguins (2006-2007) and Renée Tuner's She… (2008) and shows how the ontology of these texts is bound to elements of performance, to direct social interaction of writers and readers to the uniquely subjective …

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Towards Digital Art In Information Society, Montse Arbelo, Joseba Franco Dec 2014

Towards Digital Art In Information Society, Montse Arbelo, Joseba Franco

CLCWeb: Comparative Literature and Culture

In their article "Towards Digital Art in Information Society" Montse Arbelo and Joseba Franco propose the development of the platform of a Network of Experimental Centers be formed by small groups of people who are qualified and who seek optimal operational effectiveness and who dedicate their resources to the production of digital content and we offer artechmedia <http://www.artechmedia.org> as a base point of departure. Such an international network in a collaborative structure based on national networks would make possible to coordinate existing resources to develop social networks, generate and promote content, engage in forums of discussion and creativity workshops, and …

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Contactless Measurement Of Angular Velocity Using Circularly Polarized Antennas, Vit Sipal, Adam Narbudowicz, Max Ammann Dec 2014

Contactless Measurement Of Angular Velocity Using Circularly Polarized Antennas, Vit Sipal, Adam Narbudowicz, Max Ammann

Articles

An innovative method to measure the angular velocity using circularly polarized antennas is proposed. Due to the properties of circular polarization, the angular velocity is frequency modulated (FM) on a wireless carrier. This enables a low-cost precise continuous measurement of angular velocity using a standard FM demodulator. The hardware can be easily adapted for both high and low angular velocity values. The precise alignment angle between the antennas can be determined if the initial antenna orientation is known. The angular error is shown to be

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Insights From A Global Engineering Outreach Course, Randy S. Lewis Dec 2014

Insights From A Global Engineering Outreach Course, Randy S. Lewis

Faculty Publications

A two-semester multi-disciplinary Global Engineering Outreach (GEO) course was initiated in 2007 to provide an opportunity for junior and senior-level engineering and technology students to design and implement humanitarian-based engineering projects in developing communities. Recently, the course was integrated with a sociology course to enhance the educational opportunities between social scientists and engineers. During the GEO course, students work on small-scale projects that are selected in conjunction with members of the developing communities. Students regularly interact with community members during project development. Following the GEO course, students participate in a two-week implementation trip. Learning outcomes associated with the course are …

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Nanoparticle Dispersions With Ionic Liquid-Based Stabilizers, John Texter Dec 2014

Nanoparticle Dispersions With Ionic Liquid-Based Stabilizers, John Texter

Patents

The disclosure generally relates to a dispersion of nanoparticles in a liquid medium. The liquid medium is suitably water-based and further includes an ionic liquid-based stabilizer in the liquid medium to stabilize the dispersion of nanoparticles therein. The stabilizer can be polymeric or monomeric and generally includes a moiety with at least one quaternary ammonium cation from a corresponding ionic liquid. The dispersion suitably can be formed by shearing or otherwise mixing a mixture/combination of its components. The dispersions can be used to form nanoparticle composite films upon drying or otherwise removing the liquid medium carrier, with the stabilizer providing …

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Conventional Latex/Nanolatex Blends, Frank N. Jones, Ravi G. Joshi, Theodore Provder Dec 2014

Conventional Latex/Nanolatex Blends, Frank N. Jones, Ravi G. Joshi, Theodore Provder

Patents

Nanolatexes comprising functional monomers and methods for making nanolatexes. Compositions comprising between about 3:97 and 90:10 (w/w) nanolatex particles to conventional latex particles. Because of the particle size differences between the conventional and nanolatexes, the nanolatexes may distribute themselves advantageously amongst the conventional latexes during coalescence, resulting in films having unexpected properties. In particular, when the average particle size of the conventional latex is about six times larger than the average particle size of the nanolatex, a composition comprising a ratio of 1 conventional latex particle for every 25 nanolatex particles results in unexpectedly strong (large Young's modulus) and smooth …

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Center Pivot Sprinkler Distribution Uniformity Impacts On The Spatial Variability Of Evapotranspiration, Daniel Howes, Sean Ellenson, Lucas Hoffmann, Franklin Gaudi Dec 2014

Center Pivot Sprinkler Distribution Uniformity Impacts On The Spatial Variability Of Evapotranspiration, Daniel Howes, Sean Ellenson, Lucas Hoffmann, Franklin Gaudi

BioResource and Agricultural Engineering

Understanding variable evapotranspiration (ET) throughout a field can help maximize yield on a per-acre basis, as well as assist with proper irrigation scheduling. The results from this study indicate that irrigation system distribution uniformity (DU) has a significant effect on the uniformity of ET during water-stressed periods. The study site involved intensely managed forage (alfalfa and winter grain hay) irrigated by center pivots being supplied with reclaimed water near Palmdale, California. During spring and early summer 2007 the center pivots were operating under deficit irrigation. In 2010, after the installation of reservoirs, water was applied to meet full evapotranspiration (ETc) …

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Sulfur Vacancies In Photorefractive Sn2P2S6 Crystals, Eric M. Golden, Sergey A. Basun, A. A. Grabar, I. M. Stoika, Nancy C. Giles, D. R. Evans, Larry E. Halliburton Dec 2014

Sulfur Vacancies In Photorefractive Sn2P2S6 Crystals, Eric M. Golden, Sergey A. Basun, A. A. Grabar, I. M. Stoika, Nancy C. Giles, D. R. Evans, Larry E. Halliburton

Faculty Publications

A photoinduced electron paramagnetic resonance (EPR) spectrum in single crystals of Sn2P2S6 (SPS) is assigned to an electron trapped at a sulfur vacancy. These vacancies are unintentionally present in undoped SPS crystals and are expected to play an important role in the photorefractive behavior of the material. Nonparamagnetic sulfur vacancies are formed during the initial growth of the crystal. Subsequent illumination below 100 K with 442 nm laser light easily converts these vacancies to EPR-active defects. The resulting S = 1/2 spectrum shows well-resolved and nearly isotropic hyperfine interactions with two P ions and two Sn ions. Partially resolved interactions …

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Platinum Hollow Nanospheres With Different Sizes: Controllable Synthesis And Electrocatalytic Oxidation Toward Methanol, Xuan Lin, Mei-Qin Cheng, Zhong-Jin Shang, Ting Xiong, Xian-Tu Zhang, Wei Tian, Jian-Yun Lin, Qi-Ling Zhong, Bin Ren Dec 2014

Platinum Hollow Nanospheres With Different Sizes: Controllable Synthesis And Electrocatalytic Oxidation Toward Methanol, Xuan Lin, Mei-Qin Cheng, Zhong-Jin Shang, Ting Xiong, Xian-Tu Zhang, Wei Tian, Jian-Yun Lin, Qi-Ling Zhong, Bin Ren

Journal of Electrochemistry

The selenium (Se) templates and hollow platinum (Pthollow) nanospheres with different sizes were controllably synthesized by adjusting the concentration of sodium dodecyl sulphonate (SDSN) (CSDSN, μmol·L-1) which was used as a surfactant. Accordingly, the Pthollow nanospheres modified glassy carbon (GC) electrode (Pthollow/GC) was prepared. The morphology and composition of Pthollow nanospheres were characterized by scanning electron microscopy (SEM), transmission electron microscope (TEM), energy dispersive X-ray spectroscopy (EDX), high resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and X-ray diffraction (XRD) techniques. The electrocatalytic activities of Pthollow/GC and electrodeposited Pt nanoparticles modified glassy carbon electrode (Ptnano/GC) toward methanol oxidation …

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Comparison In Factors Affecting Electrochemical Properties Of Thermal-Reduced Graphene Oxide For Supercapacitors, Peng Xiao, Da-Hui Wang, Jun-Wei Lang Dec 2014

Comparison In Factors Affecting Electrochemical Properties Of Thermal-Reduced Graphene Oxide For Supercapacitors, Peng Xiao, Da-Hui Wang, Jun-Wei Lang

Journal of Electrochemistry

In this paper, thermal-reduced graphene oxide (T-RGO) materials are synthesized by modified Hummer’s method, followed by thermal reduction under argon atmosphere at different temperatures. Electrochemical investigations show that, for T-RGO electrodes, good electrical conductivity is necessary and the surface functional groups play more significant role than the specific surface area in determining the electrochemical capacitance. The T-RGO obtained at 900 °C (T-RGO900) with a relatively high Brunauer-Emmett-Teller (BET) surface area (314 m2·g-1) and a high electrical conductivity (2421 S·m-1) shows a low specific capacitance of 56 F·g-1. In comparison, the T-RGO obtained …

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Nafion/Thionine/Platinum Nanowires-Modified Electrode For Electrocatalyzing Glucose, Yu-Ping Lin, You-Xiu Lin, Qian Zhou, Dian-Ping Tang Dec 2014

Nafion/Thionine/Platinum Nanowires-Modified Electrode For Electrocatalyzing Glucose, Yu-Ping Lin, You-Xiu Lin, Qian Zhou, Dian-Ping Tang

Journal of Electrochemistry

A new amperometric biosensor based on Nafion, thionine and latinum nanowires was developed for sensitive detection of glucose. Initially, positively charged thionine molecules were immobilized onto the surface of Nafion-modified glassy carbon electrode through the interaction between -SO3- and -NH3+, and glucose oxidase was then assembled on the modified electrode by using platinum nanowires as the cross-linkage. The preparation process was characterized by using cyclic voltammetry. Two enzymatic biosensors modified with and without platinum nanowires were used for the detection of glucose, and the improved analytical properties were obtained with platinum nanowires. Experimental results indicated …

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Synthesis Of Namnpo4 By Spraying Drying-High Temperature Sintering And Its Electrochemical Performance, Xiao-Chen Lin, Xiao-Biao Wu, Xu Hou, Yong Yang Dec 2014

Synthesis Of Namnpo4 By Spraying Drying-High Temperature Sintering And Its Electrochemical Performance, Xiao-Chen Lin, Xiao-Biao Wu, Xu Hou, Yong Yang

Journal of Electrochemistry

As a cathode material for sodium ion batteries, NaMnPO4/C nanocomposite is successfully synthesized by the combination of spraying drying and high temperature sintering methods. The crystal structure of the as-synthesized phosphate material is confirmed as the natrophilite NaMnPO4, which possesses orthorhombic symmetry and Pmnb space group. It is shown that the precursors are hollow spherical particles and the obtained product consists of micro-scaled secondary particles, which are composed of NaMnPO4 nanocrystallites (tens of nanometres) and amorphous carbon networks. The ionic and electronic conductivities of NaMnPO4 are both effectively enhanced with the help of this …

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One-Step Synthesis Of Pani/Nihcf Hybrid Film Using Unipolar Pulse Electrodeposition And Its Electrocatalytic Reduction Performance For H2O2 Detection, Sen-Liang Liao, Xiu-Min Li, Xiao-Gang Hao, Yan-Hong Wang, Chun-Feng Xue, Yong-Hong Wang Dec 2014

One-Step Synthesis Of Pani/Nihcf Hybrid Film Using Unipolar Pulse Electrodeposition And Its Electrocatalytic Reduction Performance For H2O2 Detection, Sen-Liang Liao, Xiu-Min Li, Xiao-Gang Hao, Yan-Hong Wang, Chun-Feng Xue, Yong-Hong Wang

Journal of Electrochemistry

Organic–inorganic hybrid films composed of polyaniline/nickel hexacyanoferrate (PANI/NiHCF) were fabricated on platinum substrates using unipolar pulse one-step electrodeposition. The deposition mechanism of hybrid film was proposed: Due to high potential of unipolar pulse electrodeposition, which avoided the reduction of Fe(CN)63-, the films with high electrocatalytic property and “insoluble” form of NiHCF were achieved. The morphology and composition of PANI/NiHCF hybrid film were characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and Fourier transform infrared spectroscopy (FT-IR). The effect of pulse potential on the electrochemical performance of hybrid film was investigated in detail. Results showed that …

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Density Functional Theory Study On The Structures Of Solvent-Ion In The Electrolyte Of Lithium Ion Battery, Li-Dan Xing, Ru Yang, Xian-Wen Tang, Wen-Na Huang, Qi-Feng Liu, Qi-Peng Yu, Wei-Shan Li Dec 2014

Density Functional Theory Study On The Structures Of Solvent-Ion In The Electrolyte Of Lithium Ion Battery, Li-Dan Xing, Ru Yang, Xian-Wen Tang, Wen-Na Huang, Qi-Feng Liu, Qi-Peng Yu, Wei-Shan Li

Journal of Electrochemistry

In this work, the possible structures of solvent-ion complex, resulting from the electrostatic interaction in the propylene carbonate (PC) base electrolyte of lithium ion battery, have been investigated using the density functional theory. The calculated results show that the structure of solvent-ion complex depends on the solvent number. In the PC base electrolyte, maximum number of PC solvents that coexist in the Li+-solvent sheath is four. Additionally, the salt anion exists in a complex with the positively charged alkyl group of PC rather than in a free state. The calculated results give a good explanation to the reported …

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Electrochemical Applications Of Single-Walled Carbon Nanohorns, Su-Ping Li, Huai-Min Guan, Shu-Yun Zhu, Muhammad Rehan Hassan Shah Gilani, Saima Hanif, Guo-Bao Xu, Yue-Jin Tong Dec 2014

Electrochemical Applications Of Single-Walled Carbon Nanohorns, Su-Ping Li, Huai-Min Guan, Shu-Yun Zhu, Muhammad Rehan Hassan Shah Gilani, Saima Hanif, Guo-Bao Xu, Yue-Jin Tong

Journal of Electrochemistry

Single-wall carbon nanohorns (SWCNHs) have unique properties, such as a large specific surface area, good electrical conductivity and biocompatibility. It has been widely utilized in many fields. In the present review, the progress in electrochemistry study of SWCNHs has been summarized and the future research trends have been proposed.

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Direct Electrochemistry And Glucose Biosensing Of Glucose Oxidase-Gold Nanoparticles Composite Synthesized By Enzyme Method, Fang He, Xiao-Li Qin, Ying-Chun Fu, Chao Chen, Qing-Ji Xie, Shou-Zhuo Yao Dec 2014

Direct Electrochemistry And Glucose Biosensing Of Glucose Oxidase-Gold Nanoparticles Composite Synthesized By Enzyme Method, Fang He, Xiao-Li Qin, Ying-Chun Fu, Chao Chen, Qing-Ji Xie, Shou-Zhuo Yao

Journal of Electrochemistry

Glucose oxidase (GOx)-gold nanoparticles (AuNPs) composite was synthesized by the one-pot enzyme reaction in the mixture solution of NaAuCl4, GOx and glucose, and a Nafion/GOx-AuNPs/glassy carbon electrode was fabricated by the cast-coating method to examine the direct electrochemistry of GOx and the biosensing performance on this electrode. Such a GOx-AuNPs composite showed good direct-electrochemistry activity and bioactivity of GOx, probably because the enzyme-mediated AuNPs are close to the redox active centers of GOx. This enzyme electrode exhibited a linear amperometric response to glucose concentration (0.54 mmol·L-1) at -0.4 V (vs. SCE), and a detection limit of …

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Preparation Of Surface Molecularly Imprinted Magnetic Nanoparticles For Hemoglobin Sensing, Chun-Fang Huang, Gui-Hong Yao, Jian-Ding Qiu Dec 2014

Preparation Of Surface Molecularly Imprinted Magnetic Nanoparticles For Hemoglobin Sensing, Chun-Fang Huang, Gui-Hong Yao, Jian-Ding Qiu

Journal of Electrochemistry

Surface molecularly imprinted magnetic nanoparticles (NPs) were prepared by employing dopamine (DA) as a functional monomer, hemoglobin (Hb) as a template, H2PtCl6 as an oxidant triggered DA polymerization on the surface of the Fe3O4 NPs. The Hb and the formed platinum nanoparticles (PtNPs) were embedded into the polydopamine (PDA). After removal of the Hb, the surface molecularly imprinted magnetic nanoparticles (imprinted Fe3O4/PDA-PtNPs) were formed, and then simply immobilized on the magnetic glassy carbon electrode (imprinted Fe3O4/PDA-PtNPs/MGCE) for Hb sensing. The imprinted Fe3O4/PDA-PtNPs …

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Resolve Mono-Electronic Process In The Voltammetric Behaviors Of Multi-Redox Bis-Coenzyme Q0, Hao Zhou, Yi-Tao Long Dec 2014

Resolve Mono-Electronic Process In The Voltammetric Behaviors Of Multi-Redox Bis-Coenzyme Q0, Hao Zhou, Yi-Tao Long

Journal of Electrochemistry

A widely held concept in electrochemistry is that truly elementary electron-transfer reactions always involve the exchange of one electron, therefore, an overall process involving a change of n electrons must involve n distinct electron-transfer steps. It is highly desirable to resolve multiple-step electron transfer reactions into each electron transfer step. The electrochemical behaviors of coenzyme Q0 and methylene-bridged Bis-coenzyme Q0 were investigated by cyclic voltammetry and square wave voltammetry in nonaqueous dichloromethane containing 0.15 mol·L-1 Bu4NClO4 as the supporting electrolyte. The redox reaction of coenzyme Q0 is well described as two chemically reversible …

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